TWI462367B - 用於高壓陰極之氧化還原梭 - Google Patents
用於高壓陰極之氧化還原梭 Download PDFInfo
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- TWI462367B TWI462367B TW098104332A TW98104332A TWI462367B TW I462367 B TWI462367 B TW I462367B TW 098104332 A TW098104332 A TW 098104332A TW 98104332 A TW98104332 A TW 98104332A TW I462367 B TWI462367 B TW I462367B
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- Prior art keywords
- shuttle
- battery
- electrolyte
- positive electrode
- potential
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- 239000003792 electrolyte Substances 0.000 claims description 56
- 230000003647 oxidation Effects 0.000 claims description 46
- 238000007254 oxidation reaction Methods 0.000 claims description 46
- 125000003545 alkoxy group Chemical group 0.000 claims description 43
- 125000000217 alkyl group Chemical group 0.000 claims description 36
- 229910052744 lithium Inorganic materials 0.000 claims description 36
- 239000000126 substance Substances 0.000 claims description 29
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 27
- 229910001416 lithium ion Inorganic materials 0.000 claims description 25
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims description 23
- 239000011263 electroactive material Substances 0.000 claims description 23
- 125000003118 aryl group Chemical group 0.000 claims description 20
- 150000001875 compounds Chemical class 0.000 claims description 20
- 229910010707 LiFePO 4 Inorganic materials 0.000 claims description 19
- 150000001491 aromatic compounds Chemical group 0.000 claims description 16
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 claims description 13
- 150000003839 salts Chemical class 0.000 claims description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 12
- 125000004432 carbon atom Chemical group C* 0.000 claims description 11
- 229910052799 carbon Inorganic materials 0.000 claims description 10
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 claims description 10
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 claims description 9
- 125000004122 cyclic group Chemical group 0.000 claims description 8
- 229910013870 LiPF 6 Inorganic materials 0.000 claims description 7
- 229910003002 lithium salt Inorganic materials 0.000 claims description 7
- 159000000002 lithium salts Chemical class 0.000 claims description 7
- 229910015643 LiMn 2 O 4 Inorganic materials 0.000 claims description 6
- 229910017052 cobalt Inorganic materials 0.000 claims description 6
- 239000010941 cobalt Substances 0.000 claims description 6
- 229910044991 metal oxide Inorganic materials 0.000 claims description 6
- 229910052759 nickel Inorganic materials 0.000 claims description 6
- 229910000733 Li alloy Inorganic materials 0.000 claims description 5
- 229910012851 LiCoO 2 Inorganic materials 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 5
- 229910002804 graphite Inorganic materials 0.000 claims description 5
- 239000010439 graphite Substances 0.000 claims description 5
- 239000001989 lithium alloy Substances 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 230000002441 reversible effect Effects 0.000 claims description 5
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- 150000004706 metal oxides Chemical class 0.000 claims description 4
- 229910002099 LiNi0.5Mn1.5O4 Inorganic materials 0.000 claims description 3
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 claims description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 3
- VAYTZRYEBVHVLE-UHFFFAOYSA-N 1,3-dioxol-2-one Chemical compound O=C1OC=CO1 VAYTZRYEBVHVLE-UHFFFAOYSA-N 0.000 claims description 2
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- 229910015015 LiAsF 6 Inorganic materials 0.000 claims description 2
- 229910013063 LiBF 4 Inorganic materials 0.000 claims description 2
- 229910013375 LiC Inorganic materials 0.000 claims description 2
- 229910013684 LiClO 4 Inorganic materials 0.000 claims description 2
- 229910013528 LiN(SO2 CF3)2 Inorganic materials 0.000 claims description 2
- 229910013385 LiN(SO2C2F5)2 Inorganic materials 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
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- 239000008151 electrolyte solution Substances 0.000 claims description 2
- 150000003254 radicals Chemical class 0.000 claims description 2
- RBYFNZOIUUXJQD-UHFFFAOYSA-J tetralithium oxalate Chemical compound [Li+].[Li+].[Li+].[Li+].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O RBYFNZOIUUXJQD-UHFFFAOYSA-J 0.000 claims description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- CQDGTJPVBWZJAZ-UHFFFAOYSA-N monoethyl carbonate Chemical compound CCOC(O)=O CQDGTJPVBWZJAZ-UHFFFAOYSA-N 0.000 claims 1
- -1 fluoronaphthalene compound Chemical class 0.000 description 20
- 238000000034 method Methods 0.000 description 14
- 238000002484 cyclic voltammetry Methods 0.000 description 13
- 239000000463 material Substances 0.000 description 13
- 239000007774 positive electrode material Substances 0.000 description 12
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- 239000000203 mixture Substances 0.000 description 11
- WVKLDBVAQACGSR-UHFFFAOYSA-N 1,4-ditert-butyl-2,5-bis(2,2,2-trifluoroethoxy)benzene Chemical compound CC(C)(C)C1=CC(OCC(F)(F)F)=C(C(C)(C)C)C=C1OCC(F)(F)F WVKLDBVAQACGSR-UHFFFAOYSA-N 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
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- JDCMOHAFGDQQJX-UHFFFAOYSA-N 1,2,3,4,5,6,7,8-octafluoronaphthalene Chemical compound FC1=C(F)C(F)=C(F)C2=C(F)C(F)=C(F)C(F)=C21 JDCMOHAFGDQQJX-UHFFFAOYSA-N 0.000 description 6
- PYZDJVJBSLEAEI-UHFFFAOYSA-N 1,4-ditert-butyl-2,5-bis(2,2,3,3-tetrafluoropropoxy)benzene Chemical compound CC(C)(C)C1=CC(OCC(F)(F)C(F)F)=C(C(C)(C)C)C=C1OCC(F)(F)C(F)F PYZDJVJBSLEAEI-UHFFFAOYSA-N 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
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- 229910052731 fluorine Inorganic materials 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
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- 230000000694 effects Effects 0.000 description 5
- 239000011737 fluorine Substances 0.000 description 5
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- 238000000769 gas chromatography-flame ionisation detection Methods 0.000 description 5
- 125000001424 substituent group Chemical group 0.000 description 5
- OSTYUBBZEOIQGG-UHFFFAOYSA-N 1,2,3,4,5,6,8-heptafluoro-7-methoxynaphthalene Chemical compound FC1=C(F)C(F)=C(F)C2=C(F)C(OC)=C(F)C(F)=C21 OSTYUBBZEOIQGG-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 4
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 4
- 101150047356 dec-1 gene Proteins 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 230000002427 irreversible effect Effects 0.000 description 4
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 4
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 4
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- SBLRHMKNNHXPHG-UHFFFAOYSA-N 4-fluoro-1,3-dioxolan-2-one Chemical compound FC1COC(=O)O1 SBLRHMKNNHXPHG-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
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- 125000004438 haloalkoxy group Chemical group 0.000 description 3
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- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 125000001624 naphthyl group Chemical group 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
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- 238000012360 testing method Methods 0.000 description 3
- ATGCJUULFWEWPY-UHFFFAOYSA-N 1,4-ditert-butyl-2,5-dimethoxybenzene Chemical compound COC1=CC(C(C)(C)C)=C(OC)C=C1C(C)(C)C ATGCJUULFWEWPY-UHFFFAOYSA-N 0.000 description 2
- JZODKRWQWUWGCD-UHFFFAOYSA-N 2,5-di-tert-butylbenzene-1,4-diol Chemical compound CC(C)(C)C1=CC(O)=C(C(C)(C)C)C=C1O JZODKRWQWUWGCD-UHFFFAOYSA-N 0.000 description 2
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 2
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- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 2
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- CWLKTJOTWITYSI-UHFFFAOYSA-N 1-fluoronaphthalene Chemical class C1=CC=C2C(F)=CC=CC2=C1 CWLKTJOTWITYSI-UHFFFAOYSA-N 0.000 description 1
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- 238000004821 distillation Methods 0.000 description 1
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- AEOQMMHATQYSLZ-UHFFFAOYSA-N ethenyl ethenesulfonate Chemical compound C=COS(=O)(=O)C=C AEOQMMHATQYSLZ-UHFFFAOYSA-N 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- GZKHDVAKKLTJPO-UHFFFAOYSA-N ethyl 2,2-difluoroacetate Chemical compound CCOC(=O)C(F)F GZKHDVAKKLTJPO-UHFFFAOYSA-N 0.000 description 1
- ZBLCRMTYDQGIOK-UHFFFAOYSA-N ethyl 5,5-dimethyl-2-oxooxolane-3-carboxylate Chemical compound CCOC(=O)C1CC(C)(C)OC1=O ZBLCRMTYDQGIOK-UHFFFAOYSA-N 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
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- 230000006870 function Effects 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- 229910021397 glassy carbon Inorganic materials 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
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- 239000003999 initiator Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000003446 memory effect Effects 0.000 description 1
- NBTOZLQBSIZIKS-UHFFFAOYSA-N methoxide Chemical compound [O-]C NBTOZLQBSIZIKS-UHFFFAOYSA-N 0.000 description 1
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- CSSYKHYGURSRAZ-UHFFFAOYSA-N methyl 2,2-difluoroacetate Chemical compound COC(=O)C(F)F CSSYKHYGURSRAZ-UHFFFAOYSA-N 0.000 description 1
- XMJHPCRAQCTCFT-UHFFFAOYSA-N methyl chloroformate Chemical compound COC(Cl)=O XMJHPCRAQCTCFT-UHFFFAOYSA-N 0.000 description 1
- CCRCUPLGCSFEDV-BQYQJAHWSA-N methyl trans-cinnamate Chemical compound COC(=O)\C=C\C1=CC=CC=C1 CCRCUPLGCSFEDV-BQYQJAHWSA-N 0.000 description 1
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- 229920000642 polymer Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
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- 238000010992 reflux Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 125000006413 ring segment Chemical group 0.000 description 1
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- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
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- JRMUNVKIHCOMHV-UHFFFAOYSA-M tetrabutylammonium bromide Chemical compound [Br-].CCCC[N+](CCCC)(CCCC)CCCC JRMUNVKIHCOMHV-UHFFFAOYSA-M 0.000 description 1
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Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0567—Liquid materials characterised by the additives
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1391—Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
- H01M10/4235—Safety or regulating additives or arrangements in electrodes, separators or electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0025—Organic electrolyte
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/60—Other road transportation technologies with climate change mitigation effect
- Y02T10/70—Energy storage systems for electromobility, e.g. batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49108—Electric battery cell making
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Secondary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
Applications Claiming Priority (1)
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| US2796308P | 2008-02-12 | 2008-02-12 |
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| JP (1) | JP5932220B2 (enExample) |
| KR (1) | KR20100137447A (enExample) |
| CN (1) | CN101990721B (enExample) |
| TW (1) | TWI462367B (enExample) |
| WO (1) | WO2009102604A1 (enExample) |
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| JP2008140711A (ja) * | 2006-12-04 | 2008-06-19 | Sanyo Electric Co Ltd | パック電池 |
| US20100028784A1 (en) * | 2008-07-29 | 2010-02-04 | 3M Innovative Properties Company | Electrolyte composition, lithium-containing electrochemical cell, battery pack, and device including the same |
| JP4934704B2 (ja) * | 2009-07-27 | 2012-05-16 | 株式会社日立製作所 | リチウムイオン二次電池及びリチウムイオン二次電池用過充電抑制剤 |
| US8137841B2 (en) * | 2009-08-31 | 2012-03-20 | 3M Innovative Properties Company | Cathode compositions for lithium-ion electrochemical cells |
| KR101041127B1 (ko) * | 2009-10-01 | 2011-06-13 | 삼성에스디아이 주식회사 | 리튬 이차 전지 |
| KR20110056150A (ko) * | 2009-11-20 | 2011-05-26 | 삼성에스디아이 주식회사 | 리튬 이차 전지용 난연성 전해액 및 이를 포함하는 리튬 이차 전지 |
| US8877390B2 (en) | 2010-05-25 | 2014-11-04 | Uchicago Argonne, Llc | Redox shuttles for lithium ion batteries |
| US8609287B2 (en) | 2010-05-25 | 2013-12-17 | Uchicago Argonne, Llc | Polyether-functionalized redox shuttle additives for lithium ion batteries |
| US8968940B2 (en) | 2010-05-25 | 2015-03-03 | Uchicago Argonne, Llc | Redox shuttles for high voltage cathodes |
| CN102005619A (zh) * | 2010-10-09 | 2011-04-06 | 合肥锂鑫能源材料有限公司 | 用于锂离子电池抗过充混合添加剂中的氧化还原对 |
| CN103563155B (zh) * | 2011-06-07 | 2017-07-21 | 3M创新有限公司 | 包含碳氟化合物电解质添加剂的锂离子电化学电池 |
| EP2751030B1 (en) | 2011-08-31 | 2017-04-26 | 3M Innovative Properties Company | High capacity positive electrodes for use in lithium-ion electrochemical cells and methods of making the same |
| WO2013051636A1 (ja) * | 2011-10-03 | 2013-04-11 | ダイキン工業株式会社 | 過充電防止剤、非水電解液、及び、リチウムイオン二次電池 |
| JP5309233B2 (ja) * | 2012-02-13 | 2013-10-09 | 株式会社日立製作所 | リチウムイオン二次電池及びリチウムイオン二次電池用過充電抑制剤 |
| JP5889477B2 (ja) * | 2012-04-18 | 2016-03-22 | エルジー・ケム・リミテッド | 電極組立体及びそれを含むリチウム二次電池 |
| US9203112B2 (en) | 2012-04-26 | 2015-12-01 | Uchicago Argonne, Llc | Redox shuttles having an aromatic ring fused to a 1,1,4,4-tetrasubstituted cyclohexane ring |
| JP5977573B2 (ja) * | 2012-04-27 | 2016-08-24 | 旭化成株式会社 | 非水系二次電池 |
| CN103427125B (zh) * | 2012-05-15 | 2016-04-13 | 清华大学 | 硫基聚合物锂离子电池的循环方法 |
| US20140063219A1 (en) | 2012-08-28 | 2014-03-06 | General Electric Company | System and method including a portable user profile for medical imaging systems |
| US9005822B2 (en) | 2013-03-06 | 2015-04-14 | Uchicago Argonne, Llc | Functional electrolyte for lithium-ion batteries |
| CN103337659B (zh) * | 2013-06-27 | 2015-11-11 | 湖南有色郴州氟化学有限公司 | 添加剂组合物、电解液 |
| JP6270036B2 (ja) * | 2014-03-14 | 2018-01-31 | トヨタ自動車株式会社 | 非水電解液二次電池とその製造方法および非水電解液 |
| CN107078345B (zh) | 2014-07-18 | 2020-03-20 | 密歇根州立大学理事会 | 包含氧化还原梭添加剂的可再充电锂离子电池 |
| JP6723752B2 (ja) * | 2015-02-10 | 2020-07-15 | 公益財団法人相模中央化学研究所 | 二次電池用電解液 |
| CN104810564B (zh) * | 2015-04-28 | 2017-03-15 | 中国科学院广州能源研究所 | 一种用作锂离子电池过充保护剂的氧化还原梭 |
| US10892525B2 (en) | 2016-06-29 | 2021-01-12 | University Of Kentucky Research Foundation | Rechargeable batteries including high-voltage cathode and redox shuttle conferring overcharge protection |
| JP7089295B2 (ja) | 2016-11-22 | 2022-06-22 | ボード オブ トラスティーズ オブ ミシガン ステイト ユニバーシティ | 充電式電気化学セルおよび酸化還元フロー電池 |
| US10950893B2 (en) | 2016-12-19 | 2021-03-16 | Honda Motor Co., Ltd. | Liquid electrolyte for battery |
| WO2019018741A1 (en) | 2017-07-20 | 2019-01-24 | Board Of Trustees Of Michigan State University | REDOX FLOW BATTERY |
| DE102018206383A1 (de) | 2018-04-25 | 2019-10-31 | Bayerische Motoren Werke Aktiengesellschaft | Verfahren zum Betreiben einer Lithiumionenbatterie, Lithiumionenbatterie und Kraftfahrzeug |
| US10727545B1 (en) * | 2019-04-12 | 2020-07-28 | Ses Holdings Pte. Ltd. | Methods of charging secondary lithium metal batteries to reactive dead lithium with redox shuttling additives and battery control systems incorporating the same |
| US20210013545A1 (en) * | 2019-07-12 | 2021-01-14 | Honeywell International Inc. | Electrolyte solution for a lithium ion cell |
| EP3998664A4 (en) | 2020-05-29 | 2022-10-12 | Asahi Kasei Kabushiki Kaisha | ANHYDROUS ELECTROLYTE SOLUTION, BATTERY PACK AND METHOD OF MAKING BATTERY PACK |
| CN114171782A (zh) * | 2021-12-07 | 2022-03-11 | 河南省法恩莱特新能源科技有限公司 | 防过充钠离子电池电解液及其制备方法 |
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- 2009-02-05 JP JP2010546829A patent/JP5932220B2/ja not_active Expired - Fee Related
- 2009-02-05 WO PCT/US2009/033152 patent/WO2009102604A1/en not_active Ceased
- 2009-02-05 CN CN2009801047214A patent/CN101990721B/zh not_active Expired - Fee Related
- 2009-02-05 US US12/366,002 patent/US8101302B2/en not_active Expired - Fee Related
- 2009-02-05 EP EP09710217.2A patent/EP2250700B1/en not_active Not-in-force
- 2009-02-05 KR KR1020107019914A patent/KR20100137447A/ko not_active Ceased
- 2009-02-11 TW TW098104332A patent/TWI462367B/zh not_active IP Right Cessation
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| JP2003203673A (ja) * | 2001-12-28 | 2003-07-18 | Mitsui Chemicals Inc | 非水電解液およびそれを含むリチウム二次電池 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2250700A1 (en) | 2010-11-17 |
| KR20100137447A (ko) | 2010-12-30 |
| JP2011512014A (ja) | 2011-04-14 |
| US8101302B2 (en) | 2012-01-24 |
| US20090286162A1 (en) | 2009-11-19 |
| CN101990721A (zh) | 2011-03-23 |
| TW200952236A (en) | 2009-12-16 |
| WO2009102604A1 (en) | 2009-08-20 |
| CN101990721B (zh) | 2013-06-19 |
| EP2250700B1 (en) | 2014-09-17 |
| JP5932220B2 (ja) | 2016-06-08 |
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