KR101354477B1 - 메탈로센 촉매, 그 합성 및 올레핀들의 중합을 위한 그 용도 - Google Patents
메탈로센 촉매, 그 합성 및 올레핀들의 중합을 위한 그 용도 Download PDFInfo
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- KR101354477B1 KR101354477B1 KR1020077012546A KR20077012546A KR101354477B1 KR 101354477 B1 KR101354477 B1 KR 101354477B1 KR 1020077012546 A KR1020077012546 A KR 1020077012546A KR 20077012546 A KR20077012546 A KR 20077012546A KR 101354477 B1 KR101354477 B1 KR 101354477B1
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- South Korea
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- methyl
- indenyl
- phenyl
- zirconium dichloride
- carbon atoms
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/655—Pretreating with metals or metal-containing compounds with aluminium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
- B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/02—Carriers therefor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/001,272 | 2004-12-01 | ||
US11/001,272 US7169864B2 (en) | 2004-12-01 | 2004-12-01 | Metallocene catalysts, their synthesis and their use for the polymerization of olefins |
PCT/US2005/043421 WO2006060544A1 (en) | 2004-12-01 | 2005-12-01 | Metallocene catalysts, their synthesis and their use for the polymerization of olefins |
Publications (2)
Publication Number | Publication Date |
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KR20070092217A KR20070092217A (ko) | 2007-09-12 |
KR101354477B1 true KR101354477B1 (ko) | 2014-01-24 |
Family
ID=36129857
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1020077012546A KR101354477B1 (ko) | 2004-12-01 | 2005-12-01 | 메탈로센 촉매, 그 합성 및 올레핀들의 중합을 위한 그 용도 |
Country Status (13)
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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KR20170075533A (ko) * | 2015-12-23 | 2017-07-03 | 주식회사 엘지화학 | 혼성 담지 촉매 및 이를 이용하는 올레핀계 중합체의 제조방법 |
US9783557B2 (en) | 2014-10-17 | 2017-10-10 | Lg Chem, Ltd. | Metallocene catalyst for preparing a high molecular weight polyolefin and a preparation method thereof |
US9884926B2 (en) | 2014-11-06 | 2018-02-06 | Lg Chem, Ltd. | Metallocene catalyst for preparing a high molecular weight polyolefin and a preparation method thereof |
US10889667B2 (en) | 2016-02-17 | 2021-01-12 | Lg Chem, Ltd. | High-stiffness and energy-reducing polypropylene for foaming |
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US7169864B2 (en) * | 2004-12-01 | 2007-01-30 | Novolen Technology Holdings, C.V. | Metallocene catalysts, their synthesis and their use for the polymerization of olefins |
US7598329B2 (en) * | 2005-11-04 | 2009-10-06 | Ticona Gmbh | Process for manufacturing ultra high molecular weight polymers using novel bridged metallocene catalysts |
DE102005052654A1 (de) * | 2005-11-04 | 2007-05-16 | Ticona Gmbh | Verfahren zur Herstellung von ultrahochmolekularen Polymeren unter Verwendung von speziellen verbrückten Metallocen-Katalysatoren |
US8034886B2 (en) | 2005-11-04 | 2011-10-11 | Ticona Gmbh | Process for manufacturing high to ultra high molecular weight polymers using novel bridged metallocene catalysts |
US7683002B2 (en) * | 2006-04-04 | 2010-03-23 | Fina Technology, Inc. | Transition metal catalyst and formation thereof |
US20070299222A1 (en) | 2006-04-04 | 2007-12-27 | Fina Technology, Inc. | Transition metal catalysts and formation thereof |
EP1930348A1 (en) * | 2006-12-05 | 2008-06-11 | Ineos Manufacturing France SAS | Supported catalyst system |
CN101910216A (zh) | 2007-10-25 | 2010-12-08 | 鲁姆斯诺沃伦技术公司 | 柄型金属茂化合物的外消旋选择性合成、柄型金属茂化合物、含有该化合物的催化剂、通过使用该催化剂制备烯烃聚合物的方法和烯烃均聚物及共聚物 |
CN101889030B (zh) | 2007-10-25 | 2013-07-17 | 鲁姆斯诺沃伦技术公司 | 金属茂化合物,含有金属茂化合物的催化剂,使用该催化剂制备烯烃聚合物的方法 |
WO2009054833A2 (en) | 2007-10-25 | 2009-04-30 | Novolen Technology Holdings, C.V. | Metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo and copolymers |
TW200936619A (en) | 2007-11-15 | 2009-09-01 | Univation Tech Llc | Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom |
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US8076429B2 (en) | 2009-03-11 | 2011-12-13 | Lummus Novolen Technology Gmbh | Supertransparent high impact strength random block copolymer |
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CN102712701A (zh) | 2009-12-07 | 2012-10-03 | 尤尼威蒂恩技术有限责任公司 | 减少催化剂的静电荷的方法和使用该催化剂生产聚烯烃的方法 |
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ES2548726T3 (es) | 2015-10-20 |
WO2006060544A1 (en) | 2006-06-08 |
CN101124252A (zh) | 2008-02-13 |
US20080287286A1 (en) | 2008-11-20 |
AR052985A1 (es) | 2007-04-18 |
BRPI0518701B1 (pt) | 2018-09-25 |
JP5311827B2 (ja) | 2013-10-09 |
BRPI0518701B8 (pt) | 2023-01-24 |
RU2360931C2 (ru) | 2009-07-10 |
JP2011231328A (ja) | 2011-11-17 |
BRPI0518701A2 (pt) | 2008-12-02 |
CN101124252B (zh) | 2011-10-05 |
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US7169864B2 (en) | 2007-01-30 |
EP1828266A1 (en) | 2007-09-05 |
CN103012623A (zh) | 2013-04-03 |
ZA200704403B (en) | 2008-09-25 |
AR084818A2 (es) | 2013-06-26 |
KR20070092217A (ko) | 2007-09-12 |
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RU2007124637A (ru) | 2009-01-10 |
US20070082806A1 (en) | 2007-04-12 |
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