JP3057398B2 - 炭化水素を転換する方法 - Google Patents
炭化水素を転換する方法Info
- Publication number
- JP3057398B2 JP3057398B2 JP4129392A JP12939292A JP3057398B2 JP 3057398 B2 JP3057398 B2 JP 3057398B2 JP 4129392 A JP4129392 A JP 4129392A JP 12939292 A JP12939292 A JP 12939292A JP 3057398 B2 JP3057398 B2 JP 3057398B2
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- phosphorus
- zsm
- steam
- conversion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229930195733 hydrocarbon Natural products 0.000 title claims description 26
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 26
- 239000003054 catalyst Substances 0.000 claims description 91
- 229910052698 phosphorus Inorganic materials 0.000 claims description 39
- 239000011574 phosphorus Substances 0.000 claims description 39
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 38
- 238000000034 method Methods 0.000 claims description 21
- 239000004215 Carbon black (E152) Substances 0.000 claims description 20
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 description 28
- IAQRGUVFOMOMEM-UHFFFAOYSA-N but-2-ene Chemical compound CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 26
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 19
- 150000001336 alkenes Chemical class 0.000 description 18
- 238000001994 activation Methods 0.000 description 14
- 230000004913 activation Effects 0.000 description 14
- 238000005336 cracking Methods 0.000 description 14
- 230000000694 effects Effects 0.000 description 14
- 229910021536 Zeolite Inorganic materials 0.000 description 13
- XNMQEEKYCVKGBD-UHFFFAOYSA-N dimethylacetylene Natural products CC#CC XNMQEEKYCVKGBD-UHFFFAOYSA-N 0.000 description 13
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 13
- 239000010457 zeolite Substances 0.000 description 13
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 12
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 12
- 239000000377 silicon dioxide Substances 0.000 description 10
- 239000005995 Aluminium silicate Substances 0.000 description 9
- 235000012211 aluminium silicate Nutrition 0.000 description 9
- 229910000281 calcium bentonite Inorganic materials 0.000 description 9
- 239000000571 coke Substances 0.000 description 9
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- -1 ethylene, propylene, butene Chemical class 0.000 description 6
- 239000001282 iso-butane Substances 0.000 description 6
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 6
- 230000008929 regeneration Effects 0.000 description 6
- 238000011069 regeneration method Methods 0.000 description 6
- 230000003197 catalytic effect Effects 0.000 description 5
- 238000010335 hydrothermal treatment Methods 0.000 description 5
- 239000002002 slurry Substances 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 4
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000001294 propane Substances 0.000 description 3
- 238000010025 steaming Methods 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical group [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- 238000005004 MAS NMR spectroscopy Methods 0.000 description 2
- 238000004833 X-ray photoelectron spectroscopy Methods 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical group 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 238000004523 catalytic cracking Methods 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000006356 dehydrogenation reaction Methods 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
- 238000010926 purge Methods 0.000 description 2
- 102200118166 rs16951438 Human genes 0.000 description 2
- 238000005070 sampling Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000004230 steam cracking Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical class O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 230000029936 alkylation Effects 0.000 description 1
- 238000005804 alkylation reaction Methods 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 229940013191 edex Drugs 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 150000002500 ions Chemical group 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- GMVPRGQOIOIIMI-DWKJAMRDSA-N prostaglandin E1 Chemical compound CCCCC[C@H](O)\C=C\[C@H]1[C@H](O)CC(=O)[C@@H]1CCCCCCC(O)=O GMVPRGQOIOIIMI-DWKJAMRDSA-N 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- 238000007725 thermal activation Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
- C07C4/02—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction
- C07C4/06—Catalytic processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/36—Steaming
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/20—C2-C4 olefins
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/692,333 US5171921A (en) | 1991-04-26 | 1991-04-26 | Production of olefins |
| US07/692333 | 1991-04-26 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0673382A JPH0673382A (ja) | 1994-03-15 |
| JP3057398B2 true JP3057398B2 (ja) | 2000-06-26 |
Family
ID=24780147
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4129392A Expired - Fee Related JP3057398B2 (ja) | 1991-04-26 | 1992-04-23 | 炭化水素を転換する方法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US5171921A (cg-RX-API-DMAC7.html) |
| EP (1) | EP0511013B1 (cg-RX-API-DMAC7.html) |
| JP (1) | JP3057398B2 (cg-RX-API-DMAC7.html) |
| KR (1) | KR100237508B1 (cg-RX-API-DMAC7.html) |
| DE (1) | DE69214499T2 (cg-RX-API-DMAC7.html) |
| ES (1) | ES2092635T3 (cg-RX-API-DMAC7.html) |
| TW (1) | TW239119B (cg-RX-API-DMAC7.html) |
Families Citing this family (125)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5595709A (en) * | 1992-09-01 | 1997-01-21 | Chromatofast | Instrument for measuring non-methane organic gases in gas samples |
| HUT67948A (en) * | 1992-12-18 | 1995-05-29 | Amoco Corp | Thermal cracking process with reduced coking |
| CN1034223C (zh) * | 1993-03-29 | 1997-03-12 | 中国石油化工总公司 | 制取低碳烯烃的裂解催化剂 |
| CN1034586C (zh) * | 1993-11-05 | 1997-04-16 | 中国石油化工总公司 | 多产低碳烯烃的催化转化方法 |
| US6048816A (en) * | 1996-10-02 | 2000-04-11 | Mobil Oil Corporation | Catalyst and process for converting methanol to hydrocarbons |
| CN1059133C (zh) * | 1997-03-24 | 2000-12-06 | 中国石油化工总公司 | 具有mfi结构的含磷分子筛 |
| AU7956398A (en) * | 1997-06-10 | 1998-12-30 | Exxon Chemical Patents Inc. | Multi-reactor system for enhanced light olefin make |
| EP0921175A1 (en) * | 1997-12-05 | 1999-06-09 | Fina Research S.A. | Production of olefins |
| EP0921176A1 (en) * | 1997-12-05 | 1999-06-09 | Fina Research S.A. | Production of olefins |
| EP0920911A1 (en) | 1997-12-05 | 1999-06-09 | Fina Research S.A. | Production of catalysts for olefin conversion |
| US6080303A (en) * | 1998-03-11 | 2000-06-27 | Exxon Chemical Patents, Inc. | Zeolite catalyst activity enhancement by aluminum phosphate and phosphorus |
| US6313366B1 (en) | 1998-05-05 | 2001-11-06 | Exxonmobile Chemical Patents, Inc. | Process for selectively producing C3 olefins in a fluid catalytic cracking process |
| US6455750B1 (en) * | 1998-05-05 | 2002-09-24 | Exxonmobil Chemical Patents Inc. | Process for selectively producing light olefins |
| US6315890B1 (en) | 1998-05-05 | 2001-11-13 | Exxonmobil Chemical Patents Inc. | Naphtha cracking and hydroprocessing process for low emissions, high octane fuels |
| US6069287A (en) * | 1998-05-05 | 2000-05-30 | Exxon Research And Engineering Co. | Process for selectively producing light olefins in a fluid catalytic cracking process |
| US6118035A (en) | 1998-05-05 | 2000-09-12 | Exxon Research And Engineering Co. | Process for selectively producing light olefins in a fluid catalytic cracking process from a naphtha/steam feed |
| US6803494B1 (en) | 1998-05-05 | 2004-10-12 | Exxonmobil Chemical Patents Inc. | Process for selectively producing propylene in a fluid catalytic cracking process |
| US6339180B1 (en) | 1998-05-05 | 2002-01-15 | Exxonmobil Chemical Patents, Inc. | Process for producing polypropylene from C3 olefins selectively produced in a fluid catalytic cracking process |
| US6093867A (en) * | 1998-05-05 | 2000-07-25 | Exxon Research And Engineering Company | Process for selectively producing C3 olefins in a fluid catalytic cracking process |
| US6388152B1 (en) | 1998-05-05 | 2002-05-14 | Exxonmobil Chemical Patents Inc. | Process for producing polypropylene from C3 olefins selectively produced in a fluid catalytic cracking process |
| US6106697A (en) * | 1998-05-05 | 2000-08-22 | Exxon Research And Engineering Company | Two stage fluid catalytic cracking process for selectively producing b. C.su2 to C4 olefins |
| US6602403B1 (en) | 1998-05-05 | 2003-08-05 | Exxonmobil Chemical Patents Inc. | Process for selectively producing high octane naphtha |
| US6238550B1 (en) | 1998-05-26 | 2001-05-29 | Exxon Research And Engineering Company | Silicoaluminophosphates having AEL structure, a method for their preparation and their use as catalysts for the hydroprocessing of hydrocarbon feedstocks |
| US6395949B1 (en) | 1998-08-03 | 2002-05-28 | Phillips Petroleum Company | Acid treated zeolite containing phosphorus used as a catalyst in processes for converting hydrocarbons, and use of binary hydrocarbon mixtures as diluents in processes for converting hydrocarbons |
| US6307117B1 (en) | 1998-08-25 | 2001-10-23 | Asahi Kasei Kogyo Kabushiki Kaisha | Method for producing ethylene and propylene |
| FR2794116B1 (fr) * | 1999-05-11 | 2001-07-20 | Inst Francais Du Petrole | Zeolithe im-5 au phosphore, composition catalytique, sa preparation et son utilisation en craquage catalytique |
| US6222087B1 (en) * | 1999-07-12 | 2001-04-24 | Mobil Oil Corporation | Catalytic production of light olefins rich in propylene |
| US6835863B2 (en) | 1999-07-12 | 2004-12-28 | Exxonmobil Oil Corporation | Catalytic production of light olefins from naphtha feed |
| US6613951B1 (en) | 1999-09-23 | 2003-09-02 | Mobil Oil Corporation | Process for converting methanol to olefins |
| US6339181B1 (en) | 1999-11-09 | 2002-01-15 | Exxonmobil Chemical Patents, Inc. | Multiple feed process for the production of propylene |
| EP1116775A1 (en) | 2000-01-12 | 2001-07-18 | Akzo Nobel N.V. | Catalyst composition with high efficiency for the production of light olefins |
| US20030187315A1 (en) * | 2002-03-26 | 2003-10-02 | Voskoboynikov Timur V. | Spherical catalysts to convert hydrocarbons to light olefins |
| US7314963B2 (en) * | 2002-03-26 | 2008-01-01 | Uop Llc | Spherical catalysts to convert hydrocarbons to light olefins |
| DE10233069C1 (de) * | 2002-07-19 | 2003-09-18 | Lurgi Ag | Verfahren zur Herstellung von Propylen aus einem C¶4¶ bis C¶8¶ Olefine enthaltenden Einsatzstrom |
| US7011740B2 (en) | 2002-10-10 | 2006-03-14 | Kellogg Brown & Root, Inc. | Catalyst recovery from light olefin FCC effluent |
| US7153479B2 (en) * | 2002-10-10 | 2006-12-26 | Kellogg Brown & Root Llc | Catalyst regenerator with a centerwell |
| US7084318B2 (en) | 2003-08-01 | 2006-08-01 | Saudi Basic Industries Corporation | Toluene methylation process |
| US7060864B2 (en) | 2003-09-30 | 2006-06-13 | Saudi Basic Industries Corporation | Toluene methylation process |
| CN1257769C (zh) * | 2003-10-31 | 2006-05-31 | 中国石油化工股份有限公司 | 一种含磷和金属组分的mfi结构分子筛及其应用 |
| US7060644B2 (en) | 2004-01-08 | 2006-06-13 | Saudi Basic Industries Corporation | Aromatic alkylation catalyst and method |
| US6943131B1 (en) * | 2004-03-02 | 2005-09-13 | Saudi Basic Industries Corporation | Selective zeolite catalyst modification |
| US7399727B2 (en) | 2004-04-23 | 2008-07-15 | Saudi Basic Industries Corporation | Zeolite catalyst and method |
| US7285511B2 (en) | 2004-04-23 | 2007-10-23 | Saudi Basic Industries Corporation | Method of modifying zeolite catalyst |
| WO2005123251A1 (en) | 2004-06-09 | 2005-12-29 | Saudi Basic Industries Corporation | Fluoride-modified zeolite catalyst and method |
| US7462275B2 (en) * | 2004-07-20 | 2008-12-09 | Indian Oil Corporation Limited | Process for conversion of hydrocarbons to saturated LPG and high octane gasoline |
| KR100632563B1 (ko) * | 2004-09-10 | 2006-10-09 | 에스케이 주식회사 | 접촉 분해용 고체산 촉매 및 이를 이용하여 전범위납사로부터 경질 올레핀을 선택적으로 제조하는 공정 |
| KR101229756B1 (ko) | 2004-12-28 | 2013-02-06 | 차이나 페트로리움 앤드 케미컬 코포레이션 | 탄화수소 분해 촉매 및 탄화수소 분해 방법 |
| US7304194B2 (en) | 2005-05-05 | 2007-12-04 | Saudi Basic Industries Corporation | Hydrothermal treatment of phosphorus-modified zeolite catalysts |
| US7368410B2 (en) | 2005-08-03 | 2008-05-06 | Saudi Basic Industries Corporation | Zeolite catalyst and method of preparing and use of zeolite catalyst |
| EP1935865B1 (en) | 2005-09-16 | 2016-11-16 | Asahi Kasei Kabushiki Kaisha | Process for production of ethylene and propylene |
| EP2025402A1 (en) * | 2007-07-31 | 2009-02-18 | Total Petrochemicals Research Feluy | Phosphorus modified molecular sieves, their use in conversion of organics to olefins |
| EP2036873A1 (en) * | 2007-09-12 | 2009-03-18 | Total Petrochemicals Research Feluy | Use of phosphorus modified molecular sieves in conversion of organics to olefins |
| EP2173689B8 (en) * | 2007-07-31 | 2023-10-18 | TotalEnergies OneTech Belgium | Use of phosphorus modified molecular sieves in conversion of organics to olefins |
| EP2039427A1 (en) * | 2007-09-12 | 2009-03-25 | Total Petrochemicals Research Feluy | Cracking of olefins on phosphorus modified molecular sieves |
| WO2009016156A1 (en) * | 2007-07-31 | 2009-02-05 | Total Petrochemicals Research Feluy | Cracking of olefins on phosphorus modified molecular sieves. |
| EP2082801A1 (en) * | 2008-01-25 | 2009-07-29 | Total Petrochemicals Research Feluy | Process for obtaining modified molecular sieves |
| EP2082802A1 (en) * | 2008-01-25 | 2009-07-29 | Total Petrochemicals Research Feluy | Process for obtaining a catalyst composite |
| CN101939276B (zh) * | 2008-02-07 | 2013-05-08 | 道达尔石油化学产品研究弗吕公司 | 由乙醇制造烯烃的方法 |
| EP2238096A1 (en) * | 2008-02-07 | 2010-10-13 | Total Petrochemicals Research Feluy | Process to make olefins from ethanol |
| AU2009211364B2 (en) * | 2008-02-07 | 2012-01-19 | Total Petrochemicals Research Feluy | Dehydration of alcohols on crystalline silicates |
| EA019977B1 (ru) * | 2008-06-25 | 2014-07-30 | Тотал Петрокемикалз Ресерч Фелюи | Способ получения олефинов из органических веществ |
| EA021226B1 (ru) * | 2008-06-25 | 2015-05-29 | Тотал Ресерч Энд Текнолоджи Фелюи | Способ получения олефинов из оксигенатов |
| EP2303806B1 (en) * | 2008-06-25 | 2019-08-07 | Total Research & Technology Feluy | Process to make olefins from oxygenates |
| US8957271B2 (en) * | 2008-06-25 | 2015-02-17 | Total Research & Technology Feluy | Process to make olefins from oxygenates |
| JP2010042343A (ja) * | 2008-08-12 | 2010-02-25 | National Institute Of Advanced Industrial & Technology | 低級オレフィン製造用触媒、その製造方法及びこれを用いた低級オレフィンの製造方法 |
| US8846559B2 (en) | 2008-11-03 | 2014-09-30 | Saudi Basic Industries Corporation | Stable shape-selective catalyst for aromatic alkylation and methods of using and preparing |
| EP2364343B1 (en) | 2008-12-10 | 2017-09-06 | Reliance Industries Limited | A fluid catalytic cracking (fcc) process for manufacturing propylene and ethylene in increased yield |
| RU2548362C2 (ru) * | 2009-06-25 | 2015-04-20 | Чайна Петролеум & Кемикал Корпорейшн | Катализатор каталитического крекинга и способ повышения селективности катализатора(варианты) |
| US8062987B2 (en) | 2009-10-05 | 2011-11-22 | Saudi Basic Industries Corporation | Phosphorus-containing zeolite catalysts and their method of preparation |
| CN102050458B (zh) | 2009-10-30 | 2012-08-08 | 中国石油天然气股份有限公司 | 一种提高抗钠污染能力的改性分子筛及制备方法 |
| CN102050462B (zh) | 2009-10-30 | 2012-10-17 | 中国石油天然气股份有限公司 | 一种提高水热稳定性的双组元改性分子筛及制备方法 |
| EP2348004A1 (en) | 2010-01-25 | 2011-07-27 | Total Petrochemicals Research Feluy | Method for making a catalyst comprising a phosphorus modified zeolite to be used in a MTO or a dehydration process |
| CN102166533B (zh) * | 2010-02-25 | 2013-07-31 | 中国石油天然气股份有限公司 | 一种提高了活性与水热稳定性的复合改性分子筛及制备方法 |
| US8383052B2 (en) | 2010-04-16 | 2013-02-26 | Kellogg Brown & Root Llc | System for a heat balanced FCC forlight hydrocarbon feeds |
| US9056807B2 (en) * | 2010-08-03 | 2015-06-16 | Total Research & Technology Feluy | Process to make olefins from isobutanol |
| ES2493141T3 (es) * | 2010-08-03 | 2014-09-11 | Total Research & Technology Feluy | Procedimiento de preparación olefinas a partir de isobutanol |
| WO2012016788A1 (en) * | 2010-08-03 | 2012-02-09 | Total Petrochemicals Research Feluy | Process to make olefins from methanol and isobutanol |
| CO6460077A1 (es) * | 2010-12-06 | 2012-06-15 | Ecopetrol Sa | Proceso para modificacion de zeolita por incorporacion de fosforo en la estructura cristalina y catalizadores para oligomerizacion de olefinas |
| RU2013150347A (ru) | 2011-04-13 | 2015-05-20 | Кайор, Инк. | Усовершенствованный катализатор для термокаталитической конверсии биомассы в жидкие топлива и химические продукты |
| EP2739391B1 (en) | 2011-08-03 | 2021-02-17 | Total Research & Technology Feluy | Catalyst comprising a phosphorus modified zeolite and having partly an alpo structure |
| US10464053B2 (en) | 2011-08-03 | 2019-11-05 | Total Research & Technology Feluy | Method for making a catalyst comprising a phosphorous modified zeolite and use of said zeolite |
| WO2013017496A1 (en) | 2011-08-03 | 2013-02-07 | Total Research & Technology Feluy | Use of a catalyst comprising a phosphorus modified zeolite in an alcohol dehydration process |
| US20130281753A1 (en) | 2011-10-17 | 2013-10-24 | Stephen J. McCarthy | Phosphorus modified zeolite catalysts |
| KR101821451B1 (ko) | 2012-02-14 | 2018-01-23 | 릴라이언스 인더스트리즈 리미티드 | 저가 탄화수소 흐름을 경질 올레핀으로 촉매 전환하는 공정 |
| US9278342B2 (en) | 2012-07-02 | 2016-03-08 | Saudi Basic Industries Corporation | Method of modifying a phosphorus-containing zeolite catalyst |
| US9518229B2 (en) | 2012-07-20 | 2016-12-13 | Inaeris Technologies, Llc | Catalysts for thermo-catalytic conversion of biomass, and methods of making and using |
| US9745519B2 (en) | 2012-08-22 | 2017-08-29 | Kellogg Brown & Root Llc | FCC process using a modified catalyst |
| PT2948244T (pt) | 2013-01-23 | 2020-05-19 | Basf Corp | Melhoria da atividade aditiva do zsm-5 pela interação melhorada de zeólito e fósforo |
| US9522392B2 (en) | 2013-03-15 | 2016-12-20 | Inaeris Technologies, Llc | Phosphorous promotion of zeolite-containing catalysts |
| EP2975013A1 (en) | 2013-04-03 | 2016-01-20 | Scg Chemicals Co. Ltd. | Catalyst for converting paraffin to olefin |
| CN104108724B (zh) * | 2013-04-16 | 2016-05-25 | 中国科学院兰州化学物理研究所 | 低成本原料合成小晶粒p-zsm-5分子筛的方法 |
| RU2667146C2 (ru) * | 2013-04-24 | 2018-09-17 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Активация паром самоактивирующегося катализатора процесса гидрообработки |
| CN108431180B (zh) | 2015-12-21 | 2021-09-03 | 沙特基础工业全球技术公司 | 由焦化石脑油生产烯烃和芳烃的方法和系统 |
| US9981888B2 (en) | 2016-06-23 | 2018-05-29 | Saudi Arabian Oil Company | Processes for high severity fluid catalytic cracking systems |
| CA3028438C (en) | 2016-06-24 | 2023-12-05 | Albemarle Corporation | Mesoporous zsm-22 for increased propylene production |
| WO2018117820A1 (en) | 2016-12-21 | 2018-06-28 | Inovacat B.V. | Process to prepare propylene |
| CN110300623B (zh) | 2017-03-17 | 2023-08-11 | 雅宝公司 | 具有混合氧化铝的fcc催化剂添加剂 |
| JP6952106B2 (ja) * | 2017-03-24 | 2021-10-20 | 日揮グローバル株式会社 | ゼオライト含有触媒および低級オレフィンの製造方法 |
| KR102052437B1 (ko) * | 2017-05-12 | 2019-12-05 | 한국화학연구원 | 프로필렌으로부터 선택적 에틸렌의 제조방법 |
| US10870802B2 (en) | 2017-05-31 | 2020-12-22 | Saudi Arabian Oil Company | High-severity fluidized catalytic cracking systems and processes having partial catalyst recycle |
| KR102163124B1 (ko) | 2017-10-20 | 2020-10-07 | 라이온델 케미칼 테크놀로지, 엘.피. | 에틸렌 및 프로필렌의 제조 방법 |
| KR102162781B1 (ko) | 2017-10-26 | 2020-10-07 | 라이온델 케미칼 테크놀로지, 엘.피. | 프로필렌 및 에틸렌의 제조 방법 |
| KR102049352B1 (ko) * | 2017-11-01 | 2019-11-28 | 한국화학연구원 | 산 처리된 zsm-5를 통한 프로필렌으로부터 선택적 에틸렌의 제조방법 |
| US10889768B2 (en) | 2018-01-25 | 2021-01-12 | Saudi Arabian Oil Company | High severity fluidized catalytic cracking systems and processes for producing olefins from petroleum feeds |
| KR102234656B1 (ko) * | 2018-05-16 | 2021-04-01 | 한국화학연구원 | 프로판으로부터 선택적 에틸렌의 제조방법 |
| RU2688662C1 (ru) * | 2018-07-24 | 2019-05-22 | Федеральное государственное бюджетное учреждение науки "Федеральный исследовательский центр "Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук" (Институт катализа СО РАН, ИК СО РАН) | Способ каталитического крекинга бутан-бутиленовой фракции и катализатор для его осуществления |
| RU2709521C1 (ru) * | 2019-09-16 | 2019-12-18 | Акционерное общество "Газпромнефть - Омский НПЗ" (АО "Газпромнефть-ОНПЗ") | Катализатор крекинга нефтяных фракций |
| RU2710856C1 (ru) * | 2019-09-16 | 2020-01-14 | Акционерное общество "Газпромнефть - Омский НПЗ" (АО "Газпромнефть-ОНПЗ") | Способ совместного крекинга нефтяных фракций |
| RU2710855C1 (ru) * | 2019-09-16 | 2020-01-14 | Акционерное общество "Газпромнефть - Омский НПЗ" (АО "Газпромнефть-ОНПЗ") | Способ крекинга нефтяных фракций |
| KR20230002699A (ko) | 2020-04-13 | 2023-01-05 | 차이나 페트로리움 앤드 케미컬 코포레이션 | 인-함유/인-개질 zsm-5 분자체, 열분해 첨가제 및 이를 포함하는 열분해 촉매, 이의 제조 방법 및 이의 응용 |
| US12296323B2 (en) | 2020-04-13 | 2025-05-13 | China Petroleum & Chemical Corporation | Phosphorus-modified MFI-structured molecular sieve, catalytic cracking auxiliary and catalytic cracking catalyst containing phosphorus-modified MFI-structured molecular sieve, and processes for preparing the same |
| CN114425431B (zh) * | 2020-10-29 | 2023-07-14 | 中国石油化工股份有限公司 | 一种含磷改性mfi结构分子筛的催化裂解催化剂 |
| US11230673B1 (en) | 2020-09-01 | 2022-01-25 | Saudi Arabian Oil Company | Processes for producing petrochemical products that utilize fluid catalytic cracking of a lesser boiling point fraction with steam |
| US11230672B1 (en) | 2020-09-01 | 2022-01-25 | Saudi Arabian Oil Company | Processes for producing petrochemical products that utilize fluid catalytic cracking |
| US11352575B2 (en) | 2020-09-01 | 2022-06-07 | Saudi Arabian Oil Company | Processes for producing petrochemical products that utilize hydrotreating of cycle oil |
| US11434432B2 (en) | 2020-09-01 | 2022-09-06 | Saudi Arabian Oil Company | Processes for producing petrochemical products that utilize fluid catalytic cracking of a greater boiling point fraction with steam |
| US11505754B2 (en) | 2020-09-01 | 2022-11-22 | Saudi Arabian Oil Company | Processes for producing petrochemical products from atmospheric residues |
| US11242493B1 (en) | 2020-09-01 | 2022-02-08 | Saudi Arabian Oil Company | Methods for processing crude oils to form light olefins |
| US11332680B2 (en) | 2020-09-01 | 2022-05-17 | Saudi Arabian Oil Company | Processes for producing petrochemical products that utilize fluid catalytic cracking of lesser and greater boiling point fractions with steam |
| CN114762836B (zh) * | 2021-01-11 | 2023-09-05 | 中国石油化工股份有限公司 | 一种含磷改性mfi结构分子筛的催化裂解催化剂的制备方法和制备系统 |
| EP4275789A4 (en) * | 2021-01-11 | 2024-12-18 | China Petroleum & Chemical Corporation | CATALYTIC CRACKING AGENT CONTAINING PHOSPHORUS-MODIFIED MOLECULAR SIEVE, ITS PREPARATION METHOD, ITS PREPARATION SYSTEM AND ITS USE |
| CN114762831B (zh) * | 2021-01-11 | 2023-11-10 | 中国石油化工股份有限公司 | 一种催化裂解助剂的制备方法和制备系统 |
| FR3144023A1 (fr) | 2022-12-22 | 2024-06-28 | IFP Energies Nouvelles | Catalyseur a base d’une zeolithe et d’une structure alpo et presentant un volume macroporeux eleve |
| WO2024168329A1 (en) | 2023-02-10 | 2024-08-15 | Exelus Inc. | Multifunctional catalyst for naphtha cracking |
| JP7767559B1 (ja) * | 2024-10-29 | 2025-11-11 | 住友化学株式会社 | オレフィンの製造方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4044065A (en) * | 1974-09-23 | 1977-08-23 | Mobile Oil Corporation | Conversion utilizing a phosphorus-containing zeolite catalyst |
| US3972832A (en) * | 1974-09-23 | 1976-08-03 | Mobil Oil Corporation | Phosphorus-containing zeolite catalyst |
| US4282085A (en) * | 1978-10-23 | 1981-08-04 | Chevron Research Company | Petroleum distillate upgrading process |
| US4356338A (en) * | 1979-07-27 | 1982-10-26 | Mobil Oil Corporation | Extending catalyst life by treating with phosphorus and/or steam |
| US4423266A (en) * | 1980-10-08 | 1983-12-27 | Mobil Oil Corporation | Extending isomerization catalyst life by treating with phosphorous and/or steam |
| DE3372474D1 (en) * | 1982-11-10 | 1987-08-20 | Montedipe Spa | Process for converting olefins having 4 to 12 carbon atoms into propylene |
| JPS60222428A (ja) * | 1984-04-19 | 1985-11-07 | Res Assoc Util Of Light Oil | 炭化水素の接触転化法 |
| US5043522A (en) * | 1989-04-25 | 1991-08-27 | Arco Chemical Technology, Inc. | Production of olefins from a mixture of Cu+ olefins and paraffins |
-
1991
- 1991-04-26 US US07/692,333 patent/US5171921A/en not_active Expired - Lifetime
-
1992
- 1992-04-23 JP JP4129392A patent/JP3057398B2/ja not_active Expired - Fee Related
- 1992-04-24 DE DE69214499T patent/DE69214499T2/de not_active Expired - Fee Related
- 1992-04-24 ES ES92303737T patent/ES2092635T3/es not_active Expired - Lifetime
- 1992-04-24 EP EP92303737A patent/EP0511013B1/en not_active Expired - Lifetime
- 1992-04-27 KR KR1019920007110A patent/KR100237508B1/ko not_active Expired - Fee Related
- 1992-05-05 TW TW081103524A patent/TW239119B/zh active
Also Published As
| Publication number | Publication date |
|---|---|
| KR920019712A (ko) | 1992-11-19 |
| JPH0673382A (ja) | 1994-03-15 |
| EP0511013A2 (en) | 1992-10-28 |
| EP0511013B1 (en) | 1996-10-16 |
| EP0511013A3 (en) | 1994-08-24 |
| TW239119B (cg-RX-API-DMAC7.html) | 1995-01-21 |
| DE69214499T2 (de) | 1997-02-20 |
| DE69214499D1 (de) | 1996-11-21 |
| KR100237508B1 (ko) | 2000-01-15 |
| ES2092635T3 (es) | 1996-12-01 |
| US5171921A (en) | 1992-12-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP3057398B2 (ja) | 炭化水素を転換する方法 | |
| CA2015209C (en) | Production of olefins | |
| EP0788838B1 (en) | Method of catalytic hydrocarbon conversion with a silver zeolite catalyst | |
| US6548725B2 (en) | Process for manufacturing olefins | |
| US4613716A (en) | Production of aromatics from ethane and/or ethylene | |
| US20110137096A1 (en) | Process to Make Olefins from Ethanol | |
| CN101405241B (zh) | 利用移动床技术和热液稳定化双功能催化剂体系的含氧物至丙烯的选择性转化 | |
| US20110105815A1 (en) | Process to Make Olefins from Ethanol | |
| AU577371B2 (en) | Two stage catalytic conversion of olefins to higher hydrocarbons | |
| MXPA02000372A (es) | Produccion catalitica de olefinas ligeras ricas en propileno. | |
| US5523510A (en) | Treated bound ferrierite zeolites for skeletal isomerization of n-olefins to iso-olefins | |
| JP2008513448A (ja) | 移動床技術及びエーテル化工程を利用したアルコール性オキシジェネートのプロピレンへの転化 | |
| JPS62230885A (ja) | ガソリンの製造方法 | |
| US4620051A (en) | Dehydrogenation and cracking of C3 and C4 hydrocarbons to less saturated hydrocarbons | |
| EP2108637A1 (en) | Process to make olefins from ethanol. | |
| US4605807A (en) | Process for catalytic conversion of ethylene to higher hydrocarbons | |
| WO2001081280A1 (en) | Catalytic process for making propylene and ethylene | |
| EP1761333A1 (en) | Zeolite catalysts | |
| EP2108635A1 (en) | Process to make olefins from ethanol | |
| US7057084B2 (en) | Process for the removal of higher hydrocarbons from natural gas | |
| KR20120029429A (ko) | 배합 산소화물 전환 촉매의 제조 방법, 배합 산소화물 전환 촉매 및 올레핀계 생성물의 제조 방법 | |
| US20110313224A1 (en) | Process for the preparation of an olefinic product and an oxygenate conversion catalyst | |
| CA1199647A (en) | Conversion of certain hydrocarbons using calcined teasilicate catalyst | |
| CA1259339A (en) | Two stage process for catalytic conversion of olefins to higher hydrocarbons | |
| JPH03182592A (ja) | 芳香族炭化水素の連続接触的選択的製造方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090421 Year of fee payment: 9 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090421 Year of fee payment: 9 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100421 Year of fee payment: 10 |
|
| LAPS | Cancellation because of no payment of annual fees |