DE1963571C3 - Verfahren zur Vernetzung von Polyolefinen - Google Patents

Verfahren zur Vernetzung von Polyolefinen

Info

Publication number
DE1963571C3
DE1963571C3 DE1963571A DE1963571A DE1963571C3 DE 1963571 C3 DE1963571 C3 DE 1963571C3 DE 1963571 A DE1963571 A DE 1963571A DE 1963571 A DE1963571 A DE 1963571A DE 1963571 C3 DE1963571 C3 DE 1963571C3
Authority
DE
Germany
Prior art keywords
polyolefin
silane
reaction
crosslinking
radical
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE1963571A
Other languages
German (de)
English (en)
Other versions
DE1963571B2 (de
DE1963571A1 (de
Inventor
Henry George Glamorgan Wales Scott
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Silicones UK Ltd
Original Assignee
Dow Corning Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Corning Ltd filed Critical Dow Corning Ltd
Publication of DE1963571A1 publication Critical patent/DE1963571A1/de
Publication of DE1963571B2 publication Critical patent/DE1963571B2/de
Application granted granted Critical
Publication of DE1963571C3 publication Critical patent/DE1963571C3/de
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L43/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium or a metal; Compositions of derivatives of such polymers
    • C08L43/04—Homopolymers or copolymers of monomers containing silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/022—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/14—Peroxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C08K5/541—Silicon-containing compounds containing oxygen
    • C08K5/5425—Silicon-containing compounds containing oxygen containing at least one C=C bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/07—Flat, e.g. panels
    • B29C48/08—Flat, e.g. panels flexible, e.g. films
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2101/00—Use of unspecified macromolecular compounds as moulding material
    • B29K2101/10—Thermosetting resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2301/00—Use of unspecified macromolecular compounds as reinforcement
    • B29K2301/10—Thermosetting resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2312/00—Crosslinking

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Graft Or Block Polymers (AREA)
DE1963571A 1968-12-20 1969-12-18 Verfahren zur Vernetzung von Polyolefinen Expired DE1963571C3 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB60650/68A GB1286460A (en) 1968-12-20 1968-12-20 Improvements in or relating to polymers

Publications (3)

Publication Number Publication Date
DE1963571A1 DE1963571A1 (de) 1970-10-29
DE1963571B2 DE1963571B2 (de) 1972-10-05
DE1963571C3 true DE1963571C3 (de) 1983-12-15

Family

ID=10485883

Family Applications (1)

Application Number Title Priority Date Filing Date
DE1963571A Expired DE1963571C3 (de) 1968-12-20 1969-12-18 Verfahren zur Vernetzung von Polyolefinen

Country Status (7)

Country Link
US (1) US3646155A (OSRAM)
BE (1) BE794718Q (OSRAM)
BR (1) BR6915212D0 (OSRAM)
DE (1) DE1963571C3 (OSRAM)
FR (1) FR2030899A5 (OSRAM)
GB (1) GB1286460A (OSRAM)
SE (1) SE368211B (OSRAM)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2926830A1 (de) * 1978-07-05 1980-01-17 Mitsubishi Petrochemical Co Vernetzbare polyethylen-kunststoffmassen
EP0406793A1 (fr) * 1989-07-05 1991-01-09 Alcatel Cable Cables à fibres optiques résistant à une saute de température À  350 degrés pendant une courte durée
EP1318526A2 (de) 2001-12-06 2003-06-11 Degussa AG Verwendung flüssiger oder auf Trägermaterial aufgebrachter ungesättigter Organosilan/-mischungen zur Herstellung von feuchtigkeitsvernetzten und gefüllten Kabelcompounds
US6864323B2 (en) 2001-08-30 2005-03-08 Degussa Ag Composition for improving scorch conditions in the preparation of grafted and/or crosslinked polymers and of filled plastics
DE102008041919A1 (de) 2008-09-09 2010-03-11 Evonik Degussa Gmbh Verwendung von Silicium enthaltenden Vorläuferverbindungen einer organischen Säure als Katalysator zur Vernetzung von gefüllten und ungefüllten Polymer-Compounds
DE102008041918A1 (de) 2008-09-09 2010-03-11 Evonik Degussa Gmbh Silanolkondensationskatalysatoren zur Vernetzung von gefüllten und ungefüllten Polymer-Compounds
DE102010002358A1 (de) 2010-02-25 2011-08-25 Evonik Degussa GmbH, 45128 Carboxyfunktionalisierte Silicium enthaltende Vorläuferverbindung verschiedener organischer Carbonsäuren
DE102013216502A1 (de) 2013-08-21 2015-02-26 Evonik Industries Ag Zinn-freie Zusammensetzung für die Vernetzung von thermoplastischen Polyolefinen
DE102013216504A1 (de) 2013-08-21 2015-02-26 Evonik Industries Ag Zinn-freie Katalysator-haltige Zusammensetzung für einen Monosil-Prozess mit optimierter Prozesscharakteristik

Families Citing this family (330)

* Cited by examiner, † Cited by third party
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GB1408154A (en) * 1972-02-29 1975-10-01 Dow Corning Ltd Foamable ethylene polymer compositions
GB1396120A (en) * 1972-10-28 1975-06-04 Dow Corning Ltd Crosslinking process
US4289860A (en) * 1974-03-08 1981-09-15 Kabel- Und Metallwerke Gutehoffnungshutte Ag Grafting of silane on thermoplastics or elastomers for purposes of cross linking
DE2444829A1 (de) * 1974-09-19 1976-04-08 Kabel Metallwerke Ghh Verfahren zur herstellung von durch aufpfropfen einer silanverbindung in anwesenheit von feuchtigkeit vernetzbaren thermoplasten oder elastomeren
GB1526398A (en) * 1974-12-06 1978-09-27 Maillefer Sa Manufacture of extruded products
GB1534299A (en) 1975-09-26 1978-11-29 Bicc Ltd Manufacture of extruded products
DE2529260A1 (de) * 1975-07-01 1977-01-27 Kabel Metallwerke Ghh Verfahren und vorrichtung zur herstellung von durch aufpfropfen einer silan-verbindung in anwesenheit von feuchtigkeit vernetzbaren thermoplasten oder elastomeren
AR208346A1 (es) * 1974-12-12 1976-12-20 Kabel Metallwerke Ghh Procedimiento y dispositivo para la elaboracion de termoplasticos o elastomeros reticulables por injerto de un compuesto de silano en la presencia de humedad
DE2458776A1 (de) * 1974-12-12 1976-06-16 Kabel Metallwerke Ghh Verfahren zur herstellung von durch aufpfropfen einer silanverbindung in anwesenheit von feuchtigkeit vernetzbaren thermoplasten oder elastomeren
US4160072A (en) * 1975-03-20 1979-07-03 Sekisui Kagaku Kogyo Kabushiki Kaisha Foamable and crosslinkable polyethylene composition, process for its production, and process for producing crosslinked polyethylene foams using said composition
AR218611A1 (es) * 1975-06-23 1980-06-30 Kabel Metallwerke Ghh Procedimiento para la elaboracion de termoplasticos o elastomeros reticulables por injerto de un compuesto de silano en presencia de humedad
US4115612A (en) * 1976-05-04 1978-09-19 Closson Jr Addison W Laminated thermoplastic counter stiffener
DE2655877A1 (de) * 1976-12-09 1978-06-15 Wacker Chemie Gmbh Verfahren zum herstellen und verwendung von silanen
GB1579446A (en) * 1976-12-14 1980-11-19 Fujikura Ltd Method for producing crosslinked polyethylenes
DE2713181A1 (de) 1977-03-25 1978-10-05 Kabel Metallwerke Ghh Verfahren zur herstellung geschaeumter materialien
US4182398A (en) * 1977-04-04 1980-01-08 The United States Of America As Represented By The United States Department Of Energy Crosslinked crystalline polymer and methods for cooling and heating
GB2002684B (en) * 1977-08-06 1982-02-17 Showa Electric Wire & Cable Co Laminated insulating paper and oil-filled cable insulated thereby
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JPS5483089A (en) * 1977-12-15 1979-07-02 Sekisui Chem Co Ltd Preparation of silane-modified ethylene resin
AU4199378A (en) * 1977-12-20 1979-06-28 British Steel Corp Production of cross-linked polyolefine articles
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JPS6017353B2 (ja) * 1978-03-03 1985-05-02 古河電気工業株式会社 ポリオレフイン系樹脂の架橋方法
US4291136A (en) * 1978-03-31 1981-09-22 Union Carbide Corporation Water-curable silane modified alkylene alkylacrylate copolymer and a process for its production
AU523866B2 (en) * 1978-04-18 1982-08-19 Du Pont Canada Inc. Manufacture of film
US4413066A (en) * 1978-07-05 1983-11-01 Mitsubishi Petrochemical Company, Ltd. Crosslinkable polyethylene resin compositions
US4395459A (en) * 1978-07-11 1983-07-26 Herschdorfer C George Reinforced laminates produced from crosslinkable thermoplastic olefin polymer material
US4292106A (en) * 1978-07-11 1981-09-29 Clark-Schwebel Fiber Glass Corp. Process of producing reinforced laminates from crosslinkable thermoplastic olefin polymer material
JPS5566809A (en) * 1978-11-13 1980-05-20 Mitsubishi Petrochemical Co Method of manufacturing crosslinked polyethylene resinncoated wire
US4212756A (en) * 1979-05-17 1980-07-15 Union Carbide Corporation Dielectric composition stabilized against water treeing with organo silane compounds
JPS5695940A (en) * 1979-12-28 1981-08-03 Mitsubishi Petrochem Co Ltd Ethylene polymer composition
DE3003156A1 (de) * 1980-01-30 1981-08-06 Kabel- und Metallwerke Gutehoffnungshütte AG, 3000 Hannover Verfahren zur vernetzung von auf trommeln oder spulen befindlichem wickelgut
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US4488642A (en) * 1980-07-28 1984-12-18 Raychem Limited Polymeric articles
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ATE13156T1 (de) 1980-09-17 1985-05-15 Raychem Ltd Verfahren zur herstellung von aus polymeren bestehenden gegenstaenden.
US4434272A (en) 1980-09-30 1984-02-28 Union Carbide Corporation Water-curable, silane modified alkyl acrylate copolymers and a process for the preparation thereof
US4452937A (en) * 1980-12-22 1984-06-05 Union Carbide Corporation Ethylene polymer compositions stabilized against water treeing and electrical treeing by an organo titanium chelate; and the use thereof as insulation about electrical conductors
JPS57153004A (en) * 1981-03-19 1982-09-21 Nippon Oil Co Ltd Production of silane-crosslinked polyolefin
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FR2546172B1 (fr) * 1983-05-17 1987-03-20 Sogecan Compositions thermoplastiques contenant un polymere greffe par des silanes
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US4489029A (en) * 1983-06-01 1984-12-18 Union Carbide Corporation Compositions based on alkylene-alkyl acrylate copolymers and silanol condensation catalysts; and the use thereof in the production of covered wires and cables
US4493924A (en) * 1983-06-10 1985-01-15 Union Carbide Corporation Water-curable, silane modified chlorosulfonated olefinic polymers and a process for the preparation thereof
US4593072A (en) * 1983-09-23 1986-06-03 Union Carbide Corporation Relatively water-stable compositions based on thermoplastic polymers containing pendant silane moieties
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US3646155A (en) 1972-02-29
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SE368211B (OSRAM) 1974-06-24
BE794718Q (fr) 1973-05-16
DE1963571A1 (de) 1970-10-29
BR6915212D0 (pt) 1973-01-16
GB1286460A (en) 1972-08-23

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