DE69214499T2 - Herstellung von Olefinen - Google Patents
Herstellung von OlefinenInfo
- Publication number
- DE69214499T2 DE69214499T2 DE69214499T DE69214499T DE69214499T2 DE 69214499 T2 DE69214499 T2 DE 69214499T2 DE 69214499 T DE69214499 T DE 69214499T DE 69214499 T DE69214499 T DE 69214499T DE 69214499 T2 DE69214499 T2 DE 69214499T2
- Authority
- DE
- Germany
- Prior art keywords
- catalyst
- phosphorus
- zsm
- olefins
- steam
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 150000001336 alkenes Chemical class 0.000 title claims description 22
- 238000004519 manufacturing process Methods 0.000 title description 6
- 239000003054 catalyst Substances 0.000 claims description 68
- 229910052698 phosphorus Inorganic materials 0.000 claims description 42
- 239000011574 phosphorus Substances 0.000 claims description 42
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 41
- 238000000034 method Methods 0.000 claims description 26
- 229930195733 hydrocarbon Natural products 0.000 claims description 23
- 150000002430 hydrocarbons Chemical class 0.000 claims description 21
- 230000008569 process Effects 0.000 claims description 18
- 239000010457 zeolite Substances 0.000 claims description 16
- 229910021536 Zeolite Inorganic materials 0.000 claims description 14
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 10
- 238000010348 incorporation Methods 0.000 claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 19
- 238000006243 chemical reaction Methods 0.000 description 18
- 238000005336 cracking Methods 0.000 description 15
- 239000004215 Carbon black (E152) Substances 0.000 description 14
- 230000004913 activation Effects 0.000 description 11
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 10
- 230000000694 effects Effects 0.000 description 10
- IAQRGUVFOMOMEM-ONEGZZNKSA-N trans-but-2-ene Chemical compound C\C=C\C IAQRGUVFOMOMEM-ONEGZZNKSA-N 0.000 description 10
- 239000005995 Aluminium silicate Substances 0.000 description 9
- 235000012211 aluminium silicate Nutrition 0.000 description 9
- 229910000281 calcium bentonite Inorganic materials 0.000 description 9
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 9
- 239000000377 silicon dioxide Substances 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- 230000008929 regeneration Effects 0.000 description 6
- 238000011069 regeneration method Methods 0.000 description 6
- 230000003197 catalytic effect Effects 0.000 description 5
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 5
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 5
- 239000002002 slurry Substances 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- -1 ethylene, propylene Chemical group 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 3
- 239000003245 coal Substances 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 238000004051 1H MAS NMR Methods 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical group [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 238000004833 X-ray photoelectron spectroscopy Methods 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical group 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000004523 catalytic cracking Methods 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000006356 dehydrogenation reaction Methods 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 238000010335 hydrothermal treatment Methods 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 125000004817 pentamethylene group Chemical class [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 238000010926 purge Methods 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000004230 steam cracking Methods 0.000 description 2
- 239000007848 Bronsted acid Substances 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 230000029936 alkylation Effects 0.000 description 1
- 238000005804 alkylation reaction Methods 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 150000002500 ions Chemical group 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
- C07C4/02—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction
- C07C4/06—Catalytic processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/36—Steaming
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/20—C2-C4 olefins
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/692,333 US5171921A (en) | 1991-04-26 | 1991-04-26 | Production of olefins |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69214499D1 DE69214499D1 (de) | 1996-11-21 |
| DE69214499T2 true DE69214499T2 (de) | 1997-02-20 |
Family
ID=24780147
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69214499T Expired - Fee Related DE69214499T2 (de) | 1991-04-26 | 1992-04-24 | Herstellung von Olefinen |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US5171921A (cg-RX-API-DMAC7.html) |
| EP (1) | EP0511013B1 (cg-RX-API-DMAC7.html) |
| JP (1) | JP3057398B2 (cg-RX-API-DMAC7.html) |
| KR (1) | KR100237508B1 (cg-RX-API-DMAC7.html) |
| DE (1) | DE69214499T2 (cg-RX-API-DMAC7.html) |
| ES (1) | ES2092635T3 (cg-RX-API-DMAC7.html) |
| TW (1) | TW239119B (cg-RX-API-DMAC7.html) |
Families Citing this family (125)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5595709A (en) * | 1992-09-01 | 1997-01-21 | Chromatofast | Instrument for measuring non-methane organic gases in gas samples |
| HUT67948A (en) * | 1992-12-18 | 1995-05-29 | Amoco Corp | Thermal cracking process with reduced coking |
| CN1034223C (zh) * | 1993-03-29 | 1997-03-12 | 中国石油化工总公司 | 制取低碳烯烃的裂解催化剂 |
| CN1034586C (zh) * | 1993-11-05 | 1997-04-16 | 中国石油化工总公司 | 多产低碳烯烃的催化转化方法 |
| US6048816A (en) * | 1996-10-02 | 2000-04-11 | Mobil Oil Corporation | Catalyst and process for converting methanol to hydrocarbons |
| CN1059133C (zh) * | 1997-03-24 | 2000-12-06 | 中国石油化工总公司 | 具有mfi结构的含磷分子筛 |
| AU7956398A (en) * | 1997-06-10 | 1998-12-30 | Exxon Chemical Patents Inc. | Multi-reactor system for enhanced light olefin make |
| EP0921175A1 (en) * | 1997-12-05 | 1999-06-09 | Fina Research S.A. | Production of olefins |
| EP0921176A1 (en) * | 1997-12-05 | 1999-06-09 | Fina Research S.A. | Production of olefins |
| EP0920911A1 (en) | 1997-12-05 | 1999-06-09 | Fina Research S.A. | Production of catalysts for olefin conversion |
| US6080303A (en) * | 1998-03-11 | 2000-06-27 | Exxon Chemical Patents, Inc. | Zeolite catalyst activity enhancement by aluminum phosphate and phosphorus |
| US6313366B1 (en) | 1998-05-05 | 2001-11-06 | Exxonmobile Chemical Patents, Inc. | Process for selectively producing C3 olefins in a fluid catalytic cracking process |
| US6455750B1 (en) * | 1998-05-05 | 2002-09-24 | Exxonmobil Chemical Patents Inc. | Process for selectively producing light olefins |
| US6315890B1 (en) | 1998-05-05 | 2001-11-13 | Exxonmobil Chemical Patents Inc. | Naphtha cracking and hydroprocessing process for low emissions, high octane fuels |
| US6069287A (en) * | 1998-05-05 | 2000-05-30 | Exxon Research And Engineering Co. | Process for selectively producing light olefins in a fluid catalytic cracking process |
| US6118035A (en) | 1998-05-05 | 2000-09-12 | Exxon Research And Engineering Co. | Process for selectively producing light olefins in a fluid catalytic cracking process from a naphtha/steam feed |
| US6803494B1 (en) | 1998-05-05 | 2004-10-12 | Exxonmobil Chemical Patents Inc. | Process for selectively producing propylene in a fluid catalytic cracking process |
| US6339180B1 (en) | 1998-05-05 | 2002-01-15 | Exxonmobil Chemical Patents, Inc. | Process for producing polypropylene from C3 olefins selectively produced in a fluid catalytic cracking process |
| US6093867A (en) * | 1998-05-05 | 2000-07-25 | Exxon Research And Engineering Company | Process for selectively producing C3 olefins in a fluid catalytic cracking process |
| US6388152B1 (en) | 1998-05-05 | 2002-05-14 | Exxonmobil Chemical Patents Inc. | Process for producing polypropylene from C3 olefins selectively produced in a fluid catalytic cracking process |
| US6106697A (en) * | 1998-05-05 | 2000-08-22 | Exxon Research And Engineering Company | Two stage fluid catalytic cracking process for selectively producing b. C.su2 to C4 olefins |
| US6602403B1 (en) | 1998-05-05 | 2003-08-05 | Exxonmobil Chemical Patents Inc. | Process for selectively producing high octane naphtha |
| US6238550B1 (en) | 1998-05-26 | 2001-05-29 | Exxon Research And Engineering Company | Silicoaluminophosphates having AEL structure, a method for their preparation and their use as catalysts for the hydroprocessing of hydrocarbon feedstocks |
| US6395949B1 (en) | 1998-08-03 | 2002-05-28 | Phillips Petroleum Company | Acid treated zeolite containing phosphorus used as a catalyst in processes for converting hydrocarbons, and use of binary hydrocarbon mixtures as diluents in processes for converting hydrocarbons |
| US6307117B1 (en) | 1998-08-25 | 2001-10-23 | Asahi Kasei Kogyo Kabushiki Kaisha | Method for producing ethylene and propylene |
| FR2794116B1 (fr) * | 1999-05-11 | 2001-07-20 | Inst Francais Du Petrole | Zeolithe im-5 au phosphore, composition catalytique, sa preparation et son utilisation en craquage catalytique |
| US6222087B1 (en) * | 1999-07-12 | 2001-04-24 | Mobil Oil Corporation | Catalytic production of light olefins rich in propylene |
| US6835863B2 (en) | 1999-07-12 | 2004-12-28 | Exxonmobil Oil Corporation | Catalytic production of light olefins from naphtha feed |
| US6613951B1 (en) | 1999-09-23 | 2003-09-02 | Mobil Oil Corporation | Process for converting methanol to olefins |
| US6339181B1 (en) | 1999-11-09 | 2002-01-15 | Exxonmobil Chemical Patents, Inc. | Multiple feed process for the production of propylene |
| EP1116775A1 (en) | 2000-01-12 | 2001-07-18 | Akzo Nobel N.V. | Catalyst composition with high efficiency for the production of light olefins |
| US20030187315A1 (en) * | 2002-03-26 | 2003-10-02 | Voskoboynikov Timur V. | Spherical catalysts to convert hydrocarbons to light olefins |
| US7314963B2 (en) * | 2002-03-26 | 2008-01-01 | Uop Llc | Spherical catalysts to convert hydrocarbons to light olefins |
| DE10233069C1 (de) * | 2002-07-19 | 2003-09-18 | Lurgi Ag | Verfahren zur Herstellung von Propylen aus einem C¶4¶ bis C¶8¶ Olefine enthaltenden Einsatzstrom |
| US7011740B2 (en) | 2002-10-10 | 2006-03-14 | Kellogg Brown & Root, Inc. | Catalyst recovery from light olefin FCC effluent |
| US7153479B2 (en) * | 2002-10-10 | 2006-12-26 | Kellogg Brown & Root Llc | Catalyst regenerator with a centerwell |
| US7084318B2 (en) | 2003-08-01 | 2006-08-01 | Saudi Basic Industries Corporation | Toluene methylation process |
| US7060864B2 (en) | 2003-09-30 | 2006-06-13 | Saudi Basic Industries Corporation | Toluene methylation process |
| CN1257769C (zh) * | 2003-10-31 | 2006-05-31 | 中国石油化工股份有限公司 | 一种含磷和金属组分的mfi结构分子筛及其应用 |
| US7060644B2 (en) | 2004-01-08 | 2006-06-13 | Saudi Basic Industries Corporation | Aromatic alkylation catalyst and method |
| US6943131B1 (en) * | 2004-03-02 | 2005-09-13 | Saudi Basic Industries Corporation | Selective zeolite catalyst modification |
| US7399727B2 (en) | 2004-04-23 | 2008-07-15 | Saudi Basic Industries Corporation | Zeolite catalyst and method |
| US7285511B2 (en) | 2004-04-23 | 2007-10-23 | Saudi Basic Industries Corporation | Method of modifying zeolite catalyst |
| WO2005123251A1 (en) | 2004-06-09 | 2005-12-29 | Saudi Basic Industries Corporation | Fluoride-modified zeolite catalyst and method |
| US7462275B2 (en) * | 2004-07-20 | 2008-12-09 | Indian Oil Corporation Limited | Process for conversion of hydrocarbons to saturated LPG and high octane gasoline |
| KR100632563B1 (ko) * | 2004-09-10 | 2006-10-09 | 에스케이 주식회사 | 접촉 분해용 고체산 촉매 및 이를 이용하여 전범위납사로부터 경질 올레핀을 선택적으로 제조하는 공정 |
| KR101229756B1 (ko) | 2004-12-28 | 2013-02-06 | 차이나 페트로리움 앤드 케미컬 코포레이션 | 탄화수소 분해 촉매 및 탄화수소 분해 방법 |
| US7304194B2 (en) | 2005-05-05 | 2007-12-04 | Saudi Basic Industries Corporation | Hydrothermal treatment of phosphorus-modified zeolite catalysts |
| US7368410B2 (en) | 2005-08-03 | 2008-05-06 | Saudi Basic Industries Corporation | Zeolite catalyst and method of preparing and use of zeolite catalyst |
| EP1935865B1 (en) | 2005-09-16 | 2016-11-16 | Asahi Kasei Kabushiki Kaisha | Process for production of ethylene and propylene |
| EP2025402A1 (en) * | 2007-07-31 | 2009-02-18 | Total Petrochemicals Research Feluy | Phosphorus modified molecular sieves, their use in conversion of organics to olefins |
| EP2036873A1 (en) * | 2007-09-12 | 2009-03-18 | Total Petrochemicals Research Feluy | Use of phosphorus modified molecular sieves in conversion of organics to olefins |
| EP2173689B8 (en) * | 2007-07-31 | 2023-10-18 | TotalEnergies OneTech Belgium | Use of phosphorus modified molecular sieves in conversion of organics to olefins |
| EP2039427A1 (en) * | 2007-09-12 | 2009-03-25 | Total Petrochemicals Research Feluy | Cracking of olefins on phosphorus modified molecular sieves |
| WO2009016156A1 (en) * | 2007-07-31 | 2009-02-05 | Total Petrochemicals Research Feluy | Cracking of olefins on phosphorus modified molecular sieves. |
| EP2082801A1 (en) * | 2008-01-25 | 2009-07-29 | Total Petrochemicals Research Feluy | Process for obtaining modified molecular sieves |
| EP2082802A1 (en) * | 2008-01-25 | 2009-07-29 | Total Petrochemicals Research Feluy | Process for obtaining a catalyst composite |
| CN101939276B (zh) * | 2008-02-07 | 2013-05-08 | 道达尔石油化学产品研究弗吕公司 | 由乙醇制造烯烃的方法 |
| EP2238096A1 (en) * | 2008-02-07 | 2010-10-13 | Total Petrochemicals Research Feluy | Process to make olefins from ethanol |
| AU2009211364B2 (en) * | 2008-02-07 | 2012-01-19 | Total Petrochemicals Research Feluy | Dehydration of alcohols on crystalline silicates |
| EA019977B1 (ru) * | 2008-06-25 | 2014-07-30 | Тотал Петрокемикалз Ресерч Фелюи | Способ получения олефинов из органических веществ |
| EA021226B1 (ru) * | 2008-06-25 | 2015-05-29 | Тотал Ресерч Энд Текнолоджи Фелюи | Способ получения олефинов из оксигенатов |
| EP2303806B1 (en) * | 2008-06-25 | 2019-08-07 | Total Research & Technology Feluy | Process to make olefins from oxygenates |
| US8957271B2 (en) * | 2008-06-25 | 2015-02-17 | Total Research & Technology Feluy | Process to make olefins from oxygenates |
| JP2010042343A (ja) * | 2008-08-12 | 2010-02-25 | National Institute Of Advanced Industrial & Technology | 低級オレフィン製造用触媒、その製造方法及びこれを用いた低級オレフィンの製造方法 |
| US8846559B2 (en) | 2008-11-03 | 2014-09-30 | Saudi Basic Industries Corporation | Stable shape-selective catalyst for aromatic alkylation and methods of using and preparing |
| EP2364343B1 (en) | 2008-12-10 | 2017-09-06 | Reliance Industries Limited | A fluid catalytic cracking (fcc) process for manufacturing propylene and ethylene in increased yield |
| RU2548362C2 (ru) * | 2009-06-25 | 2015-04-20 | Чайна Петролеум & Кемикал Корпорейшн | Катализатор каталитического крекинга и способ повышения селективности катализатора(варианты) |
| US8062987B2 (en) | 2009-10-05 | 2011-11-22 | Saudi Basic Industries Corporation | Phosphorus-containing zeolite catalysts and their method of preparation |
| CN102050458B (zh) | 2009-10-30 | 2012-08-08 | 中国石油天然气股份有限公司 | 一种提高抗钠污染能力的改性分子筛及制备方法 |
| CN102050462B (zh) | 2009-10-30 | 2012-10-17 | 中国石油天然气股份有限公司 | 一种提高水热稳定性的双组元改性分子筛及制备方法 |
| EP2348004A1 (en) | 2010-01-25 | 2011-07-27 | Total Petrochemicals Research Feluy | Method for making a catalyst comprising a phosphorus modified zeolite to be used in a MTO or a dehydration process |
| CN102166533B (zh) * | 2010-02-25 | 2013-07-31 | 中国石油天然气股份有限公司 | 一种提高了活性与水热稳定性的复合改性分子筛及制备方法 |
| US8383052B2 (en) | 2010-04-16 | 2013-02-26 | Kellogg Brown & Root Llc | System for a heat balanced FCC forlight hydrocarbon feeds |
| US9056807B2 (en) * | 2010-08-03 | 2015-06-16 | Total Research & Technology Feluy | Process to make olefins from isobutanol |
| ES2493141T3 (es) * | 2010-08-03 | 2014-09-11 | Total Research & Technology Feluy | Procedimiento de preparación olefinas a partir de isobutanol |
| WO2012016788A1 (en) * | 2010-08-03 | 2012-02-09 | Total Petrochemicals Research Feluy | Process to make olefins from methanol and isobutanol |
| CO6460077A1 (es) * | 2010-12-06 | 2012-06-15 | Ecopetrol Sa | Proceso para modificacion de zeolita por incorporacion de fosforo en la estructura cristalina y catalizadores para oligomerizacion de olefinas |
| RU2013150347A (ru) | 2011-04-13 | 2015-05-20 | Кайор, Инк. | Усовершенствованный катализатор для термокаталитической конверсии биомассы в жидкие топлива и химические продукты |
| EP2739391B1 (en) | 2011-08-03 | 2021-02-17 | Total Research & Technology Feluy | Catalyst comprising a phosphorus modified zeolite and having partly an alpo structure |
| US10464053B2 (en) | 2011-08-03 | 2019-11-05 | Total Research & Technology Feluy | Method for making a catalyst comprising a phosphorous modified zeolite and use of said zeolite |
| WO2013017496A1 (en) | 2011-08-03 | 2013-02-07 | Total Research & Technology Feluy | Use of a catalyst comprising a phosphorus modified zeolite in an alcohol dehydration process |
| US20130281753A1 (en) | 2011-10-17 | 2013-10-24 | Stephen J. McCarthy | Phosphorus modified zeolite catalysts |
| KR101821451B1 (ko) | 2012-02-14 | 2018-01-23 | 릴라이언스 인더스트리즈 리미티드 | 저가 탄화수소 흐름을 경질 올레핀으로 촉매 전환하는 공정 |
| US9278342B2 (en) | 2012-07-02 | 2016-03-08 | Saudi Basic Industries Corporation | Method of modifying a phosphorus-containing zeolite catalyst |
| US9518229B2 (en) | 2012-07-20 | 2016-12-13 | Inaeris Technologies, Llc | Catalysts for thermo-catalytic conversion of biomass, and methods of making and using |
| US9745519B2 (en) | 2012-08-22 | 2017-08-29 | Kellogg Brown & Root Llc | FCC process using a modified catalyst |
| PT2948244T (pt) | 2013-01-23 | 2020-05-19 | Basf Corp | Melhoria da atividade aditiva do zsm-5 pela interação melhorada de zeólito e fósforo |
| US9522392B2 (en) | 2013-03-15 | 2016-12-20 | Inaeris Technologies, Llc | Phosphorous promotion of zeolite-containing catalysts |
| EP2975013A1 (en) | 2013-04-03 | 2016-01-20 | Scg Chemicals Co. Ltd. | Catalyst for converting paraffin to olefin |
| CN104108724B (zh) * | 2013-04-16 | 2016-05-25 | 中国科学院兰州化学物理研究所 | 低成本原料合成小晶粒p-zsm-5分子筛的方法 |
| RU2667146C2 (ru) * | 2013-04-24 | 2018-09-17 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Активация паром самоактивирующегося катализатора процесса гидрообработки |
| CN108431180B (zh) | 2015-12-21 | 2021-09-03 | 沙特基础工业全球技术公司 | 由焦化石脑油生产烯烃和芳烃的方法和系统 |
| US9981888B2 (en) | 2016-06-23 | 2018-05-29 | Saudi Arabian Oil Company | Processes for high severity fluid catalytic cracking systems |
| CA3028438C (en) | 2016-06-24 | 2023-12-05 | Albemarle Corporation | Mesoporous zsm-22 for increased propylene production |
| WO2018117820A1 (en) | 2016-12-21 | 2018-06-28 | Inovacat B.V. | Process to prepare propylene |
| CN110300623B (zh) | 2017-03-17 | 2023-08-11 | 雅宝公司 | 具有混合氧化铝的fcc催化剂添加剂 |
| JP6952106B2 (ja) * | 2017-03-24 | 2021-10-20 | 日揮グローバル株式会社 | ゼオライト含有触媒および低級オレフィンの製造方法 |
| KR102052437B1 (ko) * | 2017-05-12 | 2019-12-05 | 한국화학연구원 | 프로필렌으로부터 선택적 에틸렌의 제조방법 |
| US10870802B2 (en) | 2017-05-31 | 2020-12-22 | Saudi Arabian Oil Company | High-severity fluidized catalytic cracking systems and processes having partial catalyst recycle |
| KR102163124B1 (ko) | 2017-10-20 | 2020-10-07 | 라이온델 케미칼 테크놀로지, 엘.피. | 에틸렌 및 프로필렌의 제조 방법 |
| KR102162781B1 (ko) | 2017-10-26 | 2020-10-07 | 라이온델 케미칼 테크놀로지, 엘.피. | 프로필렌 및 에틸렌의 제조 방법 |
| KR102049352B1 (ko) * | 2017-11-01 | 2019-11-28 | 한국화학연구원 | 산 처리된 zsm-5를 통한 프로필렌으로부터 선택적 에틸렌의 제조방법 |
| US10889768B2 (en) | 2018-01-25 | 2021-01-12 | Saudi Arabian Oil Company | High severity fluidized catalytic cracking systems and processes for producing olefins from petroleum feeds |
| KR102234656B1 (ko) * | 2018-05-16 | 2021-04-01 | 한국화학연구원 | 프로판으로부터 선택적 에틸렌의 제조방법 |
| RU2688662C1 (ru) * | 2018-07-24 | 2019-05-22 | Федеральное государственное бюджетное учреждение науки "Федеральный исследовательский центр "Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук" (Институт катализа СО РАН, ИК СО РАН) | Способ каталитического крекинга бутан-бутиленовой фракции и катализатор для его осуществления |
| RU2709521C1 (ru) * | 2019-09-16 | 2019-12-18 | Акционерное общество "Газпромнефть - Омский НПЗ" (АО "Газпромнефть-ОНПЗ") | Катализатор крекинга нефтяных фракций |
| RU2710856C1 (ru) * | 2019-09-16 | 2020-01-14 | Акционерное общество "Газпромнефть - Омский НПЗ" (АО "Газпромнефть-ОНПЗ") | Способ совместного крекинга нефтяных фракций |
| RU2710855C1 (ru) * | 2019-09-16 | 2020-01-14 | Акционерное общество "Газпромнефть - Омский НПЗ" (АО "Газпромнефть-ОНПЗ") | Способ крекинга нефтяных фракций |
| KR20230002699A (ko) | 2020-04-13 | 2023-01-05 | 차이나 페트로리움 앤드 케미컬 코포레이션 | 인-함유/인-개질 zsm-5 분자체, 열분해 첨가제 및 이를 포함하는 열분해 촉매, 이의 제조 방법 및 이의 응용 |
| US12296323B2 (en) | 2020-04-13 | 2025-05-13 | China Petroleum & Chemical Corporation | Phosphorus-modified MFI-structured molecular sieve, catalytic cracking auxiliary and catalytic cracking catalyst containing phosphorus-modified MFI-structured molecular sieve, and processes for preparing the same |
| CN114425431B (zh) * | 2020-10-29 | 2023-07-14 | 中国石油化工股份有限公司 | 一种含磷改性mfi结构分子筛的催化裂解催化剂 |
| US11230673B1 (en) | 2020-09-01 | 2022-01-25 | Saudi Arabian Oil Company | Processes for producing petrochemical products that utilize fluid catalytic cracking of a lesser boiling point fraction with steam |
| US11230672B1 (en) | 2020-09-01 | 2022-01-25 | Saudi Arabian Oil Company | Processes for producing petrochemical products that utilize fluid catalytic cracking |
| US11352575B2 (en) | 2020-09-01 | 2022-06-07 | Saudi Arabian Oil Company | Processes for producing petrochemical products that utilize hydrotreating of cycle oil |
| US11434432B2 (en) | 2020-09-01 | 2022-09-06 | Saudi Arabian Oil Company | Processes for producing petrochemical products that utilize fluid catalytic cracking of a greater boiling point fraction with steam |
| US11505754B2 (en) | 2020-09-01 | 2022-11-22 | Saudi Arabian Oil Company | Processes for producing petrochemical products from atmospheric residues |
| US11242493B1 (en) | 2020-09-01 | 2022-02-08 | Saudi Arabian Oil Company | Methods for processing crude oils to form light olefins |
| US11332680B2 (en) | 2020-09-01 | 2022-05-17 | Saudi Arabian Oil Company | Processes for producing petrochemical products that utilize fluid catalytic cracking of lesser and greater boiling point fractions with steam |
| CN114762836B (zh) * | 2021-01-11 | 2023-09-05 | 中国石油化工股份有限公司 | 一种含磷改性mfi结构分子筛的催化裂解催化剂的制备方法和制备系统 |
| EP4275789A4 (en) * | 2021-01-11 | 2024-12-18 | China Petroleum & Chemical Corporation | CATALYTIC CRACKING AGENT CONTAINING PHOSPHORUS-MODIFIED MOLECULAR SIEVE, ITS PREPARATION METHOD, ITS PREPARATION SYSTEM AND ITS USE |
| CN114762831B (zh) * | 2021-01-11 | 2023-11-10 | 中国石油化工股份有限公司 | 一种催化裂解助剂的制备方法和制备系统 |
| FR3144023A1 (fr) | 2022-12-22 | 2024-06-28 | IFP Energies Nouvelles | Catalyseur a base d’une zeolithe et d’une structure alpo et presentant un volume macroporeux eleve |
| WO2024168329A1 (en) | 2023-02-10 | 2024-08-15 | Exelus Inc. | Multifunctional catalyst for naphtha cracking |
| JP7767559B1 (ja) * | 2024-10-29 | 2025-11-11 | 住友化学株式会社 | オレフィンの製造方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4044065A (en) * | 1974-09-23 | 1977-08-23 | Mobile Oil Corporation | Conversion utilizing a phosphorus-containing zeolite catalyst |
| US3972832A (en) * | 1974-09-23 | 1976-08-03 | Mobil Oil Corporation | Phosphorus-containing zeolite catalyst |
| US4282085A (en) * | 1978-10-23 | 1981-08-04 | Chevron Research Company | Petroleum distillate upgrading process |
| US4356338A (en) * | 1979-07-27 | 1982-10-26 | Mobil Oil Corporation | Extending catalyst life by treating with phosphorus and/or steam |
| US4423266A (en) * | 1980-10-08 | 1983-12-27 | Mobil Oil Corporation | Extending isomerization catalyst life by treating with phosphorous and/or steam |
| DE3372474D1 (en) * | 1982-11-10 | 1987-08-20 | Montedipe Spa | Process for converting olefins having 4 to 12 carbon atoms into propylene |
| JPS60222428A (ja) * | 1984-04-19 | 1985-11-07 | Res Assoc Util Of Light Oil | 炭化水素の接触転化法 |
| US5043522A (en) * | 1989-04-25 | 1991-08-27 | Arco Chemical Technology, Inc. | Production of olefins from a mixture of Cu+ olefins and paraffins |
-
1991
- 1991-04-26 US US07/692,333 patent/US5171921A/en not_active Expired - Lifetime
-
1992
- 1992-04-23 JP JP4129392A patent/JP3057398B2/ja not_active Expired - Fee Related
- 1992-04-24 DE DE69214499T patent/DE69214499T2/de not_active Expired - Fee Related
- 1992-04-24 ES ES92303737T patent/ES2092635T3/es not_active Expired - Lifetime
- 1992-04-24 EP EP92303737A patent/EP0511013B1/en not_active Expired - Lifetime
- 1992-04-27 KR KR1019920007110A patent/KR100237508B1/ko not_active Expired - Fee Related
- 1992-05-05 TW TW081103524A patent/TW239119B/zh active
Also Published As
| Publication number | Publication date |
|---|---|
| KR920019712A (ko) | 1992-11-19 |
| JPH0673382A (ja) | 1994-03-15 |
| EP0511013A2 (en) | 1992-10-28 |
| EP0511013B1 (en) | 1996-10-16 |
| EP0511013A3 (en) | 1994-08-24 |
| TW239119B (cg-RX-API-DMAC7.html) | 1995-01-21 |
| JP3057398B2 (ja) | 2000-06-26 |
| DE69214499D1 (de) | 1996-11-21 |
| KR100237508B1 (ko) | 2000-01-15 |
| ES2092635T3 (es) | 1996-12-01 |
| US5171921A (en) | 1992-12-15 |
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