CN1300185C - 含有异丁烯型单体交替共聚物的热固性组合物 - Google Patents

含有异丁烯型单体交替共聚物的热固性组合物 Download PDF

Info

Publication number
CN1300185C
CN1300185C CNB038050501A CN03805050A CN1300185C CN 1300185 C CN1300185 C CN 1300185C CN B038050501 A CNB038050501 A CN B038050501A CN 03805050 A CN03805050 A CN 03805050A CN 1300185 C CN1300185 C CN 1300185C
Authority
CN
China
Prior art keywords
copolymer
composition
acrylate
monomer
reactor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CNB038050501A
Other languages
English (en)
Chinese (zh)
Other versions
CN1639204A (zh
Inventor
S·科卡
E·R·科尔里奇
G·J·科勒姆
J·B·奥德怀尔
J·E·普尔
V·A·特雷特尔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
PPG Industries Inc
Original Assignee
PPG Industries Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by PPG Industries Inc filed Critical PPG Industries Inc
Publication of CN1639204A publication Critical patent/CN1639204A/zh
Application granted granted Critical
Publication of CN1300185C publication Critical patent/CN1300185C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50—Multilayers
    • B05D7/56—Three layers or more
    • B05D7/57—Three layers or more the last layer being a clear coat
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/02—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
    • B05D3/0209—Multistage baking
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/08—Butenes
    • C08F210/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
    • C08F290/04—Polymers provided for in subclasses C08C or C08F
    • C08F290/046—Polymers of unsaturated carboxylic acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
    • C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
    • C08G18/622—Polymers of esters of alpha-beta ethylenically unsaturated carboxylic acids
    • C08G18/6225—Polymers of esters of acrylic or methacrylic acid
    • C08G18/6229—Polymers of hydroxy groups containing esters of acrylic or methacrylic acid with aliphatic polyalcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
    • C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/798—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing urethdione groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C08G18/8003—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen
    • C08G18/8006—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32
    • C08G18/8009—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32 with compounds of C08G18/3203
    • C08G18/8022—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32 with compounds of C08G18/3203 with polyols having at least three hydroxy groups
    • C08G18/8025—Masked aliphatic or cycloaliphatic polyisocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
    • C08G18/807—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with nitrogen containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
    • C08G18/807—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with nitrogen containing compounds
    • C08G18/8074—Lactams
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
    • C08L23/22—Copolymers of isobutene; Butyl rubber; Homopolymers or copolymers of other iso-olefins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
    • C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D123/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C09D123/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
    • C09D123/22—Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefines
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/062—Copolymers with monomers not covered by C09D133/06
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/08—Homopolymers or copolymers of acrylic acid esters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B05D1/007—Processes for applying liquids or other fluent materials using an electrostatic field
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/06—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
    • B05D3/061—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation using U.V.
    • B05D3/065—After-treatment
    • B05D3/067—Curing or cross-linking the coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50—Multilayers
    • B05D7/52—Two layers
    • B05D7/53—Base coat plus clear coat type
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2150/00—Compositions for coatings
    • C08G2150/20—Compositions for powder coatings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/062—Copolymers with monomers not covered by C08L33/06
    • C08L33/068—Copolymers with monomers not covered by C08L33/06 containing glycidyl groups
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31511—Of epoxy ether

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Paints Or Removers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Laminated Bodies (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Epoxy Resins (AREA)
  • Polyurethanes Or Polyureas (AREA)
CNB038050501A 2002-02-15 2003-01-29 含有异丁烯型单体交替共聚物的热固性组合物 Expired - Fee Related CN1300185C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/077,645 US6784248B2 (en) 2002-02-15 2002-02-15 Thermosetting compositions containing alternating copolymers of isobutylene type monomers
US10/077,645 2002-02-15

Publications (2)

Publication Number Publication Date
CN1639204A CN1639204A (zh) 2005-07-13
CN1300185C true CN1300185C (zh) 2007-02-14

Family

ID=27752701

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB038050501A Expired - Fee Related CN1300185C (zh) 2002-02-15 2003-01-29 含有异丁烯型单体交替共聚物的热固性组合物

Country Status (12)

Country Link
US (9) US6784248B2 (enExample)
EP (2) EP1474454B1 (enExample)
JP (5) JP3993563B2 (enExample)
KR (1) KR100611868B1 (enExample)
CN (1) CN1300185C (enExample)
AU (2) AU2003210715B2 (enExample)
BR (1) BR0307577A (enExample)
CA (2) CA2476090C (enExample)
DE (4) DE60330118D1 (enExample)
ES (4) ES2334562T3 (enExample)
TW (1) TWI312358B (enExample)
WO (2) WO2003070781A1 (enExample)

Families Citing this family (76)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5807937A (en) * 1995-11-15 1998-09-15 Carnegie Mellon University Processes based on atom (or group) transfer radical polymerization and novel (co) polymers having useful structures and properties
JP2005517776A (ja) 2002-02-15 2005-06-16 ピーピージー インダストリーズ オハイオ， インコーポレイテッド イソブチレン型モノマーの交互コポリマーを含有する水系フィルム形成組成物
US7132477B2 (en) * 2002-02-15 2006-11-07 Ppg Industries Ohio, Inc. Powder coating compositions
CN1315935C (zh) * 2002-02-15 2007-05-16 Ppg工业俄亥俄公司 含有异丁烯共聚物的水性组合物
US6686432B2 (en) 2002-02-15 2004-02-03 Ppg Industries Ohio, Inc. Alternating copolymers of isobutylene type monomers
US6784248B2 (en) * 2002-02-15 2004-08-31 Ppg Industries Ohio, Inc. Thermosetting compositions containing alternating copolymers of isobutylene type monomers
ATE332934T1 (de) * 2003-03-12 2006-08-15 Ciba Sc Holding Ag Hydroxylaminester enthaltende beschichtungszusammensetzung
US20050032978A1 (en) * 2003-08-06 2005-02-10 O'dwyer James B. Etherified carbamate functional copolymers of isobutylene type monomers, and their use in curable compositions
US7105588B2 (en) * 2003-10-10 2006-09-12 E. I. Du Pont De Nemours And Company Screen printable hydrogel for medical applications
DE102004008772A1 (de) * 2004-02-23 2005-09-08 Institut für Neue Materialien Gemeinnützige GmbH Abriebbeständige und alkalibeständige Beschichtungen oder Formkörper mit Niedrigenergieoberfläche
US7893174B2 (en) * 2004-03-05 2011-02-22 Carnegie Mellon University Atom transfer radical polymerization process
DE602005013389D1 (de) * 2004-07-14 2009-04-30 3M Innovative Properties Co Dentalzusammensetzungen mit oxiran-monomeren
US20060025534A1 (en) * 2004-07-30 2006-02-02 Johnson Jeffery W High solids coating composition based on thermal initiated free-radical polymerization
US7335705B2 (en) * 2004-09-30 2008-02-26 Ppg Industries Ohio, Inc. Thermosetting coating compositions comprising a copolymer formed from chlorotrifluoroethylene and methods of making copolymers formed from chlorotrifluoroethylene
EP1794200B1 (en) * 2004-09-30 2009-05-27 PPG Industries Ohio, Inc. Fluoropolymers, methods for their production, and thermosetting compositions containing them
WO2006048708A2 (ja) * 2004-10-08 2006-05-11 Basf Coatings Japan Ltd. 塗料用水酸基含有樹脂組成物、塗料組成物、塗装仕上げ方法及び塗装物品
EP3733798B1 (en) 2004-10-20 2022-01-26 Swimc Llc Coating compositions for cans and methods of coating
US7594594B2 (en) 2004-11-17 2009-09-29 International Flavors & Fragrances Inc. Multi-compartment storage and delivery containers and delivery system for microencapsulated fragrances
US8241618B2 (en) * 2005-01-27 2012-08-14 Lubrizol Advanced Materials, Inc. Process for producing a hydrophobically modified polymer for use with personal care compositions
US20060182975A1 (en) * 2005-02-17 2006-08-17 Reichhold, Inc. Thermoset polymer substrates
DE102005023728A1 (de) * 2005-05-23 2006-11-30 Basf Coatings Ag Lackschichtbildendes Korrosionsschutzmittel und Verfahren zu dessen stromfreier Applikation
DE602006012336D1 (de) 2005-08-23 2010-04-01 Univ Carnegie Mellon Radikalische atomtransfer-polymerisation in mikroemulsion und echte emulsionspolymerisation
EP1943278B1 (en) * 2005-08-26 2010-10-06 Carnegie Mellon University Polymerization process with catalyst reactivation
JP2007126623A (ja) * 2005-10-05 2007-05-24 Dainippon Ink & Chem Inc 床用水性塗料および床塗工方法
US7547739B2 (en) * 2005-12-20 2009-06-16 E. I. Du Pont De Nemours And Company Powder coating composition providing low gloss
DE102005062442B4 (de) * 2005-12-27 2012-10-04 Lohmann Gmbh & Co. Kg Verfahren zur Herstellung eines bifunktionalen Haftklebesystems, bifunktionales Haftklebesystem und dessen Verwendung
AU2007204600A1 (en) * 2006-01-12 2007-07-19 John Lyndon Garnett Radiation curable system
EP1985640A4 (en) * 2006-01-20 2010-03-17 Hitachi Chemical Co Ltd RESIN COMPOSITION AND OPTICAL ELEMENT USING A CURED PRODUCT OF SUCH A RESIN COMPOSITION
RU2448127C2 (ru) * 2006-07-03 2012-04-20 Дау Корнинг Корпорейшн Химически отверждаемая "все в одном" уплотнение-проставка теплой кромки
JP5463612B2 (ja) * 2006-09-28 2014-04-09 横浜ゴム株式会社 ウレタンエマルジョン
US8367051B2 (en) * 2006-10-09 2013-02-05 Carnegie Mellon University Preparation of functional gel particles with a dual crosslink network
DE102006053291A1 (de) * 2006-11-13 2008-05-15 Basf Coatings Ag Lackschichtbildendes Korrosionsschutzmittel mit guter Haftung und Verfahren zu dessen stromfreier Applikation
DE102006053292A1 (de) * 2006-11-13 2008-05-15 Basf Coatings Ag Lackschichtbildendes Korrosionsschutzmittel mit verminderter Rißbildung und Verfahren zu dessen stromfreier Applikation
US7737223B2 (en) * 2006-12-19 2010-06-15 Ppg Industries Ohio, Inc. Coating compositions containing amine-hydroxy functional polymer and/or amine-carbamate functional polymer
DE102007012406A1 (de) * 2007-03-15 2008-09-18 Basf Coatings Ag Verfahren zur Korrosionsschutzausrüstung metallischer Substrate
US7790202B1 (en) * 2007-04-09 2010-09-07 Martell Helen D Multi-purpose skin composition
US8865797B2 (en) * 2007-05-23 2014-10-21 Carnegie Mellon University Hybrid particle composite structures with reduced scattering
WO2008148000A1 (en) 2007-05-23 2008-12-04 Carnegie Mellon University Atom transfer dispersion polymerization
CN101687220B (zh) * 2007-06-20 2013-05-29 关西涂料株式会社 形成多层涂膜的方法
JP4986779B2 (ja) 2007-09-13 2012-07-25 株式会社リコー 感熱記録材料
US20090298989A1 (en) * 2008-05-28 2009-12-03 Funston Sr Randall A 2K Waterborne Polyurethane Coating System and Methods Thereof
CN102076427B (zh) * 2008-06-24 2013-10-30 关西涂料株式会社 多层涂膜形成方法
US7763350B2 (en) * 2008-07-01 2010-07-27 Ppg Industries Ohio, Inc. Coated articles demonstrating heat reduction and noise reduction properties
US20100004353A1 (en) * 2008-07-01 2010-01-07 Ppg Industries Ohio, Inc. Waterborne film-forming compositions having heat reflective properties
KR101540688B1 (ko) * 2008-11-12 2015-07-31 주식회사 케이씨씨 아크릴 수지를 포함하는 투명 도료 조성물
US20100160561A1 (en) * 2008-12-24 2010-06-24 Ppg Industries Ohio, Inc. Copolymers of alpha-olefin type monomers and curable film-forming compositions containing them
DE102009007632A1 (de) 2009-02-05 2010-08-12 Basf Coatings Ag Beschichtungsmittel für korrosionsstabile Lackierungen
GB2481561B (en) 2009-03-27 2013-12-11 Univ Carnegie Mellon Preparation of functional star macromolecules
US8993070B2 (en) * 2009-09-28 2015-03-31 Carrier Corporation Dual powder coating method for aluminum substrates
KR101212668B1 (ko) * 2009-11-20 2012-12-14 제일모직주식회사 고분자, 보호막 조성물 및 이를 이용한 패턴 형성 방법
TWI565779B (zh) * 2010-05-13 2017-01-11 明基材料股份有限公司 黏著劑之組成物及其製造方法
WO2012059490A1 (en) * 2010-11-02 2012-05-10 Akzo Nobel Coatings International B.V. Matte textured powder monocoat coating compositions
WO2012091965A1 (en) 2010-12-17 2012-07-05 Carnegie Mellon University Electrochemically mediated atom transfer radical polymerization
US20120184653A1 (en) * 2011-01-18 2012-07-19 Liang Wang Synthesis of linear phosphorus-containing functional fluorocopolymer
JP5587230B2 (ja) * 2011-03-25 2014-09-10 富士フイルム株式会社 太陽電池用バックシート及びその製造方法、並びに太陽電池モジュール
WO2013028756A1 (en) 2011-08-22 2013-02-28 Carnegie Mellon University Atom transfer radical polymerization under biologically compatible conditions
CN103597585B (zh) * 2011-10-24 2016-10-19 帕莱斯化学株式会社 固定研磨粒线锯用水溶性切割液、使用其的切割方法及其回收方法
US9533297B2 (en) 2012-02-23 2017-01-03 Carnegie Mellon University Ligands designed to provide highly active catalyst complexes
US9259821B2 (en) * 2014-06-25 2016-02-16 Rohm And Haas Electronic Materials Cmp Holdings, Inc. Chemical mechanical polishing layer formulation with conditioning tolerance
US9982070B2 (en) 2015-01-12 2018-05-29 Carnegie Mellon University Aqueous ATRP in the presence of an activator regenerator
WO2016191591A1 (en) 2015-05-26 2016-12-01 Saint-Gobain Adfors Canada, Ltd. Glass mat reinforcement
KR102585109B1 (ko) 2015-09-02 2023-10-05 가부시끼가이샤 쓰리본드 광경화성 수지 조성물, 연료전지 및 밀봉 방법
EP3347422B1 (en) * 2015-09-11 2022-03-16 PPG Industries Ohio, Inc. Curable coating compositions containing poly activated methylene resins and polyisocyanates
CN108602918B (zh) 2016-02-11 2021-07-06 汉高知识产权控股有限责任公司 具有侧接羟基官能团的烯烃-丙烯酸酯共聚物及其用途
CN109153767B (zh) 2016-05-24 2021-09-24 巴斯夫涂料有限公司 涂覆剂和由其制备的具有改进抗污性和清洁性的涂层及其用途
JP6940605B2 (ja) 2016-10-19 2021-09-29 エスダブリューアイエムシー・エルエルシー アクリルポリマー及びこのようなポリマーを含有する組成物
JP6762209B2 (ja) * 2016-11-29 2020-09-30 ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツングＢＡＳＦ Ｃｏａｔｉｎｇｓ ＧｍｂＨ アクリル樹脂及びメラミン樹脂を主体樹脂とするトップコート用塗料組成物
WO2018132582A1 (en) 2017-01-12 2018-07-19 Carnegie Mellon University Surfactant assisted formation of a catalyst complex for emulsion atom transfer radical polymerization processes
US10370555B2 (en) 2017-05-16 2019-08-06 Ppg Industries Ohio, Inc. Curable film-forming compositions containing hydroxyl functional acrylic polymers and bisurea compounds and multilayer composite coatings
US11591464B2 (en) 2017-07-14 2023-02-28 Ppg Industries Ohio, Inc. Curable film-forming compositions containing reactive functional polymers and polysiloxane resins, multilayer composite coatings, and methods for their use
BR112021008517A2 (pt) * 2018-11-02 2021-08-03 Momentive Performance Materials Inc. revestimentos com resistência precoce à água
CN110003441B (zh) * 2019-04-22 2021-06-22 广州大学 一种uv固化水性异氰酸酯接枝氟硅氧烷改性环氧丙烯酸树脂的制备方法
CN111116815B (zh) * 2020-01-07 2021-08-20 复旦大学 一种三氟氯乙烯与乙烯基醚的光控制交替共聚方法
JP7533087B2 (ja) * 2020-09-30 2024-08-14 日油株式会社 共重合体、共重合体の製造方法、細胞凍結保存材及び細胞凍結保存液
CN114292567B (zh) * 2022-01-25 2022-07-15 中国科学院长春应用化学研究所 一种粉末涂料组合物及其制备厚度可控静电喷涂涂层的方法
CN118496468B (zh) * 2024-05-21 2025-02-18 旭川化学（苏州）有限公司 一种自修复聚氨酯材料及其制备方法和应用

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1213171A (en) * 1967-02-28 1970-11-18 Du Pont Polymerisation process
GB1339981A (en) * 1970-03-04 1973-12-05 Sumitomo Chemical Co Curable copolymers
US5115083A (en) * 1989-11-06 1992-05-19 The Lubrizol Corporation Curable aminoplast compositions and catalysts for curing same

Family Cites Families (104)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2411599A (en) 1940-11-09 1946-11-26 Standard Oil Dev Co Polymerization process
US2378629A (en) 1941-09-10 1945-06-19 Du Pont Copolymers of maleic anhydride
US2531196A (en) 1942-10-20 1950-11-21 Du Pont Vinyl polymers and process for producing the same
US2468664A (en) 1945-08-28 1949-04-26 Du Pont Tetrafluoroethylene copolymers
US2751367A (en) 1952-06-14 1956-06-19 American Cyanamid Co Friable polyacrylate powders
DE1045658B (de) 1956-07-23 1958-12-04 Roehm & Haas Gmbh Verfahren zur Herstellung von Derivaten der Polymethacrylsaeure aus Polymeth-acrylsaeuremethylester bzw. aus zum ueberwiegenden Teil aus Methacrylsaeure-methylester aufgebauten Mischpolymerisaten durch alkalische Hydrolyse oder durch Alkoholyse
GB1121614A (en) 1964-10-30 1968-07-31 Du Pont Elastomers
US3380974A (en) 1964-10-30 1968-04-30 Du Pont Tetrafluoroethylene, isobutylene, carboxylic copolymers
JPS4936822B1 (enExample) * 1970-03-04 1974-10-03
BE763732A (fr) 1970-03-04 1971-09-03 Sumitomo Chemical Co Interpolymere d'olefine et d'ester acrylique durcissable au soufre
US3984299A (en) 1970-06-19 1976-10-05 Ppg Industries, Inc. Process for electrodepositing cationic compositions
US4025407A (en) * 1971-05-05 1977-05-24 Ppg Industries, Inc. Method for preparing high solids films employing a plurality of curing mechanisms
US3947338A (en) 1971-10-28 1976-03-30 Ppg Industries, Inc. Method of electrodepositing self-crosslinking cationic compositions
CH582719A5 (enExample) * 1973-09-12 1976-12-15 Ciba Geigy Ag
JPS50136315A (enExample) 1974-04-17 1975-10-29
GB1469090A (en) 1974-06-27 1977-03-30 Ceskoslovenska Akademie Ved Polymers of acyloxyalkyl methacrylates method for their preparation
US4147688A (en) 1975-03-19 1979-04-03 Ppg Industries, Inc. Method of preparing dispersions of gelled polymeric microparticles and products produced thereby
US4043953A (en) * 1975-05-02 1977-08-23 Ppg Industries, Inc. Ambient temperature, moisture-curable acrylic-silane coating compositions having improved potlife
US4147679A (en) 1976-06-02 1979-04-03 Ppg Industries, Inc. Water-reduced urethane coating compositions
US4177301A (en) * 1977-01-28 1979-12-04 General Electric Company Primer compositions for adhering silicone compositions
US4147685A (en) * 1977-01-28 1979-04-03 General Electric Company Primer compositions for adhering silicone compositions
NZ186925A (en) 1977-04-25 1979-12-11 Ici Ltd Top-coating based on a basecoat and top-coat compositions not requiring an intermediate baking operation
DE3166673D1 (en) 1980-04-14 1984-11-22 Ici Plc Multi-layer coating process involving use of aqueous basecoat composition containing crosslinked polymer microparticles and having a pseudoplastic or thixotropic character
US4303581A (en) 1980-07-16 1981-12-01 Ppg Industries, Inc. Water dispersed primer-surfacer composition
JPS6021686B2 (ja) 1980-08-08 1985-05-29 旭硝子株式会社 常温硬化可能な含フツ素共重合体
US4681918A (en) 1981-06-30 1987-07-21 E. I. Du Pont De Nemours And Company "Living" polymers and process for their preparation
US4468307A (en) 1981-09-14 1984-08-28 Ppg Industries, Inc. Method of cationic electrodeposition
JPS58136605A (ja) 1982-02-05 1983-08-13 Asahi Glass Co Ltd カルボキシル基含有含フツ素重合体の製造方法
US4493056A (en) 1982-06-30 1985-01-08 International Business Machines Corporation RAM Utilizing offset contact regions for increased storage capacitance
DE3328276A1 (de) 1983-08-05 1985-02-21 Hoechst Ag, 6230 Frankfurt Polyacrylnitrile mit geringem k-wert, verfahren zu ihrer herstellung und geeignete verwendung
US4487860A (en) * 1983-12-05 1984-12-11 Scm Corporation Aqueous self-curing polymeric blends
JPS60206621A (ja) * 1984-03-31 1985-10-18 Kureha Chem Ind Co Ltd 弗化ビニリデン系樹脂フイルム，その製法および金属化フイルム
JPS6128544A (ja) 1984-07-20 1986-02-08 Nippon Oil & Fats Co Ltd 熱硬化性樹脂組成物
GB8510690D0 (en) * 1985-04-26 1985-06-05 Bostik Ltd Moisture curable sealants
US4681811A (en) 1985-08-19 1987-07-21 Ppg Industries, Inc. Color plus clear coatings employing polyepoxides and polyacid curing agents in the clear coat
US4732790A (en) 1986-08-21 1988-03-22 Ppg Industries, Inc. Color plus clear application of thermosetting high solids coating composition of hydroxy-functional epoxies and anhydrides
US5214101A (en) 1986-09-29 1993-05-25 Ppg Industries, Inc. Powder coating composition comprising a co-reactable particulate mixture of carboxylic acid group-containing polymers and beta-hydroxyalkylamide curing agent
US4937288A (en) 1986-09-29 1990-06-26 Ppg Industries, Inc. Powder coating composition
JP2609256B2 (ja) * 1987-07-21 1997-05-14 鐘淵化学工業株式会社 硬化性組成物
KR910004817B1 (ko) 1987-07-31 1991-07-13 니혼유시 가부시기가이샤 열경화성분체도료조성물
US4798746A (en) 1987-08-24 1989-01-17 Ppg Industries, Inc. Basecoat/clearcoat method of coating utilizing an anhydride additive in the thermoplastic polymer-containing basecoat for improved repairability
MX169697B (es) * 1987-12-28 1993-07-19 Ppg Industries Inc Mejoras a composiciones fraguables por radiacion basadas sobre poliesteres insaturados y compuestos teniendo por lo menos dos grupos de vinil eter
US4889890A (en) 1987-12-30 1989-12-26 Ppg Industries, Inc. Powder coating curing system containing a beta-hydroxyalkylamide
US4877837A (en) * 1988-10-07 1989-10-31 The Glidden Company Epoxy functional and silicone thermosetting powder coatings
DE68911264T2 (de) 1988-10-21 1994-05-19 Akzo Nv Wasserverdünnbare Beschichtungen und Bindemittelsysteme für die Verwendung in diesen Beschichtungen.
US5084541A (en) 1988-12-19 1992-01-28 American Cyanamid Company Triazine crosslinking agents and curable compositions
US4997900A (en) 1988-12-27 1991-03-05 Cargill, Incorporated Powder coating comprising acetone oxime blocked diisocyanate and polyester
US4968751A (en) * 1989-03-20 1990-11-06 The Glidden Company Acrylic/silicone resins for powder coatings
US5071904A (en) 1989-05-30 1991-12-10 Ppg Industries, Inc. Waterborne coating compositions for automotive applications
US5202382A (en) 1989-09-18 1993-04-13 Ppg Industries, Inc. Thermosetting powder coating composition containing a mixture of low Tg and high Tg polymers with acid functional groups
US5098955A (en) 1989-09-18 1992-03-24 Ppg Industries, Inc. Powder coating composition low Tg and high Tg polymers with acid groups
US5025085A (en) * 1989-11-06 1991-06-18 The Lubrizol Corporation Curable aminoplast compositions and catalysts for curing same
US5182355A (en) 1990-04-05 1993-01-26 Ppg Industries, Inc. Polyurethane polyanhydride oligomers and method of preparation
JP3097093B2 (ja) 1990-04-20 2000-10-10 ダイキン工業株式会社 含フッ素共重合体およびそれを用いた硬化用組成物
US5096556A (en) 1990-06-25 1992-03-17 Ppg Industries, Inc. Cationic microgels and their use in electrodeposition
JPH07110890B2 (ja) * 1990-06-29 1995-11-29 ダイキン工業株式会社 含フッ素共重合体およびそれを用いた塗料用組成物
US5216081A (en) * 1990-06-29 1993-06-01 Daikin Industries, Ltd. Fluorine-containing copolymer and curable composition containing the same
US5239012A (en) 1991-02-21 1993-08-24 Ppg Industries, Inc. Ambient temperature curing compositions containing a hydroxy component and an anhydride component and an onium salt
DE4123478A1 (de) 1991-07-16 1993-01-21 Goldschmidt Ag Th Polyacrylsaeureester mit quaternaeren ammonium- und langkettigen kohlenwasserstoffoxy-gruppen
US5424380A (en) * 1991-10-31 1995-06-13 Tosoh Corporation Resin composition
US5270391A (en) * 1991-11-27 1993-12-14 Mitsui Toatsu Chemicals, Inc. Composition for thermosetting powder coating
US5508337A (en) 1992-02-11 1996-04-16 Bayer Aktiengesellschaft Powder coating compositions, a process for their preparation, and their use for the coating of heat resistant substrates
US5356973A (en) 1992-08-31 1994-10-18 Ppg Industries, Inc. Aqueous based coating compositions having improved metallic pigment orientation
US5605965A (en) 1992-10-23 1997-02-25 Basf Corporation High gloss and/or high DOI coating utilizing carbamate-functional polymer composition
GB9222490D0 (en) 1992-10-26 1992-12-09 Rohm & Haas Means for imparting improved adhesion to polypropylene substrates
TW242644B (enExample) 1992-10-30 1995-03-11 Ppg Industries Inc
DE4306537A1 (de) 1993-03-03 1994-09-08 Goldschmidt Ag Th Polymethacrylsäureester, deren Estergruppen in alpha- und gegebenenfalls zusätzlich in omega-Stellung von den in der Kette befindlichen Estergruppen abweichen
US5407707A (en) 1993-11-01 1995-04-18 Ppg Industries, Inc. Powder coating composition based on epoxy containing polymers and polyacid curing agents
US5554692A (en) 1994-01-06 1996-09-10 Ferro Corporation Blocked isocyanate crosslinkers based on pentaerythritol for use in thermosetting coatings
DE4406157A1 (de) 1994-02-25 1995-08-31 Bayer Ag Pulverlack und seine Verwendung
EP0755420B1 (en) 1994-04-13 1999-10-20 PPG Industries Ohio, Inc. Thermosetting powder coating compositions
US5976701A (en) 1994-04-29 1999-11-02 Ppg Industries Ohio, Inc. Flexible aminoplast-curable film-forming compositions and composite coating
US5508349A (en) 1994-05-09 1996-04-16 Basf Corporation Reactive flow agent for powder coatings
US5763548A (en) 1995-03-31 1998-06-09 Carnegie-Mellon University (Co)polymers and a novel polymerization process based on atom (or group) transfer radical polymerization
US5807937A (en) 1995-11-15 1998-09-15 Carnegie Mellon University Processes based on atom (or group) transfer radical polymerization and novel (co) polymers having useful structures and properties
US5777061A (en) 1996-02-14 1998-07-07 Bayer Corporation Blocked polyisocyanate crosslinkers for providing improved flow properties to coating compositions
EP0880565B1 (en) 1996-02-16 1999-09-29 PPG Industries Ohio, Inc. Coating compositions with flow modifiers and the flow modifiers and multilayered coatings
US5703176B1 (en) 1996-03-18 2000-10-03 Para Chem Southern Inc Polyacrylate thickener and method for making same
US5789487A (en) 1996-07-10 1998-08-04 Carnegie-Mellon University Preparation of novel homo- and copolymers using atom transfer radical polymerization
US5820987A (en) 1996-08-21 1998-10-13 Ppg Industries, Inc. Cationic electrocoating compositions, method of making, and use
US6077608A (en) 1996-09-19 2000-06-20 Ppg Industries Ohio, Inc. Multilayered coating with powder clear coating and substrates therewith and method
US6114489A (en) 1997-03-27 2000-09-05 Herberts Gmbh Reactive hyperbranched polymers for powder coatings
DE19721728C2 (de) 1997-05-24 2001-07-12 Byk Chemie Gmbh Dispergiermittel für Pigmente oder Füllstoffe auf der Basis von Acrylsäurealkylester-Polymeren, Verwendung und Verfahren zur Herstellung
DE69924974T2 (de) 1998-02-18 2006-02-23 PPG Industries Ohio, Inc., Cleveland Mehrkomponentige zusammengesetzte beschichtungsmasse und beschichtetes substrat
WO1999047616A1 (en) 1998-03-18 1999-09-23 Ppg Industries Ohio, Inc. Coating compositions comprising a fluorinated terpolymer
US6365666B1 (en) * 1998-08-31 2002-04-02 Ppg Industries Ohio, Inc. Electrodepositable coating compositions comprising onium salt group-containing polymers prepared by atom transfer radical polymerization
US6191225B1 (en) * 1998-08-31 2001-02-20 Ppg Industries Ohio, Inc. Thermosetting compositions containing carboxylic acid functional polymers and epoxy functional polymers prepared by atom transfer radical polymerization
US6306965B1 (en) 1998-08-31 2001-10-23 Ppg Industries Ohio, Inc. Thermosetting compositions containing carbamate-functional polylmers prepared using atom transfer radical polymerization
US6355729B1 (en) * 1998-08-31 2002-03-12 Ppg Industries Ohio, Inc. Electrodepositable coating compositions comprising amine salt group-containing polymers prepared by atom transfer radical polymerization
US6319987B1 (en) * 1998-08-31 2001-11-20 Ppg Industries Ohio, Inc. Thermosetting compositions containing hydroxyl-functional polymers prepared using atom transfer radical polymerization
US6111001A (en) 1998-11-24 2000-08-29 Ppg Industries Ohio, Inc. Compositions containing rheology modifiers with functional group-containing polymers
US6054549A (en) 1998-11-25 2000-04-25 Dow Corning Asia, Ltd. Alkenyl ether functional polyisobutylenes and methods for the preparation thereof
US6069185A (en) 1998-11-25 2000-05-30 Dow Corning Asia, Ltd. Radiation curable compositions containing alkenyl ether functional polyisobutylenes
US6197883B1 (en) 1999-06-03 2001-03-06 Ppg Industries Ohio, Inc. Thermosetting coating compositions containing flow modifiers prepared by controlled radical polymerization
DE19928353C1 (de) 1999-06-21 2001-02-22 Roehm Gmbh Poly(meth)acrylatplastisole mit verbesserter Weichmacherverträglichkeit, Verfahren zu ihrer Herstellung sowie Verwendung
US6423778B1 (en) 1999-06-30 2002-07-23 Basf Corporation Process for coating olefinic substrates
US6414077B1 (en) * 1999-07-29 2002-07-02 Schnee-Morehead, Inc. Moisture curable acrylic sealants
US6348554B1 (en) * 1999-11-30 2002-02-19 Rohmax Additives Gmbh Method for preparation of a liquid polymer composition and use of this composition
US6451928B1 (en) 2000-09-21 2002-09-17 Ppg Industries Ohio, Inc. Aminoplast-based crosslinkers and powder coating compositions containing such crosslinkers
US6875832B2 (en) * 2001-04-24 2005-04-05 Ppg Industries Ohio, Inc. Synthesis of vinyl polymers by controlled radical polymerization
US6686432B2 (en) * 2002-02-15 2004-02-03 Ppg Industries Ohio, Inc. Alternating copolymers of isobutylene type monomers
US6784248B2 (en) * 2002-02-15 2004-08-31 Ppg Industries Ohio, Inc. Thermosetting compositions containing alternating copolymers of isobutylene type monomers
US6677422B2 (en) * 2002-02-15 2004-01-13 Ppg Industries Ohio, Inc. Method of making alternating copolymers of isobutylene type monomers
CN1315935C (zh) * 2002-02-15 2007-05-16 Ppg工业俄亥俄公司 含有异丁烯共聚物的水性组合物

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1213171A (en) * 1967-02-28 1970-11-18 Du Pont Polymerisation process
GB1339981A (en) * 1970-03-04 1973-12-05 Sumitomo Chemical Co Curable copolymers
US5115083A (en) * 1989-11-06 1992-05-19 The Lubrizol Corporation Curable aminoplast compositions and catalysts for curing same

Also Published As

Publication number Publication date
US20030199640A1 (en) 2003-10-23
DE60322666D1 (de) 2008-09-18
US20030187145A1 (en) 2003-10-02
CA2476090C (en) 2011-03-29
KR100611868B1 (ko) 2006-08-11
ES2318146T3 (es) 2009-05-01
EP1474479A2 (en) 2004-11-10
EP1474454B1 (en) 2009-11-18
WO2003070781A1 (en) 2003-08-28
KR20040091053A (ko) 2004-10-27
US20030166787A1 (en) 2003-09-04
AU2003210715B2 (en) 2006-04-06
ES2309302T3 (es) 2008-12-16
AU2003216252A1 (en) 2003-09-09
US20040245114A1 (en) 2004-12-09
US20030171498A1 (en) 2003-09-11
AU2003210715A1 (en) 2003-09-09
JP2007023300A (ja) 2007-02-01
EP1474479B1 (en) 2008-08-06
JP2005517790A (ja) 2005-06-16
CA2476090A1 (en) 2003-08-28
US6803413B2 (en) 2004-10-12
TWI312358B (en) 2009-07-21
US7122600B2 (en) 2006-10-17
DE60322022D1 (de) 2008-08-21
US7019041B2 (en) 2006-03-28
JP2009155664A (ja) 2009-07-16
JP2005517775A (ja) 2005-06-16
WO2003070826A2 (en) 2003-08-28
EP1474454A1 (en) 2004-11-10
ES2334562T3 (es) 2010-03-12
CN1639204A (zh) 2005-07-13
WO2003070826A3 (en) 2003-11-13
US6784247B2 (en) 2004-08-31
CA2476079A1 (en) 2003-08-28
US6784248B2 (en) 2004-08-31
US20040142178A1 (en) 2004-07-22
JP2007332381A (ja) 2007-12-27
JP3993563B2 (ja) 2007-10-17
US20030171497A1 (en) 2003-09-11
US20040242777A1 (en) 2004-12-02
JP4219277B2 (ja) 2009-02-04
US6900279B2 (en) 2005-05-31
TW200304467A (en) 2003-10-01
DE60325553D1 (de) 2009-02-12
US20040249075A1 (en) 2004-12-09
US7132476B2 (en) 2006-11-07
US6803426B2 (en) 2004-10-12
US7125931B2 (en) 2006-10-24
ES2311716T3 (es) 2009-02-16
BR0307577A (pt) 2005-01-11
DE60330118D1 (de) 2009-12-31

Similar Documents

Publication Publication Date Title
CN1300185C (zh) 含有异丁烯型单体交替共聚物的热固性组合物
CN1305920C (zh) 异丁烯型单体的交替共聚物
CN100335519C (zh) 含有聚氨酯分散体和高度交联的聚合物颗粒的涂料组合物
CN1105759C (zh) 防污染涂料组合物
CN1073137C (zh) 水基涂料用固化性树脂组合物
CN1131876C (zh) 水性反应性腻子(ⅰ)
CN1163559C (zh) 涂料组合物及制法和无机氧化物溶胶分散组分的制法
CN1222556C (zh) 接枝共聚物颜料分散剂
CN1182173C (zh) 具有改进的早期硬度及耐水性的透明涂料组合物
CN100349924C (zh) 高度交联的聚合物颗粒和含有该颗粒的涂料组合物
CN1265117A (zh) 一种直至成膜一直保持化学及物理稳定的活性胶乳共混物的制备方法
CN1246400C (zh) 不含表面活性剂的水性乳液
CN1278847A (zh) 水溶性聚合组合物
CN1654570A (zh) 金属底漆组合物和生产复合涂膜的方法
CN1025206C (zh) 涂料及其涂敷制品的方法
CN1639210A (zh) 异丁烯型单体交替共聚物的制造方法
CN1308358C (zh) 含异丁烯型单体交替共聚物的水性成膜用组合物
CN1069672C (zh) 热固性粉末涂料、该涂料的涂覆方法以及采用这种涂料涂覆的物品
CN1087361A (zh) 含有复合聚合物颗粒的涂料组合物
CN1032478C (zh) 着色的涂料组合物及其制备方法和用途
CN1244654C (zh) 涂料组合物
CN1008186B (zh) 加聚物的水分散相，由此产生的涂料组合物以及涂布底物的方法
CN1537152A (zh) 防污染剂、含该防污染剂的涂料用组合物以及涂装物品
CN1806019A (zh) 含溶剂的可热固化和/或光化辐照固化且没有盖底颜料的涂覆材料；其制备及用途
CN100343284C (zh) 乙烯基类聚合物、乙烯基类聚合物的制造方法、热固化性被覆用组合物和涂料

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
EE01 Entry into force of recordation of patent licensing contract

Assignee: PPG industrial coatings (Suzhou) Co., Ltd.

Assignor: PPG Industries, Inc.

Contract record no.: 2012990000290

Denomination of invention: Thermosetting compositions containing alternating copolymers of isobutylene type monomers

Granted publication date: 20070214

License type: Common License

Open date: 20050713

Record date: 20120504

EE01 Entry into force of recordation of patent licensing contract

Assignee: PPG Ind Ohio Inc.

Assignor: PPG Industries, Inc.

Contract record no.: 2012990000336

Denomination of invention: Thermosetting compositions containing alternating copolymers of isobutylene type monomers

Granted publication date: 20070214

License type: Common License

Open date: 20050713

Record date: 20120521

CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20070214

Termination date: 20150129

EXPY Termination of patent right or utility model
EC01 Cancellation of recordation of patent licensing contract

Assignee: PPG industrial coatings (Suzhou) Co., Ltd.

Assignor: PPG Industries, Inc.

Contract record no.: 2012990000290

Date of cancellation: 20170228

LICC Enforcement, change and cancellation of record of contracts on the licence for exploitation of a patent or utility model
EC01 Cancellation of recordation of patent licensing contract
EC01 Cancellation of recordation of patent licensing contract

Assignee: PPG Ind Ohio Inc.

Assignor: PPG Industries, Inc.

Contract record no.: 2012990000336

Date of cancellation: 20170320