JP2009516019A5 - - Google Patents
Download PDFInfo
- Publication number
- JP2009516019A5 JP2009516019A5 JP2008540035A JP2008540035A JP2009516019A5 JP 2009516019 A5 JP2009516019 A5 JP 2009516019A5 JP 2008540035 A JP2008540035 A JP 2008540035A JP 2008540035 A JP2008540035 A JP 2008540035A JP 2009516019 A5 JP2009516019 A5 JP 2009516019A5
- Authority
- JP
- Japan
- Prior art keywords
- copolymer
- mass
- brominated
- butadiene
- content
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920001577 copolymer Polymers 0.000 claims description 69
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 33
- 230000031709 bromination Effects 0.000 claims description 28
- 238000005893 bromination reaction Methods 0.000 claims description 28
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 18
- 229920000642 polymer Polymers 0.000 claims description 14
- QNRMTGGDHLBXQZ-UHFFFAOYSA-N buta-1,2-diene Chemical class CC=C=C QNRMTGGDHLBXQZ-UHFFFAOYSA-N 0.000 claims description 13
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 11
- -1 vinyl aromatic hydrocarbon Chemical class 0.000 claims description 11
- 229920002554 vinyl polymer Polymers 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 10
- 239000000178 monomer Substances 0.000 claims description 9
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 7
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 7
- 229910052794 bromium Inorganic materials 0.000 claims description 7
- 230000004580 weight loss Effects 0.000 claims description 7
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 6
- 239000003063 flame retardant Substances 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical group Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 claims description 4
- 238000002411 thermogravimetry Methods 0.000 claims description 4
- 238000005160 1H NMR spectroscopy Methods 0.000 claims description 3
- 229920001400 block copolymer Polymers 0.000 claims description 3
- JQRYUMGHOUYJFW-UHFFFAOYSA-N pyridine;trihydrobromide Chemical compound [Br-].[Br-].[Br-].C1=CC=[NH+]C=C1.C1=CC=[NH+]C=C1.C1=CC=[NH+]C=C1 JQRYUMGHOUYJFW-UHFFFAOYSA-N 0.000 claims description 3
- 239000004793 Polystyrene Substances 0.000 claims description 2
- 229920002223 polystyrene Polymers 0.000 claims description 2
- 229920005604 random copolymer Polymers 0.000 claims description 2
- 229920002959 polymer blend Polymers 0.000 claims 8
- 239000000203 mixture Chemical class 0.000 claims 5
- 239000002904 solvent Substances 0.000 claims 5
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims 4
- 150000003440 styrenes Chemical class 0.000 claims 4
- 125000004432 carbon atom Chemical group C* 0.000 claims 3
- 238000006243 chemical reaction Methods 0.000 claims 3
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims 3
- SSZOCHFYWWVSAI-UHFFFAOYSA-N 1-bromo-2-ethenylbenzene Chemical compound BrC1=CC=CC=C1C=C SSZOCHFYWWVSAI-UHFFFAOYSA-N 0.000 claims 2
- WGGLDBIZIQMEGH-UHFFFAOYSA-N 1-bromo-4-ethenylbenzene Chemical compound BrC1=CC=C(C=C)C=C1 WGGLDBIZIQMEGH-UHFFFAOYSA-N 0.000 claims 2
- NVZWEEGUWXZOKI-UHFFFAOYSA-N 1-ethenyl-2-methylbenzene Chemical compound CC1=CC=CC=C1C=C NVZWEEGUWXZOKI-UHFFFAOYSA-N 0.000 claims 2
- VKVLTUQLNXVANB-UHFFFAOYSA-N 1-ethenyl-2-nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1C=C VKVLTUQLNXVANB-UHFFFAOYSA-N 0.000 claims 2
- UAJRSHJHFRVGMG-UHFFFAOYSA-N 1-ethenyl-4-methoxybenzene Chemical compound COC1=CC=C(C=C)C=C1 UAJRSHJHFRVGMG-UHFFFAOYSA-N 0.000 claims 2
- YFZHODLXYNDBSM-UHFFFAOYSA-N 1-ethenyl-4-nitrobenzene Chemical compound [O-][N+](=O)C1=CC=C(C=C)C=C1 YFZHODLXYNDBSM-UHFFFAOYSA-N 0.000 claims 2
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 claims 2
- 239000000654 additive Substances 0.000 claims 2
- 230000000996 additive effect Effects 0.000 claims 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims 2
- 150000002148 esters Chemical class 0.000 claims 2
- 239000006260 foam Substances 0.000 claims 2
- SFBTTWXNCQVIEC-UHFFFAOYSA-N o-Vinylanisole Chemical compound COC1=CC=CC=C1C=C SFBTTWXNCQVIEC-UHFFFAOYSA-N 0.000 claims 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 1
- BTOVVHWKPVSLBI-UHFFFAOYSA-N 2-methylprop-1-enylbenzene Chemical compound CC(C)=CC1=CC=CC=C1 BTOVVHWKPVSLBI-UHFFFAOYSA-N 0.000 claims 1
- CVEPFOUZABPRMK-UHFFFAOYSA-N 2-methylprop-2-enoic acid;styrene Chemical compound CC(=C)C(O)=O.C=CC1=CC=CC=C1 CVEPFOUZABPRMK-UHFFFAOYSA-N 0.000 claims 1
- TXQHJLUVWZNSLH-UHFFFAOYSA-N 5-ethenyl-2,5-dimethylcyclohexa-1,3-diene Chemical compound CC1(C=C)CC=C(C=C1)C TXQHJLUVWZNSLH-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 239000002671 adjuvant Substances 0.000 claims 1
- 150000001298 alcohols Chemical class 0.000 claims 1
- 239000003963 antioxidant agent Substances 0.000 claims 1
- 230000003078 antioxidant effect Effects 0.000 claims 1
- 239000011324 bead Substances 0.000 claims 1
- 230000001413 cellular effect Effects 0.000 claims 1
- 238000004581 coalescence Methods 0.000 claims 1
- 239000003086 colorant Substances 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 229920000359 diblock copolymer Polymers 0.000 claims 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 claims 1
- 239000004088 foaming agent Substances 0.000 claims 1
- 229920000578 graft copolymer Polymers 0.000 claims 1
- 239000012760 heat stabilizer Substances 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000002667 nucleating agent Substances 0.000 claims 1
- 229920003251 poly(α-methylstyrene) Polymers 0.000 claims 1
- 239000002516 radical scavenger Substances 0.000 claims 1
- 229920000428 triblock copolymer Polymers 0.000 claims 1
- 239000000326 ultraviolet stabilizing agent Substances 0.000 claims 1
- 239000002174 Styrene-butadiene Substances 0.000 description 9
- 229920003048 styrene butadiene rubber Polymers 0.000 description 9
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 5
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000005062 Polybutadiene Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 229920002857 polybutadiene Polymers 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 239000011342 resin composition Substances 0.000 description 2
- DEIGXXQKDWULML-UHFFFAOYSA-N 1,2,5,6,9,10-hexabromocyclododecane Chemical compound BrC1CCC(Br)C(Br)CCC(Br)C(Br)CCC1Br DEIGXXQKDWULML-UHFFFAOYSA-N 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001649 bromium compounds Chemical group 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US73536105P | 2005-11-12 | 2005-11-12 | |
| US60/735,361 | 2005-11-12 | ||
| PCT/US2006/041295 WO2007058736A1 (en) | 2005-11-12 | 2006-10-23 | Brominated butadiene/vinyl aromatic copolymers, blends of such copolymers with a vinyl aromatic polymer, and polymeric foams formed from such blends |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2009516019A JP2009516019A (ja) | 2009-04-16 |
| JP2009516019A5 true JP2009516019A5 (cg-RX-API-DMAC7.html) | 2009-12-10 |
| JP5302001B2 JP5302001B2 (ja) | 2013-10-02 |
Family
ID=37836853
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008540035A Active JP5302001B2 (ja) | 2005-11-12 | 2006-10-23 | 臭素化ブタジエン・ビニル芳香族炭化水素共重合体、その共重合体とビニル芳香族炭化水素重合体との配合物、およびその配合物から形成された重合体発泡体 |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US7851558B2 (cg-RX-API-DMAC7.html) |
| EP (1) | EP1957544B1 (cg-RX-API-DMAC7.html) |
| JP (1) | JP5302001B2 (cg-RX-API-DMAC7.html) |
| KR (1) | KR20080066787A (cg-RX-API-DMAC7.html) |
| CN (1) | CN101305022B (cg-RX-API-DMAC7.html) |
| AT (1) | ATE455796T1 (cg-RX-API-DMAC7.html) |
| AU (1) | AU2006315878A1 (cg-RX-API-DMAC7.html) |
| BR (1) | BRPI0619699A2 (cg-RX-API-DMAC7.html) |
| CA (1) | CA2627253C (cg-RX-API-DMAC7.html) |
| DE (1) | DE602006011944D1 (cg-RX-API-DMAC7.html) |
| ES (1) | ES2336951T3 (cg-RX-API-DMAC7.html) |
| HR (1) | HRP20080206A2 (cg-RX-API-DMAC7.html) |
| NO (1) | NO20081960L (cg-RX-API-DMAC7.html) |
| RU (1) | RU2414479C2 (cg-RX-API-DMAC7.html) |
| WO (1) | WO2007058736A1 (cg-RX-API-DMAC7.html) |
Families Citing this family (112)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2054446B1 (en) * | 2006-08-16 | 2019-07-24 | Dow Global Technologies LLC | Process for brominating butadiene/vinyl aromatic copolymers |
| CN101583631B (zh) * | 2006-08-16 | 2012-08-08 | 陶氏环球技术公司 | 溴化丁二烯/乙烯基芳族共聚物的方法 |
| CN101848942B (zh) | 2007-11-07 | 2012-04-18 | 陶氏环球技术公司 | 从溶液中回收溴化丁二烯聚合物的部分溶剂汽提法 |
| WO2009139942A2 (en) * | 2008-03-06 | 2009-11-19 | Dow Global Technologies Inc. | Process for brominating butadiene copolymers by the addition of water or certain solvents |
| CN101981061B (zh) * | 2008-04-07 | 2013-02-06 | 陶氏环球技术公司 | 溴化丁二烯/乙烯基芳族共聚物的方法 |
| WO2009134628A1 (en) * | 2008-05-01 | 2009-11-05 | Dow Global Technologies Inc. | Two-step process for brominating butadiene copolymers |
| US9732178B1 (en) | 2008-07-24 | 2017-08-15 | Bridgestone Corporation | Block copolymers including high vinyl segments |
| JP5524964B2 (ja) * | 2008-08-05 | 2014-06-18 | ダウ グローバル テクノロジーズ エルエルシー | 有機ポリマーのための溶媒移行法 |
| CN102124047A (zh) * | 2008-08-18 | 2011-07-13 | 陶氏环球技术有限责任公司 | 用于形成溴化聚丁二烯聚合物粒子并将其脱挥发分的方法 |
| US8372921B2 (en) * | 2008-08-22 | 2013-02-12 | Dow Global Technologies Llc | Process for brominating unsaturated organic compounds using a quaternary phosphonium tribromide as the brominating agent |
| US8450383B2 (en) | 2008-10-31 | 2013-05-28 | Dow Global Technologies Llc | Extruded polymer foams containing esters of a sugar and a brominated fatty acid as a flame retardant additive |
| RU2528677C2 (ru) * | 2008-12-18 | 2014-09-20 | ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи | Стабилизаторы для полимеров, содержащих бром алифатического присоединения |
| WO2010080286A1 (en) * | 2008-12-19 | 2010-07-15 | Dow Global Technologies Inc. | Process for brominating butadiene polymers using ester solvent mixtures |
| JP5596780B2 (ja) | 2009-03-31 | 2014-09-24 | ダウ グローバル テクノロジーズ エルエルシー | 第四級アンモニウム又は第四級ホスホニウム一塩化物の除去を伴う、不飽和有機化合物の臭素化方法 |
| CN102471397B (zh) * | 2009-06-30 | 2013-11-06 | 陶氏环球技术有限责任公司 | 溴化并环氧化的阻燃剂 |
| DE102009059781A1 (de) | 2009-12-18 | 2011-06-22 | Basf Se, 67063 | Flammgeschützte Polymerschaumstoffe |
| US8691896B2 (en) | 2010-02-05 | 2014-04-08 | Basf Se | Halogen-free, phosphorus-containing flame-retardant polymer foams |
| WO2011095552A1 (de) | 2010-02-05 | 2011-08-11 | Basf Se | Flammschutzmittel |
| CN102741332A (zh) | 2010-02-05 | 2012-10-17 | 巴斯夫欧洲公司 | 无卤含磷阻燃聚合物泡沫 |
| WO2011113795A2 (de) | 2010-03-17 | 2011-09-22 | Basf Se | Flammgeschützter verbundschaumstoff |
| US9115312B2 (en) | 2010-04-01 | 2015-08-25 | Basf Se | Flame retardant |
| JP5882985B2 (ja) | 2010-04-01 | 2016-03-09 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 難燃剤 |
| EP2580250B1 (en) * | 2010-06-14 | 2021-10-27 | DDP Specialty Electronic Materials US, LLC | Process for brominating butadiene polymers |
| WO2012016906A1 (de) | 2010-08-05 | 2012-02-09 | Basf Se | Halogenhaltige polymermischungen |
| RU2593628C2 (ru) * | 2010-12-17 | 2016-08-10 | ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи | Способ экструдирования полистирола из расплава |
| PT2718358E (pt) * | 2011-06-08 | 2015-05-21 | Italmatch Chemicals Spa | Espumas de poliestireno extrudido retardadoras de chama |
| RU2014105432A (ru) * | 2011-07-14 | 2015-08-20 | ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи | Пленки для селективного переноса газов, содержащие бромированные стирол-бутадиеновые сополимеры |
| WO2013009469A1 (en) * | 2011-07-14 | 2013-01-17 | Dow Global Technologies Llc | Impact-modified styrenic polymers containing brominated vinyl aromatic-butadiene copolymer |
| WO2013017417A1 (de) | 2011-07-29 | 2013-02-07 | Basf Se | Polymeres flammschutzmittel |
| ITVI20110231A1 (it) | 2011-08-09 | 2013-02-10 | Micaela Lorenzi | Nuova composizione ritardante di fiamma per polistirene |
| ITMI20111982A1 (it) * | 2011-11-02 | 2013-05-03 | Polimeri Europa Spa | Composizioni a base di polimeri vinilaromatici espansibili autoestinguenti |
| JP2013116958A (ja) | 2011-12-02 | 2013-06-13 | Dow Global Technologies Llc | 発泡性スチレン系樹脂組成物及びスチレン系樹脂発泡体の製造方法 |
| ES2802773T3 (es) * | 2011-12-19 | 2021-01-21 | Ddp Specialty Electronic Mat Us Inc | Espuma de poliuretano termoestable que contiene retardador de llama polimérico bromado |
| WO2013092322A2 (de) | 2011-12-21 | 2013-06-27 | Basf Se | Verfahren zur herstellung von expandierbaren, graphit- und flammschutzmittelhaltigen styrolpolymerisaten |
| JP5943730B2 (ja) * | 2012-06-13 | 2016-07-05 | 株式会社ジェイエスピー | ポリスチレン系樹脂押出発泡体の製造方法 |
| WO2014014648A2 (en) | 2012-07-18 | 2014-01-23 | Rohm And Haas Company | Textiles with brominated polymer flame retardant |
| NL2009320C2 (nl) * | 2012-08-14 | 2014-02-18 | Synbra Tech Bv | Deeltjesvormig, expandeerbaar polymeer, werkwijze ter vervaardiging hiervan, alsmede de toepassing. |
| WO2014066089A1 (en) | 2012-10-24 | 2014-05-01 | Dow Global Technologies Llc | Glycerol ester and brominated polymer in styrenic polymer |
| ITMI20121808A1 (it) | 2012-10-24 | 2014-04-25 | Versalis Spa | Composizioni polimeriche concentrate di polimeri e/o copolimeri vinilaromatici |
| WO2014111629A1 (en) | 2013-01-18 | 2014-07-24 | Styrochem Finland Oy | Method of producing polystyrene beads containing athermanous particles |
| WO2014125933A1 (ja) | 2013-02-14 | 2014-08-21 | 株式会社カネカ | スチレン系樹脂押出発泡体及びそのリサイクル方法 |
| BR112015024055A2 (pt) | 2013-03-20 | 2017-07-18 | Basf Se | composição de polímero, em especial para aplicações de moldagem por injeção, processo para produzir uma composição de polímero, em especial para aplicações de moldagem por injeção, molde obtenível através de moldagem por injeção de uma composição de polímero e uso de uma moldagem por injeção |
| EP2789651A1 (de) | 2013-04-11 | 2014-10-15 | Basf Se | Flammschutzmittelzusammensetzung zur Verwendung in Styrolpolymerschaumstoffen |
| JP6128940B2 (ja) * | 2013-05-09 | 2017-05-17 | 株式会社ジェイエスピー | ポリスチレン系樹脂押出発泡板の製造方法 |
| JP6099495B2 (ja) * | 2013-06-21 | 2017-03-22 | 株式会社ジェイエスピー | 難燃剤溶融混練物及びこれを用いたポリスチレン系樹脂押出発泡体の製造方法 |
| JP6139294B2 (ja) * | 2013-06-24 | 2017-05-31 | 株式会社カネカ | スチレン系樹脂押出発泡体及びその製造方法 |
| JP6389591B2 (ja) * | 2013-07-04 | 2018-09-12 | 株式会社ジェイエスピー | ポリスチレン系樹脂発泡体の製造方法 |
| JP6133150B2 (ja) * | 2013-07-04 | 2017-05-24 | 株式会社ジェイエスピー | 難燃剤溶融混練物を用いたポリスチレン系樹脂発泡体の製造方法 |
| WO2015065393A1 (en) | 2013-10-30 | 2015-05-07 | Dow Global Technologies Llc | Foamed styrenic polymers containing a brominated styrene-butadiene copolymer and having enhanced cell size homogeneity |
| JP6192106B2 (ja) * | 2013-11-06 | 2017-09-06 | 株式会社ジェイエスピー | ポリスチレン系樹脂押出発泡板の製造方法 |
| KR102209565B1 (ko) * | 2013-11-14 | 2021-02-01 | 가부시키가이샤 가네카 | 스티렌계 수지 압출 발포체 및 그의 제조 방법 |
| JP6349697B2 (ja) * | 2013-11-27 | 2018-07-04 | 株式会社ジェイエスピー | 発泡性ポリスチレン系樹脂粒子の製造方法 |
| JP6220663B2 (ja) * | 2013-12-17 | 2017-10-25 | 株式会社カネカ | 難燃性を付与した発泡性スチレン系樹脂粒子とその製造方法 |
| CN105992793A (zh) * | 2014-02-03 | 2016-10-05 | 陶氏环球技术有限责任公司 | 具有溴化苯乙烯/丁二烯共聚物和金属氧化物红外衰减剂的稳定的苯乙烯类发泡体 |
| EP2957595A1 (de) | 2014-06-18 | 2015-12-23 | Basf Se | Flammschutzmittelzusammensetzung zur Verwendung in Styrolpolymerschaumstoffen |
| EP2957413A1 (de) | 2014-06-18 | 2015-12-23 | Basf Se | Verfahren zur entgasung von flammgeschützten, treibmittelhaltigen polymergranulaten oder flammgeschützten schaumstoffrecyclaten |
| JP6405781B2 (ja) * | 2014-08-08 | 2018-10-17 | 株式会社ジェイエスピー | 発泡性スチレン系樹脂粒子及びその製造方法 |
| CN104177531B (zh) * | 2014-08-26 | 2016-07-06 | 山东天一化学股份有限公司 | 一种含吡啶基团阻燃聚合物的制备方法 |
| EP3250613B1 (en) * | 2015-01-30 | 2019-06-19 | Dow Global Technologies LLC | Method for producing brominated and halohydrated polymers |
| CN106146768B (zh) * | 2015-04-02 | 2018-09-04 | 中国石油化工股份有限公司 | 作为阻燃剂的溴化的嵌段共聚物及其制备方法 |
| CN106146767B (zh) * | 2015-04-02 | 2018-09-04 | 中国石油化工股份有限公司 | 作为阻燃剂的溴化的嵌段共聚物及其制备方法 |
| CN106146769B (zh) * | 2015-04-24 | 2018-09-04 | 中国石油化工股份有限公司 | 作为阻燃剂的溴化的嵌段共聚物及其制备方法 |
| JP6512580B2 (ja) * | 2015-10-30 | 2019-05-15 | 株式会社ジェイエスピー | ポリスチレン系樹脂発泡板の製造方法 |
| JP6541555B2 (ja) * | 2015-11-25 | 2019-07-10 | 株式会社ジェイエスピー | ポリスチレン系樹脂発泡板の製造方法 |
| JP6124484B2 (ja) * | 2016-03-25 | 2017-05-10 | 株式会社ジェイエスピー | ポリスチレン系樹脂押出発泡体の製造方法 |
| CN118878998A (zh) | 2016-05-11 | 2024-11-01 | 欧文斯科宁知识产权资产有限公司 | 包含低水平溴化阻燃剂的聚合物泡沫及其制备方法 |
| IT201600071347A1 (it) | 2016-07-08 | 2018-01-08 | Versalis Spa | Composizioni espandibili contenenti polimeri vinil aromatici aventi proprietà autoestinguenti e migliorata processabilità |
| PL3458490T3 (pl) | 2016-09-09 | 2023-06-26 | Dynasol Elastómeros, S.A.De C.V. | Układy modyfikatorów polarnych dla wysokiej kopolimeryzacji bloku winylu |
| JP6262384B1 (ja) | 2016-10-03 | 2018-01-17 | 東洋スチレン株式会社 | 難燃性樹脂組成物及び難燃性樹脂成形体 |
| JP6192143B1 (ja) | 2016-10-03 | 2017-09-06 | 東洋スチレン株式会社 | 難燃性樹脂組成物及び難燃性樹脂成形体 |
| KR102569082B1 (ko) | 2016-11-02 | 2023-08-24 | 다우 글로벌 테크놀로지스 엘엘씨 | 반결정질 폴리올레핀계 첨가제 마스터배치 조성물 |
| CN109890878B (zh) | 2016-11-02 | 2022-07-08 | 陶氏环球技术有限责任公司 | 半结晶聚烯烃类添加剂母料组合物 |
| RU2768478C2 (ru) | 2016-11-02 | 2022-03-24 | Дау Глоубл Текнолоджиз Ллк | Полукристаллическая композиция суперконцентрата добавки на основе полиолефина |
| CN106947007A (zh) * | 2017-04-21 | 2017-07-14 | 天津天盈新型建材有限公司 | 一种溴化高分子阻燃剂及其制备方法 |
| EP3625310B1 (de) | 2017-05-17 | 2021-04-28 | Basf Se | Bromierte flammschutzmittel |
| US11248080B2 (en) | 2017-05-17 | 2022-02-15 | Basf Se | Brominated flame retardant |
| JP6335368B2 (ja) * | 2017-06-13 | 2018-05-30 | 株式会社ジェイエスピー | ポリスチレン系樹脂押出発泡板の製造方法 |
| JP6366149B2 (ja) * | 2017-06-13 | 2018-08-01 | 株式会社ジェイエスピー | ポリスチレン系樹脂押出発泡板 |
| JP6335367B2 (ja) * | 2017-06-13 | 2018-05-30 | 株式会社ジェイエスピー | ポリスチレン系樹脂押出発泡板の製造方法 |
| CN110997777B (zh) | 2017-08-04 | 2022-08-02 | 株式会社钟化 | 发泡性聚苯乙烯系树脂颗粒、聚苯乙烯系预发泡颗粒、发泡成型体、及它们的制造方法 |
| MX2020001523A (es) | 2017-08-10 | 2020-03-20 | Dow Global Technologies Llc | Composiciones que comprenden pirorretardantes bromados polimericos. |
| CN108129618B (zh) * | 2017-12-12 | 2019-10-22 | 浙江大学 | 中低分子量含溴多嵌段共聚物阻燃剂及其溶液三步制备法 |
| KR102621597B1 (ko) * | 2018-09-10 | 2024-01-08 | 에스케이이노베이션 주식회사 | 난연제 및 이를 포함하는 난연성 수지 조성물 |
| US11542355B2 (en) | 2018-10-18 | 2023-01-03 | Dynasol Elastómeros, S.A. De C.V. | Polar modifier systems for high vinyl block copolymerization |
| WO2020139113A1 (en) | 2018-12-27 | 2020-07-02 | Public Joint Stock Company "Sibur Holding" | Modified diene-containing (co)polymer, method for preparing thereof and use of the same as flame retardant |
| JP7142786B2 (ja) | 2018-12-27 | 2022-09-27 | パブリック・ジョイント・ストック・カンパニー・“シブール・ホールディング” | 変性（コ）ポリマー、それを調製する方法及びその使用 |
| EA202191702A1 (ru) * | 2018-12-27 | 2021-09-09 | Публичное акционерное общество "СИБУР Холдинг" | Модифицированный диенсодержащий (со)полимер, способ его получения и применения в качестве антипирена |
| WO2020139114A1 (en) | 2018-12-27 | 2020-07-02 | Public Joint Stock Company "Sibur Holding" | Modified diene-containing (co)polymer, method for preparing thereof and use of the same as flame retardant |
| WO2020139111A1 (en) | 2018-12-27 | 2020-07-02 | Public Joint Stock Company "Sibur Holding" | Modified diene-containing (co)polymer, method for producing the same and use of the same as a flame retardant |
| CN109762121B (zh) * | 2018-12-27 | 2021-07-30 | 山东旭锐新材有限公司 | 一种低分子量高热稳定性的溴化sbs产品及其制备方法 |
| CN109762120B (zh) * | 2018-12-27 | 2021-07-30 | 山东旭锐新材有限公司 | 一种窄分子量分布高热稳定性的溴化sbs产品及其制备方法 |
| CA3127433A1 (en) * | 2019-02-06 | 2020-08-13 | Dow Global Technologies Llc | Flame-retardant moisture-crosslinkable compositions |
| DE102019001656B4 (de) | 2019-03-07 | 2022-03-17 | lnstitut für Kunststofftechnologie und -recycling e.V. | Makromolekulare Verbindungen mit hohen Gehalten an Phosphor und Stickstoff, Verfahren zur Herstellung und Verwendung |
| US12371898B2 (en) | 2019-05-21 | 2025-07-29 | Kingspan Holdings (Irl) Limited | Barrier, construction article and method of manufacture thereof |
| EP4025635B1 (en) | 2019-09-04 | 2025-10-15 | TotalEnergies OneTech Belgium | Expandable vinyl aromatic polymers with improved flame retardancy |
| RU2732675C1 (ru) * | 2019-12-26 | 2020-09-22 | Публичное акционерное общество «СИБУР Холдинг» | Способ получения модифицированного диенсодержащего (со)полимера и его применение в качестве антипирена |
| KR20230008128A (ko) * | 2020-04-21 | 2023-01-13 | 바스프 에스이 | 중합성 브롬화 난연제를 포함하는 발포성 스티렌 중합체 |
| CN115485309B (zh) * | 2020-04-21 | 2024-12-10 | 朗盛公司 | 制备共轭二烯和苯乙烯单体的溴化共聚物的方法 |
| KR20230025694A (ko) | 2020-06-10 | 2023-02-22 | 바스프 에스이 | 난연성 스티렌 중합체 조성물 및 스티렌 중합체 함유 스크랩을 재활용하는 방법 |
| CN112079944B (zh) * | 2020-08-13 | 2022-06-14 | 山东润科化工股份有限公司 | 一种芳香族及脂肪链共同溴化的高分子聚合物及制备方法 |
| KR102878587B1 (ko) * | 2020-09-18 | 2025-10-30 | 주식회사 엘지화학 | 이소부텐-이소프렌 공중합체의 브롬화 방법 |
| CN115362183B (zh) * | 2020-09-18 | 2024-12-10 | 株式会社Lg化学 | 使异丁烯-异戊二烯共聚物卤化的方法 |
| AU2021373444A1 (en) * | 2020-11-09 | 2023-05-25 | Nippon Soda Co., Ltd. | Method for producing block copolymer |
| EP4255966A1 (en) | 2020-12-01 | 2023-10-11 | DDP Specialty Electronic Materials US, LLC | Flame retardant masterbatch composition for foams containing a ph moderator |
| EP4263753B1 (de) | 2020-12-17 | 2024-10-09 | Hochschule Hamm-Lippstadt, Körperschaft des öffentlichen Rechts | Brandhindernde copolymere und formmassen |
| EP4347668B1 (en) | 2021-05-24 | 2025-04-02 | DDP Specialty Electronic Materials US, LLC | Process for recovering quaternary salt bromination catalyst |
| CN116355154A (zh) * | 2021-12-28 | 2023-06-30 | 中国石油天然气股份有限公司 | 一种溴化接枝剂及其制备方法和应用 |
| WO2023166036A1 (en) | 2022-03-04 | 2023-09-07 | Basf Se | Polyurethane (pu) composition and method of producing pu composition |
| TW202348664A (zh) | 2022-04-11 | 2023-12-16 | 德商巴斯夫歐洲公司 | 基於木質素之ｔｐｕ組成物、其製備方法及其用途 |
| WO2024015544A1 (en) | 2022-07-15 | 2024-01-18 | Basf Se | Parcel chute and panel construction therefore, and a process for preparing the same |
| CN119894954A (zh) | 2022-09-20 | 2025-04-25 | 巴斯夫欧洲公司 | 用于围阻pfas的系统和方法 |
| WO2024137411A1 (en) | 2022-12-22 | 2024-06-27 | Basf Se | Polyurethane foam with eo/po copolymer |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1075103B (de) | 1960-02-11 | VEB Leuna-Werke "Walter Ulbricht", Leuna (Kr. Merseburg) | Verfahren zur kontinuierlichen Herstellung von Epichlorhydrin aus Glyzerin | |
| DE1301497B (de) | 1966-01-05 | 1969-08-21 | Basf Ag | Verfahren zur Herstellung bromierter Polymerisate des Butadiens |
| DE1260138B (de) | 1966-01-05 | 1968-02-01 | Basf Ag | Formmassen zur Herstellung selbstverloeschender Formkoerper |
| DE1769320A1 (de) | 1968-05-08 | 1971-09-16 | Hoechst Ag | Selbstverloeschende Styrolpolymerisate mit gleichmaessiger Porenstruktur |
| US3639304A (en) * | 1968-06-27 | 1972-02-01 | Dow Chemical Co | Self-extinguishing polyethylene foams comprising an antimony compound a halogen-containing aliphatic or cyclo-aliphatic compound and a bromine-containing aromatic or acyclic compound |
| US3668155A (en) * | 1968-06-27 | 1972-06-06 | Dow Chemical Co | Self-extinguishing ethylene copolymer foams comprising a ternary mixture of an antimony compound, a halogen-containing compound and a bromine compound |
| US3652494A (en) * | 1968-08-16 | 1972-03-28 | Phillips Petroleum Co | Stabilized flameproofed thermoplastic compositions |
| GB1277736A (en) * | 1968-09-30 | 1972-06-14 | British Petroleum Co | Catalyst support |
| DD137308A3 (de) * | 1969-09-24 | 1979-08-29 | Paul Herte | Verfahren zur herstellung von bromierten ungesaettigten niedermolekularen polymeren |
| US3640941A (en) * | 1970-05-08 | 1972-02-08 | Whittaker Corp | Adhesive composition |
| DE2314544A1 (de) * | 1973-03-23 | 1974-10-10 | Basf Ag | Feinteilige, expandierbare, schwer entflammbare styrolpolymerisate mit guter verarbeitbarkeit |
| CA1060139A (en) * | 1973-07-30 | 1979-08-07 | Shell Canada Limited | Halogenated, partially hydrogenated block copolymer consisting of a polymer block of an aromatic alkenyl or alkenylidene hydrocarbon and a polymer block of butadiene and its preparation |
| JPS5125592A (en) * | 1974-08-27 | 1976-03-02 | Toray Industries | Shusokajugotaino seizohoho |
| SU597687A1 (ru) * | 1976-03-09 | 1978-03-15 | Предприятие П/Я В-2756 | Бромированный бутадиен-нитрильный каучук как огнестойка добавка в полимерных композици х |
| JPS5424997A (en) * | 1977-07-27 | 1979-02-24 | Tokai Rubber Ind Ltd | Chlorinated brominated elastmer of styreneebutadiene copolymer |
| JPS55135101A (en) * | 1979-04-11 | 1980-10-21 | Japan Synthetic Rubber Co Ltd | Production of brominated rubber and brominated rubber composition |
| JPS55131002A (en) | 1979-03-30 | 1980-10-11 | Japan Synthetic Rubber Co Ltd | Crystalline brominated 1,2-polybutadiene and preparation thereof |
| JPS5841302B2 (ja) | 1980-12-29 | 1983-09-10 | アキレス株式会社 | 難燃性を有する発泡性ポリスチレン樹脂組成物 |
| DE4213164A1 (de) | 1992-04-22 | 1993-10-28 | Bayer Ag | Verfahren zur Herstellung von bromiertem chlorsubstituiertem Poly-1,3-butadien |
| JPH06322023A (ja) * | 1993-05-14 | 1994-11-22 | Manac Inc | 回収した発泡ポリスチレンを原料とする臭素化ポリスチレンの製造方法 |
| US5532322B1 (en) * | 1995-09-26 | 1999-12-07 | Manac Inc | Process for preparing brominated polystyrene |
| RU2177952C2 (ru) * | 1999-03-23 | 2002-01-10 | Щербань Георгий Трофимович | Способ получения галоидированного бутилкаучука |
| GB0407463D0 (en) | 2004-04-01 | 2004-05-05 | Nova Chem Int Sa | Extruded foam structure with an inorganic blowing agent |
| EP2054446B1 (en) * | 2006-08-16 | 2019-07-24 | Dow Global Technologies LLC | Process for brominating butadiene/vinyl aromatic copolymers |
-
2006
- 2006-10-23 RU RU2008123837/04A patent/RU2414479C2/ru active
- 2006-10-23 CA CA2627253A patent/CA2627253C/en active Active
- 2006-10-23 WO PCT/US2006/041295 patent/WO2007058736A1/en not_active Ceased
- 2006-10-23 KR KR1020087011118A patent/KR20080066787A/ko not_active Withdrawn
- 2006-10-23 CN CN2006800422261A patent/CN101305022B/zh active Active
- 2006-10-23 ES ES06836467T patent/ES2336951T3/es active Active
- 2006-10-23 AT AT06836467T patent/ATE455796T1/de not_active IP Right Cessation
- 2006-10-23 AU AU2006315878A patent/AU2006315878A1/en not_active Abandoned
- 2006-10-23 BR BRPI0619699-3A patent/BRPI0619699A2/pt not_active Application Discontinuation
- 2006-10-23 EP EP06836467A patent/EP1957544B1/en active Active
- 2006-10-23 DE DE602006011944T patent/DE602006011944D1/de active Active
- 2006-10-23 JP JP2008540035A patent/JP5302001B2/ja active Active
- 2006-10-23 HR HR20080206A patent/HRP20080206A2/xx not_active Application Discontinuation
- 2006-10-23 US US12/091,346 patent/US7851558B2/en active Active
-
2008
- 2008-04-25 NO NO20081960A patent/NO20081960L/no not_active Application Discontinuation
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2009516019A5 (cg-RX-API-DMAC7.html) | ||
| CN101305022B (zh) | 溴化丁二烯/乙烯基芳族共聚物、该共聚物与乙烯基芳族聚合物的掺合物和由该掺合物形成的聚合物泡沫 | |
| CN102356123B (zh) | 阻燃性发泡苯乙烯系树脂组合物 | |
| CN105189628B (zh) | 阻燃性发泡苯乙烯系树脂组合物及其发泡成形体 | |
| JP2013076100A (ja) | 難燃添加剤としての臭素化ポリマー及びそれを含むポリマー系 | |
| CN107892780B (zh) | 阻燃性树脂组合物和阻燃性树脂成型体 | |
| EP3625310A1 (de) | Bromierte flammschutzmittel | |
| EP4165129A1 (en) | Flame retardant styrene polymer composition and process for recycling styrene polymercontaining scrap | |
| BRPI0614787A2 (pt) | espumas poliméricas estirênicas retardadoras de chama e precursores da espuma | |
| CN101087819A (zh) | 阻燃发泡聚苯乙烯泡沫组合物 | |
| KR102647492B1 (ko) | 브롬화 난연제 | |
| JP7674081B2 (ja) | 押出発泡法によるスチレン系樹脂発泡体の製造方法、及び製造される発泡体、並びに、製造方法に使用する発泡性樹脂組成物 | |
| JP2001164076A (ja) | 難燃性スチレン系樹脂組成物 | |
| TW201235398A (en) | Use of polar additives for enhancing blowing agent solubility in polystyrene | |
| JP6335367B2 (ja) | ポリスチレン系樹脂押出発泡板の製造方法 | |
| JP7142786B2 (ja) | 変性（コ）ポリマー、それを調製する方法及びその使用 | |
| JP6366149B2 (ja) | ポリスチレン系樹脂押出発泡板 | |
| KR20230008128A (ko) | 중합성 브롬화 난연제를 포함하는 발포성 스티렌 중합체 |