ES2168653T3 - Procedimiento para la oxidacion directa de olefinas a oxidos de olefinas. - Google Patents

Procedimiento para la oxidacion directa de olefinas a oxidos de olefinas.

Info

Publication number
ES2168653T3
ES2168653T3 ES97933228T ES97933228T ES2168653T3 ES 2168653 T3 ES2168653 T3 ES 2168653T3 ES 97933228 T ES97933228 T ES 97933228T ES 97933228 T ES97933228 T ES 97933228T ES 2168653 T3 ES2168653 T3 ES 2168653T3
Authority
ES
Spain
Prior art keywords
catalyst
olefine
procedure
oxide
direct oxidation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97933228T
Other languages
English (en)
Spanish (es)
Inventor
Howard J Clark
Joseph J Maj
Robert G Bowman
Simon R Bare
George E Hartwell
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Application granted granted Critical
Publication of ES2168653T3 publication Critical patent/ES2168653T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/50—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Epoxy Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
ES97933228T 1996-07-01 1997-06-30 Procedimiento para la oxidacion directa de olefinas a oxidos de olefinas. Expired - Lifetime ES2168653T3 (es)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US2101396P 1996-07-01 1996-07-01
US67960596A 1996-07-11 1996-07-11
US2659196P 1996-09-20 1996-09-20
US2659096P 1996-09-20 1996-09-20

Publications (1)

Publication Number Publication Date
ES2168653T3 true ES2168653T3 (es) 2002-06-16

Family

ID=27486976

Family Applications (3)

Application Number Title Priority Date Filing Date
ES97933228T Expired - Lifetime ES2168653T3 (es) 1996-07-01 1997-06-30 Procedimiento para la oxidacion directa de olefinas a oxidos de olefinas.
ES97931499T Expired - Lifetime ES2156391T3 (es) 1996-07-01 1997-06-30 Proceso para la oxidacion directa de olefinas a oxidos de olefinas.
ES97932407T Expired - Lifetime ES2164358T3 (es) 1996-07-01 1997-06-30 Procedimiento para la oxidacion directa de olefinas a oxidos de olefinas.

Family Applications After (2)

Application Number Title Priority Date Filing Date
ES97931499T Expired - Lifetime ES2156391T3 (es) 1996-07-01 1997-06-30 Proceso para la oxidacion directa de olefinas a oxidos de olefinas.
ES97932407T Expired - Lifetime ES2164358T3 (es) 1996-07-01 1997-06-30 Procedimiento para la oxidacion directa de olefinas a oxidos de olefinas.

Country Status (11)

Country Link
US (4) US5965754A (https=)
EP (3) EP0915861B1 (https=)
JP (3) JP2000514429A (https=)
KR (3) KR100449421B1 (https=)
CN (4) CN1123568C (https=)
AU (3) AU711962B2 (https=)
BR (3) BR9710122A (https=)
DE (3) DE69704869T2 (https=)
ES (3) ES2168653T3 (https=)
RU (1) RU2189378C2 (https=)
WO (3) WO1998000414A1 (https=)

Families Citing this family (143)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100255480B1 (ko) * 1996-03-21 2000-05-01 사또 다께오 탄화수소의 부분산화용촉매 및 탄화수소의 부분산화방법
RU2189378C2 (ru) * 1996-07-01 2002-09-20 Дзе Дау Кемикал Компани Способ получения олефиноксидов прямым окислением олефинов, каталитический состав для этого процесса и способ его регенерации
US6323351B1 (en) 1997-06-30 2001-11-27 The Dow Chemical Company Process for the direct oxidation of olefins to olefin oxides
US6562986B2 (en) * 1997-06-30 2003-05-13 Dow Global Technologies, Inc. Process for the direct oxidation of olefins to olefin oxides
EP1003732A1 (de) * 1997-07-11 2000-05-31 Aventis Research & Technologies GmbH & Co KG Verfahren zur herstellung von epoxiden durch oxidation von olefinen mit luft oder sauerstoff
JP4000392B2 (ja) * 1997-11-05 2007-10-31 独立行政法人産業技術総合研究所 炭化水素の部分酸化用触媒及び含酸素有機化合物の製法
BE1011581A3 (fr) * 1997-12-01 1999-11-09 Solvay Catalyseur a base de zeolite, son utilisation et procede d'epoxydation en presence de ce catalyseur.
DE19804709A1 (de) * 1998-02-06 1999-08-12 Bayer Ag Verfahren zur katalytischen Direktoxidation ungesättigter Kohlenwasserstoffe in der Gasphase
DE19804711A1 (de) * 1998-02-06 1999-08-12 Bayer Ag Verfahren zur Regenerierung von mit Goldteilchen belegten Trägerkatalysatoren für die Oxidation ungesättigter Kohlenwasserstoffe
US6252095B1 (en) * 1998-02-24 2001-06-26 Director-General Of Agency Of Industrial Science And Technology Catalyst for partially oxidizing unsaturated hydrocarbon
ES2203109T3 (es) * 1998-04-15 2004-04-01 Dow Global Technologies Inc. Procedimiento para la oxidacion directa de olefinas a oxidos de olefina.
DE19835481A1 (de) 1998-08-07 2000-02-17 Bayer Ag Verfahren zur Oxidation von Kohlenwasserstoffen
WO2000015334A1 (en) * 1998-09-14 2000-03-23 Shell Internationale Research Maatschappij B.V. Process for preparing catalysts with improved catalytic properties
DE19847629A1 (de) 1998-10-15 2000-04-20 Basf Ag Verfahren zur Oxidation einer mindestens eine C-C-Doppelbindung aufweisenden organischen Verbindung
DE19854615C2 (de) * 1998-11-26 2001-08-09 Creavis Tech & Innovation Gmbh Verfahren zur Herstellung von Epoxiden durch Gasphasenoxidation
DE19857137A1 (de) 1998-12-11 2000-06-15 Bayer Ag Integriertes Verfahren zur Herstellung von Epoxiden aus Olefinen
JP2002532482A (ja) 1998-12-16 2002-10-02 ザ ダウ ケミカル カンパニー オレフィンのオレフィンオキシドへの直接酸化法
JP2000279809A (ja) * 1999-03-30 2000-10-10 Nippon Shokubai Co Ltd エポキシド製造用触媒及びエポキシドの製法
RU2234369C2 (ru) 1999-04-08 2004-08-20 Дау Глобал Текнолоджиз Инк. Способ гидроокисления олефинов до оксидов олефинов с использованием катализатора на основе окисленного золота
DE60021071T2 (de) * 1999-04-08 2006-05-18 Dow Global Technologies, Inc., Midland Verfahren zur herstellung eines gold und titanium beinhaltenden katalysators
US6821923B1 (en) 1999-04-08 2004-11-23 Dow Global Technologies Inc. Method of preparing a catalyst containing gold and titanium
DE19918431A1 (de) 1999-04-23 2000-10-26 Bayer Ag Verfahren zur Herstellung eines Katalysators zur selektiven Oxidation von Kohlenwasserstoffen
DE19920753A1 (de) 1999-04-23 2000-10-26 Bayer Ag Verfahren zur Herstellung von amorphen, edelmetallhaltigen Titan-Silizium-Mischoxiden
KR100326897B1 (ko) * 1999-08-05 2002-03-06 채문식 이산화티탄이 결합된 티타노실리칼라이트 광촉매 및 그 제조방법
US7608747B2 (en) * 1999-09-07 2009-10-27 Lummus Technology Inc. Aromatics hydrogenolysis using novel mesoporous catalyst system
US6930219B2 (en) * 1999-09-07 2005-08-16 Abb Lummus Global Inc. Mesoporous material with active metals
US6906208B2 (en) * 1999-09-07 2005-06-14 Abb Lummus Global Inc. Mesoporous material and use thereof for the selective oxidation of organic compounds
AU770334B2 (en) 1999-12-09 2004-02-19 Dow Global Technologies Inc. Activation and regeneration of a hydro-oxidation catalyst
DE19959525A1 (de) 1999-12-09 2001-06-13 Bayer Ag Katalysatoren auf Basis Edelmetall- und Titan-haltiger, organisch-anorganisch Hybridmaterialien zur selektiven Oxidation von Kohlenwasserstoffen
EP1125933A1 (en) * 2000-02-07 2001-08-22 Bayer Aktiengesellschaft Epoxidation catalyst containing metals of the lanthanoide series
EP1125632A1 (en) 2000-02-07 2001-08-22 Bayer Aktiengesellschaft Process for the epoxidation of olefins using gold-containing catalysts
WO2001062380A1 (en) * 2000-02-22 2001-08-30 Arco Chemical Technology, L.P. Direct epoxidation process using improved catalyst composition
JP2001232194A (ja) 2000-02-23 2001-08-28 Nippon Shokubai Co Ltd エポキシド製造用触媒、及び該触媒の製法
US6337412B1 (en) 2000-04-25 2002-01-08 Chemical Research & Licensing Company Three stage propylene oxide process
US6194591B1 (en) 2000-04-27 2001-02-27 Arco Chemical Technology, L.P. Aqueous epoxidation process using modified titanium zeolite
DE10023717A1 (de) * 2000-05-17 2001-11-22 Bayer Ag Formkörper, Verfahren zu dessen Herstellung und Verwendung dieser Formkörper zur selektiven Oxidation von Kohlenwasserstoffen
US6534621B2 (en) 2000-05-18 2003-03-18 Dow Global Technologies Inc. Process for manufacturing a hydroxyester derivative intermediate and epoxy resins prepared therefrom
DE10024096A1 (de) * 2000-05-18 2001-11-22 Bayer Ag Verfahren zur Epoxidierung von Kohlenwasserstoffen
CN1114679C (zh) * 2000-05-19 2003-07-16 中国石油化工集团公司 一种中压加氢裂化方法
US6307073B1 (en) 2000-07-25 2001-10-23 Arco Chemical Technology, L.P. Direct epoxidation process using a mixed catalyst system
DE10044798A1 (de) * 2000-09-11 2002-04-04 Basf Ag Verfahren zur Regenerierung eines Zeolith-Katalysators
DE10044788A1 (de) 2000-09-11 2002-04-04 Basf Ag Verfahren zur Regenerierung eines Zeolith-Katalysators
EP1195368A3 (en) 2000-09-25 2002-05-15 Haldor Topsoe A/S Process for the catalytic selective oxidation of a hydrocarbon compound in presence of mesoporous zeolite
US6525234B1 (en) * 2000-11-21 2003-02-25 Exxonmobil Oil Corporation Process for liquid phase aromatics alkylation comprising in-situ catalyst reactivation with polar compounds
DE10060099A1 (de) * 2000-12-04 2002-06-06 Basf Ag Regenerierung eines Dehydrierkatalysators
US6281369B1 (en) † 2000-12-07 2001-08-28 Arco Chemical Technology, L.P. Epoxidation catalyst and process
DE10107777A1 (de) 2001-02-16 2002-09-05 Bayer Ag Kontinuierlicher Prozess für die Synthese von nanoskaligen Edelmetallpartikeln
JP4265108B2 (ja) * 2001-03-14 2009-05-20 住友化学株式会社 固体触媒の再生方法
EP1254711A1 (de) * 2001-05-05 2002-11-06 OMG AG & Co. KG Edelmetallhaltiger Trägerkatalysator und Verfahren zu seiner Herstellung
US6845329B1 (en) * 2001-05-18 2005-01-18 Uop Llc Process for determining a zeolite structure and its corresponding adsorption isotherm
US20030092921A1 (en) * 2001-06-05 2003-05-15 Stangland Eric E. Method of making gold-titania catalyst for oxidation of hydrocarbons
AU2002317607A1 (en) 2001-08-01 2003-02-17 Dow Global Technologies Inc. Method of increasing the lifetime of a hydro-oxidation catalyst
US6376686B1 (en) * 2001-09-05 2002-04-23 Arco Chemical Technology, L.P. Direct epoxidation process
US6498259B1 (en) 2001-10-19 2002-12-24 Arco Chemical Technology L.P. Direct epoxidation process using a mixed catalyst system
US6441203B1 (en) 2001-10-19 2002-08-27 Arco Chemical Technology, L.P. Direct epoxidation process using a palladium on niobium-containing support
US6441204B1 (en) 2001-10-19 2002-08-27 Arco Chemical Technology, L.P. Direct epoxidation process using a mixed catalyst system
US6399794B1 (en) * 2001-11-15 2002-06-04 Arco Chemical Technology, L.P. Direct epoxidation process using carbonate modifiers
US6403815B1 (en) 2001-11-29 2002-06-11 Arco Chemical Technology, L.P. Direct epoxidation process using a mixed catalyst system
DE10201241A1 (de) * 2002-01-15 2003-07-24 Bayer Ag Katalysator
DE10205873A1 (de) * 2002-02-13 2003-08-21 Zsw Metalloxidgeträgerte Au-Katalysatoren, Verfahren zu deren Herstellung sowie deren Verwendung
EP1552886B1 (en) * 2002-05-31 2020-05-06 China Petroleum & Chemical Corporation A process for regenerating catalyst containing titanium
US6759541B2 (en) 2002-06-03 2004-07-06 Arco Chemical Technology, L.P. Epoxidation process using a supported niobium oxide catalyst
US6960671B2 (en) * 2002-09-20 2005-11-01 Arco Chemical Technology, L.P. Process for direct oxidation of propylene to propylene oxide and large particle size titanium silicalite catalysts for use therein
BR0316818A (pt) * 2002-12-02 2005-10-18 Shell Int Research Processos para a preparação de um catalisador de epoxidação, e de óxido de alquileno
US7279145B2 (en) * 2003-03-10 2007-10-09 Lyondell Chemical Technology, L.P. Multiphase reactor design incorporating filtration system for fixed--bed catalyst
US7319156B2 (en) 2003-03-25 2008-01-15 Sumitomo Chemical Company, Limited Process for producing olefin oxide
EP2316567B1 (en) 2003-09-26 2018-01-24 3M Innovative Properties Co. Nanoscale gold catalysts, activating agents, support media, and related methodologies useful for making such catalyst systems especially when the gold is deposited onto the support media using physical vapor deposition
US6884898B1 (en) * 2003-12-08 2005-04-26 Arco Chemical Technology, L.P. Propylene oxide process
WO2005056181A1 (ja) * 2003-12-11 2005-06-23 National Institute Of Advanced Industrial Science And Technology 炭化水素部分酸化用金触媒
US20050171365A1 (en) 2004-02-03 2005-08-04 Grey Roger A. Epoxidation process using a mixed catalyst system
US6984606B2 (en) 2004-02-19 2006-01-10 Lyondell Chemical Technology, L.P. Epoxidation catalyst
US7256149B2 (en) * 2004-02-24 2007-08-14 Lyondell Chemical Technology, L.P. Catalyst regeneration process
US8816006B2 (en) * 2004-03-17 2014-08-26 Dow Global Technologies Llc Compositions of ethylene/α-olefin multi-block interpolymer suitable for films
EP1735095A1 (en) * 2004-04-01 2006-12-27 Dow Gloval Technologies Inc. Hydro-oxidation of hydrocarbons using catalyst prepared by microwave heating
JP4426379B2 (ja) * 2004-05-24 2010-03-03 Ｔａｎａｋａホールディングス株式会社 触媒前駆体及び触媒、並びに、触媒前駆体及び触媒の製造方法
US7271117B2 (en) * 2004-06-17 2007-09-18 Lyondell Chemical Technology, L.P. Epoxidation catalyst
US6972337B1 (en) 2004-08-12 2005-12-06 Lyondell Chemical Technology, L.P. Epoxidation catalyst
US7081552B2 (en) 2004-08-17 2006-07-25 Solutia Inc. Catalysts for cycloalkanes oxidation and decomposition of cycloalkyl hydroperoxide
US7026492B1 (en) 2004-10-29 2006-04-11 Lyondell Chemical Technology, L.P. Direct epoxidation process using modifiers
US7057056B1 (en) 2004-12-17 2006-06-06 Lyondell Chemical Technology, L.P. Epoxidation catalyst
US8058202B2 (en) * 2005-01-04 2011-11-15 3M Innovative Properties Company Heterogeneous, composite, carbonaceous catalyst system and methods that use catalytically active gold
BRPI0518504B1 (pt) * 2005-01-14 2015-10-20 Dow Global Technologies Inc processo para reconstituir um catalisador de oxidação ativo
US7745373B2 (en) * 2005-04-08 2010-06-29 Exxonmobil Research And Engineering Company Single step decomposition and activation of noble metal complexes on catalytic supports
ES2261080B1 (es) * 2005-04-19 2007-12-16 Universidad Politecnica De Valencia Procedimiento y catalizadores para la expoxidacion de compuestos olefinicos en presencia de oxigeno.
US7759284B2 (en) * 2005-05-09 2010-07-20 Scientific Design Company, Inc. Calcination in an inert gas in the presence of a small concentration of an oxidizing component
US7138535B1 (en) 2005-06-01 2006-11-21 Lyondell Chemical Technology, L.P. Direct epoxidation process
US7273826B2 (en) 2005-07-26 2007-09-25 Lyondell Chemical Technology, L.P. Epoxidation catalyst
CN100355718C (zh) * 2005-09-21 2007-12-19 扬子石油化工股份有限公司 加氢精制对苯二甲酸的催化剂的再生方法
US7288237B2 (en) 2005-11-17 2007-10-30 Lyondell Chemical Technology, L.P. Epoxidation catalyst
US7459589B2 (en) 2005-12-22 2008-12-02 Shell Oil Company Process for the preparation of an alkylene glycol
US8357812B2 (en) 2005-12-22 2013-01-22 Shell Oil Company Process for preparing a rejuvenated epoxidation catalyst
US7704908B2 (en) 2005-12-22 2010-04-27 Shell Oil Company Method for reusing rhenium from a donor spent epoxidation catalyst
US8137750B2 (en) 2006-02-15 2012-03-20 3M Innovative Properties Company Catalytically active gold supported on thermally treated nanoporous supports
US7955570B2 (en) 2006-02-28 2011-06-07 3M Innovative Properties Company Low pressure drop, highly active catalyst systems using catalytically active gold
JP5014651B2 (ja) * 2006-03-10 2012-08-29 国立大学法人東京工業大学 オキシムの製造方法
US7671222B2 (en) 2006-07-12 2010-03-02 Lyondell Chemical Technology, L.P. Direct epoxidation process using a mixed catalyst system
US7595410B2 (en) 2006-07-18 2009-09-29 Lyondell Chemical Technology, L.P. Direct epoxidation process using improved catalyst composition
MY145792A (en) * 2006-11-17 2012-04-30 Dow Global Technologies Inc Hydro-oxidation process using a catalyst prepared from a gold cluster complex
WO2008064076A2 (en) 2006-11-20 2008-05-29 Shell Oil Company A process for treating a carrier, a process for preparing a catalyst, the catalyst, and use of the catalyst
CN101657407B (zh) * 2007-03-20 2014-02-12 陶氏技术投资有限公司 改善对产物同分异构体的控制的加氢甲酰基化方法
ATE482942T1 (de) * 2007-04-05 2010-10-15 Dow Global Technologies Inc Integriertes hydrooxidierungsverfahren mit abtrennung eines olefinoxidproduktstroms
US7696367B2 (en) 2007-04-10 2010-04-13 Lyondell Chemical Technology, L.P. Direct epoxidation process using a mixed catalyst system
US7811968B2 (en) * 2007-05-11 2010-10-12 Lyondell Chemical Technology, L.P. Preparation of palladium-gold catalysts
DE102007025223A1 (de) * 2007-05-31 2008-12-04 Süd-Chemie AG Zirkoniumoxid-dotierter VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025442B4 (de) * 2007-05-31 2023-03-02 Clariant International Ltd. Verwendung einer Vorrichtung zur Herstellung eines Schalenkatalysators und Schalenkatalysator
DE102007025443A1 (de) * 2007-05-31 2008-12-04 Süd-Chemie AG Pd/Au-Schalenkatalysator enthaltend HfO2, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025362A1 (de) * 2007-05-31 2008-12-11 Süd-Chemie AG Dotierter Pd/Au-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025444A1 (de) * 2007-05-31 2008-12-11 Süd-Chemie AG VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025315A1 (de) * 2007-05-31 2008-12-11 Süd-Chemie AG Katalysator zur selektiven Hydrierung acetylenischer Kohlenwasserstoffe und Verfahren zu seiner Herstellung
US20090042718A1 (en) * 2007-08-10 2009-02-12 Kaminsky Mark P Direct epoxidation catalyst and process
US7470801B1 (en) 2007-10-24 2008-12-30 Lyondell Chemical Technology, L.P. Direct epoxidation process using a mixed catalyst system
US7531675B1 (en) 2007-10-24 2009-05-12 Lyondell Chemical Technology, L.P. Direct epoxidation process using improved catalyst composition
WO2009061623A2 (en) * 2007-11-07 2009-05-14 Dow Global Technologies Inc. Hydro-oxidation process using a catalyst containing gold and a halogen-containing compound
EP2240272B1 (en) 2008-01-14 2015-12-23 3M Innovative Properties Company Method of making multifunctional oxidation catalysts
CN101658791B (zh) * 2008-08-29 2012-07-18 中国石油化工股份有限公司 一种钛硅分子筛材料后处理的方法
CN101658798B (zh) * 2008-08-29 2012-08-15 中国石油化工股份有限公司 一种钛硅分子筛材料的改性方法
DE202008017277U1 (de) 2008-11-30 2009-04-30 Süd-Chemie AG Katalysatorträger
US7767835B2 (en) 2008-12-18 2010-08-03 Lyondell Chemical Technology, L.P. Direct epoxidation process using improved catalyst
BRPI0918349A2 (pt) 2008-12-30 2015-08-11 Dow Global Technologies Llc Processo para preparar dióxido de divinilareno
US8124797B2 (en) 2009-06-26 2012-02-28 Lyondell Chemical Technology, Lp Epoxidation process
FR2949077B1 (fr) * 2009-08-17 2011-07-22 Inst Francais Du Petrole Procede de preparation d'un catalyseur supporte a base de ni et d'un metal du groupe ib pour l'hydrogenation selective d'hydrocarbures polyinsatures
US8124798B2 (en) 2009-12-17 2012-02-28 Lyondell Chemical Technology, Lp Direct epoxidation catalyst and process
US8440846B2 (en) 2010-09-30 2013-05-14 Lyondell Chemical Technology, L.P. Direct epoxidation process
CN103153462B (zh) 2010-10-05 2016-06-01 陶氏技术投资有限责任公司 加氢甲酰基化方法
CN104549413B (zh) * 2013-10-28 2017-05-17 中国石油化工股份有限公司 用于苯直接羟化制苯酚的纳米金催化剂、制备方法及其用途
CN104646015B (zh) * 2013-11-19 2017-02-15 中国石油天然气股份有限公司 一种丙烯氧化催化剂及制备方法
CN104649875B (zh) * 2013-11-19 2016-08-17 中国石油天然气股份有限公司 一种丙烯选择性氧化方法
US20150182959A1 (en) * 2013-12-30 2015-07-02 Shell Oil Company Relating to epoxidation catalysts
CN103752353B (zh) * 2014-01-24 2016-04-20 华东理工大学 一种丙烯环氧化制备环氧丙烷的催化剂的再生方法
CN107148312A (zh) * 2014-11-25 2017-09-08 日本碍子株式会社 分离膜结构体
CN105013480A (zh) * 2015-07-10 2015-11-04 华东理工大学 一种提高用于丙烯气相环氧化的催化剂的稳定性和活性的方法
CN106563488B (zh) * 2015-10-12 2019-09-06 中国石油化工股份有限公司 二氧化钛微球@全硅Silica-1分子筛核壳催化剂、制备方法及用途
US10017484B2 (en) * 2015-12-02 2018-07-10 Lyondell Chemical Technology, L.P. Catalysts containing specific titanium polymorphic forms
CN106345460B (zh) * 2016-08-25 2018-10-23 山东清大银光金属海绵新材料有限责任公司 一种海绵结构型甲醇空气氧化复合催化材料的制备方法
CN110327967A (zh) * 2019-07-26 2019-10-15 山东达民化工股份有限公司 催化剂及其制备方法及应用该催化剂的异丙醇安生产工艺
CN111151301B (zh) * 2020-01-13 2021-11-30 辽宁大学 一种双官能团非均相Pd@MIL-101@SGO复合材料及其制备方法和应用
EP4163274A4 (en) * 2020-07-10 2023-12-13 China Petroleum & Chemical Corporation Method for preparing propylene oxide by means of direct epoxidation of propylene
CN113912574B (zh) * 2020-07-10 2024-01-23 中国石油化工股份有限公司 碱性条件下进行丙烯直接环氧化制备环氧丙烷的方法
GB2602623B (en) * 2020-12-09 2025-05-14 Calor Gas Ltd Bio-LPG production process
CN112691684B (zh) * 2020-12-25 2023-01-13 西安近代化学研究所 一种丙烯环氧化反应中催化剂失活后的低温再生方法
US11161093B1 (en) 2021-04-16 2021-11-02 King Abdulaziz University Gold-decorated magnesium silicate catalyst for producing light olefins
CN114713212B (zh) * 2022-03-11 2024-02-06 华东理工大学 用于丙烯氢氧环氧化制备环氧丙烷的钛硅材料及制备方法
US20250281906A1 (en) * 2022-04-25 2025-09-11 Sumitomo Chemical Company, Limited Method for producing titanium-containing silicon oxide, method for producing epoxide, and titanium-containing silicon oxide

Family Cites Families (46)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1338901A (en) * 1970-10-30 1973-11-28 Bp Chem Int Ltd Production of propylene oxide
GB1327497A (en) * 1972-05-25 1973-08-22 Bp Chem Int Ltd Propylene oxide
GB1409421A (en) * 1972-07-17 1975-10-08 Bryce Smith Derek Gold compounds
GB1491447A (en) 1973-12-05 1977-11-09 Ici Ltd Alkylene oxide production and catalysts therefor
US4391756A (en) * 1978-06-05 1983-07-05 The Standard Oil Company Organo-monovalent aurus complex catalysts for the manufacture of olefin oxides
IT1127311B (it) * 1979-12-21 1986-05-21 Anic Spa Materiale sintetico,cristallino,poroso costituito da ossidi di silicio e titanio,metodo per la sua preparazione e suoi usi
IT1187661B (it) 1985-04-23 1987-12-23 Enichem Sintesi Catalizzatore a base di silicio e titanio ad elevata resistenza meccanica
JPS63252908A (ja) * 1987-04-08 1988-10-20 Agency Of Ind Science & Technol 金超微粒子固定化酸化物、その製造法、酸化触媒、還元触媒、可燃性ガスセンサ素子、及び電極用触媒
JPS6483513A (en) * 1987-09-24 1989-03-29 Agency Ind Science Techn Ultrafine gold particle immobilized alkaline earth metallic compound, production thereof, oxidation catalyst, reduction catalyst and combustible gas sensor element
US4845253A (en) 1987-11-23 1989-07-04 The Dow Chemical Company Silver-based catalyst for vapor phase oxidation of olefins to epoxides
US4827068A (en) * 1987-12-29 1989-05-02 Mobil Oil Corporation Aromatization with catalyst comprising noble-metal containing titanosilicate having the structure of zeolite beta
US4828812A (en) * 1987-12-29 1989-05-09 Mobil Oil Corporation Titanosilicates of enhanced ion exchange capacity and their preparation
US5008414A (en) * 1988-12-08 1991-04-16 The Boc Group, Inc. Process for the production of oxides
US5162283A (en) 1991-01-22 1992-11-10 Mobil Oil Corporation Highly porous amorphous titania and titania/silica phases
US5145824A (en) * 1991-01-22 1992-09-08 Shell Oil Company Ethylene oxide catalyst
JP3044836B2 (ja) * 1991-05-28 2000-05-22 東ソー株式会社 プロピレンオキシドの製法
US5506273A (en) * 1991-12-06 1996-04-09 Agency Of Industrial Science And Technology Catalyst for hydrogenation and method for hydrogenation therewith
RU2054424C1 (ru) * 1992-04-16 1996-02-20 Институт катализа СО РАН Способ получения оксида этилена
DE69426321T2 (de) * 1993-08-06 2001-04-05 Sumitomo Chemical Co., Ltd. Verfahren zur Herstellung von Olefinoxiden
JP3351583B2 (ja) * 1993-08-10 2002-11-25 花王株式会社 リン酸エステル塩の精製法
EP0638362B1 (en) * 1993-08-11 2001-03-21 Mitsubishi Gas Chemical Company, Inc. Titanosilicate catalyst particle
US5354875A (en) 1993-12-23 1994-10-11 Uop Epoxidation of olefins using a titania-supported titanosilicate
JP2615418B2 (ja) * 1994-03-10 1997-05-28 工業技術院長 金超微粒子固定化チタン系金属酸化物からなる酸化触媒、還元触媒、可燃性ガスセンサ素子および電極用触媒
DE4425672A1 (de) * 1994-07-20 1996-01-25 Basf Ag Oxidationskatalysator, Verfahren zu seiner Herstellung und Oxidationsverfahren unter Verwendung des Oxidationskatalysators
DE4435239A1 (de) * 1994-10-04 1996-04-11 Basf Ag Verfahren zur Herstellung von Hydroxylaminen aus Ammoniak oder den entsprechenden Aminen, Wasserstoff und Sauerstoff
JP2615432B2 (ja) * 1994-10-28 1997-05-28 工業技術院長 金−酸化チタン含有触媒による炭化水素の部分酸化方法
DE19501891C1 (de) * 1995-01-23 1996-09-26 Degussa Verfahren zur Herstellung eines Trägerkatalysators und seine Verwendung für die Produktion von Vinylacetat
JPH08269029A (ja) * 1995-03-29 1996-10-15 Tosoh Corp プロピレンオキシドの製造方法
WO1996031434A1 (en) * 1995-04-03 1996-10-10 Massachusetts Institute Of Technology Composition and method for producing hexagonally-packed mesoporous metal oxide
DE19520270A1 (de) * 1995-06-02 1996-12-05 Basf Ag Verfahren zur Herstellung von Aminoxiden
DE19600708A1 (de) * 1996-01-11 1997-07-17 Basf Ag Oxidationskatalysator mit einem Gehalt an Lanthanoidmetallen, Verfahren zu seiner Herstellung und Oxidationsverfahren unter Verwendung des Oxidationskatalysators
DE19600709A1 (de) * 1996-01-11 1997-07-17 Basf Ag Verfahren zur Herstellung von Epoxiden aus Olefinen, Wasserstoff und Sauerstoff
DE19607577A1 (de) * 1996-02-29 1997-09-04 Basf Ag Netzkatalysator auf Basis von Titan- oder Vanadiumzeolithen und inerten Netzgeweben zur Beschleunigung von Oxidationsreaktionen
KR100255480B1 (ko) * 1996-03-21 2000-05-01 사또 다께오 탄화수소의 부분산화용촉매 및 탄화수소의 부분산화방법
JP3777437B2 (ja) * 1996-03-21 2006-05-24 独立行政法人産業技術総合研究所 炭化水素の部分酸化方法および部分酸化用触媒
DE19623609A1 (de) * 1996-06-13 1997-12-18 Basf Ag Oxidationskatalysator und Verfahren zur Herstellung von Epoxiden aus Olefinen, Wasserstoff und Sauerstoff unter Verwendung des Oxidationskatalysators
RU2189378C2 (ru) * 1996-07-01 2002-09-20 Дзе Дау Кемикал Компани Способ получения олефиноксидов прямым окислением олефинов, каталитический состав для этого процесса и способ его регенерации
DE69731363T2 (de) * 1996-12-25 2005-12-22 Agency Of Industrial Science And Technology Verfahren zur Epoxid-Herstellung und Katalysator für die Verwendung darin
US6323351B1 (en) * 1997-06-30 2001-11-27 The Dow Chemical Company Process for the direct oxidation of olefins to olefin oxides
ES2280636T3 (es) 1997-06-30 2007-09-16 Dow Global Technologies Inc. Composicion de catalizador y procedimiento para la oxidacion directa de propileno a oxido de propileno.
JP4000392B2 (ja) * 1997-11-05 2007-10-31 独立行政法人産業技術総合研究所 炭化水素の部分酸化用触媒及び含酸素有機化合物の製法
US6252095B1 (en) * 1998-02-24 2001-06-26 Director-General Of Agency Of Industrial Science And Technology Catalyst for partially oxidizing unsaturated hydrocarbon
RU2234369C2 (ru) 1999-04-08 2004-08-20 Дау Глобал Текнолоджиз Инк. Способ гидроокисления олефинов до оксидов олефинов с использованием катализатора на основе окисленного золота
US6063942A (en) * 1999-09-27 2000-05-16 Arco Chemical Technology, L.P. Catalyst preparation and epoxidation process
US6194591B1 (en) * 2000-04-27 2001-02-27 Arco Chemical Technology, L.P. Aqueous epoxidation process using modified titanium zeolite
US6310224B1 (en) * 2001-01-19 2001-10-30 Arco Chemical Technology, L.P. Epoxidation catalyst and process

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