CN1274701C - 用于烯烃聚合的含有桥接4－苯基－茚基配体的金属茂 - Google Patents

用于烯烃聚合的含有桥接4－苯基－茚基配体的金属茂 Download PDF

Info

Publication number
CN1274701C
CN1274701C CNB018133959A CN01813395A CN1274701C CN 1274701 C CN1274701 C CN 1274701C CN B018133959 A CNB018133959 A CN B018133959A CN 01813395 A CN01813395 A CN 01813395A CN 1274701 C CN1274701 C CN 1274701C
Authority
CN
China
Prior art keywords
indenyl
alkyl
bases
phenyl
rac
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CNB018133959A
Other languages
English (en)
Chinese (zh)
Other versions
CN1444593A (zh
Inventor
M·C·库奇塔
U·M·斯特林
R·T·李
W·T·海古德
T·J·伯克哈特
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/619,749 external-priority patent/US6376407B1/en
Priority claimed from US09/620,304 external-priority patent/US6376412B1/en
Priority claimed from US09/620,198 external-priority patent/US6380330B1/en
Priority claimed from US09/619,748 external-priority patent/US6376627B1/en
Priority claimed from US09/620,303 external-priority patent/US6414095B1/en
Priority claimed from US09/620,302 external-priority patent/US6376411B1/en
Priority claimed from US09/619,752 external-priority patent/US6399723B1/en
Priority claimed from US09/620,522 external-priority patent/US6380124B1/en
Priority claimed from US09/619,764 external-priority patent/US6376409B1/en
Priority claimed from US09/620,175 external-priority patent/US6376410B1/en
Priority claimed from US09/619,750 external-priority patent/US6380120B1/en
Priority claimed from US09/619,759 external-priority patent/US6376408B1/en
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Publication of CN1444593A publication Critical patent/CN1444593A/zh
Application granted granted Critical
Publication of CN1274701C publication Critical patent/CN1274701C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CNB018133959A 2000-06-30 2001-05-21 用于烯烃聚合的含有桥接4－苯基－茚基配体的金属茂 Expired - Fee Related CN1274701C (zh)

Applications Claiming Priority (28)

Application Number Priority Date Filing Date Title
US21559700P 2000-06-30 2000-06-30
US21545900P 2000-06-30 2000-06-30
US60/215,597 2000-06-30
US60/215,459 2000-06-30
US09/620,303 US6414095B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/619,757 2000-07-19
US09/620,303 2000-07-19
US09/620,613 2000-07-19
US09/620,359 2000-07-19
US09/620,302 US6376411B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/619,764 2000-07-19
US09/619,752 US6399723B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/619,750 2000-07-19
US09/620,522 US6380124B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,046 2000-07-19
US09/619,751 2000-07-19
US09/619,749 US6376407B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/619,750 US6380120B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,304 US6376412B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/619,759 US6376408B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,302 2000-07-19
US09/620,175 US6376410B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,198 2000-07-19
US09/620,341 2000-07-19
US09/619,764 US6376409B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/619,749 2000-07-19
US09/619,748 US6376627B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,198 US6380330B1 (en) 2000-06-30 2000-07-19 Metallocene compositions

Publications (2)

Publication Number Publication Date
CN1444593A CN1444593A (zh) 2003-09-24
CN1274701C true CN1274701C (zh) 2006-09-13

Family

ID=27585092

Family Applications (2)

Application Number Title Priority Date Filing Date
CNB018133959A Expired - Fee Related CN1274701C (zh) 2000-06-30 2001-05-21 用于烯烃聚合的含有桥接4－苯基－茚基配体的金属茂
CNB018134017A Expired - Lifetime CN1332966C (zh) 2000-06-30 2001-05-21 桥接双(茚基)金属茂化合物

Family Applications After (1)

Application Number Title Priority Date Filing Date
CNB018134017A Expired - Lifetime CN1332966C (zh) 2000-06-30 2001-05-21 桥接双(茚基)金属茂化合物

Country Status (6)

Country Link
EP (2) EP1632506A1 (enExample)
JP (1) JP2004502699A (enExample)
CN (2) CN1274701C (enExample)
AT (1) ATE300550T1 (enExample)
DE (1) DE60112307T8 (enExample)
WO (1) WO2002002576A1 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105829326B (zh) * 2013-12-19 2019-11-08 埃克森美孚化学专利公司 桥连双(茚基)过渡金属络合物、其制备与应用

Families Citing this family (187)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10158656A1 (de) * 2001-11-30 2003-06-26 Basell Polyolefine Gmbh Organoübergangsmetallverbindung, Biscyclopentadienylligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen
US7091292B2 (en) 2002-04-24 2006-08-15 Symyx Technologies, Inc. Bridged bi-aromatic catalysts, complexes, and methods of using the same
US7060848B2 (en) 2002-04-24 2006-06-13 Symyx Technologies, Inc. Bridged bi-aromatic catalysts, complexes, and methods of using the same
US6897276B2 (en) 2002-04-24 2005-05-24 Symyx Technologies, Inc. Bridged bi-aromatic ligands, catalysts, processes for polymerizing and polymers therefrom
US6995279B2 (en) 2002-08-02 2006-02-07 Chisso Corporation Metallocene compounds, processes for the production of olefin polymers using catalysts containing the compounds, and olefin polymers produced by the processes
US7189790B2 (en) 2003-09-30 2007-03-13 Japan Polypropylene Corporation Catalyst component for olefin polymerization, catalyst for α-olefin polymerization and process for the production of α-olefin polymer
JP4590037B2 (ja) * 2003-09-30 2010-12-01 日本ポリプロ株式会社 オレフィン重合用触媒成分、α−オレフィン重合用触媒及びα−オレフィン重合体の製造方法
RU2007106716A (ru) 2004-07-22 2008-08-27 Базелль Полиолефине Гмбх (De) Способ получения фракционируемых полимеров 1-бутена
US7776978B2 (en) 2004-07-22 2010-08-17 Basell Polyolefine Gmbh Process for producing fractionable 1-butene polymers
KR101195320B1 (ko) * 2004-08-09 2012-10-29 다우 글로벌 테크놀로지스 엘엘씨 중합체를 제조하기 위한 지지된비스(하이드록시아릴아릴옥시) 촉매
CN101415737B (zh) * 2006-02-02 2013-06-12 巴塞尔聚烯烃股份有限公司 丙烯熔喷树脂、丙烯熔喷树脂纤维和用所述纤维制备的非织造织物及其制备方法
US7943711B2 (en) * 2007-05-14 2011-05-17 Exxonmobil Chemical Patents Inc. Ethylene elastomer compositions
EP2235071A2 (en) 2007-10-25 2010-10-06 Novolen Technology Holdings, C.V. Metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo and copolymers
EP2203483B1 (en) 2007-10-25 2014-04-09 Lummus Novolen Technology Gmbh Metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo-and copolymers
BRPI0722163A2 (pt) * 2007-10-25 2014-03-18 Lummus Novolen Technology Gmbh Síntese racemoseletiva de compostos de ansa-metaloceno, compostos de ansa-metaloceno, catalisadores compreendendo os mesmos, processo para produzir um polímero de olefina pelo uso dos catalisadores, e homo- e copolímeros de olefina
EP2103634A1 (en) 2008-03-20 2009-09-23 ExxonMobil Chemical Patents Inc. Production of propylene-based polymers
KR101351103B1 (ko) * 2008-12-31 2014-01-14 루머스 노보렌 테크놀로지 게엠베하 신규한 메탈로센 화합물, 이를 포함하는 촉매, 이 촉매를 사용한 올레핀 중합체의 제조방법, 및 올레핀 호모중합체 및 공중합체
JP5456343B2 (ja) * 2009-02-03 2014-03-26 日本ポリプロ株式会社 メタロセン錯体およびそれを含むオレフィン重合用触媒
US8501881B2 (en) 2009-11-13 2013-08-06 Borealis Ag Process for olefin polymerization
EP2322568B1 (en) 2009-11-13 2013-05-15 Borealis AG Process for producing an olefin polymerization catalyst
WO2011058089A1 (en) 2009-11-13 2011-05-19 Borealis Ag Process for producing a polymerization catalyst
EP2499169B1 (en) 2009-11-13 2014-04-02 Borealis AG Process for recovering a transition metal compound
EP2330136B1 (en) 2009-12-07 2013-08-28 Borealis AG Process for the preparation of an unsupported, solid metallocene catalyst system and its use in polymerization of olefins
JP5966321B2 (ja) * 2010-11-19 2016-08-10 日本ポリプロ株式会社 メタロセン錯体およびオレフィンの重合方法
EP2495037B1 (en) 2011-03-02 2020-08-19 Borealis AG High throughput reactor assembly for polymerization of olefins
HUE052511T2 (hu) 2011-03-02 2021-05-28 Borealis Ag Eljárás polimerek elõállítására
EP2532687A3 (en) 2011-06-10 2013-04-10 Borealis AG Bridged Metallocene Catalysts
ES2605429T3 (es) 2011-06-15 2017-03-14 Borealis Ag Mezcla del reactor in situ de un polipropileno nucleado catalizado por Ziegler-Natta y un polipropileno catalizado por metaloceno
JP5880000B2 (ja) * 2011-12-14 2016-03-08 日本ポリプロ株式会社 メタロセン錯体およびオレフィンの重合方法
WO2014032794A1 (en) 2012-08-29 2014-03-06 Borealis Ag Reactor assembly and method for polymerization of olefins
ES2711081T3 (es) 2012-10-18 2019-04-30 Borealis Ag Catalizador para la polimerización de olefinas
EP2722346A1 (en) 2012-10-18 2014-04-23 Borealis AG Polymerisation process and catalyst
ES2622627T3 (es) 2012-10-18 2017-07-06 Borealis Ag Procedimiento de polimerización
EP2745927A1 (en) 2012-12-21 2014-06-25 Borealis AG Fluidized bed reactor with internal moving bed reaction unit
EP2745926A1 (en) 2012-12-21 2014-06-25 Borealis AG Gas phase polymerization and reactor assembly comprising a fluidized bed reactor and an external moving bed reactor
CN104870462B (zh) 2012-12-21 2018-04-10 博里利斯股份公司 催化剂
ES2645256T3 (es) 2012-12-21 2017-12-04 Borealis Ag Catalizadores
EP2746301B1 (en) 2012-12-21 2018-05-30 Borealis AG Catalyst
WO2015009479A1 (en) 2013-07-17 2015-01-22 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
US9938364B2 (en) 2013-07-17 2018-04-10 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
CN105358586A (zh) * 2013-07-17 2016-02-24 埃克森美孚化学专利公司 环丙基取代的茂金属催化剂
CN105358589B (zh) * 2013-07-17 2018-07-03 埃克森美孚化学专利公司 金属茂和由其衍生的催化剂组合物
CN105377905B (zh) 2013-07-17 2018-09-14 埃克森美孚化学专利公司 茂金属和由其衍生的催化剂组合物
EP3022236B1 (en) 2013-07-17 2017-11-15 ExxonMobil Chemical Patents Inc. Process using substituted metallocene catalysts and products therefrom
EP2829558B1 (en) 2013-07-24 2016-12-14 Borealis AG Process
ES2607378T3 (es) 2013-07-24 2017-03-31 Borealis Ag Proceso
ES2651456T3 (es) 2013-08-14 2018-01-26 Borealis Ag Composición de propileno con mejor resistencia al impacto a baja temperatura
BR112016003128B1 (pt) 2013-08-21 2021-08-24 Borealis Ag Composição de poliolefina de alto fluxo com alta rigidez e resistência e artigos automotivos
MX2016001705A (es) 2013-08-21 2016-05-18 Borealis Ag Composicion de poliolefina de alto flujo con alta rigidez y tenacidad.
EP2853563B1 (en) 2013-09-27 2016-06-15 Borealis AG Films suitable for BOPP processing from polymers with high XS and high Tm
ES2568615T3 (es) 2013-10-11 2016-05-03 Borealis Ag Película para etiquetas orientada en la dirección de la máquina
WO2015059229A1 (en) 2013-10-24 2015-04-30 Borealis Ag Low melting pp homopolymer with high content of regioerrors and high molecular weight
EP2865713B1 (en) 2013-10-24 2016-04-20 Borealis AG Blow molded article based on bimodal random copolymer
WO2015065676A1 (en) * 2013-10-28 2015-05-07 Exxonmobil Chemical Patents Inc. Processes using staged hydrogen addition
US9279024B2 (en) 2013-10-28 2016-03-08 Exxonmobil Chemical Patents Inc. Processes using staged hydrogen addition
WO2015062936A1 (en) 2013-10-29 2015-05-07 Borealis Ag Solid single site catalysts with high polymerisation activity
WO2015065681A1 (en) * 2013-10-29 2015-05-07 Exxonmobil Chemical Patents Inc. Asymmetric polypropylene catalysts
US9266910B2 (en) 2013-10-29 2016-02-23 Exxonmobil Chemical Patents Inc. Asymmetric polypropylene catalysts
EA031527B1 (ru) 2013-11-22 2019-01-31 Бореалис Аг Гомополимер пропилена с низкой эмиссией и с высокой скоростью течения расплава
WO2015082379A1 (en) 2013-12-04 2015-06-11 Borealis Ag Phthalate-free pp homopolymers for meltblown fibers
JP6203405B2 (ja) 2013-12-18 2017-09-27 ボレアリス エージー 剛性／靭性バランスが改良されたｂｏｐｐフィルム
US9944665B2 (en) 2013-12-19 2018-04-17 Exxonmobil Chemical Patents Inc. Bridged bis(indenyl) transitional metal complexes, production, and use thereof
CN105829364B (zh) 2014-01-17 2017-11-10 博里利斯股份公司 用于制备丙烯/1‑丁烯共聚物的方法
ES2767498T3 (es) 2014-02-06 2020-06-17 Borealis Ag Copolímeros de impacto transparentes y suaves
CN112225997B (zh) 2014-02-06 2023-09-22 北欧化工公司 高冲击强度的柔性共聚物
EP2907841A1 (en) 2014-02-14 2015-08-19 Borealis AG Polypropylene composite
EP2933277A1 (en) 2014-04-17 2015-10-21 Borealis AG New catalyst system for producing polyethylene copolymers in a high temperature solution polymerization process
ES2841116T3 (es) 2014-04-17 2021-07-07 Borealis Ag Sistema catalítico mejorado para producir copolímeros de polietileno en un procedimiento de polimerización en solución a alta temperatura
EP2933275A1 (en) 2014-04-17 2015-10-21 Borealis AG New catalyst system for producing polyethylene copolymers in a high temperature solution polymerization process
ES2659731T3 (es) 2014-05-20 2018-03-19 Borealis Ag Composición de polipropileno para aplicaciones en interiores de automóviles
EP2995631A1 (en) 2014-09-12 2016-03-16 Borealis AG Process for producing graft copolymers on polyolefin backbone
KR101653357B1 (ko) 2014-11-06 2016-09-01 주식회사 엘지화학 고분자량 폴리올레핀 제조용 메탈로센 촉매 및 이의 제조방법
ES2635519T3 (es) 2014-11-21 2017-10-04 Borealis Ag Procedimiento para producir gránulos de copolímeros blandos
WO2016091803A1 (en) 2014-12-08 2016-06-16 Borealis Ag Process for producing pellets of copolymers of propylene
EP3303423A1 (en) 2015-06-05 2018-04-11 ExxonMobil Chemical Patents Inc. Single reactor production of polymers in gas or slurry phase
US9809664B2 (en) 2015-06-05 2017-11-07 Exxonmobil Chemical Patents Inc. Bimodal propylene polymers and sequential polymerization
US10280235B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers
US10280233B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst systems and methods of making and using the same
WO2016196339A2 (en) 2015-06-05 2016-12-08 Exxonmobil Chemical Patents Inc. Production of heterophasic polymers in gas or slurry phase
US10294316B2 (en) 2015-06-05 2019-05-21 Exxonmobil Chemical Patents Inc. Silica supports with high aluminoxane loading capability
US10723821B2 (en) 2015-06-05 2020-07-28 Exxonmobil Chemical Patents Inc. Supported metallocene catalyst systems for polymerization
US10329360B2 (en) 2015-06-05 2019-06-25 Exxonmobil Chemical Patents Inc. Catalyst system comprising supported alumoxane and unsupported alumoxane particles
US9988410B2 (en) 2015-07-15 2018-06-05 Exxonmobil Chemical Patents Inc. Substituted bis indenyl metallocene catalyst compounds comprising-Si—Si-bridge
CN107847920A (zh) * 2015-07-15 2018-03-27 埃克森美孚化学专利公司 包含‑Si‑Si‑桥基的取代的双茚基茂金属催化剂化合物
EP3124567A1 (en) 2015-07-30 2017-02-01 Borealis AG Polypropylene based hot-melt adhesive composition
EP3178853B1 (en) 2015-12-07 2018-07-25 Borealis AG Process for polymerising alpha-olefin monomers
JP7296691B2 (ja) * 2016-02-16 2023-06-23 三井化学株式会社 遷移金属化合物、オレフィン重合用触媒およびオレフィン重合体の製造方法
EP3241611B1 (en) 2016-05-02 2020-03-04 Borealis AG A process for feeding a polymerisation catalyst
EP3243622B1 (en) 2016-05-13 2020-09-09 Borealis AG Process for hydraulic conveying of polyolefin pellets
WO2017204830A1 (en) 2016-05-27 2017-11-30 Exxonmobil Chemical Patents, Inc. Metallocene catalyst compositions and polymerization process therewith
US10982019B2 (en) 2016-06-23 2021-04-20 Borealis Ag Process for catalyst deactivation
WO2018091653A1 (en) 2016-11-18 2018-05-24 Borealis Ag Catalyst
EP3541823B1 (en) 2016-11-18 2020-12-30 Borealis AG Catalysts
CN110234665B (zh) 2016-12-15 2022-05-24 博里利斯股份公司 用于在高温溶液聚合方法中制备聚乙烯共聚物的催化剂体系
CN110337455B (zh) 2016-12-15 2022-05-24 博里利斯股份公司 在高温溶液聚合法中生产聚乙烯共聚物的新催化剂体系
CN110352195B (zh) 2016-12-29 2022-11-11 博里利斯股份公司 催化剂
CN110770264B (zh) 2017-07-07 2022-10-14 博里利斯股份公司 制备多相丙烯共聚物的方法
EP3652247B2 (en) 2017-07-14 2024-09-04 Borealis AG Polypropylene composition
PT3456776T (pt) 2017-09-13 2020-03-09 Borealis Ag Composição de polipropileno
EP3710491B1 (en) * 2017-11-14 2025-01-01 ExxonMobil Chemical Patents Inc. (di)silicon bridged metallocenes that produce polyethylene broad molecular weight distribution and molecular weight
US11130827B2 (en) 2017-11-14 2021-09-28 Exxonmobil Chemical Patents Inc. Polyethylene compositions and articles made therefrom
US11214631B2 (en) 2017-11-14 2022-01-04 Exxonmobil Chemical Patents Inc. (Di)silicon bridged metallocenes that produce polyethylene with broad molecular weight distribution and high molecular weight
EP3728342A1 (en) 2017-12-21 2020-10-28 Borealis AG Process for the preparation of solid catalyst
EP3732208A1 (en) 2017-12-27 2020-11-04 Borealis AG Ziegler-natta catalyst and preparation thereof
EA202091168A1 (ru) 2017-12-28 2020-11-24 Бореалис Аг Катализатор и его получение
US11542346B2 (en) 2018-03-19 2023-01-03 Borealis Ag Catalysts for olefin polymerization
EP3790907A1 (en) 2018-05-09 2021-03-17 Borealis AG Process for preparing propylene copolymers comprising c4-c12-alpha olefin comonomer units
CA3097506C (en) 2018-05-09 2023-03-14 Borealis Ag Polypropylene-ultrahigh-molecular-weight-polyethylene composition
PL3567061T3 (pl) 2018-05-09 2024-02-26 Borealis Ag Kompozycja polipropylenowa dla rur
EP3567060A1 (en) 2018-05-09 2019-11-13 Borealis AG Process for preparing heterophasic propylene copolymers
KR102499596B1 (ko) 2018-05-09 2023-02-14 보레알리스 아게 프로필렌 폴리머를 제조하는 공정
CN112424241B (zh) 2018-06-28 2023-06-06 博里利斯股份公司 催化剂
US20210277290A1 (en) 2018-08-06 2021-09-09 Borealis Ag Propylene random copolymer based hot melt adhesive composition
EP3608364A1 (en) 2018-08-06 2020-02-12 Borealis AG Multimodal propylene random copolymer based composition suitable as hot melt adhesive composition
JP7574179B2 (ja) * 2018-09-03 2024-10-28 シントス エス．アー． アミノシリル官能化共役ジエン、その調製、およびゴムの製造におけるその使用方法
EP3620487B1 (en) 2018-09-06 2020-11-18 Borealis AG Polypropylene based composition with improved paintability
EP3636710B8 (en) 2018-10-08 2025-08-27 Borealis GmbH Foamable polypropylene composition
EP3636680B1 (en) 2018-10-08 2020-12-02 Borealis AG Foamable polypropylene compositions
WO2020109452A1 (en) 2018-11-30 2020-06-04 Borealis Ag Washing process
EP3670547B1 (en) 2018-12-21 2023-06-07 Borealis AG Polypropylene composition for film sealing layer
JP7331414B2 (ja) * 2019-03-28 2023-08-23 日本ポリエチレン株式会社 ポリエチレン樹脂並びにそれを用いた太陽電池封止材および太陽電池モジュール
WO2020221706A1 (en) 2019-04-29 2020-11-05 Borealis Ag Soft polypropylene composition with improved optical behavior
JP7671700B2 (ja) 2019-05-29 2025-05-02 ボレアリス エージー 触媒系の改善された調製
ES2950839T3 (es) 2019-05-29 2023-10-13 Borealis Ag Composición de copolímero aleatorio C2C3
EP3976677A1 (en) 2019-05-29 2022-04-06 Borealis AG C2c3 random copolymer
ES2949942T3 (es) 2019-05-29 2023-10-04 Borealis Ag Copolímero aleatorio C2C3
US11618794B2 (en) 2019-07-04 2023-04-04 Borealis Ag Long chain branched propylene polymer composition
JP7314325B2 (ja) 2019-07-04 2023-07-25 ボレアリス・アクチェンゲゼルシャフト 長鎖分岐プロピレンポリマー組成物
US20220259339A1 (en) 2019-07-19 2022-08-18 Borealis Ag Polypropylene film with improved slip performance
US12319772B2 (en) 2019-09-25 2025-06-03 Borealis Ag Catalysts
US11472828B2 (en) 2019-10-11 2022-10-18 Exxonmobil Chemical Patents Inc. Indacene based metallocene catalysts useful in the production of propylene polymers
WO2021110815A1 (en) 2019-12-04 2021-06-10 Borealis Ag Light weight melt blown webs with improved barrier properties
EP4069896A1 (en) 2019-12-04 2022-10-12 Borealis AG Filtration media made from melt-blown fibers with improved filtration properties
FR3104585B1 (fr) * 2019-12-17 2021-12-03 Michelin & Cie Système catalytique à base d’un métallocène et d’un diorganomagnésien
EP3896101B1 (en) 2020-04-17 2024-08-07 Borealis AG Hms polypropylene for foams
WO2021209326A1 (en) 2020-04-17 2021-10-21 Borealis Ag Blown film
ES2928288T3 (es) 2020-05-18 2022-11-16 Borealis Ag Película de múltiples capas con propiedades mejoradas
EP3912810B1 (en) 2020-05-18 2022-08-10 Borealis AG Polypropylene composition
ES2925719T3 (es) 2020-05-18 2022-10-19 Borealis Ag Películas sopladas con perfil de propiedades mejorado
EP3913005A1 (en) 2020-05-22 2021-11-24 Borealis AG Glass fiber reinforced composite with narrow mwd polypropylene
EP4153678B1 (en) 2020-05-22 2025-03-26 Borealis AG Glass fiber composite
CN115768827B (zh) 2020-06-29 2024-04-26 博瑞立斯有限公司 可回收聚合物膜和组合物
EP3950739B1 (en) 2020-08-05 2023-11-08 Borealis AG Polypropylene sheet
ES2984829T3 (es) 2020-08-13 2024-10-31 Borealis Ag Composición automotriz
WO2022034126A1 (en) 2020-08-13 2022-02-17 Borealis Ag Automotive composition
ES2984386T3 (es) 2020-09-11 2024-10-29 Borealis Ag Artículo a base de polipropileno que tiene una mayor retención de la tensión superficial
US20240002555A1 (en) 2020-11-23 2024-01-04 Borealis Ag In-situ reactor blend of ziegler-natta catalysed, nucleated polypropylene and a metallocene catalysed polypropylene
JP7654801B2 (ja) 2021-01-22 2025-04-01 ボレアリス エージー 繊維強化ポリプロピレン組成物
PT4036129T (pt) 2021-02-02 2023-09-11 Borealis Ag Película feita a partir de mistura de terpolímero c2c3c4 - copolímero c3c4 e mistura de terpolímero c2c3c4 - copolímero c3c4
EP4314096A2 (en) 2021-03-24 2024-02-07 Borealis AG Process for producing heterophasic propylene resin
US20240191015A1 (en) 2021-03-24 2024-06-13 Borealis Ag Copolymer
CN117255734A (zh) 2021-04-30 2023-12-19 博里利斯股份公司 包含聚丙烯和烃树脂的聚合物组合物
WO2023012159A1 (en) 2021-08-04 2023-02-09 Borealis Ag Multilayer nonwoven structure
EP4141068B1 (en) 2021-08-31 2024-05-29 Borealis AG A homopolymer-random copolymer blend having a beneficial balance of optical and mechanical properties
EP4144435A1 (en) 2021-09-01 2023-03-08 Borealis AG Gas phase polymerization process with improved gas recycling
EP4405402A1 (en) 2021-09-23 2024-07-31 Borealis AG Process for producing a propylene copolymer
US20240384083A1 (en) 2021-09-23 2024-11-21 Borealis Ag Monophasic bimodal propylene/ethylene/1-butene random terpolymer compositions with improved optical and sealing properties
WO2023062010A1 (en) 2021-10-14 2023-04-20 Borealis Ag A propylene-ethylene random copolymer with highly randomized ethylene distribution
MX2024006394A (es) 2021-12-01 2024-06-04 Borealis Ag Composicion de polipropileno de flujo de fusion elevado.
KR20240107369A (ko) 2021-12-01 2024-07-09 보레알리스 아게 패키징 적용에 적합한 폴리프로필렌 조성물
EP4496822A1 (en) 2022-03-21 2025-01-29 Borealis AG Glass fiber reinforced polypropylene composition
EP4257640B1 (en) 2022-04-04 2024-08-28 Borealis AG Pipe comprising a polypropylene composition
US20250250400A1 (en) 2022-04-26 2025-08-07 Borealis Ag A process for recycling polypropylene films
EP4514864A1 (en) 2022-04-28 2025-03-05 Borealis AG Process for producing random propylene copolymers comprising c4-c12-alpha olefin comonomer units
ES3015219T3 (en) 2022-05-31 2025-04-30 Borealis Ag Glass fiber composite
CN119497725A (zh) 2022-07-11 2025-02-21 北欧化工公司 用于管道应用的丙烯-乙烯无规共聚物
EP4554985A1 (en) 2022-07-11 2025-05-21 Borealis AG A process for preparing propylene-ethylene random copolymers for pipe applications
WO2024042070A1 (en) 2022-08-23 2024-02-29 Borealis Ag Alpha-nucleated propylene/ethylene/1-butene terpolymer compositions for blown and cast films
EP4590728A1 (en) 2022-09-21 2025-07-30 Borealis GmbH Propylene/ethylene/1-butene terpolymer compositions with multimodal base polymer
WO2024094663A1 (en) 2022-10-31 2024-05-10 Borealis Ag Process for producing high-flow heterophasic propylene copolymer compositions
WO2024094676A1 (en) 2022-10-31 2024-05-10 Borealis Ag Compositon for automotive exterior parts
EP4389776A1 (en) 2022-12-20 2024-06-26 Borealis AG Process
EP4389783A1 (en) 2022-12-20 2024-06-26 Borealis AG Catalyst transition process
CN120380037A (zh) 2022-12-23 2025-07-25 北欧化工股份公司 聚丙烯均聚物或共聚物的制造方法
CN120380039A (zh) 2022-12-23 2025-07-25 北欧化工股份公司 聚丙烯共聚物的生产方法
WO2024133045A1 (en) 2022-12-23 2024-06-27 Borealis Ag Process for producing a high-flow polypropylene homopolymer
CN121175162A (zh) 2023-05-23 2025-12-19 博里利斯有限责任公司 用于生产聚烯烃的粒料的方法和由此生产的粒料
WO2025003435A1 (en) 2023-06-30 2025-01-02 Borealis Ag Process
WO2025016569A1 (en) 2023-07-14 2025-01-23 Borealis Ag Metallocenes for the manufacture of polypropylene
WO2025016570A1 (en) 2023-07-14 2025-01-23 Borealis Ag Catalysts for olefin polymerization
WO2025016564A1 (en) 2023-07-14 2025-01-23 Borealis Ag Metallocenes for the manufacture of polypropylene
WO2025016568A1 (en) 2023-07-14 2025-01-23 Borealis Ag Metallocenes for the manufacture of polypropylene
WO2025016565A1 (en) 2023-07-14 2025-01-23 Borealis Ag Catalysts for olefin polymerization
WO2025061926A1 (en) 2023-09-21 2025-03-27 Borealis Ag Polypropylene compositions suitable for automotive applications
WO2025219537A1 (en) 2024-04-18 2025-10-23 Borealis Gmbh Process for propylene polymerization with optimized prepolymerization conditions
WO2025219533A1 (en) 2024-04-18 2025-10-23 Borealis Gmbh Process for the preparation of a propylene homopolymer
WO2025252807A1 (en) 2024-06-06 2025-12-11 Borealis Gmbh Polypropylene composition for automotive applications

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0812854B2 (en) * 1993-06-07 2011-04-20 Mitsui Chemicals, Inc. Novel transition metal compound, olefin polymerization catalyst comprising said compound, process for olefin polymerization using said catalyst and propylene homo- and copolymer
DE19544828A1 (de) * 1995-12-01 1997-06-05 Hoechst Ag Hochmolekulare Copolymere
AU7332398A (en) * 1997-03-07 1998-09-29 Targor Gmbh Method for producing olefin polymers with a higher melting point
US6160072A (en) * 1997-05-02 2000-12-12 Ewen; John A. Process for polymerizing tactioselective polyolefins in condensed phase using titanocenes
EP1031582A1 (en) * 1999-02-26 2000-08-30 Fina Research S.A. Use and production of polypropylene

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105829326B (zh) * 2013-12-19 2019-11-08 埃克森美孚化学专利公司 桥连双(茚基)过渡金属络合物、其制备与应用

Also Published As

Publication number Publication date
CN1444594A (zh) 2003-09-24
EP1313746B1 (en) 2005-07-27
EP1313746A1 (en) 2003-05-28
CN1332966C (zh) 2007-08-22
DE60112307T2 (de) 2006-05-24
ATE300550T1 (de) 2005-08-15
CN1444593A (zh) 2003-09-24
WO2002002576A1 (en) 2002-01-10
DE60112307T8 (de) 2007-02-15
JP2004502699A (ja) 2004-01-29
DE60112307D1 (de) 2005-09-01
EP1632506A1 (en) 2006-03-08

Similar Documents

Publication Publication Date Title
CN1274701C (zh) 用于烯烃聚合的含有桥接4－苯基－茚基配体的金属茂
CN100340568C (zh) 茂金属一卤化物
CN1104443C (zh) 丙烯聚合物组合物的制备方法和丙烯聚合物组合物
CN1099422C (zh) 催化剂组分化合物及其制备方法和用途
CN1104444C (zh) 丙烯聚合物组合物的制备方法
CN1176093C (zh) 双环戊二烯基二烯配合物
CN1221562C (zh) 环戊二烯并菲基金属配合物及聚合方法
CN1093543C (zh) 稠环取代的茚基金属配合物及聚合方法
CN1205238C (zh) 制备乙烯与共轭二烯烃的共聚物的方法和催化体系、该催化体系的制备方法
CN1048501C (zh) 过渡金属化合物、烯烃聚合催化剂、烯烃聚合方法
CN1049896C (zh) 过渡金属化合物及含该化合物的烯烃聚合催化剂
CN1156728A (zh) 烯烃聚合催化剂，制备烯烃聚合物的方法和烯烃聚合物
CN1182093A (zh) 承载的化合物
CN1265663A (zh) 含硼和铝的化合物
CN1436796A (zh) 用于烯烃聚合的固体催化剂组分和含该催化剂组分的催化剂及其应用
CN1174205A (zh) 载体催化剂体系、其制备方法及其在烯烃聚合中的应用
CN1946748A (zh) 金属茂配体，金属茂化合物和金属茂催化剂，它们的合成以及它们用于聚合烯烃的用途
CN1052734C (zh) 丙烯高弹体
CN1890272A (zh) 过渡金属有机化合物、双环戊二烯基配体体系，催化剂体系和聚烯烃制备
CN1684968A (zh) 烯烃聚合用交联金属茂化合物及使用该化合物的烯烃聚合方法
CN1107854A (zh) 金属茂化合物
CN1675255A (zh) 可用于α －烯烃的聚合或共聚的α－烯烃聚合或共聚用催化剂、其催化剂成分以及使用该催化剂的α －烯烃的聚合方法
CN1109061A (zh) 金属茂化合物
CN1222919A (zh) 最大分子量出现在共聚单体含量最高的组合物部分中的聚烯烃共聚物组合物
CN1128766A (zh) 烯烃聚合催化剂和烯烃聚合方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C19 Lapse of patent right due to non-payment of the annual fee
CF01 Termination of patent right due to non-payment of annual fee