CN101291733B - 烯烃低聚催化剂的制备方法 - Google Patents

烯烃低聚催化剂的制备方法 Download PDF

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CN101291733B
CN101291733B CN2006800388951A CN200680038895A CN101291733B CN 101291733 B CN101291733 B CN 101291733B CN 2006800388951 A CN2006800388951 A CN 2006800388951A CN 200680038895 A CN200680038895 A CN 200680038895A CN 101291733 B CN101291733 B CN 101291733B
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chromium
compound
catalyst
iii
halide
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CN101291733A (zh
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R·D·克努德森
R·G·阿博特
B·E·克里斯彻
E·J·巴莱尔特
B·L·斯莫尔
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Chevron Phillips Chemical Co LLC
Chevron Phillips Chemical Co LP
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/128—Mixtures of organometallic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4092—Regeneration or reactivation of catalysts containing metals involving a stripping step, with stripping gas or solvent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/125—Compounds comprising a halogen and scandium, yttrium, aluminium, gallium, indium or thallium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts
CN2006800388951A 2005-08-19 2006-08-08 烯烃低聚催化剂的制备方法 Active CN101291733B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11/207,232 2005-08-19
US11/207,232 US20070043181A1 (en) 2005-08-19 2005-08-19 Methods of preparation of an olefin oligomerization catalyst
PCT/US2006/031303 WO2007024504A1 (en) 2005-08-19 2006-08-08 Methods of preparation of an olefin oligomerization catalyst

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CN101291733A CN101291733A (zh) 2008-10-22
CN101291733B true CN101291733B (zh) 2012-07-18

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EP (1) EP1931469A1 (US07910670-20110322-C00010.png)
CN (1) CN101291733B (US07910670-20110322-C00010.png)
AR (1) AR057506A1 (US07910670-20110322-C00010.png)
AU (1) AU2006283779A1 (US07910670-20110322-C00010.png)
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Families Citing this family (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050187418A1 (en) * 2004-02-19 2005-08-25 Small Brooke L. Olefin oligomerization
US20070043181A1 (en) 2005-08-19 2007-02-22 Knudsen Ronald D Methods of preparation of an olefin oligomerization catalyst
US20050187098A1 (en) 2004-02-20 2005-08-25 Knudsen Ronald D. Methods of preparation of an olefin oligomerization catalyst
US9550841B2 (en) 2004-02-20 2017-01-24 Chevron Phillips Chemical Company Lp Methods of preparation of an olefin oligomerization catalyst
US7384886B2 (en) 2004-02-20 2008-06-10 Chevron Phillips Chemical Company Lp Methods of preparation of an olefin oligomerization catalyst
WO2008004986A1 (en) * 2006-07-05 2008-01-10 National University Of Singapore Catalyst system for oligomerization of olefins
US7378537B2 (en) * 2006-07-25 2008-05-27 Chevron Phillips Chemical Company Lp Olefin oligomerization catalysts and methods of using same
US7902415B2 (en) 2007-12-21 2011-03-08 Chevron Phillips Chemical Company Lp Processes for dimerizing or isomerizing olefins
AU2009308801B2 (en) 2008-10-31 2015-05-07 Chevron Phillips Chemical Company Lp Oligomerization catalyst system and process for oligomerizing olefins
ES2626596T3 (es) 2009-12-31 2017-07-25 Chevron Phillips Chemical Company Lp Compuestos de fosfinilamidina, complejos metálicos, sistemas catalíticos y su uso para oligomerizar o polimerizar olefinas
CA2701252C (en) * 2010-04-20 2017-01-03 Nova Chemicals Corporation Polymer mitigation
BR112012030016B8 (pt) * 2010-05-24 2021-05-18 Siluria Technologies Inc processo para preparar etileno a partir de metano e método para preparar um produto a jusante de etileno
US20120172645A1 (en) * 2010-12-29 2012-07-05 Chevron Phillips Chemical Company Lp Olefin Oligomerization catalysts and Methods of Making and Using Same
EA029867B1 (ru) 2011-05-24 2018-05-31 Силурия Текнолоджиз, Инк. Катализаторы для нефтехимического катализа
US20130158322A1 (en) 2011-11-29 2013-06-20 Siluria Technologies, Inc. Polymer templated nanowire catalysts
US8957235B2 (en) * 2011-12-12 2015-02-17 Chevron Phillips Chemical Company Lp Preparation of transition metal carboxylates
US9956548B2 (en) * 2011-12-12 2018-05-01 Chevron Phillips Chemical Company Lp Preparation of an olefin oligomerization catalyst
US9586872B2 (en) 2011-12-30 2017-03-07 Chevron Phillips Chemical Company Lp Olefin oligomerization methods
US9446397B2 (en) 2012-02-03 2016-09-20 Siluria Technologies, Inc. Method for isolation of nanomaterials
CA3125016C (en) 2012-05-24 2024-04-30 Lummus Technology Llc Catalytic forms and formulations
US8865610B2 (en) 2012-06-06 2014-10-21 Chevron Phillips Chemical Company Lp Phosphinyl guanidine compounds, metal salt complexes, catalyst systems, and their use to oligomerize or polymerize olefins
NL1039868C2 (en) * 2012-11-01 2014-05-06 Stichting Dutch Polymer Inst Process for producing an oligo(alpha-olefin) and the use of a particular form of methylaluminoxane in such process.
EP2969184A4 (en) 2013-03-15 2016-12-21 Siluria Technologies Inc CATALYSTS FOR PETROCHEMICAL CATALYSIS
WO2015168601A2 (en) 2014-05-02 2015-11-05 Siluria Technologies, Inc. Heterogeneous catalysts
US9175109B1 (en) 2014-05-20 2015-11-03 Chevron Phillips Chemical Company Lp Oligomerization processes and polymer compositions produced therefrom
HUE054014T2 (hu) 2014-09-17 2021-08-30 Lummus Technology Inc Katalizátorok metán oxidatív csatolására és etán oxidatív dehidrogenálására
US9505675B2 (en) 2015-02-09 2016-11-29 Chevron Phillips Chemical Company Lp Deactivation of a process by-product
WO2017010998A1 (en) 2015-07-14 2017-01-19 Chevron Phillips Chemical Company Lp Olefin compositions
US9732300B2 (en) 2015-07-23 2017-08-15 Chevron Phillipa Chemical Company LP Liquid propylene oligomers and methods of making same
KR102058142B1 (ko) 2015-09-02 2019-12-20 주식회사 엘지화학 리간드 화합물, 올레핀 올리고머화용 촉매계, 및 이를 이용한 올레핀 올리고머화 방법
US10513473B2 (en) 2015-09-18 2019-12-24 Chevron Phillips Chemical Company Lp Ethylene oligomerization/trimerization/tetramerization reactor
US10519077B2 (en) 2015-09-18 2019-12-31 Chevron Phillips Chemical Company Lp Ethylene oligomerization/trimerization/tetramerization reactor
KR101982789B1 (ko) 2015-12-04 2019-05-27 주식회사 엘지화학 리간드 화합물, 유기 크롬 화합물, 올레핀 올리고머화용 촉매 시스템, 및 이를 이용한 올레핀의 올리고머화 방법
US20170267605A1 (en) 2016-03-16 2017-09-21 Siluria Technologies, Inc. Catalysts and methods for natural gas processes
WO2019074303A1 (ko) * 2017-10-11 2019-04-18 롯데케미칼 주식회사 올레핀 올리고머화용 촉매계 및 이를 이용하는 올레핀 올리고머 제조방법
WO2019108081A1 (en) * 2017-12-01 2019-06-06 Public Joint Stock Company "Sibur Holding" Olefin oligomerization method using online measurement of chromium concentration in a catalytic system
CN112517080B (zh) * 2020-12-25 2023-06-23 中化泉州石化有限公司 一种乙烯选择性四聚催化剂组合物及其应用
US11859041B2 (en) 2021-08-16 2024-01-02 Chevron Phillips Chemical Company Lp Modulating co-monomer selectivity using non-covalent dispersion interactions in group 4 olefin polymerization catalysts

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1108967A (zh) * 1994-02-18 1995-09-27 菲利浦石油公司 烯烃的生产方法
WO2004056480A1 (en) * 2002-12-20 2004-07-08 Sasol Technology (Pty) Limited Tandem tetramerisation-polymerisation of olefins
CN1651142A (zh) * 2004-12-27 2005-08-10 中国石油大庆石化分公司研究院 用于乙烯齐聚的催化剂组分、制备方法及其应用

Family Cites Families (189)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3968135A (en) * 1970-01-19 1976-07-06 Aerojet-General Corporation Chromium salt catalysts
US3635869A (en) * 1970-03-16 1972-01-18 Aerojet General Co Catalysis of epoxy resin/carboxylic acid systems with trivalent chromium iii tricarboxylate salts
US3873602A (en) * 1970-09-18 1975-03-25 Aerojet General Co Beta hydroxy esters
BE794059A (fr) * 1972-01-14 1973-05-02 Aerojet General Co Nouvelles compositons a base d'oxiranne-imide leur preparation et leur utilisation
US3978026A (en) * 1972-02-18 1976-08-31 Aerojet-General Corporation Catalysts of the oxirane-anhydride reaction
US3977996A (en) * 1972-02-18 1976-08-31 Aerojet-General Corporation Catalysts for the oxirane-anhydride reaction
US3962182A (en) * 1972-11-21 1976-06-08 Aerojet-General Corporation Imide oxirane reactions
US4017429A (en) * 1973-08-17 1977-04-12 Aerojet-General Corporation Preparation of 2-hydroxyalkyl esters
US3932285A (en) * 1973-10-03 1976-01-13 Tenneco Chemicals, Inc. Chromium salt compositions and a process for their production
US4057565A (en) * 1975-07-22 1977-11-08 E. I. Du Pont De Nemours And Company 2-Dialkylaminobenzyl and 2-dialkylaminomethylphenyl derivatives of selected transition metals
EP0067607B1 (en) * 1981-06-02 1987-01-21 Asahi Kasei Kogyo Kabushiki Kaisha A catalyst for polymerization of olefins
US4853356A (en) * 1986-03-14 1989-08-01 Union Carbide Corporation Process for trimerization
US4668838A (en) * 1986-03-14 1987-05-26 Union Carbide Corporation Process for trimerization
US5198401A (en) * 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5081089A (en) * 1987-05-20 1992-01-14 National Distillers And Chemical Corporation Chromium catalyst compositions and polymerization utilizing same
US4777315A (en) * 1987-06-01 1988-10-11 Union Carbide Corporation Process for trimerization
US4971986A (en) * 1988-03-25 1990-11-20 Ciba-Geigy Corporation Arylhydrazones useful as SAMDC inhibitors
US4876229A (en) * 1988-05-31 1989-10-24 Mobil Oil Corporation Catalyst composition for polymerizing olefins of narrow molecular weight distribution and polymerization therewith
US5118648A (en) * 1988-10-05 1992-06-02 Mobil Oil Corporation Particulate polymer-supported olefin polymerization catalyst
US5198563A (en) * 1989-08-10 1993-03-30 Phillips Petroleum Company Chromium compounds and uses thereof
US5331104A (en) * 1989-08-10 1994-07-19 Phillips Petroleum Company Chromium compounds and uses thereof
US5376612A (en) * 1989-08-10 1994-12-27 Phillips Petroleum Company Chromium catalysts and process for making chromium catalysts
US5451645A (en) * 1989-08-10 1995-09-19 Phillips Petroleum Company Process for olefin polymerization
NZ235032A (en) 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5340892A (en) * 1989-09-29 1994-08-23 Idemitsu Kosan Co., Ltd. Process for producing styrene polymers
US5696240A (en) * 1991-03-15 1997-12-09 Vallarino; Lidia M. Macrocyclic complexes of yttrium, the lanthanides and the actinides having peripheral coupling functionalities
US5137994A (en) * 1991-05-23 1992-08-11 Union Carbide Chemicals & Plastics Technology Corporation Process for the simultaneous trimerization and copolymerization of ethylene
US5744677A (en) * 1991-10-16 1998-04-28 Amoco Corporation Ethylene oligomerization
US5811618A (en) * 1991-10-16 1998-09-22 Amoco Corporation Ethylene trimerization
US5550305A (en) * 1991-10-16 1996-08-27 Amoco Corporation Ethylene trimerization
US5438027A (en) * 1991-12-13 1995-08-01 Phillips Petroleum Company Chromium compounds and uses thereof
EP0548805B1 (en) * 1991-12-18 1997-03-05 Phillips Petroleum Company Process for the preparation of polymerisation catalysts
SG112881A1 (en) * 1992-09-17 2005-07-28 Mitsubishi Chem Corp Method for oligomerizing an alpha-olefin
US5331070A (en) * 1992-11-13 1994-07-19 Phillips Petroleum Company Process for olefin polymerization
WO1994015940A1 (en) 1993-01-13 1994-07-21 Idemitsu Kosan Co., Ltd. Process for producing olefin oligomer
CA2087578C (en) 1993-01-19 1998-10-27 William Kevin Reagen Preparing catalyst for olefin polymerization
TW354300B (en) * 1993-02-17 1999-03-11 Mitsubishi Chem Corp Process for producing <alpha>-olefin oligomers
CA2115639C (en) 1993-03-03 2004-10-19 Feng-Jung Wu Ethylene trimerization
TW279167B (US07910670-20110322-C00010.png) * 1993-03-12 1996-06-21 Sumitomo Chemical Co
JP3331031B2 (ja) * 1993-12-15 2002-10-07 昭和電工株式会社 ポリオレフィン重合反応器のスタートアップ制御方法および装置
CA2134503C (en) * 1994-02-18 2001-04-10 Mark E. Lashier Olefin production
US5910619A (en) * 1994-06-21 1999-06-08 Mitsubishi Chemical Corporation Process for producing α-olefin oligomers
JP3613642B2 (ja) * 1994-09-05 2005-01-26 住友化学株式会社 １−ヘキセンの製造方法
JP3847783B2 (ja) 1995-01-24 2006-11-22 イー・アイ・デュポン・ドゥ・ヌムール・アンド・カンパニー オレフィンの重合方法
KR100414008B1 (ko) * 1995-03-02 2004-04-29 미쓰비시 가가꾸 가부시키가이샤 α-올레핀올리고머의제조방법
US5714556A (en) * 1995-06-30 1998-02-03 E. I. Dupont De Nemours And Company Olefin polymerization process
JPH09143228A (ja) * 1995-11-22 1997-06-03 Sumitomo Chem Co Ltd エチレン−α−オレフィン共重合体の製造方法
US5859303A (en) * 1995-12-18 1999-01-12 Phillips Petroleum Company Olefin production
US5856612A (en) * 1996-02-02 1999-01-05 Mitsubishi Chemical Corporation Process for producing α-olefin oligomer
US5786291A (en) * 1996-02-23 1998-07-28 Exxon Chemical Patents, Inc. Engineered catalyst systems and methods for their production and use
WO1997033924A1 (fr) * 1996-03-14 1997-09-18 Mitsubishi Chemical Corporation PROCEDE DE PRODUCTION D'OLIGOMERS D'α-OLEFINES
JP3823429B2 (ja) * 1996-06-28 2006-09-20 住友化学株式会社 触媒系及びオレフィンの反応方法
US6417305B2 (en) * 1996-12-17 2002-07-09 E. I. Du Pont De Nemours And Company Oligomerization of ethylene
IL129929A0 (en) * 1996-12-17 2000-02-29 Du Pont Polymerization of ethylene with specific iron or cobalt complexes novel pyridinebis (imines) and novel complexes of pyridinebis(imines) with iron and cobalt
US6214761B1 (en) * 1996-12-17 2001-04-10 E. I. Du Pont De Nemours And Company Iron catalyst for the polymerization of olefins
US6423848B2 (en) * 1996-12-17 2002-07-23 E. I. Du Pont De Nemours And Company Tridentate ligand
AU6018198A (en) * 1997-01-13 1998-08-03 E.I. Du Pont De Nemours And Company Polymerization of propylene
FR2759922B1 (fr) * 1997-02-25 1999-05-07 Inst Francais Du Petrole Composition catalytique amelioree pour la conversion de l'ethylene en olefines alpha legeres
US6103658A (en) * 1997-03-10 2000-08-15 Eastman Chemical Company Olefin polymerization catalysts containing group 8-10 transition metals, processes employing such catalysts and polymers obtained therefrom
US5856257A (en) * 1997-05-16 1999-01-05 Phillips Petroleum Company Olefin production
FR2764524B1 (fr) * 1997-06-17 1999-07-16 Inst Francais Du Petrole Composition catalytique et procede pour l'oligomerisation de l'ethylene, en particulier en butene-1 et/ou hexene-1
US6103946A (en) * 1997-07-15 2000-08-15 E. I. Du Pont De Nemours And Company Manufacture of α-olefins
US6740715B2 (en) * 1997-07-15 2004-05-25 E. I. Du Pont De Nemours And Company Manufacture of alpha-olefins
PL198619B1 (pl) * 1997-09-05 2008-07-31 Bp Chem Int Ltd Sposób (ko)polimeryzacji etylenu z jedną lub większą liczbą 1-olefin w obecności gazowego wodoru oraz katalizatory (ko)polimeryzacji etylenu z jedną lub większą liczbą 1-olefin w obecności gazowego wodoru
US5986153A (en) * 1997-09-30 1999-11-16 Phillips Petroleum Company Olefin color stabilization
US20020182124A1 (en) 1997-10-14 2002-12-05 William M. Woodard Olefin production process
DE69918684T2 (de) * 1998-03-12 2004-12-02 Bp Chemicals Ltd. Polymerisationskatalysatoren
US6063881A (en) * 1998-04-02 2000-05-16 E. I. Du Pont De Nemours And Company Oligomerization of propylene
US6252022B1 (en) 1998-05-29 2001-06-26 E. I. Du Pont De Nemours And Company Molecular weight control in olefin polymerization
CN1203098C (zh) 1998-05-29 2005-05-25 纳幕尔杜邦公司 烯烃的共聚合
KR100379134B1 (ko) * 1998-06-16 2003-04-08 미쓰이 가가쿠 가부시키가이샤 올레핀 중합용 촉매 및 올레핀의 중합 방법
GB9817004D0 (en) * 1998-08-06 1998-09-30 Bp Chem Int Ltd Preparation of polymerisation catalysts
GB9819847D0 (en) * 1998-09-12 1998-11-04 Bp Chem Int Ltd Novel compounds
EP1117670B1 (en) 1998-10-02 2003-01-02 BP Chemicals Limited Polymerisation catalysts
US6337297B1 (en) * 1998-10-12 2002-01-08 Tosoh Corporation Catalyst for trimerization of ethylene and process for trimerizing ethylene using the catalyst
CN1108193C (zh) 1998-12-15 2003-05-14 北京燕山石油化工公司研究院 一种用于乙烯三聚的新型催化剂,其制备方法和应用
JP2000176291A (ja) 1998-12-17 2000-06-27 Tosoh Corp エチレンの三量化反応触媒及びそれを用いたエチレンの三量化反応方法
US20010053742A1 (en) * 1998-12-18 2001-12-20 Ronald D. Knudsen Catalyst and processes for olefin trimerization
JP2000202299A (ja) 1999-01-20 2000-07-25 Tosoh Corp エチレンの三量化触媒及びこれを用いたエチレンの三量化方法
JP2000212212A (ja) 1999-01-20 2000-08-02 Tosoh Corp エチレンの三量化触媒及びそれを用いたエチレンの三量化方法
CN1174805C (zh) * 1999-01-21 2004-11-10 出光石油化学株式会社 α-烯烃制造用催化剂和α-烯烃制造方法
US6545108B1 (en) * 1999-02-22 2003-04-08 Eastman Chemical Company Catalysts containing N-pyrrolyl substituted nitrogen donors
GB9906296D0 (en) * 1999-03-18 1999-05-12 Bp Chem Int Ltd Polymerisation catalysts
US6844290B1 (en) * 1999-03-29 2005-01-18 Basf Aktiengesellschaft Oligomerization catalyst
DE19931873A1 (de) * 1999-04-14 2000-10-19 Bayer Ag Katalysatorsystem zur Olefinpolymerisation
US6344594B1 (en) * 1999-04-16 2002-02-05 The Penn State Research Foundation Highly selective catalytic process for synthesizing 1-hexene from ethylene
US6239237B1 (en) * 1999-04-22 2001-05-29 Nova Chemicals (International) S.A. Group 8, 9 or 10 transition metal catalyst for olefin polymerization
US6365690B1 (en) * 1999-05-06 2002-04-02 E. I. Du Pont De Nemours And Company Polymerization of ethylene
AU4014300A (en) 1999-05-14 2000-12-05 Dow Chemical Company, The Transition metal complexes and olefin polymerization process
US6291733B1 (en) * 1999-06-02 2001-09-18 Chevron Chemical Company Llc Process for dimerizing olefins
JP2001002724A (ja) 1999-06-24 2001-01-09 Tosoh Corp エチレンの三量化触媒及びこれを用いたエチレンの三量化方法
JP4352514B2 (ja) 1999-06-24 2009-10-28 東ソー株式会社 エチレンの三量化触媒及びこの触媒を用いたエチレンの三量化方法
US6281303B1 (en) * 1999-07-27 2001-08-28 Eastman Chemical Company Olefin oligomerization and polymerization catalysts
IT1313599B1 (it) 1999-08-05 2002-09-09 Enichem Spa Complessi metallici utilizzabili nella catalisi per la (co)polimerizzazione delle alfa-olefine
US6458905B1 (en) * 1999-08-16 2002-10-01 Phillips Petroleum Company Complexes of pyridldiimines with vanadium and other transition metals, and their use as olefin oligomerization and polymerization catalysts
JP2001096164A (ja) 1999-09-30 2001-04-10 Tosoh Corp エチレンの三量化触媒及びこの触媒を用いるエチレンの三量化方法
US6399535B1 (en) * 1999-11-01 2002-06-04 W. R. Grace & Co.-Conn. Coordination catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation
DE60045557D1 (de) 1999-11-11 2011-03-03 Idemitsu Kosan Co Übergangsmetall-verbindung, katalysator zur olefin polymerisation und ein verfahren zur polymerisation von olefinen
AU1772701A (en) 1999-11-19 2001-05-30 E.I. Du Pont De Nemours And Company Copolymerization of ethylene and dienes
AU2302001A (en) 1999-11-26 2001-06-04 Sasol Technology (Pty) Ltd. Hydrocarbon conversion process
JP2001149788A (ja) 1999-11-30 2001-06-05 Tosoh Corp エチレンの三量化触媒及びそれを用いたエチレンの三量化方法
FR2802833B1 (fr) * 1999-12-24 2002-05-10 Inst Francais Du Petrole Composition catalytique et procede pour l'oligomerisation de l'ethylene, en particulier en hexene-1
US6455648B1 (en) * 1999-12-29 2002-09-24 Chevron Phillips Chemical Company Lp Olefin production
MXPA02005399A (es) 1999-12-29 2002-12-05 Phillips Petroleum Co Proceso para impedir la generacion de haluros de hidrogeno en un sistema de recuperacion de producto de oligomerizacion.
US6380451B1 (en) * 1999-12-29 2002-04-30 Phillips Petroleum Company Methods for restoring the heat transfer coefficient of an oligomerization reactor
JP2001187345A (ja) 2000-01-05 2001-07-10 Tosoh Corp エチレンの三量化触媒成分、三量化触媒及びそれを用いたエチレンの三量化方法
US6710006B2 (en) 2000-02-09 2004-03-23 Shell Oil Company Non-symmetrical ligands and catalyst systems thereof for ethylene oligomerization to linear alpha olefins
KR20020084170A (ko) 2000-03-06 2002-11-04 이데미쓰세끼유가가꾸가부시끼가이샤 비닐 화합물 중합용 촉매 및 비닐 중합체의 제조 방법
US6521724B2 (en) 2000-03-10 2003-02-18 E. I. Du Pont De Nemours And Company Polymerization process
IT1318394B1 (it) 2000-03-17 2003-08-25 Enichem Spa Processo per la preparazione di 1-esene.
GB0007764D0 (en) 2000-03-30 2000-05-17 Bp Chem Int Ltd Polymerisation catalyst
WO2001083447A2 (en) * 2000-05-04 2001-11-08 Sasol Technology (Pty) Ltd A halopyrrole ligand for use in a catalyst system
CN1128776C (zh) 2000-05-18 2003-11-26 中国石油大庆石化分公司研究院 一种乙烯齐聚制1－己烯的催化剂
GC0000291A (en) * 2000-06-30 2006-11-01 Shell Int Research Ligands and catalyst systems thereof for ethylene oligomerisation to linear alpha olefins
GB0016895D0 (en) 2000-07-11 2000-08-30 Bp Chem Int Ltd Olefin oligomerisation
US6534691B2 (en) * 2000-07-18 2003-03-18 E. I. Du Pont De Nemours And Company Manufacturing process for α-olefins
US6555723B2 (en) * 2000-07-18 2003-04-29 E. I. Du Pont De Nemours And Company Continuous manufacturing process for alpha-olefins
JP2002045703A (ja) 2000-08-01 2002-02-12 Tosoh Corp エチレンの三量化触媒及びこの触媒を用いたエチレンの三量化方法
JP2002066329A (ja) 2000-08-28 2002-03-05 Tosoh Corp エチレンの三量化触媒及びこの触媒を用いたエチレンの三量化方法
US7223893B2 (en) 2000-09-12 2007-05-29 Chevron Phillips Chemical Company Lp Linear alpha-olefin dimers possessing substantial linearity
EP1188762A1 (en) 2000-09-14 2002-03-20 Solvay Polyolefins Europe-Belgium (Société Anonyme) Chromium complexes and their use for the polymerization of alpha-olefins
JP2002102710A (ja) 2000-09-29 2002-04-09 Tosoh Corp エチレンの三量化触媒及びこの触媒を用いたエチレンの三量化方法
JP5181406B2 (ja) 2000-09-29 2013-04-10 東ソー株式会社 エチレンの三量化触媒およびこの触媒を用いたエチレンの三量化方法
US6900152B2 (en) * 2000-09-29 2005-05-31 Tosoh Corporation Catalyst for trimerization of ethylene and process for trimerizing ethylene using the catalyst
US7037988B2 (en) 2000-10-03 2006-05-02 Shell Oil Company Process for the co-oligomerisation of ethylene and alpha olefins
IT1319240B1 (it) 2000-10-26 2003-09-26 Enichem Spa Procedimento per la oligomerizzazione selettiva dell'etilene.
JP2002200429A (ja) 2000-10-27 2002-07-16 Tosoh Corp エチレンの三量化触媒及びこの触媒を用いたエチレンの三量化方法
JP2002172327A (ja) 2000-12-05 2002-06-18 Tosoh Corp エチレンの三量化触媒及びこの触媒を用いたエチレンの三量化方法
JP2002233764A (ja) 2000-12-05 2002-08-20 Tosoh Corp エチレンの三量化触媒およびこの触媒を用いたエチレンの三量化方法
CN1136242C (zh) 2000-12-13 2004-01-28 中国科学院化学研究所 一种用于制备支化聚乙烯的催化体系和制备支化聚乙烯的方法
CN1163456C (zh) 2000-12-27 2004-08-25 中国科学院化学研究所 一种固态烃类化合物包裹的乙烯齐聚催化剂及其制备方法
CN1306014A (zh) 2000-12-27 2001-08-01 中国科学院长春应用化学研究所 多核吡啶双亚胺铁、钴烯烃聚合催化剂
JP2002205960A (ja) 2001-01-09 2002-07-23 Tosoh Corp エチレンの三量化方法
WO2002066404A1 (en) 2001-02-22 2002-08-29 Stichting Dutch Polymer Institute Catalyst system for the trimerisation of olefins
WO2002066405A1 (en) 2001-02-22 2002-08-29 Stichting Dutch Polymer Institute Catalyst system for the trimerisation of olefins
CN1202049C (zh) 2001-03-09 2005-05-18 中国石油天然气股份有限公司 一种乙烯齐聚的铁系催化剂组合物及其应用
US6900153B2 (en) 2001-03-28 2005-05-31 E.I. Du Pont De Nemours And Company Supported olefin polymerization catalysts
AU2002306188A1 (en) 2001-04-12 2002-10-28 Sasol Technology (Pty) Ltd Oligomerisation process and catalyst system
CN1142142C (zh) 2001-06-01 2004-03-17 中国科学院上海有机化学研究所 乙烯齐聚催化剂、合成方法和用途
EP1404446A2 (en) 2001-07-02 2004-04-07 Sasol Technology (Proprietary) Limited Catalyst comprising chromium and a ligand comprising a substituted cyclopentadiene and its use for trimerising olefins
CA2455853A1 (en) * 2001-08-01 2003-02-13 Shell Internationale Research Maatschappij B.V. Ligands and catalyst systems thereof for ethylene oligomerisation to linear alpha olefins
US6562973B1 (en) * 2001-08-15 2003-05-13 Equistar Chemicals, Lp Method for making late transition metal catalysts for olefin polymerization
JP2003071294A (ja) 2001-09-05 2003-03-11 Tosoh Corp エチレンの三量化触媒及びこの触媒を用いたエチレンの三量化方法
DE10145619A1 (de) 2001-09-15 2003-04-10 Basf Ag Verfahren zur Trimerisierung von alpha-Olefinen
JP2003088760A (ja) 2001-09-19 2003-03-25 Tosoh Corp エチレンの三量化触媒およびその触媒を用いたエチレンの三量化方法
KR100435513B1 (ko) 2001-10-05 2004-06-10 여천엔씨씨 주식회사 에틸렌 삼량화 반응에서 1-헥센의 선택도를 증가시키는촉매계
FR2833191B1 (fr) * 2001-12-10 2004-08-20 Inst Francais Du Petrole Composition catalytique et procede ameliores pour l'oligomerisation de l'ethylene, en particulier en hexene-1
US6911506B2 (en) 2001-12-10 2005-06-28 Chevron Phillips Chemical Company Lp Catalyst composition and olefin polymerization using same
JP4308015B2 (ja) 2001-12-20 2009-08-05 サソル テクノロジー （ピーティーワイ）リミテッド クロムを主成分とした触媒を使用したオレフィン類の三量化およびオリゴマー化
CN1606539A (zh) * 2001-12-20 2005-04-13 Sasol技术股份有限公司 使用铬基催化剂的烯烃寡聚和三聚
ATE291029T1 (de) 2002-01-03 2005-04-15 Repsol Quimica Sa Chromkatalysatoren aktiv in der olefinpolymerisation
MXPA04006611A (es) 2002-01-09 2004-10-04 Du Pont Catalizador para polimerizacion de olefinas.
US6777584B2 (en) * 2002-02-22 2004-08-17 Exxonmobil Research And Engineering Company Selective coupling of terminal olefins with ethylene to manufacture linear α-olefins
US6689848B2 (en) 2002-03-04 2004-02-10 Equistar Chemicals, Lp Late transition metal polymerization catalysts
JP2004136271A (ja) 2002-08-22 2004-05-13 Tosoh Corp エチレンの三量化触媒および該触媒を用いたエチレンの三量化方法
JP2004136270A (ja) 2002-08-22 2004-05-13 Tosoh Corp エチレンの三量化触媒および該触媒を用いたエチレンの三量化方法
US7053259B2 (en) 2002-09-17 2006-05-30 E. I. Du Pont De Nemours And Company Process of producing α-olefins
AU2003293320A1 (en) 2002-09-25 2004-05-13 Shell Internationale Research Maatschappij B.V. Catalyst systems for ethylene oligomerisation to linear alpha olefins
CN100519491C (zh) 2002-09-25 2009-07-29 国际壳牌研究有限公司 使用换热器制备直链α-烯烃低聚物的方法
EP1542946A1 (en) 2002-09-25 2005-06-22 Shell Internationale Researchmaatschappij B.V. Process for making a linear alpha-olefin oligomer using a heat exchanger
US7001964B2 (en) * 2002-10-04 2006-02-21 Chevron Phillips Chemical Company, Lp Selective isomerization and linear dimerization of olefins using cobalt catalysts
US6911505B2 (en) * 2002-10-04 2005-06-28 Chevron Phillips Chemical Company, Lp Selective isomerization and linear dimerization of olefins using cobalt catalysts
US20040143147A1 (en) 2002-11-08 2004-07-22 Ittel Steven Dale Process for producing alpha-olefins
DE60331252D1 (de) 2002-12-20 2010-03-25 Sasol Tech Pty Ltd Trimerisierung von olefinen
US7045632B2 (en) 2003-03-04 2006-05-16 Chevron Phillips Chemical Company, Lp Composition and method for a hexadentate ligand and bimetallic complex for polymerization of olefins
JP2004306014A (ja) 2003-03-26 2004-11-04 Sumitomo Chem Co Ltd オレフィン三量化触媒及びオレフィン三量体の製造方法
FR2857964B1 (fr) 2003-07-25 2008-02-15 Inst Francais Du Petrole Procede ameliore de production d'olefines-alpha legeres en particulier d'hexene-1, par oligomerisation de l'ethylene
US20050187418A1 (en) * 2004-02-19 2005-08-25 Small Brooke L. Olefin oligomerization
US20050187098A1 (en) 2004-02-20 2005-08-25 Knudsen Ronald D. Methods of preparation of an olefin oligomerization catalyst
US7384886B2 (en) 2004-02-20 2008-06-10 Chevron Phillips Chemical Company Lp Methods of preparation of an olefin oligomerization catalyst
WO2005082816A1 (en) * 2004-02-20 2005-09-09 Chevron Phillips Chemical Company Lp Methods of preparation of an olefin oligomerization catalyst
US20070043181A1 (en) 2005-08-19 2007-02-22 Knudsen Ronald D Methods of preparation of an olefin oligomerization catalyst
US7429684B2 (en) 2004-02-27 2008-09-30 Exxonmobile Research And Engineering Company Process for oligomerization of ethylene to linear α-olefins
GB0410604D0 (en) 2004-05-12 2004-06-16 Bp Chem Int Ltd Ethylene copolymers
CN101010351B (zh) 2004-07-09 2011-06-22 纳幕尔杜邦公司 用于烯烃聚合或低聚的催化剂
AR049714A1 (es) 2004-07-13 2006-08-30 Shell Int Research Proceso de preparacion de alfa olefinas lineales
GB0415879D0 (en) 2004-07-15 2004-08-18 Bp Chem Int Ltd Polymerisation catalyst
GB0418022D0 (en) 2004-08-12 2004-09-15 Bp Chem Int Ltd Polymerisation and oligomerisation catalyst
US7456284B2 (en) 2004-12-10 2008-11-25 Chevron Phillips Chemical Company Lp Methods for producing a hexadentate bimetallic complex
CN100372609C (zh) 2005-04-22 2008-03-05 中国科学院化学研究所 一种用于乙烯齐聚和聚合的催化剂及制备方法和用途
US7268096B2 (en) 2005-07-21 2007-09-11 Chevron Phillips Chemical Company Lp Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization
US7727926B2 (en) 2005-07-21 2010-06-01 Chevron Phillips Chemical Company Lp Diimine metal complexes, methods of synthesis, and method of using in oligomerization and polymerization
US7271121B2 (en) 2005-07-21 2007-09-18 Chevron Phillips Chemical Company Lp Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization
US7129304B1 (en) 2005-07-21 2006-10-31 Chevron Phillips Chemical Company Lp Dimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization
WO2007021955A2 (en) 2005-08-11 2007-02-22 E. I. Du Pont De Nemours And Company NITRO SUBSTITUTED α-OLEFIN SYNTHESIS CATALYSTS
WO2007059015A1 (en) 2005-11-10 2007-05-24 E.I. Du Pont De Nemours And Company Improved catalysts for alpha-olefin manufacture
DE102006001959A1 (de) 2006-01-13 2007-07-19 Basell Polyolefine Gmbh Verfahren zur Herstellung von unsymmetrischen Bis(imino)verbindungen
WO2008038173A2 (en) 2006-09-26 2008-04-03 Sasol Technology (Pty) Limited Polymerisation (including oligomerisation) of olefinic compounds in the presence of catalyst, and a catalyst activator including a halogenated organic group
US7902415B2 (en) 2007-12-21 2011-03-08 Chevron Phillips Chemical Company Lp Processes for dimerizing or isomerizing olefins

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1108967A (zh) * 1994-02-18 1995-09-27 菲利浦石油公司 烯烃的生产方法
WO2004056480A1 (en) * 2002-12-20 2004-07-08 Sasol Technology (Pty) Limited Tandem tetramerisation-polymerisation of olefins
CN1651142A (zh) * 2004-12-27 2005-08-10 中国石油大庆石化分公司研究院 用于乙烯齐聚的催化剂组分、制备方法及其应用

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