JP2005523580A - リモートプラズマを利用してウェーハに薄膜を蒸着する装置及び方法 - Google Patents
リモートプラズマを利用してウェーハに薄膜を蒸着する装置及び方法 Download PDFInfo
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Abstract
Description
第1反応ガスのパージガスであって第1反応ガスの液状ソースバブリングガスである不活性ガスがMFC1によって流量制御された後、第1弁V1を経てソースコンテナ311に流入される段階である。不活性ガスはソースコンテナ311に貯蔵された液状の第1反応物質源をバブリングさせて第1反応ガスを発生させ、その第1反応ガスはバブリングガスと共に共に第3、4弁V3、V4を経て第1反応ガス移送ライン320を通じて反応容器100に流入される。
不活性ガスがMFC1によって流量制御された後、第2、4弁V2、V4を経て第1反応ガス移送ライン320を通じて反応容器100に流入される段階である。すなわち、パージガス(不活性ガス)がソースコンテナ311を通過せずに第1反応ガスが発生せず、したがって、パージガスのみ反応容器100に流入されてその反応容器100内の第1反応ガスをパージする。
第2反応ガスと不活性ガスとをそれぞれMFC2とMFC3とを通じて流量制御した後、第6弁V6と第7弁V7とをそれぞれ開いてリモートプラズマ生成器341に流入させる。不活性ガスと適切に混合された第2反応ガスはリモートプラズマ生成器341を経ながらプラズマガス状態に変換されてラジカルになる。ラジカルのフィーディング段階は、前記のように生成したラジカルが第8弁V8を経てラジカル移送ライン350を通じて反応容器100に流入される段階である。
第8弁V8を閉じ、第9弁V9が開くことによって、ラジカルが反応容器100には流入されず、第2バイパスライン360を通じて排気ライン200の排気ポンプ230に流れるようにし、メインパージガス供給部370から供給されるメインパージガスをラジカル移送ライン350を経て反応容器100内に流れるようにする段階である。すなわち、ラジカル移送ライン350にラジカルの供給を中断させ、MFC4を通じて流量制御されたメインパージガスを第10弁V10→第12弁V12→ラジカル移送ライン350を通じて反応容器100に流れるようにするものである。
第6弁V6を閉じ、第14弁V14を開くことによって、第2反応ガスが第3バイパスライン380を通じて排気ライン200の排気ポンプ230に流れるようにし、MFC3を経由した不活性ガスをリモートプラズマ生成器341及び第8弁V8を通じて反応容器に流れるようにする段階である。すなわち、第2反応ガスが第3、2バイパスライン380、360を通じて排気されることによってリモートプラズマ生成器341に流入されなく、これによりMFC3を経由した不活性ガスのみが反応容器100にフィーディングされてその反応容器100内部のラジカルがパージされる。
図3は、図1のALD装置を利用した薄膜蒸着方法の第1実施例を説明するためのグラフである。第1実施例では、反応容器100内部に基板を位置させ、ラフィング弁210を開くことによって反応容器100と排気ライン200間を常時開放し、ラジカルを反応容器100に常時フィードさせる状態で、第1反応ガスフィーディング段階(S1)とパージ段階(S2)とを行い続けることによって、反応容器100に位置した基板に薄膜を形成する。
Claims (13)
- ウェーハが内蔵される反応容器と、
前記反応容器からガスを外部に排出する排気ラインと、
第1反応ガスを前記反応容器または排気ラインに選択的に供給するための第1反応ガス供給部と、
前記第1反応ガス供給部と前記反応容器とを連結する第1反応ガス移送ラインと、
前記第1反応ガス供給部と前記排気ラインとを連結する第1バイパスラインと、
第2反応ガスにプラズマを印加して対応するラジカルを生成した後、そのラジカルを前記反応容器または排気ラインに選択的に供給するためのラジカル供給部と、
前記ラジカル供給部と前記反応容器とを連結するラジカル移送ラインと、
前記ラジカル供給部と前記排気ラインとを連結する第2バイパスラインと、
メインパージガスを前記第1反応ガス移送ライン及び/または前記ラジカル移送ラインに供給するメインパージガス供給部とを備えるリモートプラズマ原子層蒸着装置。 - 前記第1反応ガス供給部は、第1反応ガスになる液状の第1反応物質が一定量充填されたソースコンテナと、前記ソースコンテナに流れる不活性ガスの流量を調節する第1MFCと、前記不活性ガスまたは第1反応ガスを前記第1反応ガス移送ラインまたは前記第1バイパスラインに選択的に流れるようにするための第1流路変換部とを含む請求項1に記載のリモートプラズマ原子層蒸着装置。
- ラジカル供給部は、流入される第2反応ガスの流量を調節する第2MFCと、流入される不活性ガスの流量を調節する第3MFCと、前記第2MFC及び第3MFCを経由した前記第2反応ガス及び/または不活性ガスが流入されて流入された第2反応ガスにプラズマを印加して対応するラジカルにするリモートプラズマ生成器と、生成したラジカルをラジカル移送ライン及び/または第2バイパスラインに選択的に流れるようにするための第2流路変換部とを含む請求項1に記載のリモートプラズマ原子層蒸着装置。
- 前記第2MFCを経由した第2反応ガスを前記第2バイパスラインに選択的に流れるようにする第3バイパスラインをさらに備える請求項3に記載のリモートプラズマ原子層蒸着装置。
- 前記メインパージガス供給部は、メインパージガスの流量を制御する第4MFCと、前記メインパージガスを第1反応ガス移送ラインまたはラジカル移送ラインに流れるようにする第3流路変換部とを含む請求項1に記載のリモートプラズマ原子層蒸着装置。
- 請求項1ないし5のうち何れか1項に記載のリモートプラズマ原子層蒸着装置を利用する原子層蒸着方法であって、
前記反応容器と排気ライン間のラフィング弁を常時開放し、前記第1流路変換部、第2流路変換部それぞれの内部ポイントA、Bを流れるガスを前記反応容器ないしはバイパスラインに常時流れるようにし、ラジカルを反応容器にフィードさせる状態で、第1反応ガスを反応容器にフィードする第1反応ガスフィーディング段階と、反応容器内部にフィードされた第1反応ガスをパージする第1反応ガスパージ段階とを行い続けることによって、前記反応容器に位置した基板に薄膜を形成することを備える原子層蒸着方法。 - 薄膜蒸着段階の完了後、O、N、H、OH、NH及びその組み合わせよりなる群から選択される少なくとも1つからなるラジカルと不活性ガスとを反応容器に噴射して熱処理する段階をさら備える請求項6に記載の原子層蒸着方法。
- 請求項1ないし5のうち何れか1項に記載のリモートプラズマ原子層蒸着装置を利用する原子層蒸着方法であって、
前記反応容器と排気ライン間のラフィング弁を常時開放した状態で、前記第1流路変換部、第2流路変換部、第3流路変換部それぞれの内部ポイントA、B、Cを流れるガスを前記反応容器ないしはバイパスラインに常時流れるようにし、ラジカルを反応容器にフィードさせるラジカルフィーディング段階)と、反応容器でラジカルをパージさせるラジカルパージ段階と、反応容器に第1反応ガスをフィードする第1反応ガスフィーディング段階と、反応容器で第1反応ガスをパージする第1反応ガスパージ段階とを行い続けることによって、前記反応容器に位置した基板に薄膜を形成し、
前記ラジカルパージ段階は、前記メインパージガス供給部の第4MFCによって流量制御されたメインパージガスをラジカル移送ラインを通じて前記反応容器に噴射することを含む原子層蒸着方法。 - 前記第1反応ガスのパージ時に第1反応ガス移送ラインとラジカル移送ラインとを流れる不活性ガス流量の総和は常時一定に保たれる請求項8に記載の原子層蒸着方法。
- 前記薄膜蒸着段階の完了後、O、N、H、OH、NH及びその組み合わせよりなる群から選択された少なくとも1つからなるラジカルと不活性ガスとを反応容器に噴射して熱処理する段階をさらに備える請求項8に記載の原子層蒸着方法。
- 請求項1ないし5のうち何れか1項に記載のリモートプラズマ原子層蒸着装置を利用する原子層蒸着方法であって、
前記反応容器と排気ライン間のラフィング弁を常時開放した状態で、前記第1流路変換部、ラジカル供給部それぞれの内部ポイントA、Dを流れるガスの流れを前記反応容器ないしはバイパスラインに常時流れるようにし、ラジカルを反応容器にフィードさせるラジカルフィーディング段階と、反応容器でラジカルをパージさせるラジカルパージ段階と、反応容器に第1反応ガスをフィードする第1反応ガスフィーディング段階と、反応容器で第1反応ガスをパージする第1反応ガスパージ段階とを行い続けることによって、前記反応容器に位置した基板に薄膜を形成し、
前記ラジカルパージ段階は、前記ラジカル供給部の第3MFCにより流量制御された不活性ガス(第2反応ガスは排除)のみをラジカル移送ラインを通じて前記反応容器に噴射することを備える原子層蒸着方法。 - 前記第1反応ガスのパージ時に第1反応ガス移送ラインとラジカル移送ラインとを流れる不活性ガス流量の総和は常時一定に保たれる請求項11に記載の原子層蒸着方法。
- 前記薄膜蒸着段階の完了後、O、N、H、OH、NH及びその組み合わせよりなる群から選択された少なくとも1つからなるラジカルと不活性ガスとを反応容器に噴射して熱処理する段階をさらに備える請求項11に記載の原子層蒸着方法。
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KR10-2002-0021554A KR100439948B1 (ko) | 2002-04-19 | 2002-04-19 | 리모트 플라즈마 ald 장치 및 이를 이용한 ald 박막증착방법 |
PCT/KR2003/000786 WO2003089683A1 (en) | 2002-04-19 | 2003-04-17 | Apparatus and method for depositing thin film on wafer using remote plasma |
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- 2003-04-17 AU AU2003223126A patent/AU2003223126A1/en not_active Abandoned
- 2003-04-17 US US10/511,883 patent/US20050223982A1/en not_active Abandoned
- 2003-04-17 WO PCT/KR2003/000786 patent/WO2003089683A1/en active Application Filing
- 2003-04-17 TW TW092108874A patent/TWI233638B/zh not_active IP Right Cessation
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2008277762A (ja) * | 2007-04-02 | 2008-11-13 | Hitachi Kokusai Electric Inc | 基板処理装置および半導体装置の製造方法 |
JP2009007670A (ja) * | 2007-06-19 | 2009-01-15 | Air Products & Chemicals Inc | 金属ケイ素窒化物の被着方法 |
KR20210009391A (ko) * | 2013-07-25 | 2021-01-26 | 삼성디스플레이 주식회사 | 기상 증착 장치 |
KR102329268B1 (ko) * | 2013-07-25 | 2021-11-22 | 삼성디스플레이 주식회사 | 기상 증착 장치 |
US11408072B2 (en) | 2013-07-25 | 2022-08-09 | Samsung Display Co., Ltd. | Vapor deposition apparatus |
KR20210143701A (ko) * | 2021-01-08 | 2021-11-29 | 삼성디스플레이 주식회사 | 기상 증착 장치 |
KR102451734B1 (ko) * | 2021-01-08 | 2022-10-12 | 삼성디스플레이 주식회사 | 기상 증착 장치 |
KR20220139843A (ko) * | 2021-01-08 | 2022-10-17 | 삼성디스플레이 주식회사 | 기상 증착 장치 |
KR102504137B1 (ko) | 2021-01-08 | 2023-02-28 | 삼성디스플레이 주식회사 | 기상 증착 장치 |
Also Published As
Publication number | Publication date |
---|---|
JP4191617B2 (ja) | 2008-12-03 |
TW200307995A (en) | 2003-12-16 |
KR100439948B1 (ko) | 2004-07-12 |
AU2003223126A1 (en) | 2003-11-03 |
US20050223982A1 (en) | 2005-10-13 |
WO2003089683A1 (en) | 2003-10-30 |
TWI233638B (en) | 2005-06-01 |
KR20030083132A (ko) | 2003-10-30 |
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