ATE516388T1 - Metallplattierungszusammensetzung und verfahren zur ablagerung von kupfer-zink-blech zur herstellung einer dünnfilm-solarzelle - Google Patents
Metallplattierungszusammensetzung und verfahren zur ablagerung von kupfer-zink-blech zur herstellung einer dünnfilm-solarzelleInfo
- Publication number
- ATE516388T1 ATE516388T1 AT08090007T AT08090007T ATE516388T1 AT E516388 T1 ATE516388 T1 AT E516388T1 AT 08090007 T AT08090007 T AT 08090007T AT 08090007 T AT08090007 T AT 08090007T AT E516388 T1 ATE516388 T1 AT E516388T1
- Authority
- AT
- Austria
- Prior art keywords
- copper
- metal plating
- group
- zinc
- plating composition
- Prior art date
Links
- 238000007747 plating Methods 0.000 title abstract 8
- 239000002184 metal Substances 0.000 title abstract 4
- 229910052751 metal Inorganic materials 0.000 title abstract 4
- 239000000203 mixture Substances 0.000 title abstract 4
- 239000010409 thin film Substances 0.000 title abstract 2
- TVZPLCNGKSPOJA-UHFFFAOYSA-N copper zinc Chemical compound [Cu].[Zn] TVZPLCNGKSPOJA-UHFFFAOYSA-N 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 229910001128 Sn alloy Inorganic materials 0.000 abstract 2
- PDYXSJSAMVACOH-UHFFFAOYSA-N [Cu].[Zn].[Sn] Chemical compound [Cu].[Zn].[Sn] PDYXSJSAMVACOH-UHFFFAOYSA-N 0.000 abstract 2
- 239000006096 absorbing agent Substances 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 229910045601 alloy Inorganic materials 0.000 abstract 2
- 239000000956 alloy Substances 0.000 abstract 2
- 229910052798 chalcogen Inorganic materials 0.000 abstract 2
- 150000001787 chalcogens Chemical class 0.000 abstract 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 230000000996 additive effect Effects 0.000 abstract 1
- 150000004770 chalcogenides Chemical class 0.000 abstract 1
- 239000008139 complexing agent Substances 0.000 abstract 1
- 230000005494 condensation Effects 0.000 abstract 1
- 238000009833 condensation Methods 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 230000008021 deposition Effects 0.000 abstract 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 abstract 1
- 125000001997 phenyl group Chemical class [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 231100000614 poison Toxicity 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 229910052711 selenium Inorganic materials 0.000 abstract 1
- 239000011669 selenium Substances 0.000 abstract 1
- 239000004065 semiconductor Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 239000011593 sulfur Substances 0.000 abstract 1
- 239000003440 toxic substance Substances 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F77/00—Constructional details of devices covered by this subclass
- H10F77/10—Semiconductor bodies
- H10F77/12—Active materials
- H10F77/126—Active materials comprising only Group I-III-VI chalcopyrite materials, e.g. CuInSe2, CuGaSe2 or CuInGaSe2 [CIGS]
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/31—Coating with metals
- C23C18/38—Coating with copper
- C23C18/40—Coating with copper using reducing agents
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/48—Coating with alloys
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
- C25D3/58—Electroplating: Baths therefor from solutions of alloys containing more than 50% by weight of copper
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/10—Electroplating with more than one layer of the same or of different metals
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/48—After-treatment of electroplated surfaces
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/60—Electroplating characterised by the structure or texture of the layers
- C25D5/615—Microstructure of the layers, e.g. mixed structure
- C25D5/617—Crystalline layers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02518—Deposited layers
- H01L21/02521—Materials
- H01L21/02551—Group 12/16 materials
- H01L21/02557—Sulfides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02518—Deposited layers
- H01L21/02521—Materials
- H01L21/02551—Group 12/16 materials
- H01L21/0256—Selenides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02518—Deposited layers
- H01L21/02521—Materials
- H01L21/02568—Chalcogenide semiconducting materials not being oxides, e.g. ternary compounds
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02612—Formation types
- H01L21/02617—Deposition types
- H01L21/02623—Liquid deposition
- H01L21/02628—Liquid deposition using solutions
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F10/00—Individual photovoltaic cells, e.g. solar cells
- H10F10/10—Individual photovoltaic cells, e.g. solar cells having potential barriers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/541—CuInSe2 material PV cells
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Power Engineering (AREA)
- Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Manufacturing & Machinery (AREA)
- General Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Electroplating And Plating Baths Therefor (AREA)
- Photovoltaic Devices (AREA)
- Electroplating Methods And Accessories (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Electrolytic Production Of Metals (AREA)
- Physical Vapour Deposition (AREA)
- Chemically Coating (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP06090086 | 2006-05-24 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE516388T1 true ATE516388T1 (de) | 2011-07-15 |
Family
ID=38626814
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT08090007T ATE516388T1 (de) | 2006-05-24 | 2007-05-15 | Metallplattierungszusammensetzung und verfahren zur ablagerung von kupfer-zink-blech zur herstellung einer dünnfilm-solarzelle |
| AT07725453T ATE486156T1 (de) | 2006-05-24 | 2007-05-15 | Zusammensetzung zur stromlosen metallabscheidung und verfahren zur abscheidung von kupfer-zink- zinn, das zur herstellung einer dünnfilm- solarzelle geeignet ist |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT07725453T ATE486156T1 (de) | 2006-05-24 | 2007-05-15 | Zusammensetzung zur stromlosen metallabscheidung und verfahren zur abscheidung von kupfer-zink- zinn, das zur herstellung einer dünnfilm- solarzelle geeignet ist |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US9263609B2 (de) |
| EP (3) | EP2336394B1 (de) |
| JP (1) | JP2009537997A (de) |
| CN (1) | CN101522954B (de) |
| AT (2) | ATE516388T1 (de) |
| DE (1) | DE602007010141D1 (de) |
| ES (2) | ES2547566T3 (de) |
| PT (1) | PT2037006E (de) |
| WO (1) | WO2007134843A2 (de) |
Families Citing this family (86)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090114274A1 (en) | 2007-11-02 | 2009-05-07 | Fritzemeier Leslie G | Crystalline thin-film photovoltaic structures |
| JP5309285B2 (ja) * | 2007-11-30 | 2013-10-09 | 株式会社豊田中央研究所 | 光電素子及びその製造方法 |
| JP5476548B2 (ja) * | 2008-08-18 | 2014-04-23 | 株式会社豊田中央研究所 | 硫化物系化合物半導体 |
| KR20110108388A (ko) * | 2009-01-21 | 2011-10-05 | 퍼듀 리서치 파운데이션 | 이황화 구리 인듐 나노 입자를 함유하는 전구체 층의 셀렌화 |
| US8415187B2 (en) | 2009-01-28 | 2013-04-09 | Solexant Corporation | Large-grain crystalline thin-film structures and devices and methods for forming the same |
| US20100330367A1 (en) * | 2009-02-03 | 2010-12-30 | Ut-Battelle, Llc | Microbially-mediated method for synthesis of non-oxide semiconductor nanoparticles |
| US8580157B2 (en) | 2009-02-20 | 2013-11-12 | Kabushiki Kaisha Toyota Chuo Kenkyusho | Sulfide and photoelectric element |
| EP2432841A1 (de) * | 2009-05-21 | 2012-03-28 | E. I. du Pont de Nemours and Company | Kupferzinnsulfid- und kupferzinkzinnsulfidtintenzusammensetzungen |
| US20120055554A1 (en) * | 2009-05-21 | 2012-03-08 | E.I. Du Pont De Nemours And Company | Copper zinc tin chalcogenide nanoparticles |
| WO2010138636A2 (en) * | 2009-05-26 | 2010-12-02 | Purdue Research Foundation | Synthesis of multinary chalcogenide nanoparticles comprising cu, zn, sn, s, and se |
| US20120199173A1 (en) * | 2009-07-31 | 2012-08-09 | Aqt Solar, Inc. | Interconnection Schemes for Photovoltaic Cells |
| JP5719546B2 (ja) * | 2009-09-08 | 2015-05-20 | 東京応化工業株式会社 | 塗布装置及び塗布方法 |
| JP5469966B2 (ja) | 2009-09-08 | 2014-04-16 | 東京応化工業株式会社 | 塗布装置及び塗布方法 |
| JP5639816B2 (ja) * | 2009-09-08 | 2014-12-10 | 東京応化工業株式会社 | 塗布方法及び塗布装置 |
| JP5439097B2 (ja) * | 2009-09-08 | 2014-03-12 | 東京応化工業株式会社 | 塗布装置及び塗布方法 |
| US10147604B2 (en) | 2009-10-27 | 2018-12-04 | International Business Machines Corporation | Aqueous-based method of forming semiconductor film and photovoltaic device including the film |
| US20110094557A1 (en) * | 2009-10-27 | 2011-04-28 | International Business Machines Corporation | Method of forming semiconductor film and photovoltaic device including the film |
| TWI458115B (zh) * | 2009-11-11 | 2014-10-21 | Univ Nat Kaohsiung Marine | Solar cell X ZnSnS Y Film (CZTS) manufacturing method |
| CN101700873B (zh) * | 2009-11-20 | 2013-03-27 | 上海交通大学 | 铜锌锡硒纳米粒子的制备方法 |
| US8734687B2 (en) | 2009-11-25 | 2014-05-27 | E I Du Pont De Nemours And Company | Screen-printable quaternary chalcogenide compositions |
| US8414862B2 (en) | 2009-11-25 | 2013-04-09 | E I Du Pont De Nemours And Company | Preparation of CZTS and its analogs in ionic liquids |
| TWI426633B (zh) * | 2009-12-10 | 2014-02-11 | Univ Nat Chiao Tung | 倒置式有機太陽能元件及其製作方法 |
| KR101144738B1 (ko) * | 2009-12-28 | 2012-05-24 | 재단법인대구경북과학기술원 | 박막형 태양전지의 제조방법 |
| TWI402996B (zh) * | 2010-01-12 | 2013-07-21 | Univ Nat Kaohsiung Marine | 以銅鋅錫(CuZnSn)合金製備太陽能電池的CuxZn SnSy(CZTS)薄膜之方法 |
| KR101093663B1 (ko) | 2010-01-21 | 2011-12-15 | 전남대학교산학협력단 | 단일 공정 전기증착법을 이용한 czts 박막의 제조방법 |
| JP5641284B2 (ja) * | 2010-02-03 | 2014-12-17 | 独立行政法人国立高等専門学校機構 | 化合物半導体、光電素子及びその製造方法 |
| CN101824638B (zh) * | 2010-05-06 | 2012-12-19 | 深圳丹邦投资集团有限公司 | 一种电化学沉积铜锌锡硒半导体薄膜材料的方法 |
| CN101830444A (zh) * | 2010-05-28 | 2010-09-15 | 上海交通大学 | 铜锌锡硫硒纳米粒子的制备方法 |
| US9085829B2 (en) * | 2010-08-31 | 2015-07-21 | International Business Machines Corporation | Electrodeposition of thin-film cells containing non-toxic elements |
| US8426241B2 (en) | 2010-09-09 | 2013-04-23 | International Business Machines Corporation | Structure and method of fabricating a CZTS photovoltaic device by electrodeposition |
| US9234291B2 (en) * | 2010-09-09 | 2016-01-12 | Globalfoundries Inc. | Zinc thin films plating chemistry and methods |
| JP2012081428A (ja) | 2010-10-13 | 2012-04-26 | Tokyo Ohka Kogyo Co Ltd | 塗布装置及び塗布方法 |
| US20120100663A1 (en) * | 2010-10-26 | 2012-04-26 | International Business Machines Corporation | Fabrication of CuZnSn(S,Se) Thin Film Solar Cell with Valve Controlled S and Se |
| US20120097234A1 (en) * | 2010-10-26 | 2012-04-26 | International Business Machines Corporation | Using Diffusion Barrier Layer for CuZnSn(S,Se) Thin Film Solar Cell |
| US20140144500A1 (en) * | 2010-11-22 | 2014-05-29 | E I Du Pont De Nemours And Company | Semiconductor inks films, coated substrates and methods of preparation |
| JP5478474B2 (ja) | 2010-12-10 | 2014-04-23 | 富士フイルム株式会社 | 光電変換素子及びそれを備えた太陽電池 |
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| US20110132462A1 (en) * | 2010-12-28 | 2011-06-09 | The University Of Utah Research Foundation | Modified copper-zinc-tin semiconductor films, uses thereof and related methods |
| US20140216555A1 (en) * | 2011-01-21 | 2014-08-07 | Regents Of The University Of Minnesota | Metal chalcogenides and methods of making and using same |
| WO2012112927A2 (en) * | 2011-02-18 | 2012-08-23 | Hugh Hillhouse | Methods of forming semiconductor films including i2-ii-iv-vi4 and i2-(ii,iv)-iv-vi4 semiconductor films and electronic devices including the semiconductor films |
| US20120222730A1 (en) * | 2011-03-01 | 2012-09-06 | International Business Machines Corporation | Tandem solar cell with improved absorption material |
| CN103403851A (zh) * | 2011-03-10 | 2013-11-20 | 法国圣戈班玻璃厂 | 制备五元化合物半导体CZTSSe的方法和薄膜太阳能电池 |
| US8501526B2 (en) | 2011-04-22 | 2013-08-06 | Alliance For Sustainable Energy, Llc | Synthesizing photovoltaic thin films of high quality copper-zinc-tin alloy with at least one chalcogen species |
| JP2012250230A (ja) | 2011-06-02 | 2012-12-20 | Tokyo Ohka Kogyo Co Ltd | 加熱装置、塗布装置及び加熱方法 |
| US20130037111A1 (en) * | 2011-08-10 | 2013-02-14 | International Business Machines Corporation | Process for Preparation of Elemental Chalcogen Solutions and Method of Employing Said Solutions in Preparation of Kesterite Films |
| US9242271B2 (en) * | 2011-09-21 | 2016-01-26 | Board Of Regents, The University Of Texas System | Chemical and electrochemical synthesis and deposition of chalcogenides from room temperature ionic liquids |
| US20130074911A1 (en) * | 2011-09-23 | 2013-03-28 | Yueh-Chun Liao | Photovoltaic Device Including a CZTS Absorber Layer and Method of Manufacturing the Same |
| JP5178904B1 (ja) * | 2011-11-25 | 2013-04-10 | 昭和シェル石油株式会社 | Czts系薄膜太陽電池及びその製造方法 |
| JP5765632B2 (ja) * | 2011-11-30 | 2015-08-19 | 株式会社村田製作所 | 化合物半導体超微粒子の製造方法 |
| DE102011121799B4 (de) | 2011-12-21 | 2013-08-29 | Umicore Galvanotechnik Gmbh | Elektrolyt und Verfahren zur elektrolytischen Abscheidung von Cu-Zn-Sn-Legierungsschichten und Verfahren zur Herstellung einer Dünnschichtsolarzelle |
| DE102011121798B4 (de) * | 2011-12-21 | 2013-08-29 | Umicore Galvanotechnik Gmbh | Elektrolyt und Verfahren zur elektrolytischen Abscheidung von Cu-Zn-Sn-Legierungsschichten und Verfahren zur Herstellung einer Dünnschichtsolarzelle |
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| US20130168825A1 (en) * | 2011-12-30 | 2013-07-04 | Alliance For Sustainable Energy, Llc | Fabrication of ionic liquid electrodeposited cu-sn-zn-s-se thin films and method of making |
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| SU1236010A1 (ru) | 1984-07-17 | 1986-06-07 | Московский ордена Ленина и ордена Трудового Красного Знамени химико-технологический институт им.Д.И.Менделеева | Электролит дл осаждени покрытий сплавом медь-цинк-олово |
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- 2007-05-15 JP JP2009511397A patent/JP2009537997A/ja active Pending
- 2007-05-15 DE DE602007010141T patent/DE602007010141D1/de active Active
- 2007-05-15 US US12/302,072 patent/US9263609B2/en not_active Expired - Fee Related
- 2007-05-15 WO PCT/EP2007/004553 patent/WO2007134843A2/en not_active Ceased
- 2007-05-15 EP EP11160198.5A patent/EP2336394B1/de not_active Not-in-force
- 2007-05-15 AT AT07725453T patent/ATE486156T1/de not_active IP Right Cessation
- 2007-05-15 EP EP08090007A patent/EP2037006B9/de not_active Not-in-force
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| US20090205714A1 (en) | 2009-08-20 |
| US9263609B2 (en) | 2016-02-16 |
| EP2037006B9 (de) | 2012-02-15 |
| WO2007134843A2 (en) | 2007-11-29 |
| ES2369431T3 (es) | 2011-11-30 |
| ATE486156T1 (de) | 2010-11-15 |
| EP2032743A2 (de) | 2009-03-11 |
| EP2336394A2 (de) | 2011-06-22 |
| CN101522954B (zh) | 2011-11-16 |
| PT2037006E (pt) | 2011-08-24 |
| DE602007010141D1 (de) | 2010-12-09 |
| EP2336394B1 (de) | 2015-07-01 |
| ES2547566T3 (es) | 2015-10-07 |
| EP2037006A2 (de) | 2009-03-18 |
| EP2336394A3 (de) | 2011-11-30 |
| EP2037006B1 (de) | 2011-07-13 |
| WO2007134843A3 (en) | 2008-11-27 |
| EP2037006A3 (de) | 2009-08-05 |
| EP2032743B1 (de) | 2010-10-27 |
| JP2009537997A (ja) | 2009-10-29 |
| CN101522954A (zh) | 2009-09-02 |
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