RU2011139081A - Фильтр для поглощения твердых частиц из отработавших газов двигателя с воспламенением от сжатия - Google Patents
Фильтр для поглощения твердых частиц из отработавших газов двигателя с воспламенением от сжатия Download PDFInfo
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- RU2011139081A RU2011139081A RU2011139081/05A RU2011139081A RU2011139081A RU 2011139081 A RU2011139081 A RU 2011139081A RU 2011139081/05 A RU2011139081/05 A RU 2011139081/05A RU 2011139081 A RU2011139081 A RU 2011139081A RU 2011139081 A RU2011139081 A RU 2011139081A
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- Prior art keywords
- coating
- filter according
- substrate
- increasing
- inlet
- Prior art date
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- 239000007789 gas Substances 0.000 title claims abstract 7
- 230000006835 compression Effects 0.000 title claims abstract 4
- 238000007906 compression Methods 0.000 title claims abstract 4
- 239000002245 particle Substances 0.000 title claims 3
- 239000007787 solid Substances 0.000 title claims 3
- 239000011148 porous material Substances 0.000 claims abstract 26
- 239000011248 coating agent Substances 0.000 claims abstract 24
- 238000000576 coating method Methods 0.000 claims abstract 24
- 239000000758 substrate Substances 0.000 claims abstract 23
- 239000002808 molecular sieve Substances 0.000 claims abstract 12
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims abstract 12
- 239000013618 particulate matter Substances 0.000 claims abstract 8
- 229910052723 transition metal Inorganic materials 0.000 claims abstract 8
- 150000003624 transition metals Chemical class 0.000 claims abstract 8
- 229910052802 copper Inorganic materials 0.000 claims 4
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims 4
- 229910052684 Cerium Inorganic materials 0.000 claims 3
- 229910052742 iron Inorganic materials 0.000 claims 3
- 239000010457 zeolite Substances 0.000 claims 3
- 229910021536 Zeolite Inorganic materials 0.000 claims 2
- 229910000323 aluminium silicate Inorganic materials 0.000 claims 2
- 229910052804 chromium Inorganic materials 0.000 claims 2
- 229910052733 gallium Inorganic materials 0.000 claims 2
- 229910052735 hafnium Inorganic materials 0.000 claims 2
- 229910052738 indium Inorganic materials 0.000 claims 2
- 229910052746 lanthanum Inorganic materials 0.000 claims 2
- 229910052748 manganese Inorganic materials 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- 229910052759 nickel Inorganic materials 0.000 claims 2
- 229910000510 noble metal Inorganic materials 0.000 claims 2
- 229910052763 palladium Inorganic materials 0.000 claims 2
- 229910052697 platinum Inorganic materials 0.000 claims 2
- 229910052703 rhodium Inorganic materials 0.000 claims 2
- 229910052720 vanadium Inorganic materials 0.000 claims 2
- 229910052725 zinc Inorganic materials 0.000 claims 2
- 239000000919 ceramic Substances 0.000 claims 1
- 238000011118 depth filtration Methods 0.000 claims 1
- 238000001914 filtration Methods 0.000 claims 1
- 229910052737 gold Inorganic materials 0.000 claims 1
- 229910052680 mordenite Inorganic materials 0.000 claims 1
- 229910052709 silver Inorganic materials 0.000 claims 1
Classifications
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- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9404—Removing only nitrogen compounds
- B01D53/9409—Nitrogen oxides
- B01D53/9413—Processes characterised by a specific catalyst
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- B01J29/7615—Zeolite Beta
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- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
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- B01D46/2403—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies characterised by the physical shape or structure of the filtering element
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- B01D53/9404—Removing only nitrogen compounds
- B01D53/9409—Nitrogen oxides
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S55/00—Gas separation
- Y10S55/30—Exhaust treatment
Abstract
1. Фильтр для улавливания твердых частиц (РМ) из отработавших газов двигателей с воспламенением от сжатия, содержащий пористую подложку, имеющую впускные и выпускные поверхности, и поры подложки первого среднего размера, в котором пористая подложка покрыта увеличивающим площадь поверхности покрытием, включающим молекулярное сито, промотированное по меньшей мере одним переходным металлом, в котором увеличивающее площадь поверхности покрытие представляет собой непропитывающее пористое покрытие на упомянутой впускной и/или выпускной поверхности, и по меньшей мере один из слоев имеет поры второго среднего размера, который меньше первого среднего размера пор.2. Фильтр по п.1, в котором первый средний размер пор пористой структуры пористой подложки составляет от 8 до 45 мкм, а второй средний размер пор составляет от 5,0 нм до 5,0 мкм.3. Фильтр по п.1, в котором плотность нанесения увеличивающего площадь поверхности покрытия составляет больше 0,50 г/дюйм.4. Фильтр по п.3, в котором плотность нанесения увеличивающего площадь поверхности покрытия составляет больше 1,00 г/дюйм.5. Фильтр по п.1, в котором увеличивающее площадь поверхности покрытие представляет собой один или несколько слоев, практически покрывающих поры подложки на впускных и выпускных поверхностях.6. Фильтр по п.1, в котором увеличивающее площадь поверхности покрытие расположено так, чтобы сузить поры подложки.7. Фильтр по п.1, в котором увеличивающее площадь поверхности покрытие нанесено на впускные и выпускные поверхности и в котором средний размер пор увеличивающего площадь поверхности покрытия на впускных поверхностях меньше среднего размера пор увеличива�
Claims (17)
1. Фильтр для улавливания твердых частиц (РМ) из отработавших газов двигателей с воспламенением от сжатия, содержащий пористую подложку, имеющую впускные и выпускные поверхности, и поры подложки первого среднего размера, в котором пористая подложка покрыта увеличивающим площадь поверхности покрытием, включающим молекулярное сито, промотированное по меньшей мере одним переходным металлом, в котором увеличивающее площадь поверхности покрытие представляет собой непропитывающее пористое покрытие на упомянутой впускной и/или выпускной поверхности, и по меньшей мере один из слоев имеет поры второго среднего размера, который меньше первого среднего размера пор.
2. Фильтр по п.1, в котором первый средний размер пор пористой структуры пористой подложки составляет от 8 до 45 мкм, а второй средний размер пор составляет от 5,0 нм до 5,0 мкм.
3. Фильтр по п.1, в котором плотность нанесения увеличивающего площадь поверхности покрытия составляет больше 0,50 г/дюйм3.
4. Фильтр по п.3, в котором плотность нанесения увеличивающего площадь поверхности покрытия составляет больше 1,00 г/дюйм3.
5. Фильтр по п.1, в котором увеличивающее площадь поверхности покрытие представляет собой один или несколько слоев, практически покрывающих поры подложки на впускных и выпускных поверхностях.
6. Фильтр по п.1, в котором увеличивающее площадь поверхности покрытие расположено так, чтобы сузить поры подложки.
7. Фильтр по п.1, в котором увеличивающее площадь поверхности покрытие нанесено на впускные и выпускные поверхности и в котором средний размер пор увеличивающего площадь поверхности покрытия на впускных поверхностях меньше среднего размера пор увеличивающего площадь поверхности покрытия на выпускных поверхностях.
8. Фильтр по п.7, в котором средний размер пор увеличивающего площадь поверхности покрытия на выпускных поверхностях больше среднего размера пор пористой подложки.
9. Фильтр по п.1, в котором пористая подложка представляет собой керамический фильтр с проницаемыми стенками.
10. Фильтр по п.1, в котором молекулярное сито представляет собой нецеолитное молекулярное сито, представляющее собой алюминофосфатное молекулярное сито, выбранное из группы, состоящей из алюминофосфатных (AlPО) молекулярных сит, молекулярных сит из металлзамещенных алюминофосфатных (MeAlPO) цеолитов, силико-алюминофосфатных (SAPO) молекулярных сит и металлзамещенных силико- алюминофосфатных (MeAPSO) молекулярных сит.
11. Фильтр по п.1, в котором по меньшей мере одно молекулярное сито представляет собой алюмосиликатный цеолит или металлзамещенный алюмосиликатный цеолит, имеющий структуру каркаса, выбранную из группы, состоящей из AEI, ZSM-5, ZSM-20, ERI, LEV, морденит, BEA, Y, СНА, МСМ-22 и EU-I.
12. Фильтр по п.10, в котором переходный металл-промотор выбран из группы, состоящей из Cr, Со, Cu, Fe, Hf, La, Се, In, V, Mn, Ni, Zn, Ga и благородных металлов: Ag, Au, Pt, Pd и Rh.
13. Фильтр по п.11, в котором переходный металл выбран из группы, состоящей из Cr, Со, Cu, Fe, Hf, La, Се, In, V, Mn, Ni, Zn, Ga и благородных металлов: Ag, Au, Pt, Pd и Rh.
14. Фильтр по п.12, в котором переходный металл выбран из группы, состоящей из Cu, Fe и Се.
15. Фильтр по п.13, в котором переходный металл выбран из группы, состоящей из Се, Fe и Cu.
16. Способ улавливания твердых частиц (РМ) из отработавших газов двигателя с воспламенением от сжатия глубинной фильтрацией, включающий контактирование отработавших газов, содержащих РМ, с фильтром, включающим пористую подложку, имеющую впускные и выпускные поверхности и поры подложки первого среднего размера, в которой пористая подложка покрыта увеличивающим площадь поверхности покрытием, включающим молекулярное сито, промотированное по меньшей мере одним переходным металлом, в котором увеличивающее площадь поверхности покрытие представляет собой один или несколько непропитывающих пористых слоев, практически покрывающих поры подложки на впускных и/или выпускных поверхностях, в котором по меньшей мере один из слоев имеет поры второго среднего размера, который меньше первого среднего размера пор.
17. Способ улавливания твердых частиц (РМ) из отработавших газов двигателя с воспламенением от сжатия глубинной фильтрацией, включающий контактирование отработавших газов, содержащих РМ, с фильтром, включающим пористую подложку, имеющую впускные и выпускные поверхности и поры подложки первого среднего размера, в котором пористая подложка покрыта непропитывающим увеличивающим площадь поверхности покрытием, включающим молекулярное сито, промотированное по меньшей мере одним переходным металлом, в котором увеличивающее площадь поверхности покрытие располагается на впускных и/или выпускных поверхностях пористой подложки так, чтобы сузить поры подложки.
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RU2011139081/05A RU2527462C2 (ru) | 2009-02-26 | 2010-02-26 | Фильтр для поглощения твердых частиц из отработавших газов двигателя с воспламенением от сжатия |
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JP5351524B2 (ja) | 2008-10-14 | 2013-11-27 | 日本碍子株式会社 | ハニカム構造体 |
EP2974779A1 (de) | 2008-11-04 | 2016-01-20 | Umicore AG & Co. KG | Dieselpartikelfilter mit verbesserten staudruckeigenschaften |
WO2010062794A1 (en) * | 2008-11-26 | 2010-06-03 | Corning Incorporated | Coated particulate filter and method |
JP2010167366A (ja) * | 2009-01-22 | 2010-08-05 | Ngk Insulators Ltd | ハニカム触媒体 |
GB0903262D0 (en) * | 2009-02-26 | 2009-04-08 | Johnson Matthey Plc | Filter |
EP2516044B1 (en) * | 2009-12-24 | 2018-04-25 | Johnson Matthey PLC | Exhaust system for a vehicular positive ignition internal combustion engine |
JP5649945B2 (ja) * | 2009-12-25 | 2015-01-07 | 日本碍子株式会社 | 表面捕集層付き担体及び触媒担持表面捕集層付き担体 |
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2009
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