JP5681488B2 - フッ素樹脂フィルム及びそれを含む成形品 - Google Patents
フッ素樹脂フィルム及びそれを含む成形品 Download PDFInfo
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- JP5681488B2 JP5681488B2 JP2010516865A JP2010516865A JP5681488B2 JP 5681488 B2 JP5681488 B2 JP 5681488B2 JP 2010516865 A JP2010516865 A JP 2010516865A JP 2010516865 A JP2010516865 A JP 2010516865A JP 5681488 B2 JP5681488 B2 JP 5681488B2
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- Prior art keywords
- film
- fluororesin
- acrylate
- meth
- weight
- Prior art date
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- 239000004925 Acrylic resin Substances 0.000 claims description 92
- 229920000178 Acrylic resin Polymers 0.000 claims description 92
- 229910052731 fluorine Inorganic materials 0.000 claims description 53
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 52
- 239000011737 fluorine Substances 0.000 claims description 52
- 125000000217 alkyl group Chemical group 0.000 claims description 42
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 35
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- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 68
- -1 acrylate ester Chemical class 0.000 description 64
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- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 8
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- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 8
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
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- 239000011734 sodium Substances 0.000 description 7
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- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 6
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 6
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- 238000010558 suspension polymerization method Methods 0.000 description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 5
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 5
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 description 5
- YHAIUSTWZPMYGG-UHFFFAOYSA-L disodium;2,2-dioctyl-3-sulfobutanedioate Chemical compound [Na+].[Na+].CCCCCCCCC(C([O-])=O)(C(C([O-])=O)S(O)(=O)=O)CCCCCCCC YHAIUSTWZPMYGG-UHFFFAOYSA-L 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- QTKPMCIBUROOGY-UHFFFAOYSA-N 2,2,2-trifluoroethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(F)(F)F QTKPMCIBUROOGY-UHFFFAOYSA-N 0.000 description 4
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 4
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 description 4
- 125000005396 acrylic acid ester group Chemical group 0.000 description 4
- 230000032683 aging Effects 0.000 description 4
- 238000000149 argon plasma sintering Methods 0.000 description 4
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- XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 4
- 230000035882 stress Effects 0.000 description 4
- 238000010557 suspension polymerization reaction Methods 0.000 description 4
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 description 3
- FMQPBWHSNCRVQJ-UHFFFAOYSA-N 1,1,1,3,3,3-hexafluoropropan-2-yl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C(F)(F)F)C(F)(F)F FMQPBWHSNCRVQJ-UHFFFAOYSA-N 0.000 description 3
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 3
- VCYCUECVHJJFIQ-UHFFFAOYSA-N 2-[3-(benzotriazol-2-yl)-4-hydroxyphenyl]ethyl 2-methylprop-2-enoate Chemical class CC(=C)C(=O)OCCC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 VCYCUECVHJJFIQ-UHFFFAOYSA-N 0.000 description 3
- 239000004342 Benzoyl peroxide Substances 0.000 description 3
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 3
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- 235000010323 ascorbic acid Nutrition 0.000 description 3
- 229960005070 ascorbic acid Drugs 0.000 description 3
- 239000011668 ascorbic acid Substances 0.000 description 3
- 239000011324 bead Substances 0.000 description 3
- 235000019400 benzoyl peroxide Nutrition 0.000 description 3
- 238000012662 bulk polymerization Methods 0.000 description 3
- 239000001506 calcium phosphate Substances 0.000 description 3
- 239000003638 chemical reducing agent Substances 0.000 description 3
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- 238000007429 general method Methods 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
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- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 3
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- 150000002978 peroxides Chemical class 0.000 description 3
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 3
- 239000005060 rubber Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- PQUXFUBNSYCQAL-UHFFFAOYSA-N 1-(2,3-difluorophenyl)ethanone Chemical compound CC(=O)C1=CC=CC(F)=C1F PQUXFUBNSYCQAL-UHFFFAOYSA-N 0.000 description 2
- VBHXIMACZBQHPX-UHFFFAOYSA-N 2,2,2-trifluoroethyl prop-2-enoate Chemical compound FC(F)(F)COC(=O)C=C VBHXIMACZBQHPX-UHFFFAOYSA-N 0.000 description 2
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 2
- DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical compound CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 description 2
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 2
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- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 2
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 2
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- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
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- 238000004090 dissolution Methods 0.000 description 2
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- GFJVXXWOPWLRNU-UHFFFAOYSA-N ethenyl formate Chemical compound C=COC=O GFJVXXWOPWLRNU-UHFFFAOYSA-N 0.000 description 2
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- SONHXMAHPHADTF-UHFFFAOYSA-M sodium;2-methylprop-2-enoate Chemical compound [Na+].CC(=C)C([O-])=O SONHXMAHPHADTF-UHFFFAOYSA-M 0.000 description 2
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- AFFZTFNQQHNSEG-UHFFFAOYSA-N trifluoromethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(F)(F)F AFFZTFNQQHNSEG-UHFFFAOYSA-N 0.000 description 2
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- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
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- LYBIZMNPXTXVMV-UHFFFAOYSA-N propan-2-yl prop-2-enoate Chemical compound CC(C)OC(=O)C=C LYBIZMNPXTXVMV-UHFFFAOYSA-N 0.000 description 1
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- 235000010288 sodium nitrite Nutrition 0.000 description 1
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- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/28—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/308—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising acrylic (co)polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
- C08L33/16—Homopolymers or copolymers of esters containing halogen atoms
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/24—All layers being polymeric
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2270/00—Resin or rubber layer containing a blend of at least two different polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/412—Transparent
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/536—Hardness
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/712—Weather resistant
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2605/00—Vehicles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2605/00—Vehicles
- B32B2605/003—Interior finishings
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/22—Esters containing halogen
- C08F220/24—Esters containing halogen containing perhaloalkyl radicals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
- C08J2333/14—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
- C08J2333/16—Homopolymers or copolymers of esters containing halogen atoms
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
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- C—CHEMISTRY; METALLURGY
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- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/16—Homopolymers or copolymers or vinylidene fluoride
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- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
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- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
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- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
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- Manufacture Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
アクリル系弾性体グラフト共重合体(a−1)が、アクリル酸アルキルエステル50〜99.9重量%、共重合可能な他のビニル系単量体0〜49.9重量%および共重合可能な1分子当たり2個以上の非共役二重結合を有する多官能性単量体0.1〜10重量%からなる単量体混合物(a−1a)を重合してなる少なくとも一層のアクリル酸エステル系架橋弾性体5〜85重量部の存在下に、
メタクリル酸アルキルエステル50〜100重量%および共重合可能な他のビニル系単量体0〜50重量%からなる単量体混合物(a−1b)を95〜15重量部共重合してなる[(a−1a)および(a−1b)の合計量が100重量部]ものであり、
メタクリル系重合体(a−2)が、メタクリル酸アルキルエステル80〜100重量%および共重合可能な他のビニル系単量体0〜20重量%からなる単量体混合物を共重合してなるものであることが好ましい。
一般式(1)で示す紫外線吸収剤としては、例えば、2−(2’−ヒドロキシ−5’−メタクリロイルオキシエチルフェニル)−2H−ベンゾトリアゾ-ル類であり、2−(2’−ヒドロキシ−5’−アクリロイルオキシエチルフェニル)−2H−ベンゾトリアゾ-ル、2−(2’−ヒドロキシ−5’−メタクリロイルオキシエチルフェニル)−2H−ベンゾトリアゾ-ル、2−(2’−ヒドロキシ−5’−メタクリロイルオキシエチルフェニル)−5−クロロ−2H−ベンゾトリアゾ-ル、2−(2’−ヒドロキシ−5’−メタクリロイルオキシプロピルフェニル)−2H−ベンゾトリアゾ-ル、2−(2’−ヒドロキシ−5’−メタクリロイルオキシエチル−3’−t−ブチルフェニル)12H−ベンゾトリアゾ-ル等が挙げられる。これらのうちでは、コストおよび取り扱い性から、2−(2’−ヒドロキシ−5’−メタクリロイルオキシエチルフェニル)−2H−ベンゾトリアゾ-ルが好ましい。
得られたフィルムを、透過型電子顕微鏡(日本電子製JEM−1200EX)にて、加速電圧80kV、RuO4染色超薄切片法で撮影し、得られた写真からアクリル酸エステル系架橋弾性体粒子画像を無作為に100個選択し、それらの粒子径の平均値を求めた。
日機装株式会社製 Microtrac粒度分布測定装置MT3000を使用し、ラテックス状態で光散乱法を用いて測定した。
得られたフィルムの透明性は、JIS K6714に準じて、温度23℃±2℃、湿度50%±5%の条件下にて、曇価(ヘイズ)を測定した。
<耐キシレン性>
得られたフィルム上にキシレンを一滴(0.02g)垂らし、フィルムの変化を目視で評価した。
○:変化が全く認められない。
△:微小な滴下跡が認められる。
×:表面の劣化が酷く、滴下跡がはっきり認められる。
<耐日焼け止め剤性[耐コパトーン(登録商標)性](試験法1)>
得られたフィルム上に日焼け止め剤(コパトーン ウォーター・ベイビーズ・ローションSPF50)を少量塗布し、その上にガーゼを押し当て、500gの加重をかける。そのまま室温で1時間放置した後、オーブンで54℃、64℃、74℃で1時間加熱した後、付着した日焼け止め剤をガーゼでふき取り、フィルムを水洗し、目視で塗布部の変化を観測した。
○:変化が認められない。
△:微小な塗布跡が認められる。
×:表面の劣化が酷く、塗布跡がはっきり認められる。
得られたフィルム上に日焼け止め剤(コパトーン ウォーター・ベイビーズ・ローションSPF50)を一滴(0.005g)滴下し、2×3cmの範囲に刷毛を用いて延ばし、70℃、80℃、90℃で24時間放置した後、付着した日焼け止め剤をガーゼでふき取り、フィルムを水洗、目視で塗布部の変化を観測した。
○:変化が認められない。
△:微小な塗布跡が認められる。
×:表面の劣化が酷く、塗布跡がはっきり認められる。
得られたフィルム上に10%乳酸水溶液を一滴垂らし、80℃の温度条件化で24時間放置後、フィルムを水洗し、フィルムの変化を目視で評価した。
○:変化が全く認められない。
△:微小なピンホール状の溶解跡が認められる。
×:表面の劣化が酷く、溶解跡がはっきり認められる。
得られたフィルムを1回180度折り曲げて、折り曲げ部の変化を目視で評価した。
○:割れが認められない。
△:僅かに割れが発生する。
×:フィルムが割れ、完全に破断する。
得られたフィルムを1回180度折り曲げて、折り曲げ部の変化を目視で評価した。
○:白化が認められない。
△:光を透過した時に僅かに白化が認められる。
×:白化が認められる。
得られたフィルムの表面硬度は、JIS K5600−5−4に従い、鉛筆硬度を測定して評価した。
<フィルム連続成形性の評価:(評価法1)>
フィルム成形を2時間連続して行い、その運転状況を観察し、以下の基準により評価を行った。
○:フィルムの厚みが均一で、フィルムが破断せずに成形できる。
×:フィルムの厚みが不均一、またはフィルム破断が発生する。
積層フィルム成形を行い、その外観性を観察し、以下の基準により評価を行った。
○:表面層樹脂の展開性が均一であり、メルトフラクチャーによる界面ムラがない。
×:表面層樹脂の展開性が不均一であり、メルトフラクチャーによる界面ムラが発生する。
<耐熱老化性の評価>
得られたフィルムを、80℃の恒温槽にて168時間放置し、フィルムの状態を目視で評価、および透明性についてJIS K6714に準じて、温度23℃±2℃、湿度50%±5%の条件下にて、曇価(ヘイズ)を測定した。
○:変化が全く認められない。
△:熱によるフィルムの変形が僅かに認められる。
×:フィルムが白化、または熱により表面荒れや変形が発生する。
<含フッ素アルキル(メタ)アクリレートポリマー(b−1)>
分散容器に、脱イオン水300部、ポリビニルアルコール2部を入れた。これとは別に、2,2,2−トリフルオロエチルメタクリレート95部、エチレングリコールジメタクリレート5部およびラウリルパーオキサイド1部からなる単量体溶液を調製し、上記の分散容器に加えた。得られた混合液に対してホモミキサーを用いて分散処理を行い、液滴径を100nmに調整した分散液を得た。
上記の方法にて得られた含フッ素アルキル(メタ)アクリレートポリマー(b−1)を使用し、シリンダ温度を200℃に温度調整した40mmφ単軸押出機(大阪精機工作(株)製)を使用し、スクリュー回転数75rpm、吐出量10kg/時間にて溶融混練を行い、ストランド状に引き取り、水槽にて冷却後、ペレタイザーを用いて切断して、フッ素樹脂の樹脂ペレット(C−1)を製造した。
フッ素樹脂として、得られた含フッ素アルキル(メタ)アクリレートポリマー(b−1)を使用し、シリンダ温度200〜240℃、スクリュー回転数125rpm、吐出量15kg/時間に変更した以外は、製造例1と同様の操作にてフッ素樹脂の樹脂ペレット(C−2)を製造した。
<アクリル系弾性体グラフト共重合体(a1−1)>
攪拌機付き8L重合装置に、以下の物質を仕込んだ。
脱イオン水 200部
ジオクチルスルフォコハク酸ナトリウム 0.25部
ソディウムホルムアルデヒドスルフォキシレ−ト 0.15部
エチレンジアミン四酢酸−2−ナトリウム 0.001部
硫酸第一鉄 0.00025部
重合機内を窒素ガスで充分に置換し実質的に酸素のない状態とした後、内温を60℃にし、下記単量体混合物(a1−1a)30重量部および2−(2’−ヒドロキシ−5’−メタクリロイルオキシエチルフェニル)−2−H−ベンゾトリアゾール(大塚化学(株)製、RUVA−93)0.5部からなる混合物を10重量部/時間の割合で連続的に添加し、添加終了後、さらに0.5時間重合を継続し、アクリル酸エステル系架橋弾性体粒子(平均粒子径d=60nm)を得た。重合転化率は99.5%であった。
単量体混合物(a1−1a):
・ビニル系単量体混合物(アクリル酸ブチル(BA)90%およびメタクリル酸メチル(MMA)10%) 100部
・アリルメタクリレート(AlMA) 1部
・クメンハイドロパーオキサイド(CHP) 0.2部
その後、ジオクチルスルフォコハク酸ナトリウム0.05重量部を仕込んだ後、内温を60℃にし、ビニル系単量体混合物(BA10%およびMMA90%)100部、ターシャリードデシルメルカプタン(t−DM)0.5部およびCHP0.5部からなる単量体混合物(a1−1b)70部を10部/時間の割合で連続的に添加し、さらに1時間重合を継続し、アクリル系弾性体グラフト共重合体(a1−1)(平均粒子径=180μm)を得た。重合転化率は98.2%であった。得られたラテックスを塩化カルシウムで塩析、凝固し、水洗、乾燥して樹脂粉末(a1−1)を得た。
メタクリル系重合体(a1−2)として、メタクリル酸メチル/アクリル酸メチル共重合体(住友化学(株)製、スミペックスLG、ビーズ状物)を使用した。
上記の如く得られたアクリル系弾性体グラフト共重合体(a1−1)70部およびメタクリル系重合体(a1−2)30部をヘンシェルミキサーを用いて混合した後、シリンダ温度を200℃〜260℃に温度調整した40mmφ単軸押出機(大阪精機工作(株)製)を使用し、スクリュー回転数90rpm、吐出量15kg/時間にて溶融混練を行い、ストランド状に引き取り、水槽にて冷却後、ペレタイザーを用いて切断して、アクリル系樹脂の樹脂ペレット(A−1)を製造した。
フッ素樹脂として、製造例1で得られた含フッ素アルキル(メタ)アクリレートポリマー(b−1)80部と製造例2で得られたアクリル系弾性体グラフト共重合体20部の混合物を使用した以外は、製造例2と同様の操作にて、フッ素樹脂の樹脂ペレット(C−3)を製造した。
<アクリル系弾性体グラフト共重合体(a2−1)>
攪拌機、温度計、窒素ガス導入管、モノマー供給管、還流冷却器を備えた8リットル重合機に以下の物質 を仕込んだ。
水(イオン交換水) 200部
ナトリウムホルムアルデヒドスルホキシレート 0.15部
硫酸第一鉄・2水塩 0.0015部
エチレンジアミン四酢酸−2−ナトリウム 0.006部
ジオクチルスルホコハク酸ナトリウム 0.0015部
重合器内を窒素ガスで十分に置換して実質的に酸素のない状態とした後、内温を60℃にし、ビニル系単量体混合物(BA84%、MMA8%およびスチレン(ST)8%)100部、AlMA1部およびCHP0.1部からなる単量体混合物(a2−1a)50部を15部/時間の割合で連続的に添加し、添加終了後、さらに1時間重合を継続し、アクリル酸エステル系架橋弾性体粒子(a2−1a)(平均粒子径d=210nm)を得た。重合転化率は98.5%であった。
メタクリル系重合体(a2−2)として、メタクリル酸メチル/アクリル酸メチル共重合体(住友化学(株)製、スミペックスEX、ビーズ状物)を使用した。
上記の如く得られたアクリル系弾性体グラフト共重合体(a2−1)25部およびメタクリル系重合体(a2−2)75部、紫外線吸収剤としてチヌビン234(チバジャパン製)1.0部をヘンシェルミキサーを用いて混合した後、シリンダ温度を240℃に温度調整した以外は、製造例2と同様にして、アクリル系樹脂の樹脂ペレット(A−2)を製造した。
フッ素樹脂として、ポリフッ化ビニリデン(SOLVAY社製、SOLEF−1008)100部のみを用い、シリンダ温度を260℃に変更した以外は、製造例2と同様の方法にて、フッ素樹脂の樹脂ペレット(C−4)を製造した。
フッ素樹脂として、エチレン−テトラフルオロエチレン共重合体(旭硝子(株)製、フルオンETFE AH−2000)100部のみを用いた以外は、比較製造例2と同様の方法にて、フッ素樹脂の樹脂ペレット(C−5)を製造した。
フッ素樹脂として、製造例1で得られた含フッ素アルキル(メタ)アクリレートポリマー(b−1)100部とポリフッ化ビニリデン10部の混合物を使用した以外は、製造例3と同様の操作にてフッ素樹脂の樹脂ペレット(C−6)を製造した。
フッ素樹脂として、製造例1で得られた含フッ素アルキル(メタ)アクリレートポリマー(b−1)100部とポリフッ化ビニリデン0.1部の混合物を使用した以外は、製造例1と同様の操作にてフッ素樹脂の樹脂ペレット(C−7)を製造した。
(実施例1)
製造例1で得られたフッ素樹脂の樹脂ペレット(C−1)を、Tダイ付40mmφ単軸押出機を用いて、シリンダ設定温度160〜220℃にて吐出量10kg/hrにて溶融混練し、ダイス温度240℃にて、厚み125μmの単層樹脂フィルムを得た。
製造例2で得られたフッ素樹脂の樹脂ペレット(C−2)を使用し、Tダイ付40mmφ単軸押出機のシリンダ設定温度180〜240℃に変更した以外は、実施例1と同様の操作にて、厚み125μmの単層樹脂フィルムを得た。
製造例2で得られたアクリル系樹脂の樹脂ペレット(A−1)を用いた以外は、実施例1と同様の操作にてアクリル系樹脂単層フィルムを得た。
比較製造例1で得られたフッ素樹脂の樹脂ペレット(C−4)を用いた以外は、実施例1と同様の操作にてフッ素樹脂単層フィルムを得た。
(実施例3)
製造例3で得られたアクリル系樹脂の樹脂ペレット(A−1)をベース樹脂とし、製造例2で得られたフッ素樹脂の樹脂ペレット(C−2)を表面層樹脂として、以下の共押出方法により、厚み125μm(ベース樹脂層110μmおよび表層樹脂層15μm)の積層フィルムを得た。
表面層樹脂を、製造例4で得られたフッ素樹脂の樹脂ペレット(C−3)に変更した以外は、実施例3と同様の操作により、積層フィルムを得た。
ベース樹脂を、製造例5で得られたアクリル系樹脂の樹脂ペレット(A−2)に変更した以外は、実施例3と同様の操作により、積層フィルムを得た。
表面層樹脂を、比較製造例1で得られたフッ素樹脂の樹脂ペレット(C−4)に変更した以外は、実施例3と同様の操作により、積層フィルムを得た。
表面層樹脂を、比較製造例2で得られたフッ素樹脂の樹脂ペレット(C−5)に変更した以外は、実施例3と同様の操作により、積層フィルムを得た。
(実施例6)
製造例6で得られたフッ素樹脂の樹脂ペレット(C−6)を用いた以外は、実施例2と同様の操作にてフッ素樹脂単層フィルムを得た。
(実施例7)
表面層樹脂を、製造例6で得られたフッ素樹脂の樹脂ペレット(C−6)に変更した以外は、実施例3と同様の操作により、積層フィルムを得た。
表面層樹脂を製造例7で得られたフッ素樹脂ペレット(C−7)に変更し、共押出に用いるTダイを2種2層Tダイ(スタックプレート方式)にした以外は、実施例3と同様の操作により、積層フィルムを得た。
表面層樹脂として、製造例6で得られたフッ素樹脂の樹脂ペレット(C−6)を使用し、積層フィルムの厚みをベース樹脂層85μmおよび表層樹脂層40μmに変更した以外は、実施例3と同様の操作により、積層フィルムを得た。
Claims (4)
- 含フッ素アルキル(メタ)アクリレートポリマー成分を含むフッ素系(メタ)アクリル樹脂(B)
を含むフッ素樹脂(C)を成形してなり、
前記フッ素樹脂(C)が、フッ素系(メタ)アクリル樹脂(B)100重量部に対し、0.1〜10重量部のポリフッ化ビニリデンを含有するか、又は、ポリフッ化ビニリデンを含有しないものであり、
前記含フッ素アルキル(メタ)アクリレートポリマー成分における含フッ素アルキル(メタ)アクリレートの含量が90重量%以上であり、
厚みが30〜300μmである、
フッ素樹脂フィルム。 - 含フッ素アルキル(メタ)アクリレートポリマー成分の含有量が、フッ素系(メタ)アクリル樹脂(B)100重量%において80重量%以上である、請求項1に記載のフッ素樹脂フィルム。
- フッ素系(メタ)アクリル樹脂(B)の溶融粘度が、JIS K7199に基づく、ダイス温度220℃、剪断速度122sec−1、キャピラリーダイ径1mmの条件下において300〜4000Pa・secである、請求項1又は2に記載のフッ素樹脂フィルム。
- 請求項1〜3のいずれかに記載のフッ素樹脂フィルムを積層してなる成形品。
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Families Citing this family (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102753587B (zh) * | 2010-02-17 | 2016-11-23 | 株式会社钟化 | 含氟(甲基)丙烯酸(共)聚合物及其膜成型体 |
JP2011168681A (ja) * | 2010-02-17 | 2011-09-01 | Kaneka Corp | フッ素系(メタ)アクリル樹脂、そのフッ素系樹脂組成物、そのフッ素系樹脂フィルムおよびフッ素系樹脂積層アクリル系樹脂フィルム |
WO2012074055A1 (ja) * | 2010-12-01 | 2012-06-07 | 日産化学工業株式会社 | 表面改質された押出成形フィルム |
KR101378187B1 (ko) * | 2011-05-19 | 2014-03-26 | 주식회사 엘지화학 | 내후성 및 표면오염성이 개선된 광확산 수지 조성물 |
KR101489996B1 (ko) | 2012-09-12 | 2015-02-12 | (주)엘지하우시스 | 고내후성 아크릴계 다층 필름 및 그 제조 방법 |
CN104736578B (zh) * | 2012-10-17 | 2017-03-15 | 三菱丽阳株式会社 | 丙烯酸树脂膜、使用该丙烯酸树脂膜的层叠体及太阳能电池模块 |
SG11201504914SA (en) | 2012-12-20 | 2015-07-30 | 3M Innovative Properties Co | Copolymers including ultraviolet absorbing groups and fluoropolymer compositions including them |
KR102194159B1 (ko) | 2012-12-20 | 2020-12-22 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | 자외선 흡수 기를 갖는 올리고머를 포함하는 플루오로중합체 조성물 |
WO2015174070A1 (ja) | 2014-05-15 | 2015-11-19 | 株式会社カネカ | フッ素含有アクリル樹脂からなるコーティング層を基材フィルムに積層させたフィルム |
CN106661365B (zh) | 2014-06-25 | 2019-03-01 | 3M创新有限公司 | 包含至少一种低聚物的含氟聚合物组合物 |
US11110689B2 (en) | 2014-06-25 | 2021-09-07 | 3M Innovative Properties Company | Pressure sensitive adhesive composition including ultraviolet light-absorbing oligomer |
JP6371684B2 (ja) * | 2014-11-14 | 2018-08-08 | 株式会社カネカ | 積層フィルム |
EP3398772B1 (en) * | 2014-11-26 | 2020-04-29 | Mitsubishi Chemical Corporation | Resin laminate film, method for manufacturing same, and melamine decorative panel |
WO2016125795A1 (ja) * | 2015-02-05 | 2016-08-11 | 旭硝子株式会社 | 感光性樹脂組成物、樹脂膜の製造方法、有機半導体素子の製造方法および含フッ素重合体 |
US10519350B2 (en) | 2015-06-25 | 2019-12-31 | 3M Innovative Properties Company | Copolymer including ultraviolet light-absorbing group and compositions including the same |
KR20180032609A (ko) | 2015-09-11 | 2018-03-30 | 미쯔비시 케미컬 주식회사 | 적층 필름 및 적층 성형품 |
US10442950B2 (en) * | 2017-05-18 | 2019-10-15 | Canon Kabushiki Kaisha | Film formed on a sliding surface of a component |
KR101934448B1 (ko) * | 2017-10-17 | 2019-01-02 | 에스케이씨 주식회사 | 편광판용 보호필름 및 이를 포함하는 액정표시장치 |
WO2019181752A1 (ja) | 2018-03-22 | 2019-09-26 | 株式会社カネカ | アクリル系樹脂フィルム、積層フィルム、積層フィルムの製造方法、及び成形品 |
KR102217744B1 (ko) * | 2019-04-05 | 2021-02-22 | 에스케이씨에코솔루션즈(주) | 불소 함유 시트 및 이를 포함하는 라미네이트 강판 |
CN110116508A (zh) * | 2019-04-19 | 2019-08-13 | 苏州亨利通信材料有限公司 | 用于电缆的铝塑复合带加工方法 |
CN115052919A (zh) | 2020-02-10 | 2022-09-13 | 电化株式会社 | 树脂膜及其制造方法 |
EP4382558A1 (en) | 2021-08-06 | 2024-06-12 | Denka Company Limited | Film having methacrylic acid ester-based resin as main component thereof |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60248762A (ja) * | 1984-05-23 | 1985-12-09 | Unitika Ltd | ポリ弗化ビニリデン系重合体組成物 |
JPH03157163A (ja) * | 1989-11-15 | 1991-07-05 | Nippon Oil & Fats Co Ltd | 高分子超薄膜およびその製造方法 |
JPH0524160A (ja) * | 1991-07-19 | 1993-02-02 | Mitsubishi Kasei Vinyl Co | 農業用軟質塩化ビニル系樹脂フイルム |
Family Cites Families (39)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4382985A (en) | 1980-10-11 | 1983-05-10 | Daikin Kogyo Co., Ltd. | Process for forming film of fluoroalkyl acrylate polymer on substrate and process for preparing patterned resist from the film |
JPS57187248A (en) | 1981-05-12 | 1982-11-17 | Kureha Chemical Ind Co Ltd | Laminate |
JPS5915411A (ja) * | 1982-07-16 | 1984-01-26 | Mitsubishi Rayon Co Ltd | メタクリル酸フルオロアルキル共重合体の製造法 |
JPS5931130A (ja) | 1982-08-17 | 1984-02-20 | Dainippon Printing Co Ltd | 射出成形同時絵付装置 |
JPS59116702A (ja) * | 1982-12-24 | 1984-07-05 | Mitsubishi Rayon Co Ltd | 光伝送性繊維 |
JPH0671785B2 (ja) | 1984-06-23 | 1994-09-14 | 電気化学工業株式会社 | フッ化ビニリデン樹脂系複合フイルムの製造方法 |
JPH0636339B2 (ja) | 1987-09-26 | 1994-05-11 | 株式会社日立製作所 | ガス絶縁開閉装置 |
JPH01129201A (ja) * | 1987-11-16 | 1989-05-22 | Mitsubishi Rayon Co Ltd | 屈折率分布型レンズアレイ |
JPH01304143A (ja) * | 1988-05-31 | 1989-12-07 | Nippon Penuoruto Kk | 塗装用組成物 |
JPH0251548A (ja) * | 1988-08-12 | 1990-02-21 | Mitsubishi Rayon Co Ltd | 熱可逆的曇点現象を示す高分子混合物 |
JPH03288640A (ja) * | 1990-04-05 | 1991-12-18 | Mitsubishi Rayon Co Ltd | 積層フィルム |
JPH049647A (ja) | 1990-04-26 | 1992-01-14 | Tdk Corp | 湿度センシング方法 |
US5183839A (en) | 1990-12-17 | 1993-02-02 | Allied-Signal Inc. | Fluoropolymers and fluoropolymer coatings |
JPH05185570A (ja) * | 1992-01-14 | 1993-07-27 | Mitsubishi Kasei Vinyl Co | 車両用成形部品 |
JP3328330B2 (ja) | 1992-09-02 | 2002-09-24 | 呉羽化学工業株式会社 | フッ化ビニリデン樹脂フィルム、その用途およびその製造方法 |
JP2725735B2 (ja) | 1993-06-22 | 1998-03-11 | 大日本印刷株式会社 | 射出成形同時絵付け方法及びそれに用いる絵付けフィルム |
JPH07126552A (ja) | 1993-10-29 | 1995-05-16 | Nippon Oil & Fats Co Ltd | 含フッ素硬化性塗液及び含フッ素硬化被膜 |
JP3203929B2 (ja) * | 1994-01-10 | 2001-09-04 | 三菱化学エムケーブイ株式会社 | 農業用ポリエチレンテレフタレートフィルム |
JP3526080B2 (ja) * | 1994-07-19 | 2004-05-10 | 大倉工業株式会社 | 半導電性フッ素樹脂組成物 |
JP3142774B2 (ja) | 1995-03-28 | 2001-03-07 | 三菱レイヨン株式会社 | アクリルフィルムおよびこれを用いたアクリル積層射出成型品 |
JP3287255B2 (ja) | 1996-02-16 | 2002-06-04 | 住友化学工業株式会社 | アクリルフィルムおよびそれを用いた成形体 |
JP3887879B2 (ja) * | 1997-06-06 | 2007-02-28 | ソニーケミカル&インフォメーションデバイス株式会社 | 含フッ素(メタ)アクリル系重合体の製造方法 |
JPH1134249A (ja) | 1997-07-18 | 1999-02-09 | Teijin Ltd | 農業用延伸フッ素樹脂フィルム |
JPH11174971A (ja) | 1997-12-15 | 1999-07-02 | Nof Corp | 反射防止ディスプレイ |
JP2000102950A (ja) | 1998-09-30 | 2000-04-11 | Kansai Paint Co Ltd | プラスチック成型用化粧フィルム及びそのフィルムを使用して得られる射出成型物品 |
DE19859393A1 (de) * | 1998-12-22 | 2000-06-29 | Roehm Gmbh | Verfahren zur Herstellung von Folien |
JP2003026734A (ja) | 2001-07-16 | 2003-01-29 | Dainippon Ink & Chem Inc | 活性エネルギー線硬化型組成物およびそれを用いた多層フィルム |
US6764799B2 (en) * | 2002-06-20 | 2004-07-20 | Xerox Corporation | Carrier compositions |
EP1582538B1 (en) * | 2003-01-10 | 2010-05-05 | Mitsubishi Rayon Co., Ltd. | Multilayer structure polymer and resin composition together with acrylic resin film material, acrylic resin laminate film, photocurable acrylic resin film or sheet, laminate film or sheet and laminate molding obtained by laminating thereof |
CN100424106C (zh) * | 2003-01-10 | 2008-10-08 | 三菱丽阳株式会社 | 多层构造聚合物及含有该聚合物的树脂组合物、膜状物、叠层膜或片 |
JP4406304B2 (ja) * | 2003-02-19 | 2010-01-27 | 三菱レイヨン株式会社 | 多層構造重合体及びこれを含む樹脂組成物、並びに、アクリル樹脂フィルム状物、アクリル樹脂積層フィルム、光硬化性アクリル樹脂フィルム又はシート、積層フィルム又はシート、及び、これらを積層した積層成形品 |
JP4177214B2 (ja) * | 2003-09-09 | 2008-11-05 | 関東電化工業株式会社 | 含フッ素共重合体及びその組成物、それらの被膜 |
FR2866652B1 (fr) * | 2004-02-20 | 2007-08-17 | Arkema | Composition coextrudable avec le pvdf et sans effet de blanchiment sous contrainte |
CN100482703C (zh) * | 2004-03-31 | 2009-04-29 | 株式会社钟化 | 甲基丙烯酸系树脂组合物、甲基丙烯酸系树脂薄膜与该薄膜层合氯乙烯系成型体 |
JP4958552B2 (ja) | 2004-08-11 | 2012-06-20 | 株式会社カネカ | フッ化ビニリデン系樹脂フィルム |
JP4539840B2 (ja) | 2004-12-15 | 2010-09-08 | 株式会社クラレ | 光硬化性樹脂組成物及びそれを用いた積層体の製造方法 |
WO2006132208A1 (ja) * | 2005-06-08 | 2006-12-14 | Kaneka Corporation | フッ素原子含有(メタ)アクリル酸エステル系重合体の製造方法及びその重合体 |
EP1908797B1 (en) * | 2005-07-05 | 2012-06-06 | Kaneka Corporation | Methacrylic resin composition |
JP2008049524A (ja) * | 2006-08-23 | 2008-03-06 | Kaneka Corp | 積層フィルム |
-
2009
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Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60248762A (ja) * | 1984-05-23 | 1985-12-09 | Unitika Ltd | ポリ弗化ビニリデン系重合体組成物 |
JPH03157163A (ja) * | 1989-11-15 | 1991-07-05 | Nippon Oil & Fats Co Ltd | 高分子超薄膜およびその製造方法 |
JPH0524160A (ja) * | 1991-07-19 | 1993-02-02 | Mitsubishi Kasei Vinyl Co | 農業用軟質塩化ビニル系樹脂フイルム |
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KR101346872B1 (ko) | 2014-01-02 |
CN102056984A (zh) | 2011-05-11 |
CN102056984B (zh) | 2014-07-16 |
CN102275366B (zh) | 2014-10-15 |
EP2325005A3 (en) | 2011-06-29 |
JP5698709B2 (ja) | 2015-04-08 |
EP2292692A4 (en) | 2014-06-18 |
US20110151229A1 (en) | 2011-06-23 |
CN102275366A (zh) | 2011-12-14 |
KR101228690B1 (ko) | 2013-02-01 |
US20110124816A1 (en) | 2011-05-26 |
US10253143B2 (en) | 2019-04-09 |
KR20110007252A (ko) | 2011-01-21 |
KR20110009223A (ko) | 2011-01-27 |
CN104044323A (zh) | 2014-09-17 |
EP2292692A1 (en) | 2011-03-09 |
JP5771713B2 (ja) | 2015-09-02 |
JP2014139019A (ja) | 2014-07-31 |
EP2325005A2 (en) | 2011-05-25 |
EP2325005B1 (en) | 2015-11-11 |
US9074058B2 (en) | 2015-07-07 |
JP2012187934A (ja) | 2012-10-04 |
CN104044323B (zh) | 2017-06-30 |
WO2009151071A1 (ja) | 2009-12-17 |
JPWO2009151071A1 (ja) | 2011-11-17 |
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