CA2843358A1 - Lithium-containing, lithium-intercalating phosphates and their use as the positive or negative electrode material in a lithium secondary battery - Google Patents

Lithium-containing, lithium-intercalating phosphates and their use as the positive or negative electrode material in a lithium secondary battery Download PDF

Info

Publication number
CA2843358A1
CA2843358A1 CA2843358A CA2843358A CA2843358A1 CA 2843358 A1 CA2843358 A1 CA 2843358A1 CA 2843358 A CA2843358 A CA 2843358A CA 2843358 A CA2843358 A CA 2843358A CA 2843358 A1 CA2843358 A1 CA 2843358A1
Authority
CA
Canada
Prior art keywords
lithium
compound
metal
phosphate
mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA2843358A
Other languages
English (en)
French (fr)
Inventor
Jeremy Barker
Mohamed-Yazid Saidi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Valence Technology Inc
Original Assignee
Valence Technology Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Valence Technology Inc filed Critical Valence Technology Inc
Publication of CA2843358A1 publication Critical patent/CA2843358A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/26—Phosphates
    • C01B25/45—Phosphates containing plural metal, or metal and ammonium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0402—Methods of deposition of the material
    • H01M4/0404—Methods of deposition of the material by coating on electrode collectors
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0402—Methods of deposition of the material
    • H01M4/0409—Methods of deposition of the material by a doctor blade method, slip-casting or roller coating
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0402—Methods of deposition of the material
    • H01M4/0416—Methods of deposition of the material involving impregnation with a solution, dispersion, paste or dry powder
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/621—Binders
    • H01M4/622—Binders being polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • H01M4/625—Carbon or graphite
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/021—Physical characteristics, e.g. porosity, surface area
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028—Positive electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
CA2843358A 1996-09-23 1997-09-04 Lithium-containing, lithium-intercalating phosphates and their use as the positive or negative electrode material in a lithium secondary battery Abandoned CA2843358A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/717,979 1996-09-23
US08/717,979 US5871866A (en) 1996-09-23 1996-09-23 Lithium-containing phosphates, method of preparation, and use thereof
CA2266365A CA2266365C (en) 1996-09-23 1997-09-04 Lithium-containing, lithium-intercalating phosphates and their use as the positive or negative electrode material in a lithium secondary battery

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
CA2266365A Division CA2266365C (en) 1996-09-23 1997-09-04 Lithium-containing, lithium-intercalating phosphates and their use as the positive or negative electrode material in a lithium secondary battery

Publications (1)

Publication Number Publication Date
CA2843358A1 true CA2843358A1 (en) 1998-03-26

Family

ID=24884314

Family Applications (2)

Application Number Title Priority Date Filing Date
CA2843358A Abandoned CA2843358A1 (en) 1996-09-23 1997-09-04 Lithium-containing, lithium-intercalating phosphates and their use as the positive or negative electrode material in a lithium secondary battery
CA2266365A Expired - Lifetime CA2266365C (en) 1996-09-23 1997-09-04 Lithium-containing, lithium-intercalating phosphates and their use as the positive or negative electrode material in a lithium secondary battery

Family Applications After (1)

Application Number Title Priority Date Filing Date
CA2266365A Expired - Lifetime CA2266365C (en) 1996-09-23 1997-09-04 Lithium-containing, lithium-intercalating phosphates and their use as the positive or negative electrode material in a lithium secondary battery

Country Status (9)

Country Link
US (1) US5871866A (enExample)
EP (3) EP1093174B1 (enExample)
JP (1) JP4292317B2 (enExample)
KR (1) KR100458099B1 (enExample)
AU (1) AU4410297A (enExample)
CA (2) CA2843358A1 (enExample)
DE (3) DE69735317T2 (enExample)
ES (2) ES2169425T3 (enExample)
WO (1) WO1998012761A1 (enExample)

Families Citing this family (152)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5910382A (en) * 1996-04-23 1999-06-08 Board Of Regents, University Of Texas Systems Cathode materials for secondary (rechargeable) lithium batteries
US6514640B1 (en) * 1996-04-23 2003-02-04 Board Of Regents, The University Of Texas System Cathode materials for secondary (rechargeable) lithium batteries
US6447951B1 (en) * 1996-09-23 2002-09-10 Valence Technology, Inc. Lithium based phosphates, method of preparation, and uses thereof
US6203946B1 (en) 1998-12-03 2001-03-20 Valence Technology, Inc. Lithium-containing phosphates, method of preparation, and uses thereof
US6136472A (en) * 1998-06-26 2000-10-24 Valence Technology, Inc. Lithium-containing silicon/phosphates, method of preparation, and uses thereof including as electrodes for a battery
US6322744B1 (en) * 1999-02-17 2001-11-27 Valence Technology, Inc. Lithium manganese oxide-based active material
US6153333A (en) 1999-03-23 2000-11-28 Valence Technology, Inc. Lithium-containing phosphate active materials
US7001690B2 (en) * 2000-01-18 2006-02-21 Valence Technology, Inc. Lithium-based active materials and preparation thereof
US6528033B1 (en) 2000-01-18 2003-03-04 Valence Technology, Inc. Method of making lithium-containing materials
US8057769B2 (en) * 2000-04-27 2011-11-15 Valence Technology, Inc. Method for making phosphate-based electrode active materials
US6387568B1 (en) * 2000-04-27 2002-05-14 Valence Technology, Inc. Lithium metal fluorophosphate materials and preparation thereof
US6777132B2 (en) * 2000-04-27 2004-08-17 Valence Technology, Inc. Alkali/transition metal halo—and hydroxy-phosphates and related electrode active materials
US6964827B2 (en) * 2000-04-27 2005-11-15 Valence Technology, Inc. Alkali/transition metal halo- and hydroxy-phosphates and related electrode active materials
US7524584B2 (en) * 2000-04-27 2009-04-28 Valence Technology, Inc. Electrode active material for a secondary electrochemical cell
JP2002025559A (ja) * 2000-07-03 2002-01-25 Sony Corp 電 池
JP2002056848A (ja) * 2000-08-09 2002-02-22 Toshiba Battery Co Ltd リチウムイオン二次電池
JP2002056849A (ja) * 2000-08-09 2002-02-22 Toshiba Battery Co Ltd リチウムイオン二次電池
JP3826746B2 (ja) * 2000-08-18 2006-09-27 ソニー株式会社 非水電解液二次電池
CA2320661A1 (fr) * 2000-09-26 2002-03-26 Hydro-Quebec Nouveau procede de synthese de materiaux limpo4 a structure olivine
JP4734700B2 (ja) 2000-09-29 2011-07-27 ソニー株式会社 正極活物質の製造方法及び非水電解質電池の製造方法
JP4491946B2 (ja) * 2000-09-29 2010-06-30 ソニー株式会社 正極活物質の製造方法及び非水電解質電池の製造方法
JP3982165B2 (ja) * 2000-10-05 2007-09-26 ソニー株式会社 固体電解質電池
US6814764B2 (en) 2000-10-06 2004-11-09 Sony Corporation Method for producing cathode active material and method for producing non-aqueous electrolyte cell
JP3988374B2 (ja) * 2000-10-06 2007-10-10 ソニー株式会社 非水電解液二次電池
JP4491949B2 (ja) * 2000-10-06 2010-06-30 ソニー株式会社 正極活物質の製造方法及び非水電解質電池の製造方法
JP2002117908A (ja) * 2000-10-06 2002-04-19 Sony Corp 非水電解液電池
ATE405960T1 (de) 2000-10-20 2008-09-15 Massachusetts Inst Technology Elektroden mit vernetzter oder poröser struktur
US7387851B2 (en) 2001-07-27 2008-06-17 A123 Systems, Inc. Self-organizing battery structure with electrode particles that exert a repelling force on the opposite electrode
US7662265B2 (en) 2000-10-20 2010-02-16 Massachusetts Institute Of Technology Electrophoretic assembly of electrochemical devices
US6645452B1 (en) * 2000-11-28 2003-11-11 Valence Technology, Inc. Methods of making lithium metal cathode active materials
CA2378278C (en) * 2001-03-26 2008-11-18 Kabushiki Kaisha Toshiba Positive electrode active material and nonaqueous electrolyte secondary battery
KR100814540B1 (ko) * 2001-04-06 2008-03-17 발렌스 테크놀로지, 인코포레이티드 나트륨 이온 배터리
DE10117904B4 (de) * 2001-04-10 2012-11-15 Zentrum für Sonnenenergie- und Wasserstoff-Forschung Baden-Württemberg Gemeinnützige Stiftung Binäre, ternäre und quaternäre Lithiumeisenphosphate, Verfahren zu ihrer Herstellung und ihre Verwendung
JP4236390B2 (ja) * 2001-04-19 2009-03-11 三洋電機株式会社 リチウム二次電池
EP1261050A1 (en) * 2001-05-23 2002-11-27 n.v. Umicore s.a. Lithium transition-metal phosphate powder for rechargeable batteries
KR101178643B1 (ko) 2001-07-27 2012-09-07 에이일이삼 시스템즈 인코포레이티드 배터리 구조, 자기 조직화 구조 및 관련 방법
EP2278643B1 (en) 2001-12-21 2018-03-28 Massachusetts Institute of Technology (MIT) Conductive lithium storage electrode
AU2002361689A1 (en) * 2002-01-04 2003-07-30 University Of Dayton Non-toxic corrosion protection pigments based on cobalt
US6815122B2 (en) 2002-03-06 2004-11-09 Valence Technology, Inc. Alkali transition metal phosphates and related electrode active materials
US7482097B2 (en) * 2002-04-03 2009-01-27 Valence Technology, Inc. Alkali-transition metal phosphates having a +3 valence non-transition element and related electrode active materials
US7422823B2 (en) * 2002-04-03 2008-09-09 Valence Technology, Inc. Alkali-iron-cobalt phosphates and related electrode active materials
US20030190527A1 (en) * 2002-04-03 2003-10-09 James Pugh Batteries comprising alkali-transition metal phosphates and preferred electrolytes
US6913855B2 (en) * 2002-07-22 2005-07-05 Valence Technology, Inc. Method of synthesizing electrochemically active materials from a slurry of precursors
US7087348B2 (en) 2002-07-26 2006-08-08 A123 Systems, Inc. Coated electrode particles for composite electrodes and electrochemical cells
KR100449073B1 (ko) * 2002-10-15 2004-09-18 한국전자통신연구원 리튬 이차 전지용 양극 활물질 및 그 제조 방법
CA2776362A1 (en) * 2002-12-19 2004-06-19 Valence Technology, Inc. Batteries with alkali metal phosphate electrodes
CN1754275A (zh) * 2002-12-23 2006-03-29 A123系统公司 高能量和高功率密度电化学电池
US20040011252A1 (en) * 2003-01-13 2004-01-22 Sturgill Jeffrey A. Non-toxic corrosion-protection pigments based on manganese
US7326494B2 (en) * 2003-01-30 2008-02-05 T/J Technologies, Inc. Composite material and electrodes made therefrom
US7041239B2 (en) * 2003-04-03 2006-05-09 Valence Technology, Inc. Electrodes comprising mixed active particles
US20070141468A1 (en) * 2003-04-03 2007-06-21 Jeremy Barker Electrodes Comprising Mixed Active Particles
US20040202935A1 (en) * 2003-04-08 2004-10-14 Jeremy Barker Cathode active material with increased alkali/metal content and method of making same
US7318982B2 (en) 2003-06-23 2008-01-15 A123 Systems, Inc. Polymer composition for encapsulation of electrode particles
US7986124B2 (en) 2003-09-22 2011-07-26 Valence Technology, Inc. Electrical systems, battery assemblies, and battery assembly operational methods
WO2005041327A1 (ja) * 2003-10-27 2005-05-06 Mitsui Engineering & Shipbuilding Co.,Ltd. 二次電池用正極材料、二次電池用正極材料の製造方法、および二次電池
CA2906604A1 (en) 2003-12-23 2005-07-07 Laurent Gauthier Process for preparing electroactive insertion compounds and electrode materials obtained therefrom
US7008726B2 (en) * 2004-01-22 2006-03-07 Valence Technology, Inc. Secondary battery electrode active materials and methods for making the same
US20050170256A1 (en) * 2004-01-30 2005-08-04 John Cummings Electrical power source apparatuses, electrical power source operational methods, and electrochemical device charging methods
US8617745B2 (en) 2004-02-06 2013-12-31 A123 Systems Llc Lithium secondary cell with high charge and discharge rate capability and low impedance growth
US7719227B2 (en) * 2004-02-13 2010-05-18 Valence Technology, Inc. Electrical energy supply methods and electrical energy power supplies
US7960057B2 (en) * 2004-05-17 2011-06-14 Toyota Motor Engineering & Manufacturing North America, Inc. Battery with molten salt electrolyte and phosphorus-containing cathode
WO2005113863A2 (en) * 2004-05-20 2005-12-01 Valence Technology, Inc. Secondary electrochemical cell
US7629080B1 (en) 2004-07-23 2009-12-08 The United States Of America As Represented By The Secretary Of The Army Electrode materials for electrochemical cells
US7842420B2 (en) 2005-02-03 2010-11-30 A123 Systems, Inc. Electrode material with enhanced ionic transport properties
US7205067B2 (en) * 2005-02-08 2007-04-17 Valence Technology, Inc. Method and apparatus for dissipation of heat generated by a secondary electrochemical cell
US20080138710A1 (en) * 2005-05-10 2008-06-12 Ben-Jie Liaw Electrochemical Composition and Associated Technology
US7887954B2 (en) * 2005-05-10 2011-02-15 Advanced Lithium Electrochemistry Co., Ltd. Electrochemical composition and associated technology
US20070009184A1 (en) * 2005-07-05 2007-01-11 Bhogal Kulvir S Associating attributes to captured input within a digital pen
US7609146B2 (en) * 2005-07-27 2009-10-27 Lear Corporation System and method for controlling a function using a variable sensitivity receiver
JP2009508302A (ja) 2005-09-09 2009-02-26 エイ １２３ システムズ，インク． 高い充放電率能力と小さいインピーダンス増加を有するリチウム二次電池
JP4862357B2 (ja) * 2005-10-28 2012-01-25 株式会社豊田中央研究所 負極活物質及び水系リチウム二次電池
JP5188677B2 (ja) * 2005-12-21 2013-04-24 三星エスディアイ株式会社 リチウム二次電池及びリチウム二次電池の製造方法
US9444120B2 (en) 2005-12-21 2016-09-13 Samsung Sdi Co., Ltd. Rechargeable lithium battery and method for manufacturing the same
US7914932B2 (en) 2006-02-24 2011-03-29 Ngk Insulators, Ltd. All-solid-state battery
KR20130106440A (ko) 2006-02-28 2013-09-27 프리메트 프리시젼 머테리알스, 인크. 리튬계 화합물 나노입자 조성물 및 이의 제조 방법
US7723958B2 (en) 2006-03-31 2010-05-25 Valence Technology, Inc. Battery charge indication methods, battery charge monitoring devices, rechargeable batteries, and articles of manufacture
US20090061314A1 (en) * 2007-08-30 2009-03-05 Ming Dong Method of Processing Active Materials For Use In Secondary Electrochemical Cells
EP2067198A2 (en) * 2006-09-25 2009-06-10 Board of Regents, The University of Texas System Cation-substituted spinel oxide and oxyfluoride cathodes for lithium ion batteries
EP2266160A4 (en) 2006-10-17 2010-12-29 Valence Technology Inc METHOD AND DEVICE FOR MONITORING AND CONTROLLING AN ELECTROCHEMICAL CELL
EP2093824A4 (en) * 2006-11-14 2014-08-06 Ngk Insulators Ltd FIXED ELECTROLYTE STRUCTURE FOR A THRESHOLD SOLID BODY BATTERY, THRESHOLD FIXED BODY BATTERY AND MANUFACTURING METHOD THEREFOR
JP4983356B2 (ja) * 2007-04-10 2012-07-25 株式会社豊田中央研究所 水系リチウム二次電池
JP2008260666A (ja) * 2007-04-13 2008-10-30 Kyushu Univ ナトリウム二次電池用活物質およびその製造方法
US20090202903A1 (en) 2007-05-25 2009-08-13 Massachusetts Institute Of Technology Batteries and electrodes for use thereof
US20080305256A1 (en) * 2007-06-08 2008-12-11 Conocophillips Company Method for producing lithium vanadium polyanion powders for batteries
US20080303004A1 (en) * 2007-06-08 2008-12-11 Conocophillips Company Method for producing lithium transition metal polyanion powders for batteries
US8168329B2 (en) * 2007-06-18 2012-05-01 Advanced Lithium Electrochemistry Co., Ltd. Electrochemical composition and associated technology
EP2015382A1 (en) * 2007-07-13 2009-01-14 High Power Lithium S.A. Carbon coated lithium manganese phosphate cathode material
JP5705541B2 (ja) * 2007-10-01 2015-04-22 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 結晶性リチウム−、バナジウム−、及びフォスフェイト−含有材料を製造するための方法
CN102123943B (zh) 2007-10-01 2013-07-10 巴斯夫欧洲公司 制备包含锂、钒和磷酸根的多孔材料的方法
JP5200613B2 (ja) * 2008-03-25 2013-06-05 株式会社Ｇｓユアサ 非水電解質電池
CN102378738A (zh) 2009-04-03 2012-03-14 旭硝子株式会社 磷酸铁锂颗粒的制造方法及二次电池的制造方法
US20100266474A1 (en) * 2009-04-16 2010-10-21 Titus Faulkner Method of Making Active Materials for Use in Secondary Electrochemical Cells
US8372540B2 (en) * 2009-04-16 2013-02-12 Valence Technology, Inc. Electrode active material for secondary electrochemical cell
WO2011027682A1 (ja) * 2009-09-03 2011-03-10 株式会社 村田製作所 二次電池用電極活物質の製造方法と二次電池用電極活物質の前駆体
JP5489063B2 (ja) 2009-11-02 2014-05-14 株式会社Ｇｓユアサ リチウム二次電池用正極活物質、リチウム二次電池用電極及びリチウム二次電池
KR101070174B1 (ko) 2010-01-21 2011-10-05 한화케미칼 주식회사 전극 활물질인 음이온 부족형 리튬 전이금속 인산화합물, 그 제조방법, 및 그를 이용한 전기화학 소자
WO2011102358A1 (ja) * 2010-02-17 2011-08-25 株式会社Ｇｓユアサ 非水電解質二次電池用正極活物質及び非水電解質二次電池
CN101924205B (zh) * 2010-06-03 2013-06-05 清华大学 锂电池电极材料的制备方法
CN101859891B (zh) * 2010-06-03 2012-08-29 清华大学 锂电池电极材料
US20110300446A1 (en) * 2010-06-03 2011-12-08 Hon Hai Precision Industry Co., Ltd. Lithium battery cathode composite material
JP5604216B2 (ja) * 2010-08-09 2014-10-08 日本化学工業株式会社 リン酸バナジウムリチウム炭素複合体の製造方法
JP5604217B2 (ja) * 2010-08-09 2014-10-08 日本化学工業株式会社 リン酸バナジウムリチウム炭素複合体の製造方法
US9437866B2 (en) 2010-09-27 2016-09-06 Nippon Chemical Industrial Co., Ltd. Process for producing lithium vanadium phosphate-carbon composite
US9160001B2 (en) 2010-12-23 2015-10-13 Wildcat Discovery Technologies, Inc. Lithium-ion battery materials with improved properties
US9065093B2 (en) 2011-04-07 2015-06-23 Massachusetts Institute Of Technology Controlled porosity in electrodes
JP5255138B2 (ja) 2011-05-18 2013-08-07 富士重工業株式会社 蓄電デバイス及び蓄電デバイス用正極
KR102650871B1 (ko) 2011-06-03 2024-03-26 가부시키가이샤 한도오따이 에네루기 켄큐쇼 전극을 제조하기 위한 방법
US9218916B2 (en) 2011-06-24 2015-12-22 Semiconductor Energy Laboratory Co., Ltd. Graphene, power storage device, and electric device
US9249524B2 (en) 2011-08-31 2016-02-02 Semiconductor Energy Laboratory Co., Ltd. Manufacturing method of composite oxide and manufacturing method of power storage device
JP2013084566A (ja) 2011-09-30 2013-05-09 Fuji Heavy Ind Ltd 非水電解質二次電池
KR102514830B1 (ko) 2011-09-30 2023-03-30 가부시키가이샤 한도오따이 에네루기 켄큐쇼 양극, 리튬 이차 전지, 전기 자동차, 하이브리드 자동차, 이동체, 시스템, 및 전기 기기
JP2013077424A (ja) 2011-09-30 2013-04-25 Fuji Heavy Ind Ltd リチウムイオン二次電池
JP5797993B2 (ja) * 2011-09-30 2015-10-21 富士重工業株式会社 非水電解質二次電池
JP5255143B2 (ja) 2011-09-30 2013-08-07 富士重工業株式会社 正極材料、これを用いたリチウムイオン二次電池、及び正極材料の製造方法
US9487880B2 (en) 2011-11-25 2016-11-08 Semiconductor Energy Laboratory Co., Ltd. Flexible substrate processing apparatus
JP6016597B2 (ja) 2011-12-16 2016-10-26 株式会社半導体エネルギー研究所 リチウムイオン二次電池用正極の製造方法
US20130157140A1 (en) * 2011-12-20 2013-06-20 General Electric Company Methods of making and using electrode compositions and articles
JP5719859B2 (ja) 2012-02-29 2015-05-20 株式会社半導体エネルギー研究所 蓄電装置
US9263736B2 (en) 2012-03-27 2016-02-16 Tdk Corporation Positive electrode material for lithium ion secondary battery, positive electrode for lithium ion secondary battery, and lithium ion secondary battery
TW201405920A (zh) 2012-05-29 2014-02-01 Clariant Canada Inc 製備晶形電極材料的方法及由之獲致的材料
US9225003B2 (en) 2012-06-15 2015-12-29 Semiconductor Energy Laboratory Co., Ltd. Method for manufacturing storage battery electrode, storage battery electrode, storage battery, and electronic device
JPWO2014006948A1 (ja) * 2012-07-04 2016-06-02 富士重工業株式会社 非水溶媒系蓄電デバイス
JP6159228B2 (ja) 2012-11-07 2017-07-05 株式会社半導体エネルギー研究所 非水系二次電池用正極の製造方法
US9673454B2 (en) 2013-02-18 2017-06-06 Semiconductor Energy Laboratory Co., Ltd. Sodium-ion secondary battery
US9490472B2 (en) 2013-03-28 2016-11-08 Semiconductor Energy Laboratory Co., Ltd. Method for manufacturing electrode for storage battery
DE112014002346B4 (de) 2013-05-10 2021-07-29 Semiconductor Energy Laboratory Co., Ltd. Speicherbatterie mit Lithiummanganoxid-Verbundstoff und deren Verwendung
ES2798309T3 (es) 2013-07-09 2020-12-10 Dow Global Technologies Llc Material activo positivo mixto que comprende óxido metálico de litio y fosfato metálico de litio
TWI661600B (zh) 2013-07-15 2019-06-01 日商半導體能源研究所股份有限公司 鋰錳複合氧化物、二次電池以及電器設備
KR101672575B1 (ko) * 2013-08-01 2016-11-03 주식회사 엘지화학 리튬 망간 인산화물을 포함하는 음극 활물질, 이의 제조 방법, 및 이를 포함하는 리튬 이차전지 또는 하이브리드 캐패시터
JP6194719B2 (ja) * 2013-09-25 2017-09-13 株式会社村田製作所 全固体電池
RU2556011C2 (ru) * 2013-09-27 2015-07-10 Общество с ограниченной ответственностью "Научный центр "Автономные источники тока" (ООО "Научный центр "АИТ") Катодный материал для литий-ионных аккумуляторов на основе модифицированных фосфатов
RU2542721C1 (ru) * 2013-09-27 2015-02-27 Общество с ограниченной ответственностью "Научный центр "Автономные источники тока" (ООО "Научный центр "АИТ") Композитный катодный материал литий-ионного аккумулятора на основе li3v2(po4)3со структурой насикон и способ его получения
KR20160065837A (ko) 2013-10-04 2016-06-09 가부시키가이샤 한도오따이 에네루기 켄큐쇼 리튬 망가니즈 복합 산화물, 이차 전지, 및 전자 기기, 및 층의 형성 방법
US9865867B2 (en) 2013-10-04 2018-01-09 Semiconductor Energy Laboratory Co., Ltd. Lithium manganese composite oxide, secondary battery, and electrical device
WO2015079372A1 (en) 2013-11-29 2015-06-04 Semiconductor Energy Laboratory Co., Ltd. Lithium-manganese composite oxide and secondary battery
CA2944454A1 (en) 2014-04-01 2015-10-08 The Research Foundation For The State University Of New York Electrode materials for group ii cation-based batteries
KR20240132127A (ko) 2014-05-09 2024-09-02 가부시키가이샤 한도오따이 에네루기 켄큐쇼 리튬 이온 이차 전지 및 전자 장치
JP6745587B2 (ja) 2014-05-29 2020-08-26 株式会社半導体エネルギー研究所 電極の製造方法
JP2016039027A (ja) 2014-08-07 2016-03-22 トヨタ自動車株式会社 リチウム二次電池用正極活物質、リチウム二次電池およびリチウム二次電池用正極活物質の製造方法
US10675819B2 (en) 2014-10-03 2020-06-09 Massachusetts Institute Of Technology Magnetic field alignment of emulsions to produce porous articles
WO2016054530A1 (en) 2014-10-03 2016-04-07 Massachusetts Institute Of Technology Pore orientation using magnetic fields
WO2016095177A1 (en) 2014-12-18 2016-06-23 Dow Global Technologies Llc Lithium ion battery having improved thermal stability
US10256470B2 (en) 2014-12-26 2019-04-09 Semiconductor Energy Laboratory Co., Ltd. Electrode, power storage device, electronic device, and manufacturing method of electrode
WO2017154690A1 (ja) 2016-03-08 2017-09-14 日本化学工業株式会社 リン酸バナジウムリチウムの製造方法
DE112017007748B3 (de) 2016-07-05 2022-07-28 Semiconductor Energy Laboratory Co., Ltd. Lithiumionen-Sekundärbatterie
US12308421B2 (en) 2016-09-12 2025-05-20 Semiconductor Energy Laboratory Co., Ltd. Electrode and power storage device comprising graphene compound
CN116387602A (zh) 2016-10-12 2023-07-04 株式会社半导体能源研究所 正极活性物质粒子以及正极活性物质粒子的制造方法
US11489151B2 (en) 2017-05-12 2022-11-01 Semiconductor Energy Laboratory Co., Ltd. Positive electrode active material particle
CN117038957A (zh) 2017-05-19 2023-11-10 株式会社半导体能源研究所 锂离子二次电池
CN118335885A (zh) 2017-06-26 2024-07-12 株式会社半导体能源研究所 正极活性物质的制造方法及二次电池
WO2019167783A1 (ja) * 2018-02-27 2019-09-06 Tdk株式会社 活物質及び全固体二次電池
CN113165908A (zh) 2018-12-17 2021-07-23 株式会社半导体能源研究所 正极活性物质及二次电池

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3736184A (en) * 1972-03-29 1973-05-29 Mallory & Co Inc P R Metal phosphate and metal arsenate organic electrolyte cells
US4009092A (en) * 1976-02-27 1977-02-22 E. I. Du Pont De Nemours And Company Substituted lithium phosphates and solid electrolytes therefrom
US4049891A (en) * 1976-06-21 1977-09-20 Massachusetts Institute Of Technology Compositions for fast alkali-metal-ion transport
FR2457018A1 (fr) * 1979-02-16 1980-12-12 Accumulateurs Fixes Matiere active positive pour generateur electrochimique a electrolyte non aqueux et methode de preparation de celle-ci
US4434216A (en) * 1980-10-24 1984-02-28 Rayovac Corporation Solid state electrolyte
US4512905A (en) * 1982-05-18 1985-04-23 The Texas A&M University System Method of making sodium zirconium silico-phosphates
US4707422A (en) * 1983-06-27 1987-11-17 Voltaix, Inc. Composite coating for electrochemical electrode and method
FR2563382B1 (fr) * 1984-04-24 1986-05-30 Elf Aquitaine Nouveau generateur electrochimique a electrode composite
FR2576712B1 (fr) * 1985-01-30 1988-07-08 Accumulateurs Fixes Generateur electrochimique a electrolyte non aqueux
JPS61263069A (ja) * 1985-05-17 1986-11-21 Matsushita Electric Ind Co Ltd 電池
US4985317A (en) * 1988-11-30 1991-01-15 Japan Synthetic Rubber Co., Ltd. Lithium ion-conductive solid electrolyte containing lithium titanium phosphate
US5262548A (en) * 1990-05-21 1993-11-16 Scientific Design Company, Inc. Phosphorous/vanadium oxidation catalyst
US5232794A (en) * 1991-10-17 1993-08-03 The United States Of America As Represented By The United States Department Of Energy Ionic conductors for solid oxide fuel cells
US5296436A (en) * 1993-01-08 1994-03-22 Scientific Design Company, Inc. Phosphorous/vanadium oxidation catalyst
JPH06251764A (ja) * 1993-02-22 1994-09-09 Fuji Elelctrochem Co Ltd リチウム二次電池
JP2966261B2 (ja) * 1993-11-02 1999-10-25 三菱電線工業株式会社 リチウム電池用正極材及びその製造方法
US5514490A (en) * 1994-08-30 1996-05-07 Industrial Technology Research Institute Secondary lithium battery using a new layered anode material
US5910382A (en) * 1996-04-23 1999-06-08 Board Of Regents, University Of Texas Systems Cathode materials for secondary (rechargeable) lithium batteries

Also Published As

Publication number Publication date
EP1403945B1 (en) 2006-03-01
DE69735317D1 (de) 2006-04-27
DE69735317T2 (de) 2006-11-09
WO1998012761A1 (en) 1998-03-26
DE69726893T2 (de) 2004-10-28
KR100458099B1 (ko) 2004-11-26
ES2169425T3 (es) 2002-07-01
JP2001500665A (ja) 2001-01-16
EP1403945A1 (en) 2004-03-31
DE69708904D1 (de) 2002-01-17
KR20000036230A (ko) 2000-06-26
HK1023850A1 (en) 2000-09-22
JP4292317B2 (ja) 2009-07-08
US5871866A (en) 1999-02-16
EP0931361B1 (en) 2001-12-05
DE69726893D1 (de) 2004-01-29
EP1093174A1 (en) 2001-04-18
CA2266365C (en) 2014-04-29
DE69708904T2 (de) 2002-08-14
CA2266365A1 (en) 1998-03-26
ES2258196T3 (es) 2006-08-16
EP1093174B1 (en) 2003-12-17
EP0931361A1 (en) 1999-07-28
AU4410297A (en) 1998-04-14

Similar Documents

Publication Publication Date Title
CA2266365C (en) Lithium-containing, lithium-intercalating phosphates and their use as the positive or negative electrode material in a lithium secondary battery
US6720110B2 (en) Lithium-containing phosphates, method of preparation, and uses thereof
US6447951B1 (en) Lithium based phosphates, method of preparation, and uses thereof
US6702961B2 (en) Preparation of lithium-containing materials
US7438992B2 (en) Lithium-based active materials and preparation thereof
US5670277A (en) Lithium copper oxide cathode for lithium cells and batteries
US5744265A (en) Lithium cell having mixed lithium--metal--chalcogenide cathode
HK1023850B (en) Lithium-containing, lithium-intercalating phosphates and their use as the positive or negative electrode material in a lithium secondary battery
HK1051174B (en) Preparation of lithium-containing materials

Legal Events

Date Code Title Description
EEER Examination request

Effective date: 20140211

EEER Examination request

Effective date: 20140211

FZDE Discontinued

Effective date: 20150930

FZDE Discontinued

Effective date: 20150930