JPH08507766A - 濃縮生分解性四級アンモニウム布帛柔軟剤組成物、および中間ヨウ素価不飽和脂肪酸鎖を含む化合物 - Google Patents
濃縮生分解性四級アンモニウム布帛柔軟剤組成物、および中間ヨウ素価不飽和脂肪酸鎖を含む化合物Info
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/645—Mixtures of compounds all of which are cationic
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/835—Mixtures of non-ionic with cationic compounds
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/047—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on cationic surface-active compounds and soap
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
- C11D3/0015—Softening compositions liquid
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
Abstract
Description
Claims (1)
- 【特許請求の範囲】 1. 下記構造を有する四級アンモニウム化合物であって、 (R)4-m‐N+‐〔(CH2)n‐Y‐R2〕mX- 上記式中、 各Yは‐O‐(O)C‐または‐C(O)‐O‐であり、 mは2または3であり、 nは1〜4であり、 各RはC1‐C6アルキル基、ベンジル基またはそれらの混合であり、 各R2は、好ましくは少くとも90%のC16‐C18鎖長を有する脂肪酸から誘導 される、C11‐C21ヒドロカルビルまたは置換ヒドロカルビル置換基であり、 X-は柔軟剤適合性アニオンであり、 ここで、上記化合物が、最良の静電気制御のために、20〜100、好ましく は20〜65、更に好ましくは40〜60のヨウ素価を有するC12‐C22脂肪ア シル基から誘導されるものであり、該脂肪アシル基の不飽和レベルが65重量% 以下であり、上記化合物が化合物の原料中に存在する一般的極性有機溶媒以外の 粘度調節剤または添加電解質なしに13重量%以上の濃度の濃縮水性組成物を形 成することができ、獣脂由来のいずれの脂肪アシル基も修飾されていなければな らず、好ましくはシス/トランス異性体重量比が80/20以上である、化合物 。 2. 下記構造を有する四級アンモニウム化合物であって、 (R)4-m‐N+‐〔(CH2)n‐Y‐R2〕mX- 上記式中、 各Yは‐O‐(O)C‐または‐C(O)‐O‐であり、 mは2または3であり、 nは1〜4であり、 各RはC1‐C6アルキル基、ベンジル基またはそれらの混合であり、 各R2は、好ましくは少くとも90%のC16‐C18鎖長を有する脂肪酸から誘導 される、C11‐C21ヒドロカルビルまたは置換ヒドロカルビル置換基であり、 X-は柔軟剤適合性アニオンであり、 ここで、上記化合物が、最良の低温安定性のために、5〜25、好ましくは1 0〜25、更に好ましくは15〜20のヨウ素価を有するC12‐C22脂肪アシル 基から誘導されるものであり、シス/トランス異性体重量比が30/70以上、 好ましくは50/50以上、更に好ましくは70/30以上である、化合物。 3. I.(A)生分解性四級アンモニウム布帛柔軟化化合物50〜95%、 好ましくは60〜90% (B)1.C10‐C22単一長鎖アルキルカチオン系界面活性剤、好ましくはコ ココリンエステル、タロウコリンエステルおよびそれらの混合物 2.少くとも8つのエトキシ部分を有するノニオン系界面活性剤、好ましく はポリ(10〜18)エトキシレートを有するC10‐C14アルコール、 3.アミンオキシド、好ましくはココアミンオキシド 4.C12‐C25脂肪酸、好ましくはココ脂肪酸 5.それらの混合物 からなる群より選択される分散性調節剤0〜30%、および (C)好ましくはアスコルビン酸、没食子酸プロピル、アスコルビン酸パルミ テート、ブチル化ヒドロキシトルエン、三級ブチルヒドロキノン、天然トコフェ ロール類、ブチル化ヒドロキシアニソール、クエン酸、没食子酸のC8 からなる群より選択される安定剤0〜2% を含んでなる固形粒状組成物; II.(A)生分解性四級アンモニウム布帛柔軟化化合物5〜50%、好ましくは 15〜50% (B)1.C10‐C22単一長鎖アルキルカチオン系界面活性剤、好ましくはコ ココリンエステルまたはタロウコリンエステル 2.少くとも8つのエトキシ部分を有するノニオン系界面活性剤、好ましく はポリ(10〜18)エトキシレートを有するC10‐C14アルコール、 3.アミンオキシド、好ましくはココアミンオキシド 4.C12‐C25脂肪酸、好ましくはココ脂肪酸 5.それらの混合物 からなる群より選択される分散性調節剤0〜5%、 (C)好ましくはアスコルビン酸、没食子酸プロピル、アスコルビン酸パルミ テート、ブチル化ヒドロキシトルエン、三級ブチルヒドロキノン、天然トコフェ ロール類、ブチル化ヒドロキシアニソール、クエン酸、没食子酸のC8 からなる群より選択される安定剤0〜2%、および (D)水性液体キャリア を含んでなる液体組成物 〔四級アンモニウム布帛柔軟化化合物は下記式を有し、 (R)4-m‐N+‐〔(CH2)n‐Y‐R2〕mX- 上記式中、 各Yは‐O‐(O)C‐または‐C(O)‐O‐であり、 mは2または3であり、 nは1〜4であり、 各RはC1‐C6アルキル基、ベンジル基またはそれらの混合であり、 各R2は、好ましくは少くとも90%のC16‐C18鎖長を有する脂肪酸から誘導 される、C11‐C21ヒドロカルビルまたは置換ヒドロカルビル置換基であり、 X-は柔軟剤適合性アニオンであり、 ここで、上記化合物は最良の静電気制御のために、20〜100、好ましくは 20〜65、更に好ましくは40〜60のヨウ素価を有するC12‐C22脂肪アシ ル基から誘導されるものであり、該脂肪アシル基の不飽和レベルは65重量%以 下であり、液体組成物は濃度が13%以下であるときノニオン系粘度調節剤なし に安定であり、好ましくは組成物は有効量、10%以内の汚物放出ポリマーを更 に含み、分散性調節剤は組成物粘度、分散性または双方に影響を与える〕 からなる群より選択される安定な均一布帛柔軟化組成物。 4. I.(A)生分解性四級アンモニウム布帛柔軟化化合物50〜95%、 好ましくは60〜90% (B)1.C10‐C22単一長鎖アルキルカチオン系界面活性剤、好ましくはコ ココリンエステル、タロウコリンエステルおよびそれらの混合物 2.少くとも8つのエトキシ部分を有するノニオン系界面活性剤、好ましく はポリ(10〜18)エトキシレートを有するC10‐C14アルコール、 3.アミンオキシド、好ましくはココアミンオキシド 4.C12‐C25脂肪酸、好ましくはココ脂肪酸 5.それらの混合物 からなる群より選択される分散性調節剤0〜30%、および (C)好ましくはアスコルビン酸、没食子酸プロピル、アスコルビン酸パルミ テート、ブチル化ヒドロキシトルエン、三級ブチルヒドロキノン、天然トコ フェロール類、ブチル化ヒドロキシアニソール、クエン酸、没食子酸のC8 からなる群より選択される安定剤0〜2% を含んでなる固形粒状組成物; II.(A)生分解性四級アンモニウム布帛柔軟化化合物5〜50%、 (B)1.C10‐C22単一長鎖アルキルカチオン系界面活性剤、好ましくはコ ココリンエステル、タロウコリンエステルおよびそれらの混合物 2.少くとも8つのエトキシ部分を有するノニオン系界面活性剤、好ましく はポリ(10〜18)エトキシレートを有するC10‐C14アルコール、 3.アミンオキシド、好ましくはココアミンオキシド 4.C12‐C25脂肪酸、好ましくはココ脂肪酸、 5.それらの混合物 からなる群より選択される分散性調節剤0〜5%、 (C)好ましくはアスコルビン酸、没食子酸プロピル、アスコルビン酸パルミ テート、ブチル化ヒドロキシトルエン、三級ブチルヒドロキノン、天然トコフェ ロール類、ブチル化ヒドロキシアニソール、クエン酸、没食子酸のC8 からなる群より選択される安定剤0〜2%、および (D)水性液体キャリア を含んでなる液体組成物 〔四級アンモニウム布帛柔軟化化合物は下記式を有し、 (R)4-m‐N+‐〔(CH2)n‐Y‐R2〕mX- 上記式中、 各Yは‐O‐(O)C‐または‐C(O)‐O‐であり、 mは2または3であり、 nは1〜4であり、 各RはC1‐C6アルキル基、ベンジル基またはそれらの混合であり、 各R2は、好ましくは少くとも90%のC16‐C18鎖長を有する脂肪酸から誘導 される、C11‐C21ヒドロカルビルまたは置換ヒドロカルビル置換基であり、 X-は柔軟剤適合性アニオンであるり、 ここで、上記化合物は、最良の低温安定性のために、5〜25、好ましくは1 0〜25、更に好ましくは15〜20のヨウ素価を有するC12‐C22脂肪アシル 基から誘導されるものであり、該脂肪アシル基の不飽和レベルは65重量%以下 であり、シス/トランス異性体重量比は30/70以上、好ましくは50/50 以上、更に好ましくは70/30以上であり、液体組成物のpHは2〜5であり 、好ましくはIの場合に粒度は50〜1000ミクロンであり、分散性調節剤は 組成物粘度、分散性または双方に影響を与え、好ましくは組成物は有効量、10 %以内の汚物放出ポリマーを含む〕 からなる群より選択される安定な均一布帛柔軟化組成物。 5. 脂肪アシル基の多不飽和含有率が5重量%以下、好ましくは1重量%以 下である、請求項1〜4のいずれか一項に記載の化合物および組成物。 6. (A)130〜190°F、好ましくは155〜175°Fの温度を有 する四級アンモニウム布帛柔軟化化合物前混合物を130〜190°F、好まし くは155〜175°Fの温度を有する酸ウォーターシート中に注入し、 (B)注入中にバッチを混合および粉砕し、 (C)注入時間中1/2〜2/3の過程で0〜1000ppm、好ましくは50 0〜600ppmのCaCl2を加え、 (D)前混合物注入が完了した後、好ましくは200〜2500ppm/minの注 入速度で、1000〜5000ppm、好ましくは2000〜4000ppmのCaC l2を全体で2〜7分間かけて加え、 (E)105〜160°F、好ましくは145〜155°F温度で香料を加え 、 (F)バッチが55〜95°F、好ましくは65〜85°Fの温度に冷却され た後、1000〜5000ppm、好ましくは2000〜4000ppmのCaCl2 を加える工程からなり、 組成物中の全CaCl2が2000〜11000ppm、好ましくは6000〜7 500ppmであり、組成物が粘度調節剤を含有していない、請求項3に記載の液 体柔軟化組成物の製造法。 7. (A)130〜190°Fの温度を有する四級アンモニウム布帛柔軟化 化合物前混合物を130〜190°Fの温度を有する酸ウォーターシート中に注 入し、 (B)100〜130°Fの温度で1000〜5000ppmのCaCl2を加え 、 (C)組成物を粉砕し、 (D)バッチが55〜95°Fの温度に冷却された後、1000〜5000pp mのCaCl2を加える工程からなり、 組成物中の全CaCl2が2000〜11000ppmであり、香料力江程(C) 中または後に加えられ、但し工程(D)の前であって、温度が≦130°Fに下 がった後で加えられる、請求項3に記載の液体柔軟化組成物の製造法。 8. (A)生分解性四級アンモニウム布帛柔軟化化合物0.1〜92%、 (B)アルコール溶媒8〜18%、好ましくは12〜16% (C)安定剤0〜2%、好ましくは還元剤安定剤0.01〜0.2%、酸化防 止剤安定剤0.035〜0.1%、およびそれらの混合物 を含んでなり、 水分レベル1%以下、好ましくは0.5%以下であり、好ましくはアルコール がエタノール、イソプロピルアルコール、プロピレングリコール、エチレングリ コールおよびそれらの混合物からなる群より選択され、安定剤が好ましくはアス コルビン酸、没食子酸プロピル、アスコルビン酸、ブチル化ヒドロキシトルエン 、三級ブチルヒドロキノン、天然トコフェロール類、ブチル化ヒドロキシアニソ ール、水素化ホウ素ナトリウム、次亜リン酸、クエン酸イソプロピル、没食子酸 の らの混合物からなる群より選択される、色および臭気安定性溶融布帛柔軟化原料 。 9. ≧28%の生分解性四級アンモニウム布帛柔軟活性剤を有する分散物の 形をした濃縮水性生分解性四級アンモニウム布帛柔軟化組成物の製造法であって 、 (A)約150°Fで有機前混合物をウォーターシート中に分散し、 (有機前混合物は: (1)生分解性四級アンモニウム布帛柔軟剤、および (2)有効量の低分子量アルコール加工助剤から構成される) (B)生分解性四級アンモニウム布帛柔軟剤の主熱転移温度より高い約30〜 約60°Fの温度まで得られた分散物を冷却し、 (C)生分解性布帛柔軟剤の熱転移温度より高い約30〜約60°Fの温度で 約400〜約7000ppmの電解質を加え、好ましくは高剪断粉砕し、 (D)分散物を周囲温度まで冷却し、その後約600〜約8000ppmの量で 電解質を追加することからなり、 四級アンモニウム布帛柔軟剤が下記式を有し、 (R)4-m‐N+‐〔(CH2)n‐Y‐R2〕mX- 上記式中、 各Yは‐O‐(O)C‐または‐C(O)‐O‐であり、 mは2または3であり、 nは1〜4であり、 各RはC1‐C6アルキル基、ベンジル基またはそれらの混合であり、 各R2はC11‐C21ヒドロカルビルまたは置換ヒドロカルビル置換基であり、 X-は柔軟剤適合性アニオンであり、 好ましくは周囲温度まで冷却した後かつ残留電解質の添加前において香料が工 程(D)中に加えられ、好ましくは組成物が低分子量アルコール、電解質および 香料以外の粘度および分散性調節剤を実質上含まず、好ましくは電解質の全レベ ルが1000〜15000ppmである、方法。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US2454193A | 1993-03-01 | 1993-03-01 | |
US08/024,541 | 1993-03-01 | ||
US14273993A | 1993-10-25 | 1993-10-25 | |
US08/142,739 | 1993-10-25 | ||
PCT/US1994/001936 WO1994020597A1 (en) | 1993-03-01 | 1994-02-23 | Concentrated biodegradable quaternary ammonium fabric softener compositions and compounds containing intermediate iodine value unsaturated fatty acid chains |
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JP2005368678A Division JP3902783B2 (ja) | 1993-03-01 | 2005-12-21 | 濃縮生分解性四級アンモニウム布帛柔軟剤組成物、および中間ヨウ素価不飽和脂肪酸鎖を含む化合物 |
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JP2005368678A Expired - Lifetime JP3902783B2 (ja) | 1993-03-01 | 2005-12-21 | 濃縮生分解性四級アンモニウム布帛柔軟剤組成物、および中間ヨウ素価不飽和脂肪酸鎖を含む化合物 |
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US (3) | US5562849A (ja) |
EP (1) | EP0687291B2 (ja) |
JP (2) | JPH08507766A (ja) |
CN (3) | CN1066188C (ja) |
AT (1) | ATE191743T1 (ja) |
AU (1) | AU6271294A (ja) |
BR (1) | BR9405945A (ja) |
CA (1) | CA2157178C (ja) |
DE (1) | DE69423963T3 (ja) |
DK (1) | DK0687291T4 (ja) |
ES (1) | ES2144515T5 (ja) |
FI (1) | FI954084A (ja) |
GR (1) | GR3033212T3 (ja) |
NO (1) | NO305020B1 (ja) |
PT (1) | PT687291E (ja) |
WO (1) | WO1994020597A1 (ja) |
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JPH0756112B2 (ja) * | 1988-02-17 | 1995-06-14 | 花王株式会社 | 濃縮型衣料用柔軟仕上剤 |
JPH01229877A (ja) * | 1988-03-04 | 1989-09-13 | Lion Corp | 液体柔軟剤組成物 |
JPH01249129A (ja) * | 1988-03-30 | 1989-10-04 | Kao Corp | 柔軟仕上剤の製造方法 |
DE3811247A1 (de) * | 1988-04-02 | 1989-10-12 | Henkel Kgaa | Quartaere ammoniumverbindungen |
DE3818061A1 (de) * | 1988-05-27 | 1989-12-07 | Henkel Kgaa | Fluessiges, waessriges waeschenachbehandlungsmittel |
JPH02113095A (ja) * | 1988-10-24 | 1990-04-25 | Lion Corp | 洗濯用柔軟剤組成物 |
JPH02139480A (ja) * | 1988-11-21 | 1990-05-29 | Kao Corp | 柔軟仕上剤 |
JPH02169769A (ja) * | 1988-12-19 | 1990-06-29 | Kao Corp | 柔軟仕上剤 |
DE3905754A1 (de) * | 1989-02-24 | 1990-08-30 | Ht Maschvertrieb Gmbh | Hatem-wendezahngliederband |
US5066414A (en) * | 1989-03-06 | 1991-11-19 | The Procter & Gamble Co. | Stable biodegradable fabric softening compositions containing linear alkoxylated alcohols |
GB8914054D0 (en) * | 1989-06-19 | 1989-08-09 | Unilever Plc | Fabric softening composition |
ES2021900A6 (es) * | 1989-07-17 | 1991-11-16 | Pulcra Sa | Procedimiento de obtencion de tensioactivos cationicos derivados de amonio cuaternario con funcion amino-ester. |
GB8916307D0 (en) * | 1989-07-17 | 1989-08-31 | Unilever Plc | Fabric softening composition |
GB8916306D0 (en) * | 1989-07-17 | 1989-08-31 | Unilever Plc | Fabric softening composition |
ZA907746B (en) * | 1989-10-16 | 1992-05-27 | Colgate Palmolive Co | New softening compositions and methods for making and using same |
DE4004294A1 (de) * | 1990-02-13 | 1991-08-14 | Henkel Kgaa | Wirkstoff-kombination zur textilbehandlung |
DE4015849A1 (de) * | 1990-05-17 | 1991-11-21 | Henkel Kgaa | Quaternierte ester |
JP2763651B2 (ja) * | 1990-06-06 | 1998-06-11 | 花王株式会社 | 柔軟仕上剤 |
JPH0768669B2 (ja) * | 1990-10-05 | 1995-07-26 | 花王株式会社 | 濃縮型柔軟仕上剤 |
GB9106308D0 (en) * | 1991-03-25 | 1991-05-08 | Unilever Plc | Fabric softening composition |
JP2956274B2 (ja) * | 1991-05-10 | 1999-10-04 | ライオン株式会社 | 液体柔軟剤組成物 |
JP2970132B2 (ja) * | 1991-10-04 | 1999-11-02 | ライオン株式会社 | 液体柔軟剤組成物 |
FR2693665B1 (fr) † | 1992-07-17 | 1994-09-23 | Stepan Europe | Compositions tensioactives cationiques, à base de mono ou polyalkyl ester et/ou amido ammonium, et leurs procédés de préparation. |
ES2094893T3 (es) † | 1991-12-31 | 1997-02-01 | Stepan Europe | Tensioactivos a base de compuestos de amonio cuaternario, procedimientos de preparacion, bases, y composiciones suavizantes derivadas. |
WO1993017085A1 (en) * | 1992-02-20 | 1993-09-02 | Akzo Nobel N.V. | Biodegradable fabric softeners |
DE4212156A1 (de) * | 1992-04-10 | 1993-10-14 | Henkel Kgaa | Wäßrige Textil-Behandlungsmittel mit geringer Viskosität |
CA2147840A1 (en) * | 1992-10-26 | 1994-05-11 | Errol Hoffman Wahl | Fabric softeners containing dyes for reduced staining |
US5474690A (en) * | 1994-11-14 | 1995-12-12 | The Procter & Gamble Company | Concentrated biodegradable quaternary ammonium fabric softener compositions containing intermediate iodine value fatty acid chains |
-
1994
- 1994-02-23 EP EP94910160A patent/EP0687291B2/en not_active Expired - Lifetime
- 1994-02-23 DK DK94910160T patent/DK0687291T4/da active
- 1994-02-23 ES ES94910160T patent/ES2144515T5/es not_active Expired - Lifetime
- 1994-02-23 JP JP6520037A patent/JPH08507766A/ja not_active Withdrawn
- 1994-02-23 CN CN94191846.7A patent/CN1066188C/zh not_active Expired - Lifetime
- 1994-02-23 AT AT94910160T patent/ATE191743T1/de active
- 1994-02-23 BR BR9405945A patent/BR9405945A/pt not_active IP Right Cessation
- 1994-02-23 CA CA002157178A patent/CA2157178C/en not_active Expired - Lifetime
- 1994-02-23 WO PCT/US1994/001936 patent/WO1994020597A1/en active IP Right Grant
- 1994-02-23 DE DE69423963T patent/DE69423963T3/de not_active Expired - Lifetime
- 1994-02-23 PT PT94910160T patent/PT687291E/pt unknown
- 1994-02-23 AU AU62712/94A patent/AU6271294A/en not_active Abandoned
-
1995
- 1995-02-28 US US08/395,261 patent/US5562849A/en not_active Expired - Lifetime
- 1995-02-28 US US08/395,263 patent/US5574179A/en not_active Expired - Lifetime
- 1995-06-05 US US08/461,207 patent/US5545340A/en not_active Expired - Lifetime
- 1995-08-31 NO NO953415A patent/NO305020B1/no unknown
- 1995-08-31 FI FI954084A patent/FI954084A/fi unknown
-
2000
- 2000-04-13 GR GR20000400861T patent/GR3033212T3/el unknown
- 2000-05-31 CN CN00117898.9A patent/CN1288986A/zh active Pending
- 2000-05-31 CN CN00117897.0A patent/CN1288985A/zh active Pending
-
2005
- 2005-12-21 JP JP2005368678A patent/JP3902783B2/ja not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4781527B2 (ja) * | 1997-07-29 | 2011-09-28 | ザ プロクター アンド ギャンブル カンパニー | アミン布地柔軟剤を含有する濃縮された安定な、好ましくは透明な布地柔軟組成物 |
JP2012082538A (ja) * | 2010-10-07 | 2012-04-26 | Lion Corp | 液体柔軟剤組成物 |
Also Published As
Publication number | Publication date |
---|---|
EP0687291B1 (en) | 2000-04-12 |
EP0687291A1 (en) | 1995-12-20 |
DE69423963D1 (de) | 2000-05-18 |
DK0687291T4 (da) | 2005-12-05 |
CN1288985A (zh) | 2001-03-28 |
WO1994020597A1 (en) | 1994-09-15 |
CA2157178A1 (en) | 1994-09-15 |
FI954084A0 (fi) | 1995-08-31 |
DE69423963T2 (de) | 2000-11-16 |
JP2006138063A (ja) | 2006-06-01 |
NO305020B1 (no) | 1999-03-22 |
DE69423963T3 (de) | 2006-05-24 |
US5574179A (en) | 1996-11-12 |
CN1288986A (zh) | 2001-03-28 |
CA2157178C (en) | 2002-08-20 |
NO953415D0 (no) | 1995-08-31 |
ATE191743T1 (de) | 2000-04-15 |
GR3033212T3 (en) | 2000-08-31 |
CN1066188C (zh) | 2001-05-23 |
ES2144515T3 (es) | 2000-06-16 |
BR9405945A (pt) | 1996-01-30 |
DK0687291T3 (da) | 2000-07-03 |
PT687291E (pt) | 2000-09-29 |
NO953415L (no) | 1995-11-01 |
JP3902783B2 (ja) | 2007-04-11 |
FI954084A (fi) | 1995-08-31 |
AU6271294A (en) | 1994-09-26 |
US5545340A (en) | 1996-08-13 |
EP0687291B2 (en) | 2005-08-24 |
ES2144515T5 (es) | 2006-03-16 |
US5562849A (en) | 1996-10-08 |
CN1121352A (zh) | 1996-04-24 |
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