JP2017501303A5 - - Google Patents

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JP2017501303A5
JP2017501303A5 JP2016538624A JP2016538624A JP2017501303A5 JP 2017501303 A5 JP2017501303 A5 JP 2017501303A5 JP 2016538624 A JP2016538624 A JP 2016538624A JP 2016538624 A JP2016538624 A JP 2016538624A JP 2017501303 A5 JP2017501303 A5 JP 2017501303A5
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reactant
metal
gas phase
substrate
thin film
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Claims (29)

  1. 反応空間内で基板上に硫化マグネシウム薄膜を堆積する方法であって、当該方法は、
    気相マグネシウム反応物質を前記反応空間に提供する工程と、
    過剰な気相マグネシウム反応物質及び反応副生成物を除去する工程と、
    硫黄を含む第2の気相反応物質を前記反応空間に提供する工程と、
    過剰な第2の気相反応物質及び反応副生成物を除去する工程と、
    を含む、1つ以上の堆積サイクルを含む、方法。
  2. 前記気相マグネシウム反応物質を前記反応空間に提供する前に、前記第2の気相反応物質は、前記反応空間に提供される、請求項1に記載の方法。
  3. 前記硫化マグネシウム薄膜は、マグネシウム以外の少なくとも1種の金属を含む、請求項1に記載の方法。
  4. 前記気相マグネシウム反応物質は、少なくとも1つのシクロペンタジエニル(Cp)配位子を含む、請求項1に記載の方法。
  5. 前記気相マグネシウム反応物質はMg(Cp) 又はその誘導体である、請求項1に記載の方法。
  6. マグネシウムは、その上に前記硫化マグネシウム薄膜が形成されつつある前記基板の部分に存在しない、請求項1に記載の方法。
  7. 前記第2の気相反応物質はH Sである、請求項1に記載の方法。
  8. 前記第2の気相反応物質は、硫黄原子、硫黄含有プラズマ、又は硫黄ラジカルを含む、請求項1に記載の方法。
  9. 前記硫化マグネシウム薄膜が堆積される前記基板の表面は、ケイ素を含まない、請求項1に記載の方法。
  10. 前記硫化マグネシウム薄膜が堆積される前記基板の表面は、InGaAsを含む、請求項1に記載の方法。
  11. 前記硫化マグネシウム薄膜を堆積する前に、ex situ又はin situで前記基板を前処理反応物質に曝露する工程を更に含む、請求項1に記載の方法。
  12. 堆積された前記硫化マグネシウム薄膜は、約1Å〜約20Åの厚さを有する、請求項1に記載の方法。
  13. 反応空間内で基板の表面上に金属硫化物薄膜を堆積する方法であって、当該方法は、
    前記基板を第1の気相金属反応物質と接触させる工程と、
    過剰な気相金属反応物質及び反応副生成物を前記基板から除去する工程と、
    前記基板を第2の気相硫黄反応物質と接触させる工程と、
    過剰な気相硫黄反応物質及び反応副生成物を前記基板から除去する工程と、
    を含む、1つ以上の堆積サイクルを含み、
    前記気相金属反応物質は、シクロペンタジエニル(Cp)配位子又はβ−ジケトナート配位子と、Mg、Ca、Y、Sc、Sr、Ba、La、及びその他のランタニドからなる群から選択される金属と、を含む、
    方法。
  14. 前記第1の気相金属反応物質を前記反応空間に導入する前に、前記第2の気相硫黄反応物質は、前記反応空間に導入される、請求項13に記載の方法。
  15. 前記第1の気相金属反応物質は、少なくとも1つのシクロペンタジエニル(Cp)配位子を含む、請求項13に記載の方法。
  16. 前記第1の気相金属反応物質の金属はMgである、請求項13に記載の方法。
  17. 前記第1の気相金属反応物質はMg(Cp) 又はその誘導体である、請求項13に記載の方法。
  18. 前記第1の気相金属反応物質は、シクロペンタジエニル(Cp)又はその誘導体を含み、前記金属は、Ca、La若しくはその他のランタニド、Sc、又はYである、請求項13に記載の方法。
  19. 前記第1の気相金属反応物質は、その上に前記金属硫化物薄膜が形成されつつある前記基板の部分に存在しない金属を含む、請求項13に記載の方法。
  20. 前記第2の気相硫黄反応物質はH Sである、請求項13に記載の方法。
  21. 前記第2の気相硫黄反応物質は、硫黄原子、硫黄含有プラズマ、又は硫黄ラジカルを含む、請求項13に記載の方法。
  22. 前記金属硫化物薄膜はMgSを含む、請求項13に記載の方法。
  23. 前記金属硫化物薄膜が堆積される前記基板の表面は、ケイ素を含まない、請求項13に記載の方法。
  24. 前記金属硫化物薄膜は、1種を超える金属を含む、請求項13に記載の方法。
  25. 前記金属硫化物薄膜を堆積する前に、ex situ又はin situで前記基板を前処理反応物質に曝露する工程を更に含む、請求項13に記載の方法。
  26. 堆積された前記金属硫化物薄膜は、約1Å〜約20Åの厚さを有する、請求項13に記載の方法。
  27. 反応空間内で基板の表面上に金属硫化物薄膜を堆積する方法であって、当該方法は、
    前記基板を第1の気相金属反応物質と接触させる工程と、
    過剰な気相金属反応物質及び反応副生成物を前記基板から除去する工程と、
    前記基板を第2の気相硫黄反応物質と接触させる工程と、
    過剰な気相硫黄反応物質及び反応副生成物を前記基板から除去する工程と、
    を順に含む、1つ以上の堆積サイクルを含み、
    前記第1の気相金属反応物質は、Mg、Ca、Y、Sc、Sr、Ba、La、及びその他のランタニドからなる群から選択される金属を含み、
    前記金属硫化物薄膜が堆積される前記基板の表面は、InGaAsを含む、
    方法。
  28. 過剰な反応物質を除去するステップは、前記基板をパージガスに曝露するステップを含む、請求項27に記載の方法。
  29. 過剰な反応物質を除去するステップは、前記基板をパージガスに曝露するステップを含む、請求項13に記載の方法。
JP2016538624A 2013-12-18 2014-11-19 硫黄含有薄膜 Active JP6408584B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US14/133,509 2013-12-18
US14/133,509 US9245742B2 (en) 2013-12-18 2013-12-18 Sulfur-containing thin films
PCT/US2014/066316 WO2015094551A1 (en) 2013-12-18 2014-11-19 Sulfur-containing thin films

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JP2017501303A JP2017501303A (ja) 2017-01-12
JP2017501303A5 true JP2017501303A5 (ja) 2017-11-30
JP6408584B2 JP6408584B2 (ja) 2018-10-17

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KR (1) KR102195954B1 (ja)
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