DE69735317T2 - Lithium-Vanadium-Phosphate, deren Herstellung und diese verwendende Lithium-Ionen-Batterien - Google Patents
Lithium-Vanadium-Phosphate, deren Herstellung und diese verwendende Lithium-Ionen-Batterien Download PDFInfo
- Publication number
- DE69735317T2 DE69735317T2 DE69735317T DE69735317T DE69735317T2 DE 69735317 T2 DE69735317 T2 DE 69735317T2 DE 69735317 T DE69735317 T DE 69735317T DE 69735317 T DE69735317 T DE 69735317T DE 69735317 T2 DE69735317 T2 DE 69735317T2
- Authority
- DE
- Germany
- Prior art keywords
- electrode
- lithium
- electrically conductive
- battery
- ethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910001416 lithium ion Inorganic materials 0.000 title description 27
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 title description 24
- 238000004519 manufacturing process Methods 0.000 title description 5
- YWJVFBOUPMWANA-UHFFFAOYSA-H [Li+].[V+5].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O Chemical class [Li+].[V+5].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O YWJVFBOUPMWANA-UHFFFAOYSA-H 0.000 title description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 38
- 239000000203 mixture Substances 0.000 claims description 26
- 239000011149 active material Substances 0.000 claims description 25
- 150000001875 compounds Chemical class 0.000 claims description 25
- 239000000463 material Substances 0.000 claims description 25
- 239000003792 electrolyte Substances 0.000 claims description 22
- 239000011230 binding agent Substances 0.000 claims description 20
- 230000003647 oxidation Effects 0.000 claims description 20
- 238000007254 oxidation reaction Methods 0.000 claims description 20
- 239000010439 graphite Substances 0.000 claims description 19
- 229910002804 graphite Inorganic materials 0.000 claims description 19
- 229910052799 carbon Inorganic materials 0.000 claims description 15
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims description 14
- 239000003085 diluting agent Substances 0.000 claims description 13
- 229910052751 metal Inorganic materials 0.000 claims description 13
- 239000002184 metal Substances 0.000 claims description 13
- 239000007772 electrode material Substances 0.000 claims description 12
- 238000009830 intercalation Methods 0.000 claims description 12
- 239000006229 carbon black Substances 0.000 claims description 8
- 230000002687 intercalation Effects 0.000 claims description 8
- 150000004770 chalcogenides Chemical class 0.000 claims description 7
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 5
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 5
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 claims description 4
- 229910000314 transition metal oxide Inorganic materials 0.000 claims description 3
- 239000004071 soot Substances 0.000 claims 5
- 239000004020 conductor Substances 0.000 claims 1
- 239000000178 monomer Substances 0.000 claims 1
- 229910052744 lithium Inorganic materials 0.000 description 102
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 55
- 229910019142 PO4 Inorganic materials 0.000 description 36
- 235000021317 phosphate Nutrition 0.000 description 36
- 239000010452 phosphate Substances 0.000 description 33
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 26
- 238000000034 method Methods 0.000 description 22
- -1 phosphorus compound Chemical class 0.000 description 20
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 description 16
- 239000002243 precursor Substances 0.000 description 13
- 239000007774 positive electrode material Substances 0.000 description 10
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 9
- 229910015643 LiMn 2 O 4 Inorganic materials 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 9
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 9
- 229910044991 metal oxide Inorganic materials 0.000 description 8
- 230000008569 process Effects 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 229910052720 vanadium Inorganic materials 0.000 description 8
- 229920002943 EPDM rubber Polymers 0.000 description 7
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 7
- 230000001351 cycling effect Effects 0.000 description 7
- 150000002500 ions Chemical class 0.000 description 7
- 239000002245 particle Substances 0.000 description 7
- 150000003839 salts Chemical class 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 239000006182 cathode active material Substances 0.000 description 6
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 6
- 150000004706 metal oxides Chemical class 0.000 description 6
- 239000007773 negative electrode material Substances 0.000 description 6
- 229910052698 phosphorus Inorganic materials 0.000 description 6
- 239000011574 phosphorus Substances 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 239000002002 slurry Substances 0.000 description 6
- 238000002441 X-ray diffraction Methods 0.000 description 5
- 238000007599 discharging Methods 0.000 description 5
- 238000000605 extraction Methods 0.000 description 5
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 5
- 230000002829 reductive effect Effects 0.000 description 5
- 125000006850 spacer group Chemical group 0.000 description 5
- 229910012851 LiCoO 2 Inorganic materials 0.000 description 4
- 229910013290 LiNiO 2 Inorganic materials 0.000 description 4
- 229910013870 LiPF 6 Inorganic materials 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 150000002642 lithium compounds Chemical class 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 239000007784 solid electrolyte Substances 0.000 description 4
- 239000007858 starting material Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 235000019241 carbon black Nutrition 0.000 description 3
- 239000003638 chemical reducing agent Substances 0.000 description 3
- 239000011889 copper foil Substances 0.000 description 3
- 238000003487 electrochemical reaction Methods 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 238000010348 incorporation Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 3
- 239000011572 manganese Substances 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 229910001463 metal phosphate Inorganic materials 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000004611 spectroscopical analysis Methods 0.000 description 3
- 239000004254 Ammonium phosphate Substances 0.000 description 2
- 229910018871 CoO 2 Inorganic materials 0.000 description 2
- 229910013553 LiNO Inorganic materials 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 2
- 235000019289 ammonium phosphates Nutrition 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- UNTBPXHCXVWYOI-UHFFFAOYSA-O azanium;oxido(dioxo)vanadium Chemical compound [NH4+].[O-][V](=O)=O UNTBPXHCXVWYOI-UHFFFAOYSA-O 0.000 description 2
- 239000000571 coke Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 230000000670 limiting effect Effects 0.000 description 2
- 239000011244 liquid electrolyte Substances 0.000 description 2
- 229910021450 lithium metal oxide Inorganic materials 0.000 description 2
- IIPYXGDZVMZOAP-UHFFFAOYSA-N lithium nitrate Chemical compound [Li+].[O-][N+]([O-])=O IIPYXGDZVMZOAP-UHFFFAOYSA-N 0.000 description 2
- 229910003002 lithium salt Inorganic materials 0.000 description 2
- 159000000002 lithium salts Chemical class 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000003746 solid phase reaction Methods 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- AFINAILKDBCXMX-PBHICJAKSA-N (2s,3r)-2-amino-3-hydroxy-n-(4-octylphenyl)butanamide Chemical compound CCCCCCCCC1=CC=C(NC(=O)[C@@H](N)[C@@H](C)O)C=C1 AFINAILKDBCXMX-PBHICJAKSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229920013683 Celanese Polymers 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 229910016523 CuKa Inorganic materials 0.000 description 1
- 241001232464 Delma Species 0.000 description 1
- 229910018068 Li 2 O Inorganic materials 0.000 description 1
- 229910013292 LiNiO Inorganic materials 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 101001094044 Mus musculus Solute carrier family 26 member 6 Proteins 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 description 1
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000006183 anode active material Substances 0.000 description 1
- 239000010405 anode material Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 238000001479 atomic absorption spectroscopy Methods 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000010406 cathode material Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001869 cobalt compounds Chemical class 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000009831 deintercalation Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000006056 electrooxidation reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 238000007759 kiss coating Methods 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- XIXADJRWDQXREU-UHFFFAOYSA-M lithium acetate Chemical compound [Li+].CC([O-])=O XIXADJRWDQXREU-UHFFFAOYSA-M 0.000 description 1
- 229910052808 lithium carbonate Inorganic materials 0.000 description 1
- 229910000625 lithium cobalt oxide Inorganic materials 0.000 description 1
- 229910001386 lithium phosphate Inorganic materials 0.000 description 1
- CJYZTOPVWURGAI-UHFFFAOYSA-N lithium;manganese;manganese(3+);oxygen(2-) Chemical compound [Li+].[O-2].[O-2].[O-2].[O-2].[Mn].[Mn+3] CJYZTOPVWURGAI-UHFFFAOYSA-N 0.000 description 1
- BFZPBUKRYWOWDV-UHFFFAOYSA-N lithium;oxido(oxo)cobalt Chemical compound [Li+].[O-][Co]=O BFZPBUKRYWOWDV-UHFFFAOYSA-N 0.000 description 1
- VROAXDSNYPAOBJ-UHFFFAOYSA-N lithium;oxido(oxo)nickel Chemical compound [Li+].[O-][Ni]=O VROAXDSNYPAOBJ-UHFFFAOYSA-N 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 235000019837 monoammonium phosphate Nutrition 0.000 description 1
- 150000002816 nickel compounds Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000000807 solvent casting Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- JUWGUJSXVOBPHP-UHFFFAOYSA-B titanium(4+);tetraphosphate Chemical compound [Ti+4].[Ti+4].[Ti+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O JUWGUJSXVOBPHP-UHFFFAOYSA-B 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 150000003681 vanadium Chemical class 0.000 description 1
- 229910001456 vanadium ion Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/26—Phosphates
- C01B25/45—Phosphates containing plural metal, or metal and ammonium
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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- H01M4/0404—Methods of deposition of the material by coating on electrode collectors
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- H—ELECTRICITY
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- H01M4/0409—Methods of deposition of the material by a doctor blade method, slip-casting or roller coating
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
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- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
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- H01M4/622—Binders being polymers
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- H—ELECTRICITY
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- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
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- H01M2004/021—Physical characteristics, e.g. porosity, surface area
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/028—Positive electrodes
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Dispersion Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Battery Electrode And Active Subsutance (AREA)
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Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US717979 | 1996-09-23 | ||
| US08/717,979 US5871866A (en) | 1996-09-23 | 1996-09-23 | Lithium-containing phosphates, method of preparation, and use thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69735317D1 DE69735317D1 (de) | 2006-04-27 |
| DE69735317T2 true DE69735317T2 (de) | 2006-11-09 |
Family
ID=24884314
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69735317T Expired - Lifetime DE69735317T2 (de) | 1996-09-23 | 1997-09-04 | Lithium-Vanadium-Phosphate, deren Herstellung und diese verwendende Lithium-Ionen-Batterien |
| DE69726893T Expired - Lifetime DE69726893T2 (de) | 1996-09-23 | 1997-09-04 | Lithium enthaltende Phosphate, deren Herstellung und diese verwendende Lithium-Ionen-Batterien |
| DE69708904T Expired - Lifetime DE69708904T2 (de) | 1996-09-23 | 1997-09-04 | Lithiumenthaltende, lithiuminterkalierende phosphate und deren verwendung als positives oder negatives elektrodenmaterial in einer sekundären lithiumbatterie |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69726893T Expired - Lifetime DE69726893T2 (de) | 1996-09-23 | 1997-09-04 | Lithium enthaltende Phosphate, deren Herstellung und diese verwendende Lithium-Ionen-Batterien |
| DE69708904T Expired - Lifetime DE69708904T2 (de) | 1996-09-23 | 1997-09-04 | Lithiumenthaltende, lithiuminterkalierende phosphate und deren verwendung als positives oder negatives elektrodenmaterial in einer sekundären lithiumbatterie |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US5871866A (enExample) |
| EP (3) | EP1093174B1 (enExample) |
| JP (1) | JP4292317B2 (enExample) |
| KR (1) | KR100458099B1 (enExample) |
| AU (1) | AU4410297A (enExample) |
| CA (2) | CA2843358A1 (enExample) |
| DE (3) | DE69735317T2 (enExample) |
| ES (2) | ES2169425T3 (enExample) |
| WO (1) | WO1998012761A1 (enExample) |
Families Citing this family (152)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5910382A (en) * | 1996-04-23 | 1999-06-08 | Board Of Regents, University Of Texas Systems | Cathode materials for secondary (rechargeable) lithium batteries |
| US6514640B1 (en) * | 1996-04-23 | 2003-02-04 | Board Of Regents, The University Of Texas System | Cathode materials for secondary (rechargeable) lithium batteries |
| US6447951B1 (en) * | 1996-09-23 | 2002-09-10 | Valence Technology, Inc. | Lithium based phosphates, method of preparation, and uses thereof |
| US6203946B1 (en) | 1998-12-03 | 2001-03-20 | Valence Technology, Inc. | Lithium-containing phosphates, method of preparation, and uses thereof |
| US6136472A (en) * | 1998-06-26 | 2000-10-24 | Valence Technology, Inc. | Lithium-containing silicon/phosphates, method of preparation, and uses thereof including as electrodes for a battery |
| US6322744B1 (en) * | 1999-02-17 | 2001-11-27 | Valence Technology, Inc. | Lithium manganese oxide-based active material |
| US6153333A (en) | 1999-03-23 | 2000-11-28 | Valence Technology, Inc. | Lithium-containing phosphate active materials |
| US7001690B2 (en) * | 2000-01-18 | 2006-02-21 | Valence Technology, Inc. | Lithium-based active materials and preparation thereof |
| US6528033B1 (en) | 2000-01-18 | 2003-03-04 | Valence Technology, Inc. | Method of making lithium-containing materials |
| US8057769B2 (en) * | 2000-04-27 | 2011-11-15 | Valence Technology, Inc. | Method for making phosphate-based electrode active materials |
| US6387568B1 (en) * | 2000-04-27 | 2002-05-14 | Valence Technology, Inc. | Lithium metal fluorophosphate materials and preparation thereof |
| US6777132B2 (en) * | 2000-04-27 | 2004-08-17 | Valence Technology, Inc. | Alkali/transition metal halo—and hydroxy-phosphates and related electrode active materials |
| US6964827B2 (en) * | 2000-04-27 | 2005-11-15 | Valence Technology, Inc. | Alkali/transition metal halo- and hydroxy-phosphates and related electrode active materials |
| US7524584B2 (en) * | 2000-04-27 | 2009-04-28 | Valence Technology, Inc. | Electrode active material for a secondary electrochemical cell |
| JP2002025559A (ja) * | 2000-07-03 | 2002-01-25 | Sony Corp | 電 池 |
| JP2002056848A (ja) * | 2000-08-09 | 2002-02-22 | Toshiba Battery Co Ltd | リチウムイオン二次電池 |
| JP2002056849A (ja) * | 2000-08-09 | 2002-02-22 | Toshiba Battery Co Ltd | リチウムイオン二次電池 |
| JP3826746B2 (ja) * | 2000-08-18 | 2006-09-27 | ソニー株式会社 | 非水電解液二次電池 |
| CA2320661A1 (fr) * | 2000-09-26 | 2002-03-26 | Hydro-Quebec | Nouveau procede de synthese de materiaux limpo4 a structure olivine |
| JP4734700B2 (ja) | 2000-09-29 | 2011-07-27 | ソニー株式会社 | 正極活物質の製造方法及び非水電解質電池の製造方法 |
| JP4491946B2 (ja) * | 2000-09-29 | 2010-06-30 | ソニー株式会社 | 正極活物質の製造方法及び非水電解質電池の製造方法 |
| JP3982165B2 (ja) * | 2000-10-05 | 2007-09-26 | ソニー株式会社 | 固体電解質電池 |
| US6814764B2 (en) | 2000-10-06 | 2004-11-09 | Sony Corporation | Method for producing cathode active material and method for producing non-aqueous electrolyte cell |
| JP3988374B2 (ja) * | 2000-10-06 | 2007-10-10 | ソニー株式会社 | 非水電解液二次電池 |
| JP4491949B2 (ja) * | 2000-10-06 | 2010-06-30 | ソニー株式会社 | 正極活物質の製造方法及び非水電解質電池の製造方法 |
| JP2002117908A (ja) * | 2000-10-06 | 2002-04-19 | Sony Corp | 非水電解液電池 |
| ATE405960T1 (de) | 2000-10-20 | 2008-09-15 | Massachusetts Inst Technology | Elektroden mit vernetzter oder poröser struktur |
| US7387851B2 (en) | 2001-07-27 | 2008-06-17 | A123 Systems, Inc. | Self-organizing battery structure with electrode particles that exert a repelling force on the opposite electrode |
| US7662265B2 (en) | 2000-10-20 | 2010-02-16 | Massachusetts Institute Of Technology | Electrophoretic assembly of electrochemical devices |
| US6645452B1 (en) * | 2000-11-28 | 2003-11-11 | Valence Technology, Inc. | Methods of making lithium metal cathode active materials |
| CA2378278C (en) * | 2001-03-26 | 2008-11-18 | Kabushiki Kaisha Toshiba | Positive electrode active material and nonaqueous electrolyte secondary battery |
| KR100814540B1 (ko) * | 2001-04-06 | 2008-03-17 | 발렌스 테크놀로지, 인코포레이티드 | 나트륨 이온 배터리 |
| DE10117904B4 (de) * | 2001-04-10 | 2012-11-15 | Zentrum für Sonnenenergie- und Wasserstoff-Forschung Baden-Württemberg Gemeinnützige Stiftung | Binäre, ternäre und quaternäre Lithiumeisenphosphate, Verfahren zu ihrer Herstellung und ihre Verwendung |
| JP4236390B2 (ja) * | 2001-04-19 | 2009-03-11 | 三洋電機株式会社 | リチウム二次電池 |
| EP1261050A1 (en) * | 2001-05-23 | 2002-11-27 | n.v. Umicore s.a. | Lithium transition-metal phosphate powder for rechargeable batteries |
| KR101178643B1 (ko) | 2001-07-27 | 2012-09-07 | 에이일이삼 시스템즈 인코포레이티드 | 배터리 구조, 자기 조직화 구조 및 관련 방법 |
| EP2278643B1 (en) | 2001-12-21 | 2018-03-28 | Massachusetts Institute of Technology (MIT) | Conductive lithium storage electrode |
| AU2002361689A1 (en) * | 2002-01-04 | 2003-07-30 | University Of Dayton | Non-toxic corrosion protection pigments based on cobalt |
| US6815122B2 (en) | 2002-03-06 | 2004-11-09 | Valence Technology, Inc. | Alkali transition metal phosphates and related electrode active materials |
| US7482097B2 (en) * | 2002-04-03 | 2009-01-27 | Valence Technology, Inc. | Alkali-transition metal phosphates having a +3 valence non-transition element and related electrode active materials |
| US7422823B2 (en) * | 2002-04-03 | 2008-09-09 | Valence Technology, Inc. | Alkali-iron-cobalt phosphates and related electrode active materials |
| US20030190527A1 (en) * | 2002-04-03 | 2003-10-09 | James Pugh | Batteries comprising alkali-transition metal phosphates and preferred electrolytes |
| US6913855B2 (en) * | 2002-07-22 | 2005-07-05 | Valence Technology, Inc. | Method of synthesizing electrochemically active materials from a slurry of precursors |
| US7087348B2 (en) | 2002-07-26 | 2006-08-08 | A123 Systems, Inc. | Coated electrode particles for composite electrodes and electrochemical cells |
| KR100449073B1 (ko) * | 2002-10-15 | 2004-09-18 | 한국전자통신연구원 | 리튬 이차 전지용 양극 활물질 및 그 제조 방법 |
| CA2776362A1 (en) * | 2002-12-19 | 2004-06-19 | Valence Technology, Inc. | Batteries with alkali metal phosphate electrodes |
| CN1754275A (zh) * | 2002-12-23 | 2006-03-29 | A123系统公司 | 高能量和高功率密度电化学电池 |
| US20040011252A1 (en) * | 2003-01-13 | 2004-01-22 | Sturgill Jeffrey A. | Non-toxic corrosion-protection pigments based on manganese |
| US7326494B2 (en) * | 2003-01-30 | 2008-02-05 | T/J Technologies, Inc. | Composite material and electrodes made therefrom |
| US7041239B2 (en) * | 2003-04-03 | 2006-05-09 | Valence Technology, Inc. | Electrodes comprising mixed active particles |
| US20070141468A1 (en) * | 2003-04-03 | 2007-06-21 | Jeremy Barker | Electrodes Comprising Mixed Active Particles |
| US20040202935A1 (en) * | 2003-04-08 | 2004-10-14 | Jeremy Barker | Cathode active material with increased alkali/metal content and method of making same |
| US7318982B2 (en) | 2003-06-23 | 2008-01-15 | A123 Systems, Inc. | Polymer composition for encapsulation of electrode particles |
| US7986124B2 (en) | 2003-09-22 | 2011-07-26 | Valence Technology, Inc. | Electrical systems, battery assemblies, and battery assembly operational methods |
| WO2005041327A1 (ja) * | 2003-10-27 | 2005-05-06 | Mitsui Engineering & Shipbuilding Co.,Ltd. | 二次電池用正極材料、二次電池用正極材料の製造方法、および二次電池 |
| CA2906604A1 (en) | 2003-12-23 | 2005-07-07 | Laurent Gauthier | Process for preparing electroactive insertion compounds and electrode materials obtained therefrom |
| US7008726B2 (en) * | 2004-01-22 | 2006-03-07 | Valence Technology, Inc. | Secondary battery electrode active materials and methods for making the same |
| US20050170256A1 (en) * | 2004-01-30 | 2005-08-04 | John Cummings | Electrical power source apparatuses, electrical power source operational methods, and electrochemical device charging methods |
| US8617745B2 (en) | 2004-02-06 | 2013-12-31 | A123 Systems Llc | Lithium secondary cell with high charge and discharge rate capability and low impedance growth |
| US7719227B2 (en) * | 2004-02-13 | 2010-05-18 | Valence Technology, Inc. | Electrical energy supply methods and electrical energy power supplies |
| US7960057B2 (en) * | 2004-05-17 | 2011-06-14 | Toyota Motor Engineering & Manufacturing North America, Inc. | Battery with molten salt electrolyte and phosphorus-containing cathode |
| WO2005113863A2 (en) * | 2004-05-20 | 2005-12-01 | Valence Technology, Inc. | Secondary electrochemical cell |
| US7629080B1 (en) | 2004-07-23 | 2009-12-08 | The United States Of America As Represented By The Secretary Of The Army | Electrode materials for electrochemical cells |
| US7842420B2 (en) | 2005-02-03 | 2010-11-30 | A123 Systems, Inc. | Electrode material with enhanced ionic transport properties |
| US7205067B2 (en) * | 2005-02-08 | 2007-04-17 | Valence Technology, Inc. | Method and apparatus for dissipation of heat generated by a secondary electrochemical cell |
| US20080138710A1 (en) * | 2005-05-10 | 2008-06-12 | Ben-Jie Liaw | Electrochemical Composition and Associated Technology |
| US7887954B2 (en) * | 2005-05-10 | 2011-02-15 | Advanced Lithium Electrochemistry Co., Ltd. | Electrochemical composition and associated technology |
| US20070009184A1 (en) * | 2005-07-05 | 2007-01-11 | Bhogal Kulvir S | Associating attributes to captured input within a digital pen |
| US7609146B2 (en) * | 2005-07-27 | 2009-10-27 | Lear Corporation | System and method for controlling a function using a variable sensitivity receiver |
| JP2009508302A (ja) | 2005-09-09 | 2009-02-26 | エイ 123 システムズ,インク. | 高い充放電率能力と小さいインピーダンス増加を有するリチウム二次電池 |
| JP4862357B2 (ja) * | 2005-10-28 | 2012-01-25 | 株式会社豊田中央研究所 | 負極活物質及び水系リチウム二次電池 |
| JP5188677B2 (ja) * | 2005-12-21 | 2013-04-24 | 三星エスディアイ株式会社 | リチウム二次電池及びリチウム二次電池の製造方法 |
| US9444120B2 (en) | 2005-12-21 | 2016-09-13 | Samsung Sdi Co., Ltd. | Rechargeable lithium battery and method for manufacturing the same |
| US7914932B2 (en) | 2006-02-24 | 2011-03-29 | Ngk Insulators, Ltd. | All-solid-state battery |
| KR20130106440A (ko) | 2006-02-28 | 2013-09-27 | 프리메트 프리시젼 머테리알스, 인크. | 리튬계 화합물 나노입자 조성물 및 이의 제조 방법 |
| US7723958B2 (en) | 2006-03-31 | 2010-05-25 | Valence Technology, Inc. | Battery charge indication methods, battery charge monitoring devices, rechargeable batteries, and articles of manufacture |
| US20090061314A1 (en) * | 2007-08-30 | 2009-03-05 | Ming Dong | Method of Processing Active Materials For Use In Secondary Electrochemical Cells |
| EP2067198A2 (en) * | 2006-09-25 | 2009-06-10 | Board of Regents, The University of Texas System | Cation-substituted spinel oxide and oxyfluoride cathodes for lithium ion batteries |
| EP2266160A4 (en) | 2006-10-17 | 2010-12-29 | Valence Technology Inc | METHOD AND DEVICE FOR MONITORING AND CONTROLLING AN ELECTROCHEMICAL CELL |
| EP2093824A4 (en) * | 2006-11-14 | 2014-08-06 | Ngk Insulators Ltd | FIXED ELECTROLYTE STRUCTURE FOR A THRESHOLD SOLID BODY BATTERY, THRESHOLD FIXED BODY BATTERY AND MANUFACTURING METHOD THEREFOR |
| JP4983356B2 (ja) * | 2007-04-10 | 2012-07-25 | 株式会社豊田中央研究所 | 水系リチウム二次電池 |
| JP2008260666A (ja) * | 2007-04-13 | 2008-10-30 | Kyushu Univ | ナトリウム二次電池用活物質およびその製造方法 |
| US20090202903A1 (en) | 2007-05-25 | 2009-08-13 | Massachusetts Institute Of Technology | Batteries and electrodes for use thereof |
| US20080305256A1 (en) * | 2007-06-08 | 2008-12-11 | Conocophillips Company | Method for producing lithium vanadium polyanion powders for batteries |
| US20080303004A1 (en) * | 2007-06-08 | 2008-12-11 | Conocophillips Company | Method for producing lithium transition metal polyanion powders for batteries |
| US8168329B2 (en) * | 2007-06-18 | 2012-05-01 | Advanced Lithium Electrochemistry Co., Ltd. | Electrochemical composition and associated technology |
| EP2015382A1 (en) * | 2007-07-13 | 2009-01-14 | High Power Lithium S.A. | Carbon coated lithium manganese phosphate cathode material |
| JP5705541B2 (ja) * | 2007-10-01 | 2015-04-22 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | 結晶性リチウム−、バナジウム−、及びフォスフェイト−含有材料を製造するための方法 |
| CN102123943B (zh) | 2007-10-01 | 2013-07-10 | 巴斯夫欧洲公司 | 制备包含锂、钒和磷酸根的多孔材料的方法 |
| JP5200613B2 (ja) * | 2008-03-25 | 2013-06-05 | 株式会社Gsユアサ | 非水電解質電池 |
| CN102378738A (zh) | 2009-04-03 | 2012-03-14 | 旭硝子株式会社 | 磷酸铁锂颗粒的制造方法及二次电池的制造方法 |
| US20100266474A1 (en) * | 2009-04-16 | 2010-10-21 | Titus Faulkner | Method of Making Active Materials for Use in Secondary Electrochemical Cells |
| US8372540B2 (en) * | 2009-04-16 | 2013-02-12 | Valence Technology, Inc. | Electrode active material for secondary electrochemical cell |
| WO2011027682A1 (ja) * | 2009-09-03 | 2011-03-10 | 株式会社 村田製作所 | 二次電池用電極活物質の製造方法と二次電池用電極活物質の前駆体 |
| JP5489063B2 (ja) | 2009-11-02 | 2014-05-14 | 株式会社Gsユアサ | リチウム二次電池用正極活物質、リチウム二次電池用電極及びリチウム二次電池 |
| KR101070174B1 (ko) | 2010-01-21 | 2011-10-05 | 한화케미칼 주식회사 | 전극 활물질인 음이온 부족형 리튬 전이금속 인산화합물, 그 제조방법, 및 그를 이용한 전기화학 소자 |
| WO2011102358A1 (ja) * | 2010-02-17 | 2011-08-25 | 株式会社Gsユアサ | 非水電解質二次電池用正極活物質及び非水電解質二次電池 |
| CN101924205B (zh) * | 2010-06-03 | 2013-06-05 | 清华大学 | 锂电池电极材料的制备方法 |
| CN101859891B (zh) * | 2010-06-03 | 2012-08-29 | 清华大学 | 锂电池电极材料 |
| US20110300446A1 (en) * | 2010-06-03 | 2011-12-08 | Hon Hai Precision Industry Co., Ltd. | Lithium battery cathode composite material |
| JP5604216B2 (ja) * | 2010-08-09 | 2014-10-08 | 日本化学工業株式会社 | リン酸バナジウムリチウム炭素複合体の製造方法 |
| JP5604217B2 (ja) * | 2010-08-09 | 2014-10-08 | 日本化学工業株式会社 | リン酸バナジウムリチウム炭素複合体の製造方法 |
| US9437866B2 (en) | 2010-09-27 | 2016-09-06 | Nippon Chemical Industrial Co., Ltd. | Process for producing lithium vanadium phosphate-carbon composite |
| US9160001B2 (en) | 2010-12-23 | 2015-10-13 | Wildcat Discovery Technologies, Inc. | Lithium-ion battery materials with improved properties |
| US9065093B2 (en) | 2011-04-07 | 2015-06-23 | Massachusetts Institute Of Technology | Controlled porosity in electrodes |
| JP5255138B2 (ja) | 2011-05-18 | 2013-08-07 | 富士重工業株式会社 | 蓄電デバイス及び蓄電デバイス用正極 |
| KR102650871B1 (ko) | 2011-06-03 | 2024-03-26 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | 전극을 제조하기 위한 방법 |
| US9218916B2 (en) | 2011-06-24 | 2015-12-22 | Semiconductor Energy Laboratory Co., Ltd. | Graphene, power storage device, and electric device |
| US9249524B2 (en) | 2011-08-31 | 2016-02-02 | Semiconductor Energy Laboratory Co., Ltd. | Manufacturing method of composite oxide and manufacturing method of power storage device |
| JP2013084566A (ja) | 2011-09-30 | 2013-05-09 | Fuji Heavy Ind Ltd | 非水電解質二次電池 |
| KR102514830B1 (ko) | 2011-09-30 | 2023-03-30 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | 양극, 리튬 이차 전지, 전기 자동차, 하이브리드 자동차, 이동체, 시스템, 및 전기 기기 |
| JP2013077424A (ja) | 2011-09-30 | 2013-04-25 | Fuji Heavy Ind Ltd | リチウムイオン二次電池 |
| JP5797993B2 (ja) * | 2011-09-30 | 2015-10-21 | 富士重工業株式会社 | 非水電解質二次電池 |
| JP5255143B2 (ja) | 2011-09-30 | 2013-08-07 | 富士重工業株式会社 | 正極材料、これを用いたリチウムイオン二次電池、及び正極材料の製造方法 |
| US9487880B2 (en) | 2011-11-25 | 2016-11-08 | Semiconductor Energy Laboratory Co., Ltd. | Flexible substrate processing apparatus |
| JP6016597B2 (ja) | 2011-12-16 | 2016-10-26 | 株式会社半導体エネルギー研究所 | リチウムイオン二次電池用正極の製造方法 |
| US20130157140A1 (en) * | 2011-12-20 | 2013-06-20 | General Electric Company | Methods of making and using electrode compositions and articles |
| JP5719859B2 (ja) | 2012-02-29 | 2015-05-20 | 株式会社半導体エネルギー研究所 | 蓄電装置 |
| US9263736B2 (en) | 2012-03-27 | 2016-02-16 | Tdk Corporation | Positive electrode material for lithium ion secondary battery, positive electrode for lithium ion secondary battery, and lithium ion secondary battery |
| TW201405920A (zh) | 2012-05-29 | 2014-02-01 | Clariant Canada Inc | 製備晶形電極材料的方法及由之獲致的材料 |
| US9225003B2 (en) | 2012-06-15 | 2015-12-29 | Semiconductor Energy Laboratory Co., Ltd. | Method for manufacturing storage battery electrode, storage battery electrode, storage battery, and electronic device |
| JPWO2014006948A1 (ja) * | 2012-07-04 | 2016-06-02 | 富士重工業株式会社 | 非水溶媒系蓄電デバイス |
| JP6159228B2 (ja) | 2012-11-07 | 2017-07-05 | 株式会社半導体エネルギー研究所 | 非水系二次電池用正極の製造方法 |
| US9673454B2 (en) | 2013-02-18 | 2017-06-06 | Semiconductor Energy Laboratory Co., Ltd. | Sodium-ion secondary battery |
| US9490472B2 (en) | 2013-03-28 | 2016-11-08 | Semiconductor Energy Laboratory Co., Ltd. | Method for manufacturing electrode for storage battery |
| DE112014002346B4 (de) | 2013-05-10 | 2021-07-29 | Semiconductor Energy Laboratory Co., Ltd. | Speicherbatterie mit Lithiummanganoxid-Verbundstoff und deren Verwendung |
| ES2798309T3 (es) | 2013-07-09 | 2020-12-10 | Dow Global Technologies Llc | Material activo positivo mixto que comprende óxido metálico de litio y fosfato metálico de litio |
| TWI661600B (zh) | 2013-07-15 | 2019-06-01 | 日商半導體能源研究所股份有限公司 | 鋰錳複合氧化物、二次電池以及電器設備 |
| KR101672575B1 (ko) * | 2013-08-01 | 2016-11-03 | 주식회사 엘지화학 | 리튬 망간 인산화물을 포함하는 음극 활물질, 이의 제조 방법, 및 이를 포함하는 리튬 이차전지 또는 하이브리드 캐패시터 |
| JP6194719B2 (ja) * | 2013-09-25 | 2017-09-13 | 株式会社村田製作所 | 全固体電池 |
| RU2556011C2 (ru) * | 2013-09-27 | 2015-07-10 | Общество с ограниченной ответственностью "Научный центр "Автономные источники тока" (ООО "Научный центр "АИТ") | Катодный материал для литий-ионных аккумуляторов на основе модифицированных фосфатов |
| RU2542721C1 (ru) * | 2013-09-27 | 2015-02-27 | Общество с ограниченной ответственностью "Научный центр "Автономные источники тока" (ООО "Научный центр "АИТ") | Композитный катодный материал литий-ионного аккумулятора на основе li3v2(po4)3со структурой насикон и способ его получения |
| KR20160065837A (ko) | 2013-10-04 | 2016-06-09 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | 리튬 망가니즈 복합 산화물, 이차 전지, 및 전자 기기, 및 층의 형성 방법 |
| US9865867B2 (en) | 2013-10-04 | 2018-01-09 | Semiconductor Energy Laboratory Co., Ltd. | Lithium manganese composite oxide, secondary battery, and electrical device |
| WO2015079372A1 (en) | 2013-11-29 | 2015-06-04 | Semiconductor Energy Laboratory Co., Ltd. | Lithium-manganese composite oxide and secondary battery |
| CA2944454A1 (en) | 2014-04-01 | 2015-10-08 | The Research Foundation For The State University Of New York | Electrode materials for group ii cation-based batteries |
| KR20240132127A (ko) | 2014-05-09 | 2024-09-02 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | 리튬 이온 이차 전지 및 전자 장치 |
| JP6745587B2 (ja) | 2014-05-29 | 2020-08-26 | 株式会社半導体エネルギー研究所 | 電極の製造方法 |
| JP2016039027A (ja) | 2014-08-07 | 2016-03-22 | トヨタ自動車株式会社 | リチウム二次電池用正極活物質、リチウム二次電池およびリチウム二次電池用正極活物質の製造方法 |
| US10675819B2 (en) | 2014-10-03 | 2020-06-09 | Massachusetts Institute Of Technology | Magnetic field alignment of emulsions to produce porous articles |
| WO2016054530A1 (en) | 2014-10-03 | 2016-04-07 | Massachusetts Institute Of Technology | Pore orientation using magnetic fields |
| WO2016095177A1 (en) | 2014-12-18 | 2016-06-23 | Dow Global Technologies Llc | Lithium ion battery having improved thermal stability |
| US10256470B2 (en) | 2014-12-26 | 2019-04-09 | Semiconductor Energy Laboratory Co., Ltd. | Electrode, power storage device, electronic device, and manufacturing method of electrode |
| WO2017154690A1 (ja) | 2016-03-08 | 2017-09-14 | 日本化学工業株式会社 | リン酸バナジウムリチウムの製造方法 |
| DE112017007748B3 (de) | 2016-07-05 | 2022-07-28 | Semiconductor Energy Laboratory Co., Ltd. | Lithiumionen-Sekundärbatterie |
| US12308421B2 (en) | 2016-09-12 | 2025-05-20 | Semiconductor Energy Laboratory Co., Ltd. | Electrode and power storage device comprising graphene compound |
| CN116387602A (zh) | 2016-10-12 | 2023-07-04 | 株式会社半导体能源研究所 | 正极活性物质粒子以及正极活性物质粒子的制造方法 |
| US11489151B2 (en) | 2017-05-12 | 2022-11-01 | Semiconductor Energy Laboratory Co., Ltd. | Positive electrode active material particle |
| CN117038957A (zh) | 2017-05-19 | 2023-11-10 | 株式会社半导体能源研究所 | 锂离子二次电池 |
| CN118335885A (zh) | 2017-06-26 | 2024-07-12 | 株式会社半导体能源研究所 | 正极活性物质的制造方法及二次电池 |
| WO2019167783A1 (ja) * | 2018-02-27 | 2019-09-06 | Tdk株式会社 | 活物質及び全固体二次電池 |
| CN113165908A (zh) | 2018-12-17 | 2021-07-23 | 株式会社半导体能源研究所 | 正极活性物质及二次电池 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3736184A (en) * | 1972-03-29 | 1973-05-29 | Mallory & Co Inc P R | Metal phosphate and metal arsenate organic electrolyte cells |
| US4009092A (en) * | 1976-02-27 | 1977-02-22 | E. I. Du Pont De Nemours And Company | Substituted lithium phosphates and solid electrolytes therefrom |
| US4049891A (en) * | 1976-06-21 | 1977-09-20 | Massachusetts Institute Of Technology | Compositions for fast alkali-metal-ion transport |
| FR2457018A1 (fr) * | 1979-02-16 | 1980-12-12 | Accumulateurs Fixes | Matiere active positive pour generateur electrochimique a electrolyte non aqueux et methode de preparation de celle-ci |
| US4434216A (en) * | 1980-10-24 | 1984-02-28 | Rayovac Corporation | Solid state electrolyte |
| US4512905A (en) * | 1982-05-18 | 1985-04-23 | The Texas A&M University System | Method of making sodium zirconium silico-phosphates |
| US4707422A (en) * | 1983-06-27 | 1987-11-17 | Voltaix, Inc. | Composite coating for electrochemical electrode and method |
| FR2563382B1 (fr) * | 1984-04-24 | 1986-05-30 | Elf Aquitaine | Nouveau generateur electrochimique a electrode composite |
| FR2576712B1 (fr) * | 1985-01-30 | 1988-07-08 | Accumulateurs Fixes | Generateur electrochimique a electrolyte non aqueux |
| JPS61263069A (ja) * | 1985-05-17 | 1986-11-21 | Matsushita Electric Ind Co Ltd | 電池 |
| US4985317A (en) * | 1988-11-30 | 1991-01-15 | Japan Synthetic Rubber Co., Ltd. | Lithium ion-conductive solid electrolyte containing lithium titanium phosphate |
| US5262548A (en) * | 1990-05-21 | 1993-11-16 | Scientific Design Company, Inc. | Phosphorous/vanadium oxidation catalyst |
| US5232794A (en) * | 1991-10-17 | 1993-08-03 | The United States Of America As Represented By The United States Department Of Energy | Ionic conductors for solid oxide fuel cells |
| US5296436A (en) * | 1993-01-08 | 1994-03-22 | Scientific Design Company, Inc. | Phosphorous/vanadium oxidation catalyst |
| JPH06251764A (ja) * | 1993-02-22 | 1994-09-09 | Fuji Elelctrochem Co Ltd | リチウム二次電池 |
| JP2966261B2 (ja) * | 1993-11-02 | 1999-10-25 | 三菱電線工業株式会社 | リチウム電池用正極材及びその製造方法 |
| US5514490A (en) * | 1994-08-30 | 1996-05-07 | Industrial Technology Research Institute | Secondary lithium battery using a new layered anode material |
| US5910382A (en) * | 1996-04-23 | 1999-06-08 | Board Of Regents, University Of Texas Systems | Cathode materials for secondary (rechargeable) lithium batteries |
-
1996
- 1996-09-23 US US08/717,979 patent/US5871866A/en not_active Expired - Lifetime
-
1997
- 1997-09-04 CA CA2843358A patent/CA2843358A1/en not_active Abandoned
- 1997-09-04 DE DE69735317T patent/DE69735317T2/de not_active Expired - Lifetime
- 1997-09-04 KR KR10-1999-7002302A patent/KR100458099B1/ko not_active Expired - Fee Related
- 1997-09-04 CA CA2266365A patent/CA2266365C/en not_active Expired - Lifetime
- 1997-09-04 DE DE69726893T patent/DE69726893T2/de not_active Expired - Lifetime
- 1997-09-04 EP EP01200220A patent/EP1093174B1/en not_active Expired - Lifetime
- 1997-09-04 AU AU44102/97A patent/AU4410297A/en not_active Abandoned
- 1997-09-04 DE DE69708904T patent/DE69708904T2/de not_active Expired - Lifetime
- 1997-09-04 EP EP03025462A patent/EP1403945B1/en not_active Expired - Lifetime
- 1997-09-04 ES ES97942393T patent/ES2169425T3/es not_active Expired - Lifetime
- 1997-09-04 JP JP51469398A patent/JP4292317B2/ja not_active Expired - Fee Related
- 1997-09-04 EP EP97942393A patent/EP0931361B1/en not_active Expired - Lifetime
- 1997-09-04 ES ES03025462T patent/ES2258196T3/es not_active Expired - Lifetime
- 1997-09-04 WO PCT/US1997/015544 patent/WO1998012761A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| EP1403945B1 (en) | 2006-03-01 |
| CA2843358A1 (en) | 1998-03-26 |
| DE69735317D1 (de) | 2006-04-27 |
| WO1998012761A1 (en) | 1998-03-26 |
| DE69726893T2 (de) | 2004-10-28 |
| KR100458099B1 (ko) | 2004-11-26 |
| ES2169425T3 (es) | 2002-07-01 |
| JP2001500665A (ja) | 2001-01-16 |
| EP1403945A1 (en) | 2004-03-31 |
| DE69708904D1 (de) | 2002-01-17 |
| KR20000036230A (ko) | 2000-06-26 |
| HK1023850A1 (en) | 2000-09-22 |
| JP4292317B2 (ja) | 2009-07-08 |
| US5871866A (en) | 1999-02-16 |
| EP0931361B1 (en) | 2001-12-05 |
| DE69726893D1 (de) | 2004-01-29 |
| EP1093174A1 (en) | 2001-04-18 |
| CA2266365C (en) | 2014-04-29 |
| DE69708904T2 (de) | 2002-08-14 |
| CA2266365A1 (en) | 1998-03-26 |
| ES2258196T3 (es) | 2006-08-16 |
| EP1093174B1 (en) | 2003-12-17 |
| EP0931361A1 (en) | 1999-07-28 |
| AU4410297A (en) | 1998-04-14 |
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