JP2015502967A5 - - Google Patents
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- JP2015502967A5 JP2015502967A5 JP2014548048A JP2014548048A JP2015502967A5 JP 2015502967 A5 JP2015502967 A5 JP 2015502967A5 JP 2014548048 A JP2014548048 A JP 2014548048A JP 2014548048 A JP2014548048 A JP 2014548048A JP 2015502967 A5 JP2015502967 A5 JP 2015502967A5
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- Prior art keywords
- alkyl
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- cycloalkyl
- groups
- Prior art date
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- 125000001424 substituent group Chemical group 0.000 claims description 185
- 150000001875 compounds Chemical class 0.000 claims description 147
- 125000005842 heteroatom Chemical group 0.000 claims description 147
- 125000000623 heterocyclic group Chemical group 0.000 claims description 124
- 229910052739 hydrogen Inorganic materials 0.000 claims description 121
- 239000001257 hydrogen Substances 0.000 claims description 121
- 229910052760 oxygen Inorganic materials 0.000 claims description 100
- 150000002431 hydrogen Chemical class 0.000 claims description 99
- 229910052717 sulfur Inorganic materials 0.000 claims description 96
- 229910052736 halogen Inorganic materials 0.000 claims description 86
- 150000002367 halogens Chemical class 0.000 claims description 86
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 79
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 78
- 229920006395 saturated elastomer Polymers 0.000 claims description 76
- 229910052799 carbon Inorganic materials 0.000 claims description 68
- 125000001931 aliphatic group Chemical group 0.000 claims description 53
- -1 C 1 -C 6 - alkyl Chemical group 0.000 claims description 50
- 229910052757 nitrogen Inorganic materials 0.000 claims description 46
- 125000002911 monocyclic heterocycle group Chemical group 0.000 claims description 43
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 38
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 38
- 238000000034 method Methods 0.000 claims description 37
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 34
- 150000003839 salts Chemical class 0.000 claims description 34
- 125000004432 carbon atom Chemical group C* 0.000 claims description 28
- 125000002723 alicyclic group Chemical group 0.000 claims description 26
- 241000607479 Yersinia pestis Species 0.000 claims description 22
- 125000002618 bicyclic heterocycle group Chemical group 0.000 claims description 22
- 125000000232 haloalkynyl group Chemical group 0.000 claims description 21
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 18
- 125000004438 haloalkoxy group Chemical group 0.000 claims description 15
- 239000000463 material Substances 0.000 claims description 14
- 239000002243 precursor Substances 0.000 claims description 14
- 125000000217 alkyl group Chemical group 0.000 claims description 13
- 241001465754 Metazoa Species 0.000 claims description 10
- 125000004076 pyridyl group Chemical group 0.000 claims description 10
- 125000000304 alkynyl group Chemical group 0.000 claims description 9
- 125000003342 alkenyl group Chemical group 0.000 claims description 8
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 8
- KWEDUNSJJZVRKR-UHFFFAOYSA-N carbononitridic azide Chemical compound [N-]=[N+]=NC#N KWEDUNSJJZVRKR-UHFFFAOYSA-N 0.000 claims description 8
- 125000004122 cyclic group Chemical group 0.000 claims description 8
- 229910052731 fluorine Inorganic materials 0.000 claims description 8
- 125000001072 heteroaryl group Chemical group 0.000 claims description 8
- 230000009545 invasion Effects 0.000 claims description 8
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims description 8
- 125000001981 tert-butyldimethylsilyl group Chemical group [H]C([H])([H])[Si]([H])(C([H])([H])[H])[*]C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 8
- HTSGKJQDMSTCGS-UHFFFAOYSA-N 1,4-bis(4-chlorophenyl)-2-(4-methylphenyl)sulfonylbutane-1,4-dione Chemical compound C1=CC(C)=CC=C1S(=O)(=O)C(C(=O)C=1C=CC(Cl)=CC=1)CC(=O)C1=CC=C(Cl)C=C1 HTSGKJQDMSTCGS-UHFFFAOYSA-N 0.000 claims description 6
- LMBFAGIMSUYTBN-MPZNNTNKSA-N teixobactin Chemical compound C([C@H](C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H](CCC(N)=O)C(=O)N[C@H]([C@@H](C)CC)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H]1C(N[C@@H](C)C(=O)N[C@@H](C[C@@H]2NC(=N)NC2)C(=O)N[C@H](C(=O)O[C@H]1C)[C@@H](C)CC)=O)NC)C1=CC=CC=C1 LMBFAGIMSUYTBN-MPZNNTNKSA-N 0.000 claims description 6
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 6
- 125000003118 aryl group Chemical group 0.000 claims description 5
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- 238000005580 one pot reaction Methods 0.000 claims description 5
- 239000002689 soil Substances 0.000 claims description 5
- FKLJPTJMIBLJAV-UHFFFAOYSA-N Compound IV Chemical compound O1N=C(C)C=C1CCCCCCCOC1=CC=C(C=2OCCN=2)C=C1 FKLJPTJMIBLJAV-UHFFFAOYSA-N 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- NLFBCYMMUAKCPC-KQQUZDAGSA-N ethyl (e)-3-[3-amino-2-cyano-1-[(e)-3-ethoxy-3-oxoprop-1-enyl]sulfanyl-3-oxoprop-1-enyl]sulfanylprop-2-enoate Chemical compound CCOC(=O)\C=C\SC(=C(C#N)C(N)=O)S\C=C\C(=O)OCC NLFBCYMMUAKCPC-KQQUZDAGSA-N 0.000 claims description 4
- 239000012025 fluorinating agent Substances 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 125000006413 ring segment Chemical group 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 125000004390 alkyl sulfonyl group Chemical group 0.000 claims description 3
- 125000002837 carbocyclic group Chemical group 0.000 claims description 3
- 150000001204 N-oxides Chemical class 0.000 claims description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 2
- 125000006615 aromatic heterocyclic group Chemical group 0.000 claims description 2
- 125000004429 atom Chemical group 0.000 claims description 2
- 238000009395 breeding Methods 0.000 claims description 2
- 230000001488 breeding effect Effects 0.000 claims description 2
- 125000004995 haloalkylthio group Chemical group 0.000 claims description 2
- 230000003301 hydrolyzing effect Effects 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 150000002466 imines Chemical class 0.000 claims description 2
- 239000011593 sulfur Substances 0.000 claims description 2
- 125000000171 (C1-C6) haloalkyl group Chemical group 0.000 claims 43
- 125000003601 C2-C6 alkynyl group Chemical group 0.000 claims 26
- SNOOUWRIMMFWNE-UHFFFAOYSA-M sodium;6-[(3,4,5-trimethoxybenzoyl)amino]hexanoate Chemical compound [Na+].COC1=CC(C(=O)NCCCCCC([O-])=O)=CC(OC)=C1OC SNOOUWRIMMFWNE-UHFFFAOYSA-M 0.000 claims 26
- 125000004737 (C1-C6) haloalkoxy group Chemical group 0.000 claims 24
- 125000000882 C2-C6 alkenyl group Chemical group 0.000 claims 23
- 125000005913 (C3-C6) cycloalkyl group Chemical group 0.000 claims 21
- 125000006552 (C3-C8) cycloalkyl group Chemical group 0.000 claims 21
- 125000004765 (C1-C4) haloalkyl group Chemical group 0.000 claims 15
- 125000004767 (C1-C4) haloalkoxy group Chemical group 0.000 claims 11
- 125000006643 (C2-C6) haloalkenyl group Chemical group 0.000 claims 11
- 125000006650 (C2-C4) alkynyl group Chemical group 0.000 claims 10
- 125000006700 (C1-C6) alkylthio group Chemical group 0.000 claims 8
- 125000006656 (C2-C4) alkenyl group Chemical group 0.000 claims 8
- 125000006645 (C3-C4) cycloalkyl group Chemical group 0.000 claims 8
- 125000006771 (C1-C6) haloalkylthio group Chemical group 0.000 claims 7
- 125000004739 (C1-C6) alkylsulfonyl group Chemical group 0.000 claims 5
- 125000004749 (C1-C6) haloalkylsulfinyl group Chemical group 0.000 claims 5
- 125000004741 (C1-C6) haloalkylsulfonyl group Chemical group 0.000 claims 5
- 125000006374 C2-C10 alkenyl group Chemical group 0.000 claims 5
- 125000005865 C2-C10alkynyl group Chemical group 0.000 claims 5
- 125000001188 haloalkyl group Chemical group 0.000 claims 5
- 125000004738 (C1-C6) alkyl sulfinyl group Chemical group 0.000 claims 4
- 238000004519 manufacturing process Methods 0.000 claims 3
- 125000004768 (C1-C4) alkylsulfinyl group Chemical group 0.000 claims 2
- 125000003545 alkoxy group Chemical group 0.000 claims 2
- 125000000852 azido group Chemical group *N=[N+]=[N-] 0.000 claims 2
- 125000002619 bicyclic group Chemical group 0.000 claims 2
- 125000004441 haloalkylsulfonyl group Chemical group 0.000 claims 2
- 125000001475 halogen functional group Chemical group 0.000 claims 2
- 125000004769 (C1-C4) alkylsulfonyl group Chemical group 0.000 claims 1
- 125000004916 (C1-C6) alkylcarbonyl group Chemical group 0.000 claims 1
- 125000004766 (C3-C6) cyclohaloalkyl group Chemical group 0.000 claims 1
- GUUULVAMQJLDSY-UHFFFAOYSA-N 4,5-dihydro-1,2-thiazole Chemical class C1CC=NS1 GUUULVAMQJLDSY-UHFFFAOYSA-N 0.000 claims 1
- 125000005102 carbonylalkoxy group Chemical group 0.000 claims 1
- 239000003925 fat Substances 0.000 claims 1
- 125000005347 halocycloalkyl group Chemical group 0.000 claims 1
- AGJSNMGHAVDLRQ-IWFBPKFRSA-N methyl (2s)-2-[[(2s)-2-[[(2s)-2-[[(2r)-2-amino-3-sulfanylpropanoyl]amino]-3-methylbutanoyl]amino]-3-(4-hydroxy-2,3-dimethylphenyl)propanoyl]amino]-4-methylsulfanylbutanoate Chemical compound SC[C@H](N)C(=O)N[C@@H](C(C)C)C(=O)N[C@H](C(=O)N[C@@H](CCSC)C(=O)OC)CC1=CC=C(O)C(C)=C1C AGJSNMGHAVDLRQ-IWFBPKFRSA-N 0.000 claims 1
- 125000004043 oxo group Chemical group O=* 0.000 claims 1
- 238000003976 plant breeding Methods 0.000 claims 1
- 238000006467 substitution reaction Methods 0.000 claims 1
- 0 CC[C@](C)*C1(C)CC(C)*CC1 Chemical compound CC[C@](C)*C1(C)CC(C)*CC1 0.000 description 20
- 208000015181 infectious disease Diseases 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 230000000749 insecticidal effect Effects 0.000 description 1
- 150000002547 isoxazolines Chemical class 0.000 description 1
- 125000002950 monocyclic group Chemical group 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- 125000003396 thiol group Chemical class [H]S* 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161579676P | 2011-12-23 | 2011-12-23 | |
| US61/579,676 | 2011-12-23 | ||
| PCT/EP2012/076539 WO2013092943A1 (en) | 2011-12-23 | 2012-12-21 | Isothiazoline compounds for combating invertebrate pests |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2015502967A JP2015502967A (ja) | 2015-01-29 |
| JP2015502967A5 true JP2015502967A5 (cg-RX-API-DMAC7.html) | 2016-12-15 |
| JP6415983B2 JP6415983B2 (ja) | 2018-10-31 |
Family
ID=47504990
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014548048A Expired - Fee Related JP6415983B2 (ja) | 2011-12-23 | 2012-12-21 | 無脊椎有害生物を駆除するためのイソチアゾリン化合物 |
Country Status (18)
Families Citing this family (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9078444B2 (en) * | 2011-09-13 | 2015-07-14 | Syngenta Participations Ag | Isothiazoline derivatives as insecticidal compounds |
| CN105050405A (zh) * | 2013-03-28 | 2015-11-11 | 巴斯夫欧洲公司 | 制备硫亚胺的方法及其原位转化成n-(2-氨基苯甲酰基)硫亚胺 |
| WO2014202437A1 (en) * | 2013-06-21 | 2014-12-24 | Basf Se | Suspension concentrate composition comprising isothiazoline insecticide and activated charcoal |
| US20160145222A1 (en) | 2013-06-21 | 2016-05-26 | Basf Se | Methods for Controlling Pests in Soybean |
| US10327446B2 (en) | 2013-06-24 | 2019-06-25 | Boehringer Ingelheim Animal Health USA Inc. | Naphthyl- or isoquinolinyl-substituted isothiazoline compounds |
| JP2016527208A (ja) * | 2013-06-24 | 2016-09-08 | メリアル インコーポレイテッド | 無脊椎有害生物を駆除するためのイソチアゾリン化合物 |
| WO2015091045A1 (en) | 2013-12-18 | 2015-06-25 | BASF Agro B.V. | Process for the preparation of substituted phenoxyphenyl ketones |
| WO2015104422A1 (en) | 2014-01-13 | 2015-07-16 | Basf Se | Dihydrothiophene compounds for controlling invertebrate pests |
| BR112016017165B1 (pt) | 2014-02-03 | 2021-12-14 | Basf Se | Compostos de ciclopenteno ou ciclopentadieno, composição agrícola ou veterinária, uso de um composto e método para proteger material de propagação de planta |
| TN2017000503A1 (en) | 2015-06-03 | 2019-04-12 | Bristol Myers Squibb Co | 4-hydroxy-3-(heteroaryl)pyridine-2-one apj agonists for use in the treatment of cardiovascular disorders |
| WO2017016883A1 (en) | 2015-07-24 | 2017-02-02 | Basf Se | Process for preparation of cyclopentene compounds |
| EP3497101B1 (de) | 2016-08-10 | 2020-12-30 | Bayer CropScience Aktiengesellschaft | Substituierte 2-heterocyclyl-imidazolyl-carboxamide als schädlingsbekämpfungsmittel |
| CN110234645A (zh) | 2017-01-25 | 2019-09-13 | 巴斯夫欧洲公司 | 制备卞型酰胺的方法 |
| US11974572B2 (en) | 2017-03-31 | 2024-05-07 | Sygenta Participations Ag | Fungicidal compositions |
| BR112019020134B1 (pt) | 2017-03-31 | 2023-05-09 | Syngenta Participations Ag | Composições fungicidas |
| WO2018184984A1 (en) | 2017-04-05 | 2018-10-11 | Syngenta Participations Ag | Microbiocidal oxadiazole derivatives |
| BR112019021019B1 (pt) | 2017-04-05 | 2023-12-05 | Syngenta Participations Ag | Compostos derivados de oxadiazol microbiocidas, composição agrícola, método para controlar ou prevenir a infestação de plantas úteis por microrganismos fitopatogênicos e uso de um composto derivado de oxadiazol |
| BR112019020735B1 (pt) | 2017-04-05 | 2023-12-05 | Syngenta Participations Ag | Compostos derivados de oxadiazol microbiocidas e seu uso, composição agroquímica e método para controlar ou prevenir a infestação de plantas úteis por microrganismos fitopatogênicos |
| WO2018184988A1 (en) | 2017-04-05 | 2018-10-11 | Syngenta Participations Ag | Microbiocidal oxadiazole derivatives |
| WO2018184986A1 (en) | 2017-04-05 | 2018-10-11 | Syngenta Participations Ag | Microbiocidal oxadiazole derivatives |
| BR112019020739B1 (pt) | 2017-04-05 | 2023-12-19 | Syngenta Participations Ag | Compostos derivados de oxadiazol microbiocidas e seu uso, composição agroquímica, método para controlar ou prevenir a infestação de plantas úteis por microrganismos fitopatogênicos |
| CA3058104A1 (en) * | 2017-04-26 | 2018-11-01 | Basf Se | Substituted succinimide derivatives as pesticides |
| WO2019243263A1 (en) * | 2018-06-19 | 2019-12-26 | Syngenta Participations Ag | Insecticidal compounds |
| WO2020002331A1 (en) | 2018-06-29 | 2020-01-02 | Syngenta Crop Protection Ag | Microbiocidal oxadiazole derivatives |
| EP3846793B1 (en) | 2018-09-07 | 2024-01-24 | PIC Therapeutics, Inc. | Eif4e inhibitors and uses thereof |
| US20220048876A1 (en) * | 2018-09-26 | 2022-02-17 | Syngenta Participations Ag | Insecticidal compounds |
| JOP20210272A1 (ar) * | 2019-04-05 | 2023-01-30 | Syngenta Crop Protection Ag | مركبات دايازين - أميد نشطة بشكل مبيد للآفات |
| MA55587A (fr) * | 2019-04-11 | 2022-02-16 | Syngenta Crop Protection Ag | Composés diazine-amide à action pesticide |
| US12497370B2 (en) * | 2019-12-18 | 2025-12-16 | Elanco Tiergesundheit Ag | Isoxazoline derivatives |
| EP4114529A1 (en) | 2020-03-03 | 2023-01-11 | PIC Therapeutics, Inc. | Eif4e inhibitors and uses thereof |
| US12108762B2 (en) * | 2020-09-08 | 2024-10-08 | Santanu Maitra | Methods of controlling crop pests using aromatic amide insect repellents, methods of making aromatic amide insect repellents, and novel aromatic amide insect repellents |
| JP7703648B2 (ja) * | 2021-05-14 | 2025-07-07 | 日本曹達株式会社 | （ヘテロ）アリールアミド化合物および有害生物防除剤 |
| CN113563322B (zh) * | 2021-07-26 | 2023-07-07 | 海利尔药业集团股份有限公司 | 一种取代的苯甲酰胺类异噁唑啉衍生物或其作为农药可接受的盐、组合物及其用途 |
| CN115710195B (zh) * | 2021-08-22 | 2025-02-14 | 华东理工大学 | 具有杀线虫活性的三氟烯烃类化合物及其制备方法和用途 |
| CA3229560A1 (en) | 2021-08-25 | 2023-03-02 | Christopher L. Vandeusen | Eif4e inhibitors and uses thereof |
| EP4392421A1 (en) | 2021-08-25 | 2024-07-03 | PIC Therapeutics, Inc. | Eif4e inhibitors and uses thereof |
| CN113582987B (zh) * | 2021-09-02 | 2023-06-30 | 海利尔药业集团股份有限公司 | 一种取代的苯甲酰胺异噁唑啉衍生物或其作为农药可接受的盐、组合物及其用途 |
| CN114380762A (zh) * | 2022-01-23 | 2022-04-22 | 贵州大学 | 异恶唑啉酰肼衍生物及其制备方法和用途 |
| CN114933597B (zh) * | 2022-04-28 | 2023-04-07 | 武汉工程大学 | 一种3-羟基异噻唑啉衍生物、制备方法和应用 |
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| BRPI0917369A2 (pt) | 2008-08-22 | 2015-08-04 | Syngenta Participations Ag | Compostos inseticidas |
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| BRPI1006543A2 (pt) | 2009-04-01 | 2015-08-25 | Basf Se | "compostos de isoxazolina, composição agrícola, composição veterinária, uso de composto, método para o controle de pragas invertebradas, material de propagação de plantas e método para o tratamento, controle, prevenção ou proteção de animais contra infestação ou infecção por parasitas" |
| JP5335588B2 (ja) * | 2009-07-15 | 2013-11-06 | フジ日本精糖株式会社 | 切り花用鮮度保持剤 |
| TWI487486B (zh) | 2009-12-01 | 2015-06-11 | Syngenta Participations Ag | 以異唑啉衍生物為主之殺蟲化合物 |
| WO2011073444A2 (en) | 2009-12-18 | 2011-06-23 | Basf Se | Azoline compounds for combating invertebrate pests |
| CN102762543B (zh) | 2010-02-01 | 2016-03-09 | 巴斯夫欧洲公司 | 用于防除动物害虫的取代的酮型异*唑啉化合物和衍生物 |
| JP2011212522A (ja) * | 2010-03-31 | 2011-10-27 | Aquas Corp | 水系中のイソチアゾリン系化合物の分解抑制方法、及び、水系の微生物制御方法 |
| US9078444B2 (en) | 2011-09-13 | 2015-07-14 | Syngenta Participations Ag | Isothiazoline derivatives as insecticidal compounds |
-
2012
- 2012-12-21 AU AU2012356947A patent/AU2012356947A1/en not_active Abandoned
- 2012-12-21 MX MX2014006973A patent/MX2014006973A/es unknown
- 2012-12-21 JP JP2014548048A patent/JP6415983B2/ja not_active Expired - Fee Related
- 2012-12-21 KR KR1020147020594A patent/KR20140115329A/ko not_active Ceased
- 2012-12-21 CA CA2858766A patent/CA2858766A1/en not_active Abandoned
- 2012-12-21 WO PCT/EP2012/076539 patent/WO2013092943A1/en not_active Ceased
- 2012-12-21 US US14/366,161 patent/US9732051B2/en not_active Expired - Fee Related
- 2012-12-21 EP EP12810287.8A patent/EP2794601B1/en not_active Not-in-force
- 2012-12-21 BR BR112014015553-4A patent/BR112014015553B1/pt not_active IP Right Cessation
- 2012-12-21 CN CN201280070554.8A patent/CN104169278B/zh not_active Expired - Fee Related
- 2012-12-21 IN IN4376CHN2014 patent/IN2014CN04376A/en unknown
- 2012-12-21 ES ES12810287T patent/ES2727479T3/es active Active
- 2012-12-26 AR ARP120104961A patent/AR090045A1/es unknown
-
2014
- 2014-06-12 CR CR20140276A patent/CR20140276A/es unknown
- 2014-06-16 CO CO14130271A patent/CO6980665A2/es unknown
- 2014-06-23 CL CL2014001688A patent/CL2014001688A1/es unknown
- 2014-06-23 IL IL233312A patent/IL233312A0/en unknown
- 2014-07-21 ZA ZA2014/05336A patent/ZA201405336B/en unknown
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