EP1069211A3 - Electroplating solutions - Google Patents
Electroplating solutions Download PDFInfo
- Publication number
- EP1069211A3 EP1069211A3 EP00305941A EP00305941A EP1069211A3 EP 1069211 A3 EP1069211 A3 EP 1069211A3 EP 00305941 A EP00305941 A EP 00305941A EP 00305941 A EP00305941 A EP 00305941A EP 1069211 A3 EP1069211 A3 EP 1069211A3
- Authority
- EP
- European Patent Office
- Prior art keywords
- compound
- acid
- electroplating solutions
- organic
- leveller
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/38—Electroplating: Baths therefor from solutions of copper
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US14415999P | 1999-07-15 | 1999-07-15 | |
US144159P | 1999-07-15 | ||
US58359900A | 2000-05-31 | 2000-05-31 | |
US583599 | 2000-05-31 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1069211A2 EP1069211A2 (en) | 2001-01-17 |
EP1069211A3 true EP1069211A3 (en) | 2003-12-17 |
Family
ID=26841728
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP00305941A Withdrawn EP1069211A3 (en) | 1999-07-15 | 2000-07-13 | Electroplating solutions |
Country Status (4)
Country | Link |
---|---|
US (1) | US20040187731A1 (ja) |
EP (1) | EP1069211A3 (ja) |
JP (1) | JP2001073182A (ja) |
KR (1) | KR20010015342A (ja) |
Families Citing this family (78)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2004531640A (ja) * | 2001-02-07 | 2004-10-14 | マイクロリス・コーポレイシヨン | 水性めっき液の脱気方法 |
KR20020092444A (ko) * | 2001-02-23 | 2002-12-11 | 가부시키 가이샤 에바라 세이사꾸쇼 | 구리-도금 용액, 도금 방법 및 도금 장치 |
JP4793530B2 (ja) * | 2001-07-02 | 2011-10-12 | 上村工業株式会社 | 硫酸銅めっき浴 |
US6736954B2 (en) * | 2001-10-02 | 2004-05-18 | Shipley Company, L.L.C. | Plating bath and method for depositing a metal layer on a substrate |
US7316772B2 (en) * | 2002-03-05 | 2008-01-08 | Enthone Inc. | Defect reduction in electrodeposited copper for semiconductor applications |
US8002962B2 (en) * | 2002-03-05 | 2011-08-23 | Enthone Inc. | Copper electrodeposition in microelectronics |
JP3789107B2 (ja) * | 2002-07-23 | 2006-06-21 | 株式会社日鉱マテリアルズ | 特定骨格を有するアミン化合物及び有機硫黄化合物を添加剤として含む銅電解液並びにそれにより製造される電解銅箔 |
JP4115240B2 (ja) * | 2002-10-21 | 2008-07-09 | 日鉱金属株式会社 | 特定骨格を有する四級アミン化合物及び有機硫黄化合物を添加剤として含む銅電解液並びにそれにより製造される電解銅箔 |
JP4534460B2 (ja) * | 2002-11-11 | 2010-09-01 | 凸版印刷株式会社 | 銅めっき硬度維持剤及び銅めっき方法並びにそれを用いたグラビア版、レンズ金型 |
JP4510369B2 (ja) | 2002-11-28 | 2010-07-21 | 日本リーロナール有限会社 | 電解銅めっき方法 |
WO2004059040A1 (ja) * | 2002-12-25 | 2004-07-15 | Nikko Materials Co., Ltd. | 特定骨格を有する四級アミン化合物重合体及び有機硫黄化合物を添加剤として含む銅電解液並びにそれにより製造される電解銅箔 |
EP1477588A1 (en) * | 2003-02-19 | 2004-11-17 | Rohm and Haas Electronic Materials, L.L.C. | Copper Electroplating composition for wafers |
US7128822B2 (en) | 2003-06-04 | 2006-10-31 | Shipley Company, L.L.C. | Leveler compounds |
JP2005029818A (ja) * | 2003-07-09 | 2005-02-03 | Ebara Corp | めっき方法 |
US20050211564A1 (en) * | 2004-03-29 | 2005-09-29 | Taiwan Semiconductor Manufacturing Co., Ltd. | Method and composition to enhance wetting of ECP electrolyte to copper seed |
TW200613586A (en) | 2004-07-22 | 2006-05-01 | Rohm & Haas Elect Mat | Leveler compounds |
WO2006018872A1 (ja) * | 2004-08-18 | 2006-02-23 | Ebara-Udylite Co., Ltd. | 銅めっき用添加剤およびこれを用いる電子回路基板の製造方法 |
US7442634B2 (en) * | 2004-12-21 | 2008-10-28 | Intel Corporation | Method for constructing contact formations |
JP4976725B2 (ja) * | 2005-03-31 | 2012-07-18 | 三井金属鉱業株式会社 | 銅電解液及びその銅電解液を用いた電析銅皮膜の形成方法 |
US7662981B2 (en) | 2005-07-16 | 2010-02-16 | Rohm And Haas Electronic Materials Llc | Leveler compounds |
TWI328622B (en) * | 2005-09-30 | 2010-08-11 | Rohm & Haas Elect Mat | Leveler compounds |
JP2007146289A (ja) * | 2005-10-31 | 2007-06-14 | Mitsui Mining & Smelting Co Ltd | 電解銅箔の製造方法、該製造方法で得られる電解銅箔、該電解銅箔を用いて得られる表面処理銅箔及び該電解銅箔又は該表面処理銅箔を用いて得られる銅張積層板 |
JP4816901B2 (ja) * | 2005-11-21 | 2011-11-16 | 上村工業株式会社 | 電気銅めっき浴 |
US20070158199A1 (en) * | 2005-12-30 | 2007-07-12 | Haight Scott M | Method to modulate the surface roughness of a plated deposit and create fine-grained flat bumps |
JP4895734B2 (ja) * | 2006-09-08 | 2012-03-14 | 荏原ユージライト株式会社 | めっき用レベリング剤、酸性銅めっき浴用添加剤組成物、酸性銅めっき浴および該めっき浴を用いるめっき方法 |
CN101517131B (zh) * | 2006-10-03 | 2011-02-16 | 三井金属矿业株式会社 | 硫酸酸性铜电解液制备方法及使用该制备方法制备的硫酸酸性铜电解液及电析铜薄膜 |
JP2008088524A (ja) * | 2006-10-04 | 2008-04-17 | Ebara Udylite Kk | プリント基板用硫酸銅めっき液 |
US20080181813A1 (en) * | 2007-01-26 | 2008-07-31 | Baker Hughes Incorporated | Novel Mercaptan-Based Corrosion Inhibitors |
EP2161355A4 (en) * | 2007-05-21 | 2012-01-25 | Uyemura C & Co Ltd | ELECTROLYTIC COPPER BATH |
US20090188805A1 (en) * | 2008-01-25 | 2009-07-30 | Government Of The United States Of America, As Represented By The | Superconformal electrodeposition of nickel iron and cobalt magnetic alloys |
ES2624637T3 (es) * | 2008-05-30 | 2017-07-17 | Atotech Deutschland Gmbh | Aditivo de electrogalvanoplastia para la deposición de una aleación de un metal del grupo IB/binaria o ternaria del grupo IB-grupo IIIA/ternaria, cuaternaria o quinaria del grupo IB, el grupo IIIA-grupo VIA |
JP5525762B2 (ja) * | 2008-07-01 | 2014-06-18 | 上村工業株式会社 | 無電解めっき液及びそれを用いた無電解めっき方法、並びに配線基板の製造方法 |
US8388824B2 (en) | 2008-11-26 | 2013-03-05 | Enthone Inc. | Method and composition for electrodeposition of copper in microelectronics with dipyridyl-based levelers |
EP2199315B1 (en) | 2008-12-19 | 2013-12-11 | Basf Se | Composition for metal electroplating comprising leveling agent |
JP5578697B2 (ja) * | 2009-04-03 | 2014-08-27 | 公立大学法人大阪府立大学 | 銅充填方法 |
JP5568250B2 (ja) * | 2009-05-18 | 2014-08-06 | 公立大学法人大阪府立大学 | 銅を充填する方法 |
EP2504396B1 (en) | 2009-11-27 | 2021-02-24 | Basf Se | Composition for copper electroplating comprising leveling agent |
US9834677B2 (en) | 2010-03-18 | 2017-12-05 | Basf Se | Composition for metal electroplating comprising leveling agent |
TWI572750B (zh) | 2010-05-24 | 2017-03-01 | 安頌股份有限公司 | 直通矽穿孔之銅充填 |
EP2392692A1 (en) | 2010-06-01 | 2011-12-07 | Basf Se | Composition for metal electroplating comprising leveling agent |
KR101829866B1 (ko) | 2010-06-01 | 2018-02-20 | 바스프 에스이 | 레벨링제를 포함하는 금속 전기도금용 조성물 |
JP5505153B2 (ja) * | 2010-07-16 | 2014-05-28 | 上村工業株式会社 | 電気銅めっき浴及び電気銅めっき方法 |
JP2012127003A (ja) | 2010-12-15 | 2012-07-05 | Rohm & Haas Electronic Materials Llc | 銅層を均一にする電気めっき方法 |
GB201100447D0 (en) * | 2011-01-12 | 2011-02-23 | Johnson Matthey Plc | Improvements in coating technology |
KR101705734B1 (ko) * | 2011-02-18 | 2017-02-14 | 삼성전자주식회사 | 구리 도금 용액 및 이것을 이용한 구리 도금 방법 |
EP2537962A1 (en) * | 2011-06-22 | 2012-12-26 | Atotech Deutschland GmbH | Method for copper plating |
EP2735627A1 (en) | 2012-11-26 | 2014-05-28 | ATOTECH Deutschland GmbH | Copper plating bath composition |
US20140238868A1 (en) * | 2013-02-25 | 2014-08-28 | Dow Global Technologies Llc | Electroplating bath |
CN103469260A (zh) * | 2013-09-27 | 2013-12-25 | 昆山纯柏精密五金有限公司 | 一种五金件的酸性镀铜的方法 |
EP2865787A1 (en) * | 2013-10-22 | 2015-04-29 | ATOTECH Deutschland GmbH | Copper electroplating method |
KR102312018B1 (ko) * | 2013-12-09 | 2021-10-13 | 아베니 | 전기화학적 불활성 양이온을 함유하는 구리 전착 배쓰 |
TWI710671B (zh) * | 2014-09-15 | 2020-11-21 | 美商麥德美樂思公司 | 微電子技術中銅沈積用之平整劑 |
US10450667B2 (en) | 2014-10-27 | 2019-10-22 | International Business Machines Corporation | System for treating solution for use in electroplating application and method for treating solution for use in electroplating application |
TWI689630B (zh) | 2014-11-05 | 2020-04-01 | 美商康寧公司 | 底部向上電解質通孔鍍覆方法 |
US9783905B2 (en) | 2014-12-30 | 2017-10-10 | Rohm and Haas Electronic Mateirals LLC | Reaction products of amino acids and epoxies |
US9725816B2 (en) | 2014-12-30 | 2017-08-08 | Rohm And Haas Electronic Materials Llc | Amino sulfonic acid based polymers for copper electroplating |
US9611560B2 (en) | 2014-12-30 | 2017-04-04 | Rohm And Haas Electronic Materials Llc | Sulfonamide based polymers for copper electroplating |
CN107771227B (zh) | 2015-04-20 | 2019-04-02 | 埃托特克德国有限公司 | 电解铜镀液组合物及其用法 |
CN107636209B (zh) * | 2015-06-26 | 2021-07-02 | 住友金属矿山股份有限公司 | 导电性基板 |
EP3135709B1 (en) | 2015-08-31 | 2018-01-10 | ATOTECH Deutschland GmbH | Imidazoyl urea polymers and their use in metal or metal alloy plating bath compositions |
EP3344800B1 (en) | 2015-08-31 | 2019-03-13 | ATOTECH Deutschland GmbH | Aqueous copper plating baths and a method for deposition of copper or copper alloy onto a substrate |
CN105239109A (zh) * | 2015-10-28 | 2016-01-13 | 福州瑞华印制线路板有限公司 | 一种哈林槽镀铜方法 |
CN105200467B (zh) * | 2015-11-02 | 2019-01-29 | 江苏梦得新材料科技有限公司 | 一种凹版硬铜添加剂及镀液 |
WO2017090161A1 (ja) * | 2015-11-26 | 2017-06-01 | 近藤 和夫 | 酸性銅めっき液、酸性銅めっき物および半導体デバイスの製造方法 |
EP3360988B1 (en) | 2017-02-09 | 2019-06-26 | ATOTECH Deutschland GmbH | Pyridinium compounds, a synthesis method therefor, metal or metal alloy plating baths containing said pyridinium compounds and a method for use of said metal or metal alloy plating baths |
PT3508620T (pt) | 2018-01-09 | 2021-07-12 | Atotech Deutschland Gmbh | Aditivo de ureileno, a sua utilização e um método de preparação para esse fim |
US10917966B2 (en) | 2018-01-29 | 2021-02-09 | Corning Incorporated | Articles including metallized vias |
JP6645609B2 (ja) | 2018-07-27 | 2020-02-14 | 三菱マテリアル株式会社 | 錫合金めっき液 |
CN112236548B (zh) * | 2018-07-27 | 2022-03-04 | 三菱综合材料株式会社 | 锡合金镀液 |
US11746433B2 (en) | 2019-11-05 | 2023-09-05 | Macdermid Enthone Inc. | Single step electrolytic method of filling through holes in printed circuit boards and other substrates |
CN110938848B (zh) * | 2019-12-26 | 2021-05-11 | 江苏艾森半导体材料股份有限公司 | 一种用于电解沉积铜的组合物及酸铜电镀液 |
EP3933073B1 (en) | 2020-06-29 | 2023-11-29 | Atotech Deutschland GmbH & Co. KG | Copper electroplating bath |
CN112144083B (zh) * | 2020-09-22 | 2021-12-10 | 广州三孚新材料科技股份有限公司 | 一种太阳能电池用无氰镀铜电镀液及制备方法 |
WO2022158277A1 (ja) * | 2021-01-20 | 2022-07-28 | 富士フイルム株式会社 | めっき液、および、金属充填構造体の製造方法 |
EP4032930B1 (en) | 2021-01-22 | 2023-08-30 | Atotech Deutschland GmbH & Co. KG | Biuret-based quaternized polymers and their use in metal or metal alloy plating baths |
CN113430598B (zh) * | 2021-08-27 | 2021-11-16 | 深圳市板明科技股份有限公司 | 一种线路板盲孔填充电镀铜溶液及其应用 |
CN113956479B (zh) * | 2021-11-26 | 2022-12-02 | 电子科技大学 | 电镀铜加速剂及合成方法和应用 |
CN116751362B (zh) * | 2023-08-21 | 2024-01-09 | 广东腐蚀科学与技术创新研究院 | 一种水溶性二胺基脲聚合物及其制备方法和应用 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4430173A (en) * | 1981-07-24 | 1984-02-07 | Rhone-Poulenc Specialties Chimiques | Additive composition, bath and process for acid copper electroplating |
US5051154A (en) * | 1988-08-23 | 1991-09-24 | Shipley Company Inc. | Additive for acid-copper electroplating baths to increase throwing power |
US5174886A (en) * | 1991-02-22 | 1992-12-29 | Mcgean-Rohco, Inc. | High-throw acid copper plating using inert electrolyte |
US5433840A (en) * | 1991-08-07 | 1995-07-18 | Atotech Deutschland Gmbh | Acid bath for the galvanic deposition of copper, and the use of such a bath |
US5849171A (en) * | 1990-10-13 | 1998-12-15 | Atotech Deutschland Gmbh | Acid bath for copper plating and process with the use of this combination |
Family Cites Families (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2954331A (en) * | 1958-08-14 | 1960-09-27 | Dayton Bright Copper Company | Bright copper plating bath |
NL291575A (ja) * | 1962-04-16 | |||
US3328273A (en) * | 1966-08-15 | 1967-06-27 | Udylite Corp | Electro-deposition of copper from acidic baths |
US3615736A (en) * | 1969-01-06 | 1971-10-26 | Enthone | Electroless copper plating bath |
BE755019A (fr) * | 1969-08-19 | 1971-02-19 | Kuraray Co | Materiau en feuille utilisable comme succedane du cuir. |
US3715289A (en) * | 1971-02-08 | 1973-02-06 | Stauffer Chemical Co | Brightener composition for acid copper electroplating baths |
US4004956A (en) * | 1974-08-14 | 1977-01-25 | Enthone, Incorporated | Selectively stripping tin or tin-lead alloys from copper substrates |
US4134803A (en) * | 1977-12-21 | 1979-01-16 | R. O. Hull & Company, Inc. | Nitrogen and sulfur compositions and acid copper plating baths |
JPS6021240B2 (ja) * | 1980-01-12 | 1985-05-25 | 株式会社小糸製作所 | 堆積される銅をメッキ液に補給する方法及び装置 |
US4304646A (en) * | 1980-10-27 | 1981-12-08 | Enthone, Incorporated | Method for selective removal of copper contaminants from activator solutions containing palladium and tin |
US4376685A (en) * | 1981-06-24 | 1983-03-15 | M&T Chemicals Inc. | Acid copper electroplating baths containing brightening and leveling additives |
US4384930A (en) * | 1981-08-21 | 1983-05-24 | Mcgean-Rohco, Inc. | Electroplating baths, additives therefor and methods for the electrodeposition of metals |
US4490220A (en) * | 1982-09-30 | 1984-12-25 | Learonal, Inc. | Electrolytic copper plating solutions |
US4555315A (en) * | 1984-05-29 | 1985-11-26 | Omi International Corporation | High speed copper electroplating process and bath therefor |
US4790912A (en) * | 1985-06-06 | 1988-12-13 | Techno-Instruments Investments Ltd. | Selective plating process for the electrolytic coating of circuit boards without an electroless metal coating |
US4717439A (en) * | 1985-10-24 | 1988-01-05 | Enthone, Incorporated | Process for the treatment of copper oxide in the preparation of printed circuit boards |
US4808481A (en) * | 1986-10-31 | 1989-02-28 | American Cyanamid Company | Injection molding granules comprising copper coated fibers |
US4786746A (en) * | 1987-09-18 | 1988-11-22 | Pennsylvania Research Corporation | Copper electroplating solutions and methods of making and using them |
US4948474A (en) * | 1987-09-18 | 1990-08-14 | Pennsylvania Research Corporation | Copper electroplating solutions and methods |
US4897165A (en) * | 1988-08-23 | 1990-01-30 | Shipley Company Inc. | Electroplating composition and process for plating through holes in printed circuit boards |
US4954226A (en) * | 1988-12-21 | 1990-09-04 | International Business Machines Corporation | Additive plating bath and process |
US5215645A (en) * | 1989-09-13 | 1993-06-01 | Gould Inc. | Electrodeposited foil with controlled properties for printed circuit board applications and procedures and electrolyte bath solutions for preparing the same |
US5147905A (en) * | 1991-05-01 | 1992-09-15 | The Dow Chemical Company | Advanced and unadvanced compositions, nucleophilic derivatives thereof and curable and coating compositions thereof |
US5151170A (en) * | 1991-12-19 | 1992-09-29 | Mcgean-Rohco, Inc. | Acid copper electroplating bath containing brightening additive |
US5266212A (en) * | 1992-10-13 | 1993-11-30 | Enthone-Omi, Inc. | Purification of cyanide-free copper plating baths |
US5328589A (en) * | 1992-12-23 | 1994-07-12 | Enthone-Omi, Inc. | Functional fluid additives for acid copper electroplating baths |
US5630950A (en) * | 1993-07-09 | 1997-05-20 | Enthone-Omi, Inc. | Copper brightening process and bath |
US5402465A (en) * | 1993-12-02 | 1995-03-28 | Foltz; Jack D. | Telephone trouble isolator |
US5730854A (en) * | 1996-05-30 | 1998-03-24 | Enthone-Omi, Inc. | Alkoxylated dimercaptans as copper additives and de-polarizing additives |
US5733429A (en) * | 1996-09-10 | 1998-03-31 | Enthone-Omi, Inc. | Polyacrylic acid additives for copper electrorefining and electrowinning |
US5750018A (en) * | 1997-03-18 | 1998-05-12 | Learonal, Inc. | Cyanide-free monovalent copper electroplating solutions |
US5863410A (en) * | 1997-06-23 | 1999-01-26 | Circuit Foil Usa, Inc. | Process for the manufacture of high quality very low profile copper foil and copper foil produced thereby |
KR100616198B1 (ko) * | 1998-04-21 | 2006-08-25 | 어플라이드 머티어리얼스, 인코포레이티드 | 기판상에 전기도금하는 전기화학적 증착 시스템 및 방법 |
-
2000
- 2000-07-11 JP JP2000210188A patent/JP2001073182A/ja active Pending
- 2000-07-13 EP EP00305941A patent/EP1069211A3/en not_active Withdrawn
- 2000-07-14 KR KR1020000040658A patent/KR20010015342A/ko not_active Application Discontinuation
-
2004
- 2004-04-14 US US10/823,982 patent/US20040187731A1/en not_active Abandoned
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4430173A (en) * | 1981-07-24 | 1984-02-07 | Rhone-Poulenc Specialties Chimiques | Additive composition, bath and process for acid copper electroplating |
US5051154A (en) * | 1988-08-23 | 1991-09-24 | Shipley Company Inc. | Additive for acid-copper electroplating baths to increase throwing power |
US5849171A (en) * | 1990-10-13 | 1998-12-15 | Atotech Deutschland Gmbh | Acid bath for copper plating and process with the use of this combination |
US5174886A (en) * | 1991-02-22 | 1992-12-29 | Mcgean-Rohco, Inc. | High-throw acid copper plating using inert electrolyte |
US5433840A (en) * | 1991-08-07 | 1995-07-18 | Atotech Deutschland Gmbh | Acid bath for the galvanic deposition of copper, and the use of such a bath |
Also Published As
Publication number | Publication date |
---|---|
KR20010015342A (ko) | 2001-02-26 |
EP1069211A2 (en) | 2001-01-17 |
JP2001073182A (ja) | 2001-03-21 |
US20040187731A1 (en) | 2004-09-30 |
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