RU2177948C2 - Металлоцены, способ их получения, катализатор полимеризации, способ полимеризации олефинов, гомополимеры и сополимер пропилена - Google Patents

Металлоцены, способ их получения, катализатор полимеризации, способ полимеризации олефинов, гомополимеры и сополимер пропилена Download PDF

Info

Publication number
RU2177948C2
RU2177948C2 RU96121252/04A RU96121252A RU2177948C2 RU 2177948 C2 RU2177948 C2 RU 2177948C2 RU 96121252/04 A RU96121252/04 A RU 96121252/04A RU 96121252 A RU96121252 A RU 96121252A RU 2177948 C2 RU2177948 C2 RU 2177948C2
Authority
RU
Russia
Prior art keywords
substituents
formula
hydrogen atoms
atoms
bis
Prior art date
Application number
RU96121252/04A
Other languages
English (en)
Russian (ru)
Other versions
RU96121252A (ru
Inventor
Луиджи Рескони
Фабрицио Пьемонтези
И.Е. Нифантьев
П.В. Ивченко
Original Assignee
Монтелл Текнолоджи Компани Б.В.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=11370281&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=RU2177948(C2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Монтелл Текнолоджи Компани Б.В. filed Critical Монтелл Текнолоджи Компани Б.В.
Publication of RU96121252A publication Critical patent/RU96121252A/ru
Application granted granted Critical
Publication of RU2177948C2 publication Critical patent/RU2177948C2/ru

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04Monomers containing three or four carbon atoms
    • C08F10/06Propene
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
RU96121252/04A 1995-01-23 1996-01-17 Металлоцены, способ их получения, катализатор полимеризации, способ полимеризации олефинов, гомополимеры и сополимер пропилена RU2177948C2 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
ITMI95A0000099 1995-01-23
ITMI95A000099 1995-01-23
ITMI950099A IT1272923B (it) 1995-01-23 1995-01-23 Composti metallocenici,procedimento per la loro preparazione,e loro utilizzo in catalizzatori per la polimerizzazione delle olefine

Publications (2)

Publication Number Publication Date
RU96121252A RU96121252A (ru) 1999-01-20
RU2177948C2 true RU2177948C2 (ru) 2002-01-10

Family

ID=11370281

Family Applications (1)

Application Number Title Priority Date Filing Date
RU96121252/04A RU2177948C2 (ru) 1995-01-23 1996-01-17 Металлоцены, способ их получения, катализатор полимеризации, способ полимеризации олефинов, гомополимеры и сополимер пропилена

Country Status (24)

Country Link
US (3) US6051728A (cg-RX-API-DMAC10.html)
EP (1) EP0751946B2 (cg-RX-API-DMAC10.html)
JP (1) JP3838662B2 (cg-RX-API-DMAC10.html)
KR (2) KR100418106B1 (cg-RX-API-DMAC10.html)
CN (2) CN1075076C (cg-RX-API-DMAC10.html)
AR (1) AR000776A1 (cg-RX-API-DMAC10.html)
AU (1) AU700256B2 (cg-RX-API-DMAC10.html)
BG (1) BG100904A (cg-RX-API-DMAC10.html)
BR (1) BR9606373A (cg-RX-API-DMAC10.html)
CA (1) CA2186232A1 (cg-RX-API-DMAC10.html)
CZ (1) CZ309596A3 (cg-RX-API-DMAC10.html)
DE (1) DE69617543T3 (cg-RX-API-DMAC10.html)
ES (1) ES2167539T5 (cg-RX-API-DMAC10.html)
FI (1) FI963759L (cg-RX-API-DMAC10.html)
HU (1) HUP9602907A3 (cg-RX-API-DMAC10.html)
IL (1) IL116853A (cg-RX-API-DMAC10.html)
IT (1) IT1272923B (cg-RX-API-DMAC10.html)
MX (1) MX9604229A (cg-RX-API-DMAC10.html)
PL (1) PL185055B1 (cg-RX-API-DMAC10.html)
RU (1) RU2177948C2 (cg-RX-API-DMAC10.html)
TR (1) TR199600720T1 (cg-RX-API-DMAC10.html)
TW (1) TW319777B (cg-RX-API-DMAC10.html)
WO (1) WO1996022995A1 (cg-RX-API-DMAC10.html)
ZA (1) ZA96485B (cg-RX-API-DMAC10.html)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2214415C1 (ru) * 2002-05-13 2003-10-20 Общество с ограниченной ответственностью "Научно-исследовательская лаборатория "Синор" Способ получения галогенидов металлоценов (варианты)

Families Citing this family (60)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19533336A1 (de) * 1995-09-11 1997-03-13 Basf Ag Verfahren zur Herstellung von Propen/But-1-en-Copolymeren
DE19533337A1 (de) * 1995-09-11 1997-03-13 Basf Ag Propen/But-1-en-Copolymere
JP3566819B2 (ja) * 1996-10-04 2004-09-15 関東化学株式会社 新規な有機遷移金属化合物
DE19644039A1 (de) * 1996-10-31 1998-05-07 Hoechst Ag Metallocene
HUP9904527A2 (hu) * 1996-11-15 2000-05-28 Montell Technology Company B.V. Új heterogyűrűs metallocének és ezeket tartalmazó polimerizációs katalizátorok
US5900497A (en) * 1996-12-20 1999-05-04 Union Carbide Chemicals & Plsatics Technology Corporation Process for preparing metallocene procatalysts
ES2203965T3 (es) * 1997-03-29 2004-04-16 Basell Polyolefine Gmbh Metalocenos y catalizadores para la polimerizacion de olefinas.
AT405834B (de) 1997-10-09 1999-11-25 Borealis Ag Metallocene mit ferrocenyl-substituierten brücken und deren einsatz für die olefinpolymerisation
DE19748388A1 (de) * 1997-11-03 1999-05-06 Borealis Polymere Holding Gmbh Metallocene mit ferrocenyl-substituierten Brücken und deren Einsatz für die Olefinpolymerisation
WO1999054369A1 (en) * 1998-04-21 1999-10-28 Montell Technology Company B.V. Process for the preparation of copolymers of ethylene with alpha-olefins
CA2302287A1 (en) * 1998-07-02 2000-01-13 Montell Technology Company B.V. Process for the preparation of substantially amorphous alpha-olefin polymers and compositions containing them and process for the preparation of bridged ligand
DE19922020A1 (de) * 1999-05-12 2000-11-16 Targor Gmbh Übergangsmetallverbindung, Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
AU783058B2 (en) 2000-02-24 2005-09-22 Basell Technology Company B.V. Organometallic compound useful as cocatalyst for polymerizing olefins
AU5620301A (en) 2000-03-22 2001-10-03 Basell Technology Company B.V. Thermoplastic compositions of isotactic propylene polymers and flexible propylene polymers having reduced isotacticity and a process for the preparation thereof
WO2001090205A1 (en) * 2000-05-24 2001-11-29 Basell Technology Company B.V. Propylene polymers and process for the preparation thereof
US6673869B2 (en) 2000-07-27 2004-01-06 Basell Poliolefine Italia S.P.A. Transparent elastomeric thermoplastic polyolefin compositions
WO2002051887A2 (en) 2000-12-22 2002-07-04 Basell Poliolefine Italia S.P.A. Process for the preparation of porous polymers and polymers obtainable thereof
EP1265933B1 (en) 2000-12-22 2008-08-13 Basell Polyolefine GmbH Catalyst components for the polymerization of olefins
JP4173803B2 (ja) 2001-05-21 2008-10-29 バーゼル・ポリオレフィン・ゲーエムベーハー オレフィンの重合用触媒系
ES2361734T3 (es) * 2001-07-19 2011-06-21 Univation Technologies Llc Películas de polietileno con propiedades físicas mejoradas.
US6936675B2 (en) 2001-07-19 2005-08-30 Univation Technologies, Llc High tear films from hafnocene catalyzed polyethylenes
KR100577139B1 (ko) 2001-07-19 2006-05-10 유니베이션 테크놀로지즈, 엘엘씨 불충분한 공단량체 혼입제 및 충분한 공단량체 혼입제를 함유하는 혼합 메탈로센 촉매계
EP1412394A2 (en) 2001-07-19 2004-04-28 Univation Technologies LLC Low comonomer incorporating metallocene catalyst compounds
JP2005510590A (ja) 2001-11-27 2005-04-21 バセル ポリオレフィン ジーエムビーエイチ ポリマー組成物の処理の方法
EP1517954B1 (en) 2002-06-26 2014-05-28 Basell Poliolefine Italia S.r.l. Impact-resistant polyolefin compositions
CN100354356C (zh) * 2002-06-26 2007-12-12 巴塞尔聚烯烃意大利有限公司 抗冲击聚烯烃组合物
US7449246B2 (en) * 2004-06-30 2008-11-11 General Electric Company Barrier coatings
EP1549688A2 (en) * 2002-10-10 2005-07-06 Basell Polyolefine GmbH Process for the copolymerization of ethylene
US7550528B2 (en) 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
KR101113341B1 (ko) * 2002-10-15 2012-09-27 엑손모빌 케미칼 패턴츠 인코포레이티드 올레핀 중합용 다중 촉매 시스템 및 이로부터 제조된중합체
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US7541402B2 (en) 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
CA2522917A1 (en) 2003-04-17 2004-10-28 Basell Poliolefine Italia S.R.L. Gas-phase olefin polymerization process
CN101163723B (zh) 2003-07-04 2010-12-22 巴塞尔聚烯烃股份有限公司 烯烃聚合方法
EP1564226A1 (en) 2004-02-16 2005-08-17 Stichting Dutch Polymer Institute Titanocene-based catalyst system
US7943716B2 (en) 2004-03-12 2011-05-17 Basell Polyolefine Gmbh Process for polymerizing 1-hexene or higher alpha-olefins
KR20070004712A (ko) 2004-03-12 2007-01-09 바젤 폴리올레핀 게엠베하 올레핀 중합용 촉매 시스템
US7977444B2 (en) 2004-03-12 2011-07-12 Basell Polyolefine Gmbh Process for polymerizaing 1-hexene or higher alpha-olefins
EP1655314A1 (en) 2004-11-09 2006-05-10 Basell Polyolefine GmbH Process for the preparation of 1-butene/propylene copolymers
US7300994B2 (en) * 2004-11-22 2007-11-27 Cornell Research Foundation, Inc. Isotactic polypropylene containing polymers
US8101695B2 (en) 2004-11-22 2012-01-24 Basell Polyolefine Gmbh Propylene based terpolymers
US20080160862A1 (en) * 2004-12-13 2008-07-03 Basell Poliolefine Italia S.R.L. Polyolefin Composition, Fibres and Nonwoven Fabrics
WO2006067214A1 (en) * 2004-12-23 2006-06-29 Basell Poliolefine Italia S.R.L. Fibres having elastic properties
US7026494B1 (en) 2005-01-10 2006-04-11 Chevron Phillips Chemical Company, Lp Polymerization catalysts for producing high melt index polymers without the use of hydrogen
EP2231724B1 (en) 2007-12-18 2011-08-10 Basell Polyolefine GmbH Gas-phase process for the polymerization of alpha-olefins
US20100280153A1 (en) * 2008-01-11 2010-11-04 Keita Itakura Modified propylene resin
EP2247424B1 (en) * 2008-02-29 2012-07-04 Basell Poliolefine Italia S.r.l. Polyolefin compositions
US8637625B2 (en) 2008-11-18 2014-01-28 Borealis Ag Propylene-butene random copolymer produced in the presence of a metallocene catalyst
EP2341086A1 (en) 2009-12-30 2011-07-06 Borealis AG Bopp-film
CN110845546A (zh) 2013-07-17 2020-02-28 埃克森美孚化学专利公司 取代的茂金属催化剂
US9249239B2 (en) 2013-07-17 2016-02-02 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
US9458260B2 (en) 2013-07-17 2016-10-04 Exxonmobil Chemical Patents Inc. Process using substituted metallocene catalysts and products therefrom
US9938364B2 (en) 2013-07-17 2018-04-10 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
SG10201802959WA (en) 2013-07-17 2018-05-30 Exxonmobil Chemical Patents Inc Cyclopropyl substituted metallocene catalysts
ES2703344T3 (es) 2013-07-17 2019-03-08 Exxonmobil Chemical Patents Inc Metalocenos y composiciones catalíticas derivadas de ellos
CN105555813B (zh) * 2013-09-30 2018-01-05 株式会社Lg化学 丙烯‑1‑丁烯共聚物的制备方法以及由此获得的丙烯‑1‑丁烯共聚物
JP6440832B2 (ja) * 2014-12-15 2018-12-19 エルジー・ケム・リミテッド メタロセン化合物、メタロセン担持触媒およびこれを用いるポリオレフィンの製造方法
KR101826253B1 (ko) 2015-07-15 2018-02-06 한화케미칼 주식회사 메탈로센 화합물 및 이의 제조방법
KR102212822B1 (ko) * 2016-12-05 2021-02-08 엑손모빌 케미칼 패턴츠 인코포레이티드 필름용의 브로드 오쏘고날 분포 메탈로센 폴리에틸렌
EP3694811B1 (en) 2017-10-11 2024-04-03 Basell Polyolefine GmbH Supported catalyst system

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0416566A2 (de) * 1989-09-07 1991-03-13 Hoechst Aktiengesellschaft Verfahren zur Herstellung eines Polyolefinwachses
EP0485821A1 (de) * 1990-11-12 1992-05-20 Hoechst Aktiengesellschaft Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
EP0485823A1 (de) * 1990-11-12 1992-05-20 Hoechst Aktiengesellschaft 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation
WO1992012184A1 (en) * 1990-12-28 1992-07-23 Exxon Chemical Patents Inc. Syndiotactic polypropylene
EP0516018A2 (de) * 1991-05-27 1992-12-02 Hoechst Aktiengesellschaft Verfahren zur Herstellung von Polyolefinen mit breiter Molmassenverteilung
US5196496A (en) * 1990-06-27 1993-03-23 Himont Incorporated Syndiotactic crystalline copolymers of propylene and 1-butene
EP0588208A2 (de) * 1992-09-12 1994-03-23 Hoechst Aktiengesellschaft Polyolefin-Formmasse mit breitem Schmelzbereich, Verfahren zu ihrer Herstellung und ihre Verwendung
EP0629632A2 (en) * 1993-06-07 1994-12-21 Mitsui Petrochemical Industries, Ltd. Novel transition metal compound for use as a polymerization catalyst
RU2111219C1 (ru) * 1992-04-01 1998-05-20 Хехст АГ Катализатор полимеризации олефинов, способ его получения и способ получения олефинового полимера

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA844157B (en) * 1983-06-06 1986-01-29 Exxon Research Engineering Co Process and catalyst for polyolefin density and molecular weight control
DE3443087A1 (de) * 1984-11-27 1986-05-28 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von polyolefinen
US4668773A (en) * 1985-03-25 1987-05-26 Northwestern University Organolanthanide catalysts
DE3751694T2 (de) * 1987-04-03 1996-08-01 Fina Technology Metallocen-katalysatorsysteme für die Polymersation von Olefinen, mit einer Silizium-Hydrocarbyl-Brücke.
US4892851A (en) * 1988-07-15 1990-01-09 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
WO1990007526A1 (fr) * 1988-12-26 1990-07-12 Mitsui Petrochemical Industries, Ltd. Copolymeres olefines et leur production
US5026798A (en) * 1989-09-13 1991-06-25 Exxon Chemical Patents Inc. Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
JPH04351638A (ja) * 1991-05-29 1992-12-07 Toray Dow Corning Silicone Co Ltd ヘキセニル基含有シリコーンレジンおよびその製造方法
TW300901B (cg-RX-API-DMAC10.html) * 1991-08-26 1997-03-21 Hoechst Ag
US5330948A (en) * 1992-03-31 1994-07-19 Northwestern University Homogeneous catalysts for stereoregular olefin polymerization
ES2128371T3 (es) * 1992-08-15 1999-05-16 Targor Gmbh Procedimiento para la obtencion de poliolefinas.
TW272985B (cg-RX-API-DMAC10.html) * 1992-09-11 1996-03-21 Hoechst Ag
JP3307704B2 (ja) * 1993-02-19 2002-07-24 三菱化学株式会社 α‐オレフィン重合体の製造法
CA2125246C (en) * 1993-06-07 2001-07-03 Junichi Imuta Transition metal compound and olefin polymerization catalyst using the same
US5459117A (en) * 1993-08-27 1995-10-17 Ewen; John A. Doubly-conformationally locked, stereorigid catalysts for the preparation of tactiospecific polymers
DE4333128A1 (de) * 1993-09-29 1995-03-30 Hoechst Ag Verfahren zur Herstellung von Polyolefinen
DE4344689A1 (de) * 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
US5504223A (en) * 1994-01-25 1996-04-02 The Dow Chemical Company Synthesis of cyclopentadienyl metal coordination complexes from metal hydrocarbyloxides

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0416566A2 (de) * 1989-09-07 1991-03-13 Hoechst Aktiengesellschaft Verfahren zur Herstellung eines Polyolefinwachses
US5196496A (en) * 1990-06-27 1993-03-23 Himont Incorporated Syndiotactic crystalline copolymers of propylene and 1-butene
EP0485821A1 (de) * 1990-11-12 1992-05-20 Hoechst Aktiengesellschaft Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
EP0485823A1 (de) * 1990-11-12 1992-05-20 Hoechst Aktiengesellschaft 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation
WO1992012184A1 (en) * 1990-12-28 1992-07-23 Exxon Chemical Patents Inc. Syndiotactic polypropylene
EP0516018A2 (de) * 1991-05-27 1992-12-02 Hoechst Aktiengesellschaft Verfahren zur Herstellung von Polyolefinen mit breiter Molmassenverteilung
RU2111219C1 (ru) * 1992-04-01 1998-05-20 Хехст АГ Катализатор полимеризации олефинов, способ его получения и способ получения олефинового полимера
EP0588208A2 (de) * 1992-09-12 1994-03-23 Hoechst Aktiengesellschaft Polyolefin-Formmasse mit breitem Schmelzbereich, Verfahren zu ihrer Herstellung und ihre Verwendung
EP0629632A2 (en) * 1993-06-07 1994-12-21 Mitsui Petrochemical Industries, Ltd. Novel transition metal compound for use as a polymerization catalyst

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Э.Фишер, Г.Вернер. Т - комплексы металлов. - М.: Мир, 1968, с.43-54. *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2214415C1 (ru) * 2002-05-13 2003-10-20 Общество с ограниченной ответственностью "Научно-исследовательская лаборатория "Синор" Способ получения галогенидов металлоценов (варианты)

Also Published As

Publication number Publication date
BR9606373A (pt) 2004-06-29
US6051728A (en) 2000-04-18
AU4536696A (en) 1996-08-14
FI963759A0 (fi) 1996-09-20
PL316387A1 (en) 1997-01-06
IL116853A (en) 2000-09-28
WO1996022995A1 (en) 1996-08-01
TR199600720T1 (tr) 1997-03-21
IL116853A0 (en) 1996-07-23
HUP9602907A3 (en) 1997-12-29
US6518386B1 (en) 2003-02-11
PL185055B1 (pl) 2003-02-28
US20030120015A1 (en) 2003-06-26
TW319777B (cg-RX-API-DMAC10.html) 1997-11-11
KR970701723A (ko) 1997-04-12
CN1075076C (zh) 2001-11-21
AR000776A1 (es) 1997-08-06
EP0751946B1 (en) 2001-12-05
EP0751946B2 (en) 2006-08-09
EP0751946A1 (en) 1997-01-08
HUP9602907A2 (en) 1997-05-28
JPH09510994A (ja) 1997-11-04
MX9604229A (es) 1997-12-31
KR100414759B1 (ko) 2004-01-13
BG100904A (bg) 1997-07-31
FI963759A7 (fi) 1996-09-20
KR100418106B1 (ko) 2004-04-30
FI963759L (fi) 1996-09-20
DE69617543D1 (de) 2002-01-17
ES2167539T5 (es) 2007-04-01
IT1272923B (it) 1997-07-01
CA2186232A1 (en) 1996-08-01
ITMI950099A1 (it) 1996-07-23
CN1150430A (zh) 1997-05-21
CN1196721C (zh) 2005-04-13
ZA96485B (en) 1996-08-13
JP3838662B2 (ja) 2006-10-25
AU700256B2 (en) 1998-12-24
CZ309596A3 (en) 1997-04-16
CN1355256A (zh) 2002-06-26
ITMI950099A0 (it) 1995-01-23
DE69617543T3 (de) 2007-01-18
ES2167539T3 (es) 2002-05-16
DE69617543T2 (de) 2002-08-01

Similar Documents

Publication Publication Date Title
RU2177948C2 (ru) Металлоцены, способ их получения, катализатор полимеризации, способ полимеризации олефинов, гомополимеры и сополимер пропилена
JP3287617B2 (ja) アイソタクチツクポリオレフイン製造の方法及び触媒
USRE37208E1 (en) Polyolefins prepared with metallocene catalysts having 2-substituted indenyl type ligands
USRE37384E1 (en) 2-substituted disindenylmetallocenes, process for their preparation, and their use as catalysts in the polymerization of olefins
US6627764B1 (en) Transition metal compound, ligand system, catalyst system and its use for the polymerization of olefins
US6350830B1 (en) Catalyst system, method for the production thereof and its use for the polymerization of olefins
EP0628577A2 (en) Silyl bridged metallocenes and use thereof
JPH05345793A (ja) ブリッジのあるキラルなメタロセン、その製造方法およびそれの触媒としての用途
US6365764B1 (en) Bridged bis-fluorenyl metallocenes process for the preparation thereof and use thereof in catalysts for the polymerization of olefins
CZ434598A3 (cs) Metalocenové sloučeniny
JPH03193796A (ja) メタロセン化合物
CZ365489A3 (en) Syndiotactic polypropylene
JPH09136930A (ja) シンジオタクチツク/アイソタクチツクブロツクポリオレフインの製造方法
RU2168515C2 (ru) Способ получения мостикового металлоценового соединения, мостиковый бис-циклопентадиенильный лиганд
US6376418B1 (en) Process and catalyst for producing polyolefins having low molecular weight
KR20010024225A (ko) 라세미형 메탈로센 착물의 선택적 제조방법
JP4454225B2 (ja) ラセミメタロセン錯体の製造方法
US7635783B2 (en) Meso-selective synthesis of ansa-metallocenes
EP1742954B1 (en) Process for the racemoselective preparation of ansa-metallocenes

Legal Events

Date Code Title Description
MM4A The patent is invalid due to non-payment of fees

Effective date: 20080118