JP2009537997A - 薄膜太陽電池を製造するのに適した銅−亜鉛−錫析出のための金属メッキ組成及び方法 - Google Patents
薄膜太陽電池を製造するのに適した銅−亜鉛−錫析出のための金属メッキ組成及び方法 Download PDFInfo
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- JP2009537997A JP2009537997A JP2009511397A JP2009511397A JP2009537997A JP 2009537997 A JP2009537997 A JP 2009537997A JP 2009511397 A JP2009511397 A JP 2009511397A JP 2009511397 A JP2009511397 A JP 2009511397A JP 2009537997 A JP2009537997 A JP 2009537997A
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- Prior art keywords
- copper
- zinc
- tin
- plating
- layer
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- REIDAMBAPLIATC-UHFFFAOYSA-N COC(c(cc1)ccc1C(O)=O)=O Chemical compound COC(c(cc1)ccc1C(O)=O)=O REIDAMBAPLIATC-UHFFFAOYSA-N 0.000 description 1
- HVBSAKJJOYLTQU-UHFFFAOYSA-N Nc(cc1)ccc1S(O)(=O)=O Chemical compound Nc(cc1)ccc1S(O)(=O)=O HVBSAKJJOYLTQU-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F77/00—Constructional details of devices covered by this subclass
- H10F77/10—Semiconductor bodies
- H10F77/12—Active materials
- H10F77/126—Active materials comprising only Group I-III-VI chalcopyrite materials, e.g. CuInSe2, CuGaSe2 or CuInGaSe2 [CIGS]
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/31—Coating with metals
- C23C18/38—Coating with copper
- C23C18/40—Coating with copper using reducing agents
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/48—Coating with alloys
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
- C25D3/58—Electroplating: Baths therefor from solutions of alloys containing more than 50% by weight of copper
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/10—Electroplating with more than one layer of the same or of different metals
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/48—After-treatment of electroplated surfaces
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/60—Electroplating characterised by the structure or texture of the layers
- C25D5/615—Microstructure of the layers, e.g. mixed structure
- C25D5/617—Crystalline layers
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F10/00—Individual photovoltaic cells, e.g. solar cells
- H10F10/10—Individual photovoltaic cells, e.g. solar cells having potential barriers
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- H10P14/00—Formation of materials, e.g. in the shape of layers or pillars
- H10P14/20—Formation of materials, e.g. in the shape of layers or pillars of semiconductor materials
- H10P14/26—Formation of materials, e.g. in the shape of layers or pillars of semiconductor materials using liquid deposition
- H10P14/265—Formation of materials, e.g. in the shape of layers or pillars of semiconductor materials using liquid deposition using solutions
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- H10P14/00—Formation of materials, e.g. in the shape of layers or pillars
- H10P14/20—Formation of materials, e.g. in the shape of layers or pillars of semiconductor materials
- H10P14/34—Deposited materials, e.g. layers
- H10P14/3402—Deposited materials, e.g. layers characterised by the chemical composition
- H10P14/3424—Deposited materials, e.g. layers characterised by the chemical composition being Group IIB-VIA materials
- H10P14/3428—Sulfides
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- H10P14/00—Formation of materials, e.g. in the shape of layers or pillars
- H10P14/20—Formation of materials, e.g. in the shape of layers or pillars of semiconductor materials
- H10P14/34—Deposited materials, e.g. layers
- H10P14/3402—Deposited materials, e.g. layers characterised by the chemical composition
- H10P14/3424—Deposited materials, e.g. layers characterised by the chemical composition being Group IIB-VIA materials
- H10P14/3431—Selenides
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- H10P14/00—Formation of materials, e.g. in the shape of layers or pillars
- H10P14/20—Formation of materials, e.g. in the shape of layers or pillars of semiconductor materials
- H10P14/34—Deposited materials, e.g. layers
- H10P14/3402—Deposited materials, e.g. layers characterised by the chemical composition
- H10P14/3436—Deposited materials, e.g. layers characterised by the chemical composition being chalcogenide semiconductor materials not being oxides, e.g. ternary compounds
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/541—CuInSe2 material PV cells
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Electroplating And Plating Baths Therefor (AREA)
- Photovoltaic Devices (AREA)
- Electroplating Methods And Accessories (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Chemically Coating (AREA)
- Physical Vapour Deposition (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Electrolytic Production Of Metals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP06090086 | 2006-05-24 | ||
| PCT/EP2007/004553 WO2007134843A2 (en) | 2006-05-24 | 2007-05-15 | Metal plating composition and method for the deposition of copper-zinc-tin suitable for manufacturing thin film solar cell |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2009537997A true JP2009537997A (ja) | 2009-10-29 |
| JP2009537997A5 JP2009537997A5 (https=) | 2010-03-04 |
Family
ID=38626814
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009511397A Pending JP2009537997A (ja) | 2006-05-24 | 2007-05-15 | 薄膜太陽電池を製造するのに適した銅−亜鉛−錫析出のための金属メッキ組成及び方法 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US9263609B2 (https=) |
| EP (3) | EP2336394B1 (https=) |
| JP (1) | JP2009537997A (https=) |
| CN (1) | CN101522954B (https=) |
| AT (2) | ATE516388T1 (https=) |
| DE (1) | DE602007010141D1 (https=) |
| ES (2) | ES2547566T3 (https=) |
| PT (1) | PT2037006E (https=) |
| WO (1) | WO2007134843A2 (https=) |
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011159920A (ja) * | 2010-02-03 | 2011-08-18 | Institute Of National Colleges Of Technology Japan | 化合物半導体、光電素子及びその製造方法 |
| KR101093663B1 (ko) | 2010-01-21 | 2011-12-15 | 전남대학교산학협력단 | 단일 공정 전기증착법을 이용한 czts 박막의 제조방법 |
| JP2013508988A (ja) * | 2009-10-27 | 2013-03-07 | インターナショナル・ビジネス・マシーンズ・コーポレーション | 半導体膜を形成する方法およびその膜を含む光起電デバイス |
| WO2013077417A1 (ja) * | 2011-11-25 | 2013-05-30 | 昭和シェル石油株式会社 | Czts系薄膜太陽電池及びその製造方法 |
| US8485126B2 (en) | 2009-09-08 | 2013-07-16 | Tokyo Ohka Kogyo Co., Ltd. | Coating apparatus including a glove part and a controller for stopping coating |
| WO2013129484A1 (ja) * | 2012-02-29 | 2013-09-06 | Ikeda Shigeru | 混合結晶、混合結晶製造方法、太陽電池、太陽電池製造方法及び電析浴 |
| JP2014513413A (ja) * | 2011-03-10 | 2014-05-29 | サン−ゴバン グラス フランス | 五元化合物半導体CZTSSeおよび薄膜太陽電池の製造方法 |
| KR101500858B1 (ko) * | 2013-09-17 | 2015-03-12 | 전남대학교산학협력단 | 전착법을 이용한 주석 박막 및 태양전지 광흡수층용 czts 기반 박막의 제조방법 |
| KR101507255B1 (ko) | 2010-12-10 | 2015-03-30 | 후지필름 가부시키가이샤 | 광전 변환 소자 및 그것을 구비한 태양 전지 |
| EP2858103A1 (en) | 2013-08-30 | 2015-04-08 | Tokyo Ohka Kogyo Co., Ltd. | Chamber apparatus and heating method |
| US9027504B2 (en) | 2011-06-02 | 2015-05-12 | Tokyo Ohka Kogyo Co., Ltd. | Heating apparatus, coating apparatus and heating method |
| US9186696B2 (en) | 2009-09-08 | 2015-11-17 | Tokyo Ohka Kogyo Co., Ltd. | Coating apparatus including a chamber, sensor, removal unit and control device for application of liquid to a substrate |
| US9236283B2 (en) | 2013-03-12 | 2016-01-12 | Tokyo Ohka Kogyo Co., Ltd. | Chamber apparatus and heating method |
| WO2016013670A1 (ja) * | 2014-07-25 | 2016-01-28 | 凸版印刷株式会社 | 化合物薄膜太陽電池、化合物薄膜太陽電池の製造方法、および、光吸収層 |
| US9299874B2 (en) | 2010-10-13 | 2016-03-29 | Tokyo Ohka Kogyo Co., Ltd. | Coating apparatus and coating method |
| JP2016540893A (ja) * | 2013-12-17 | 2016-12-28 | ウミコレ・ガルファノテフニック・ゲーエムベーハー | 電解質からの銅−スズ及び銅−スズ−亜鉛合金の析出 |
| US10147604B2 (en) | 2009-10-27 | 2018-12-04 | International Business Machines Corporation | Aqueous-based method of forming semiconductor film and photovoltaic device including the film |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011503847A (ja) | 2007-11-02 | 2011-01-27 | ワコンダ テクノロジーズ, インコーポレイテッド | 結晶質薄膜光起電力構造およびその形成方法 |
| JP5309285B2 (ja) * | 2007-11-30 | 2013-10-09 | 株式会社豊田中央研究所 | 光電素子及びその製造方法 |
| JP5476548B2 (ja) * | 2008-08-18 | 2014-04-23 | 株式会社豊田中央研究所 | 硫化物系化合物半導体 |
| EP2379458A4 (en) | 2009-01-21 | 2015-02-11 | Purdue Research Foundation | SELENIZATION OF PRECIPITATION LAYERS WITH CULNS2 NANOPARTICLES |
| US8415187B2 (en) | 2009-01-28 | 2013-04-09 | Solexant Corporation | Large-grain crystalline thin-film structures and devices and methods for forming the same |
| US20100330367A1 (en) * | 2009-02-03 | 2010-12-30 | Ut-Battelle, Llc | Microbially-mediated method for synthesis of non-oxide semiconductor nanoparticles |
| US8580157B2 (en) | 2009-02-20 | 2013-11-12 | Kabushiki Kaisha Toyota Chuo Kenkyusho | Sulfide and photoelectric element |
| JP2012527523A (ja) * | 2009-05-21 | 2012-11-08 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 銅スズ硫化物および銅亜鉛スズ硫化物インク組成物 |
| US20120055554A1 (en) * | 2009-05-21 | 2012-03-08 | E.I. Du Pont De Nemours And Company | Copper zinc tin chalcogenide nanoparticles |
| AU2010254120A1 (en) * | 2009-05-26 | 2012-01-12 | Purdue Research Foundation | Synthesis of multinary chalcogenide nanoparticles comprising Cu, Zn, Sn, S, and Se |
| US20120199173A1 (en) * | 2009-07-31 | 2012-08-09 | Aqt Solar, Inc. | Interconnection Schemes for Photovoltaic Cells |
| JP5639816B2 (ja) * | 2009-09-08 | 2014-12-10 | 東京応化工業株式会社 | 塗布方法及び塗布装置 |
| JP5719546B2 (ja) * | 2009-09-08 | 2015-05-20 | 東京応化工業株式会社 | 塗布装置及び塗布方法 |
| TWI458115B (zh) * | 2009-11-11 | 2014-10-21 | Univ Nat Kaohsiung Marine | Solar cell X ZnSnS Y Film (CZTS) manufacturing method |
| CN101700873B (zh) * | 2009-11-20 | 2013-03-27 | 上海交通大学 | 铜锌锡硒纳米粒子的制备方法 |
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| US8414862B2 (en) | 2009-11-25 | 2013-04-09 | E I Du Pont De Nemours And Company | Preparation of CZTS and its analogs in ionic liquids |
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| CN103650155B (zh) * | 2011-02-18 | 2016-10-12 | 华盛顿大学商业中心 | 形成包括i2-ii-iv-vi4和i2-(ii,iv)-iv-vi4半导体膜在内的半导体膜的方法以及包括所述半导体膜的电子装置 |
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| JP2013508988A (ja) * | 2009-10-27 | 2013-03-07 | インターナショナル・ビジネス・マシーンズ・コーポレーション | 半導体膜を形成する方法およびその膜を含む光起電デバイス |
| US10147604B2 (en) | 2009-10-27 | 2018-12-04 | International Business Machines Corporation | Aqueous-based method of forming semiconductor film and photovoltaic device including the film |
| KR101093663B1 (ko) | 2010-01-21 | 2011-12-15 | 전남대학교산학협력단 | 단일 공정 전기증착법을 이용한 czts 박막의 제조방법 |
| JP2011159920A (ja) * | 2010-02-03 | 2011-08-18 | Institute Of National Colleges Of Technology Japan | 化合物半導体、光電素子及びその製造方法 |
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| KR101507255B1 (ko) | 2010-12-10 | 2015-03-30 | 후지필름 가부시키가이샤 | 광전 변환 소자 및 그것을 구비한 태양 전지 |
| KR101522128B1 (ko) * | 2011-03-10 | 2015-05-20 | 쌩-고벵 글래스 프랑스 | 5원 화합물 반도체 cztsse의 제조 방법, 및 박막 태양광 전지 |
| JP2014513413A (ja) * | 2011-03-10 | 2014-05-29 | サン−ゴバン グラス フランス | 五元化合物半導体CZTSSeおよび薄膜太陽電池の製造方法 |
| US9027504B2 (en) | 2011-06-02 | 2015-05-12 | Tokyo Ohka Kogyo Co., Ltd. | Heating apparatus, coating apparatus and heating method |
| WO2013077417A1 (ja) * | 2011-11-25 | 2013-05-30 | 昭和シェル石油株式会社 | Czts系薄膜太陽電池及びその製造方法 |
| JP2013115126A (ja) * | 2011-11-25 | 2013-06-10 | Showa Shell Sekiyu Kk | Czts系薄膜太陽電池及びその製造方法 |
| WO2013129484A1 (ja) * | 2012-02-29 | 2013-09-06 | Ikeda Shigeru | 混合結晶、混合結晶製造方法、太陽電池、太陽電池製造方法及び電析浴 |
| US9236283B2 (en) | 2013-03-12 | 2016-01-12 | Tokyo Ohka Kogyo Co., Ltd. | Chamber apparatus and heating method |
| EP2858103A1 (en) | 2013-08-30 | 2015-04-08 | Tokyo Ohka Kogyo Co., Ltd. | Chamber apparatus and heating method |
| TWI641157B (zh) * | 2013-08-30 | 2018-11-11 | 日商東京應化工業股份有限公司 | 室裝置及加熱方法 |
| KR101500858B1 (ko) * | 2013-09-17 | 2015-03-12 | 전남대학교산학협력단 | 전착법을 이용한 주석 박막 및 태양전지 광흡수층용 czts 기반 박막의 제조방법 |
| JP2016540893A (ja) * | 2013-12-17 | 2016-12-28 | ウミコレ・ガルファノテフニック・ゲーエムベーハー | 電解質からの銅−スズ及び銅−スズ−亜鉛合金の析出 |
| WO2016013670A1 (ja) * | 2014-07-25 | 2016-01-28 | 凸版印刷株式会社 | 化合物薄膜太陽電池、化合物薄膜太陽電池の製造方法、および、光吸収層 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2032743B1 (en) | 2010-10-27 |
| EP2336394B1 (en) | 2015-07-01 |
| EP2037006B1 (en) | 2011-07-13 |
| EP2037006B9 (en) | 2012-02-15 |
| US9263609B2 (en) | 2016-02-16 |
| CN101522954B (zh) | 2011-11-16 |
| EP2037006A2 (en) | 2009-03-18 |
| EP2336394A2 (en) | 2011-06-22 |
| WO2007134843A2 (en) | 2007-11-29 |
| WO2007134843A3 (en) | 2008-11-27 |
| EP2336394A3 (en) | 2011-11-30 |
| EP2032743A2 (en) | 2009-03-11 |
| ES2369431T3 (es) | 2011-11-30 |
| DE602007010141D1 (de) | 2010-12-09 |
| ATE486156T1 (de) | 2010-11-15 |
| ES2547566T3 (es) | 2015-10-07 |
| CN101522954A (zh) | 2009-09-02 |
| US20090205714A1 (en) | 2009-08-20 |
| EP2037006A3 (en) | 2009-08-05 |
| PT2037006E (pt) | 2011-08-24 |
| ATE516388T1 (de) | 2011-07-15 |
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