ES2558946T3 - Método para limpiar un sustrato sucio humedecido con partículas poliméricas - Google Patents

Método para limpiar un sustrato sucio humedecido con partículas poliméricas Download PDF

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Publication number
ES2558946T3
ES2558946T3 ES11716010.1T ES11716010T ES2558946T3 ES 2558946 T3 ES2558946 T3 ES 2558946T3 ES 11716010 T ES11716010 T ES 11716010T ES 2558946 T3 ES2558946 T3 ES 2558946T3
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Prior art keywords
dose
cleaning
formulation
polymer particles
cotton
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Stephen Derek Jenkins
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Xeros Ltd
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Xeros Ltd
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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F39/00—Details of washing machines not specific to a single type of machines covered by groups D06F9/00 - D06F27/00 
    • D06F39/02—Devices for adding soap or other washing agents
    • D06F39/022—Devices for adding soap or other washing agents in a liquid state
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B08—CLEANING
    • B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04—Cleaning involving contact with liquid
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C11D17/046—Insoluble free body dispenser
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3715—Polyesters or polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3719—Polyamides or polyimides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
    • D06L1/12—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
    • D06L1/16—Multi-step processes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
    • D06L1/12—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
    • D06L1/20—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents combined with mechanical means
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/12—Soft surfaces, e.g. textile
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/14—Hard surfaces
    • C11D2111/18—Glass; Plastics

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Detergent Compositions (AREA)
  • Separation Of Solids By Using Liquids Or Pneumatic Power (AREA)
  • Accessory Of Washing/Drying Machine, Commercial Washing/Drying Machine, Other Washing/Drying Machine (AREA)
  • Cleaning By Liquid Or Steam (AREA)

Abstract

Un método para limpiar un sustrato sucio, comprendiendo dicho método el tratamiento del sustrato humedecido con una formulación que comprende una multiplicidad de particular poliméricas, donde dichas partículas poliméricas se aplican en combinación con una formulación detergente, caracterizado por que dicha formulación de detergente se divide en sus constituyentes químicos separados y dichos constituyentes químicos se añaden en diferentes momentos durante el ciclo de lavado donde las partes limpiadoras de la formulación se añaden antes o durante el ciclo principal de lavado y el resto de partes de la formulación se añaden como un post-tratamiento después de la eliminación de las partículas poliméricas del proceso de lavado.

Description

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TABLA 1 ENSAYOS DE LIMPIEZA
5
15
25
35
45
Prueba
Dosis de detergente (g) Ritmo de la dosis Carga de lavado (kg) Dosis de detergente (g/kg) Temperatura de lavado (ºC) Tiempo de ciclo (minutos)
Xero Plus Multi Dosis
Surfactante 32,9 Al inicio del lavado principal (Tiempo t=0) 12 2,74 28 90
Peróxido de hidrógeno 60,0 (35% ac.)
Durante el lavado principal (Tiempo t=10 minutos) 1,75
TAED 14,3
Durante el lavado principal (Tiempo t=10 minutos) 1,19
Abrillantador óptico 1,5
En el enjuague final (Tiempo t=85 minutos) 0,12
Perfume 0,7
En el enjuague final (Tiempo t=85 minutos) 0,06
Xeros Plus Única
Surfactante 32,9 Todos al inicio del lavado principal 12 2,74 28 90
Dosis
Peróxido de hidrógeno 60,0 (35% ac.) (Tiempo t=0) 1,75
TAED 14,3
1,19
Abrillantador óptico 1,5
0,12
Perfume 0,7
0,06
Los ciclos de Xeros Plus Multi Dosis y de Xeros Plus Única Dosis funcionaron a temperaturas equivalentes de lavado de 28 ºC. Cuando se usó el ciclo de Xeros Plus Multi Dosis, estuvo disponible la facilidad para calentar el componente oxidante y su activador por separado del lavado principal en un tanque mezclador a 60 ºC, y esta técnica se utilizó con el fin de permitir que el componente se vuelva más químicamente activo antes de la adición. Como se ha observado previamente, en cambio, la temperatura de lavado durante este ciclo solamente alcanzó 28 ºC ya que, aunque se añadió una pequeña cantidad de agua a 60 ºC, la temperatura ambiente de los otros
55 componentes de lavado se mantuvieron a la temperatura general en el nivel más bajo. Debería señalarse que se añadió la misma cantidad de agua a 60 ºC en la misma fase durante el ciclo de lavado del ciclo Xeros Plus Única Dosis, pero sin ningún componente oxidante o activador, habiéndose ya añadido al inicio del lavado principal, como se muestra en la Tabla 1. El fin de esta agua adicional calentada en el ciclo de Xeros Plus Única Dosis fue, por lo tanto, asegurar un perfil idéntico de temperatura a lo largo del proceso de lavado al aplicado en el caso de Xeros Plus Multi Dosis, hasta la misma temperatura de lavado final de 28 ºC. Por ello, la única diferencia entre estos dos ciclos fue los medios de la adición de detergente (esto es, múltiples dosis de componentes a lo largo del ciclo, contra una única dosis de todos los componentes al inicio del lavado principal). Los tiempos totales de ciclo de ambos ciclos, incluyendo el lavado, la separación de gotas y enjuague, fueron idénticos en 90 minutos. Se usó un programa de tres enjuagues para ambos procedimientos, añadiéndose el abrillantador óptico y el perfume en el enjuague final
65 para el ciclo Xeros Plus Multi Dosis, como se muestra en la Tabla 1.
8
El nivel de limpieza se evaluó usando medición de color. Los valores de reflectancia de monitores de manchas WFC se midieron usando un espectrofotómetro Datacolor Spectraflash SF600 conectado a un ordenador personal, empleando un observador estándar de 10º bajo iluminante D65, con el componente UV incluido y el componente especular excluido, se usó una apertura de visión de 3 cm. Se tomó una coordenada de color CIE L * para cada mancha en el monitores de manchas, y después se hizo la media de estos valores para cada tipo de mancha. Debería señalarse que los valores L * más altos son indicativos de una limpieza mejor. Los resultados se exponen en la Tabla 2.
TABLA 2 RESULTADOS DE LIMPIEZA
15
25
35
45
55
Código de monitor de mancha WFK
Tipo de mancha Xeros Plus Multi Dosis L*MD Xeros Plus Única Dosis L*SD Xeros Plus Multi Dosis-Xeros Plus Única Dosis (L*MD -L*SD) Comentarios
10C
Pigmento/lanolina en algodón 79,99 79,93 0,06 Igualdad
20C
Pigmento/lanolina en poliéster/ algodón 76,55 75,56 0,99 Multi Dosis Superior
90LI
Vino tinto en algodón, maduro (IEC 456) 86,58 85,95 0,63 Multi Dosis Superior
10D
Sebo/pigmento en algodón 84,78 83,53 1,25 Multi Dosis Superior
20D
Sebo/pigmento en poliéster/algodón 85,67 85,51 1,16 Multi Dosis Superior
10U
Curry en algodón 90,45 89,97 0,48 Multi Dosis Superior
10M
Aceite de motor/pigmento en algodón 76,93 75,93 1,00 Multi Dosis Superior
90RM
Hollín/aceite mineral en algodón (IEC 456) 69,48 70,98 -1,50 Única Dosis Superior
90PB
Sangre en algodón, madura (IEC 4569 91,54 89,12 2,42 Multi Dosis Superior
10N
Huevo/pigmento en algodón 83,04 82,12 0,32 Multi Dosis Superior
10R
Almidón/pigmento en algodón 73,12 74,74 -1,62 Única Dosis Superior
10PPM
Grasa vegetal/leche/pigmento en algodón 73,07 72,45 0,62 Multi Dosis Superior
90MF
Cacao en algodón, maduro (IEC 456) 74,99 74,03 0,96 Multi Dosis Superior
Como puede verse en la Tabla 2, el ciclo de Xeros Plus Multi Dosis proporcionó una limpieza abrumadoramente superior al ciclo Xeros Plus Única Dosis. De los trece tipos de mancha analizadas, diez mostraron 65 una limpieza superior con Xeros Plus Multi Dosis, en un caso se observó igualdad en la limpieza con ambos casos,
mientras que solamente dos demostraron una limpieza superior con Xeros Plus Única Dosis.
9
imagen7

Claims (1)

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ES11716010.1T 2010-04-12 2011-04-12 Método para limpiar un sustrato sucio humedecido con partículas poliméricas Active ES2558946T3 (es)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
GB201006076 2010-04-12
GBGB1006076.2A GB201006076D0 (en) 2010-04-12 2010-04-12 Novel cleaning apparatus and method
GBGB1010591.4A GB201010591D0 (en) 2010-04-12 2010-06-24 Novel cleaning method
GB201010591 2010-06-24
PCT/GB2011/050725 WO2011128680A2 (en) 2010-04-12 2011-04-12 Method to clean a moistened soiled substrate with polymeric particles

Publications (1)

Publication Number Publication Date
ES2558946T3 true ES2558946T3 (es) 2016-02-09

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US (3) US9297107B2 (es)
EP (3) EP2677075A1 (es)
JP (3) JP5770264B2 (es)
KR (2) KR101918131B1 (es)
CN (2) CN102933761B (es)
AU (2) AU2011239767B2 (es)
BR (2) BR112012026137A2 (es)
CA (2) CA2795874A1 (es)
ES (1) ES2558946T3 (es)
GB (3) GB201006076D0 (es)
MX (2) MX337414B (es)
NZ (1) NZ602922A (es)
PL (1) PL2558635T3 (es)
RU (1) RU2560273C2 (es)
WO (2) WO2011128680A2 (es)
ZA (1) ZA201207619B (es)

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