WO2014199626A1 - 熱硬化性組成物、有機el素子用面封止剤およびその硬化物 - Google Patents
熱硬化性組成物、有機el素子用面封止剤およびその硬化物 Download PDFInfo
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- WO2014199626A1 WO2014199626A1 PCT/JP2014/003074 JP2014003074W WO2014199626A1 WO 2014199626 A1 WO2014199626 A1 WO 2014199626A1 JP 2014003074 W JP2014003074 W JP 2014003074W WO 2014199626 A1 WO2014199626 A1 WO 2014199626A1
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- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- DQZNLOXENNXVAD-UHFFFAOYSA-N trimethoxy-[2-(7-oxabicyclo[4.1.0]heptan-4-yl)ethyl]silane Chemical compound C1C(CC[Si](OC)(OC)OC)CCC2OC21 DQZNLOXENNXVAD-UHFFFAOYSA-N 0.000 description 1
- 238000007738 vacuum evaporation Methods 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/02—Polyalkylene oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
- C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
- C08G65/08—Saturated oxiranes
- C08G65/10—Saturated oxiranes characterised by the catalysts used
- C08G65/105—Onium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
- C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
- C08G65/16—Cyclic ethers having four or more ring atoms
- C08G65/18—Oxetanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0041—Optical brightening agents, organic pigments
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/80—Constructional details
- H10K59/87—Passivation; Containers; Encapsulations
- H10K59/871—Self-supporting sealing arrangements
- H10K59/8722—Peripheral sealing arrangements, e.g. adhesives, sealants
Definitions
- the present invention relates to a thermosetting composition, a surface sealing agent for organic EL elements, and a cured product thereof.
- Organic EL elements are expected as liquid crystal backlights and self-luminous thin flat display devices.
- organic EL elements are extremely susceptible to deterioration when exposed to moisture and oxygen. Specifically, the interface between the metal electrode and the organic EL layer is peeled off due to the influence of moisture, the metal is oxidized to increase resistance, or the organic matter itself is altered by moisture. As a result, the organic EL element may not emit light or the brightness may be reduced.
- the organic EL element As one method for protecting the organic EL element from moisture and oxygen, there is a method of sealing the surface of the organic EL element with a transparent resin layer.
- the organic EL element is sealed by photocuring or thermosetting.
- a photocurable resin composition for example, a patent
- Document 1 and organic EL element sealing resin compositions for example, Patent Document 6) containing an epoxy compound, a polyester resin, and a Lewis acid compound have been proposed.
- a photocurable resin composition (Patent Documents 2 and 3) containing an epoxy resin, a photocationic polymerization initiator, and a polyoxymethylene polymer compound; and an epoxy resin;
- An epoxy resin powder coating (Patent Document 4) containing a curing agent, a curing accelerator, and a polyol; a thermosetting composition containing an epoxy compound, an amino compound, a catalyst such as nitrate, and a polyalkylene ether glycol
- Patent Documents 2 and 3 containing an epoxy resin, a photocationic polymerization initiator, and a polyoxymethylene polymer compound; and an epoxy resin
- An epoxy resin powder coating (Patent Document 4) containing a curing agent, a curing accelerator, and a polyol;
- a thermosetting composition containing an epoxy compound, an amino compound, a catalyst such as nitrate, and a polyalkylene ether glycol
- the surface sealing of the organic EL element is performed by applying a surface sealing agent on the organic EL element and then curing it.
- the curing can be photocuring or heat curing, but when the element is deteriorated by light, it is desirable to be heat curing.
- the present inventors have applied the surface sealant and heat-curing process; particularly, in the heat-curing process, the temperature distribution and viscosity of the coating film are changed, and unevenness and repellency are likely to occur, and the smoothness of the cured product layer surface It has been found that a new problem arises that tends to be low.
- the unevenness acts like a lens, and the light extracted from the organic EL element tends to be non-uniform in the surface.
- a barrier film such as an inorganic thin film is formed on the cured product layer, defects such as pinholes are likely to occur, a uniform inorganic barrier film cannot be formed, and sufficient barrier properties are difficult to obtain.
- thermosetting composition capable of forming a cured product layer having a high surface smoothness with less unevenness and repellency on an object to be coated such as an organic EL element.
- the purpose is to provide goods.
- thermosetting composition [1] (A) a cationically polymerizable compound having two or more cationically polymerizable functional groups in one molecule, (B) a thermal cationic polymerization initiator, and (C) a polyether compound And (D) a leveling agent, and has a viscosity of 50 to 30000 mPa ⁇ s at 25 ° C. and 2.5 rpm as measured with an E-type viscometer. [2] The thermosetting composition according to [1], wherein the component (D) is a compound selected from the group consisting of a silicone polymer and an acrylate polymer.
- thermosetting composition according to [1] or [2], wherein the component (C) has a weight average molecular weight of 250 to 10,000.
- the thermosetting according to any one of [1] to [4], wherein the cationically polymerizable functional group is one or more groups selected from the group consisting of an epoxy group, an oxetanyl group, and a vinyl ether group. Composition.
- thermosetting composition according to any one of [1] to [6], wherein the component (C) is a polyalkylene oxide. [8] 0.1 to 5 parts by mass of the component (B) and 0.01 to 1 part by mass of the component (D) with respect to 100 parts by mass of the component (A) [1] to [7 ] The thermosetting composition in any one of. [9] The thermosetting composition according to [8], wherein the component (C) is contained in an amount of less than 10 parts by mass with respect to 100 parts by mass of the component (A).
- thermosetting composition comprising the thermosetting composition according to any one of [1] to [9].
- thermosetting composition comprising the thermosetting composition according to any one of [1] to [9].
- thermosetting composition comprising the thermosetting composition according to any one of [1] to [9].
- thermosetting composition comprising the thermosetting composition according to any one of [1] to [9].
- thermosetting composition comprising the thermosetting composition according to any one of [1] to [9].
- thermosetting composition capable of forming a cured product layer with less surface irregularities and repellency and high surface smoothness on an object to be coated such as an organic EL element.
- thermosetting composition of the present invention includes (A) a cationic polymerizable compound, (B) a thermal cationic polymerization initiator, (C) a polyether compound, and (D) a leveling agent. .
- the cationic polymerizable compound may be a compound having two or more cationic polymerizable functional groups in one molecule.
- the cationic polymerizable functional group is at least one selected from the group consisting of an epoxy group, an oxetanyl group, and a vinyl ether group.
- there are a plurality of cationically polymerizable functional groups they may be the same as or different from each other.
- epoxy resins having two or more epoxy groups in one molecule include bisphenol type epoxy resins such as bisphenol A type, bisphenol F type, bisphenol E type, bisphenol S type, bisphenol AD type, and hydrogenated bisphenol A type.
- Diphenyl ether type epoxy resin phenol novolak type, cresol novolak type, biphenyl novolak type, bisphenol novolak type, naphthol novolak type, trisphenol novolak type, dicyclopentadiene novolak type and other novolak type epoxy resins; biphenyl type epoxy resin; naphthyl type Epoxy resin; aromatic epoxy resin such as triphenolalkane type epoxy resin such as triphenolmethane type, triphenolethane type, triphenolpropane type; Alicyclic epoxy resin; Aliphatic epoxy resins and the like are included.
- oxetanyl compounds having two or more oxetanyl groups in one molecule include 1,3-bis [(3-ethyl-3-oxetanyl) methoxy] benzene, 1,4-bis ⁇ [(3-ethyl-3 Aromatic oxetane compounds such as -oxetanyl) methoxy] methyl ⁇ benzene; Alicyclic such as 1,4-bis ⁇ [(3-ethyl-3-oxetanyl) methoxy] methyl ⁇ cyclohexane, 4,4′-bis ⁇ [(3-ethyl-3-oxetanyl) methoxy] methyl ⁇ bicyclohexane Oxetane compounds; Di [1-ethyl (3-oxetanyl)] methyl ether, bis (3-ethyl-3-oxetanylmethyl) ether, trimethylolpropane tris (3-ethyl-3-ox
- vinyl ether compounds having two or more vinyl ether groups in one molecule include alicyclic vinyl ether compounds such as cyclohexanedimethanol divinyl ether; Examples include aliphatic vinyl ether compounds such as ethylene glycol divinyl ether, diethylene glycol divinyl ether, triethylene glycol divinyl ether, propylene glycol divinyl ether, and dipropylene glycol divinyl ether.
- a cationically polymerizable compound that is liquid at 25 ° C. is preferable because the viscosity of the thermosetting composition can be easily adjusted.
- the cationically polymerizable compound that is liquid at 25 ° C. is preferably an epoxy resin having two or more epoxy groups in one molecule from the viewpoint that adhesion to an object is easily obtained.
- the epoxy resin is preferably an aromatic epoxy resin because it easily improves the moisture resistance of the cured product.
- the aromatic epoxy resin is preferably a bisphenol type epoxy compound or a cresol novolac type epoxy compound, and more preferably a bisphenol type epoxy compound.
- the bisphenol-type epoxy compound is preferably a compound represented by the general formula (X), and preferred examples include a compound represented by the general formula (X ′).
- X represents a single bond, a methylene group, an isopropylidene group, —S— or —SO 2 —; each R 1 independently has 1 to 5 carbon atoms.
- N represents an integer of 2 or more;
- P represents an integer of 0 to 4.
- n is preferably 2 to 4.
- the cationically polymerizable compound preferably has a low molecular weight because it is easy to adjust the viscosity of the thermosetting composition to a range described later and to ensure fluidity during coating or curing.
- the weight average molecular weight of the cationic polymerizable compound is preferably 200 to 800, and more preferably 300 to 700.
- the “weight average molecular weight (Mw)” is measured by gel permeation chromatography (GPC) using polystyrene as a standard substance.
- the cation polymerizable functional group equivalent of the cation polymerizable compound is preferably 100 to 800 g / eq.
- the viscosity of the cationically polymerizable compound at 25 ° C. and 2.5 rpm measured with an E-type viscometer is preferably 50 to 30000 mPa ⁇ s. This is because an epoxy resin having a viscosity in the above range can easily adjust the viscosity of the thermosetting composition to a range described later.
- the content of the cationically polymerizable compound can be 60% by mass or more, preferably 70% by mass or more with respect to the thermosetting composition.
- One type of (A) cationic polymerizable compound contained in the thermosetting composition may be used, or two or more types having different types and molecular weights may be combined.
- the thermal cationic polymerization initiator is a compound capable of generating a cationic species that initiates polymerization upon heating.
- the thermal cationic polymerization initiator is not particularly limited, and may be appropriately selected according to the curing conditions and the type of the cationic polymerizable compound.
- the thermal cationic polymerization initiator may be an onium salt such as a quaternary ammonium salt or a phosphonium salt.
- quaternary ammonium salt is preferable from the viewpoint that the storage stability of the thermosetting composition can be improved and coloring of the cured product can be suppressed.
- the quaternary ammonium salt include a salt (B1) containing a specific quaternary ammonium ion and a counter anion.
- the quaternary ammonium ion constituting the salt (B1) can be represented by the following general formula (1).
- R 1 , R 2 and R 3 in the general formula (1) are each independently an alkyl group having 1 to 10 carbon atoms which may have a substituent, and 6 to 10 carbon atoms which may have a substituent. Or an aryl group having 7 to 20 carbon atoms which may have a substituent.
- R 1 , R 2 and R 3 are preferably each independently a methyl group, a phenyl group or a benzyl group.
- R 1 , R 2 , and R 3 may have is not particularly limited, but is an alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, —F, —Cl, —Br , —I, —NO 2 , —CN, and a functional group selected from the group consisting of groups represented by the following general formula (2).
- R 13 , R 14 , and R 15 in the general formula (2) each independently represent a hydrogen group or a hydrocarbon group having 1 to 10 carbon atoms. Especially, it is preferable that all of R ⁇ 13> , R ⁇ 14> , and R ⁇ 15 > are hydrocarbon groups from a viewpoint of improving the storage stability of a thermosetting composition.
- the hydrocarbon group may be a linear, branched or cyclic aliphatic group, or may be aromatic.
- Ar in the general formula (1) represents an aryl group having 6 to 10 carbon atoms which may have a substituent.
- Ar is preferably an aromatic hydrocarbon group, and may be, for example, a phenyl group or a naphthyl group.
- the substituent that Ar in the general formula (1) may have is not particularly limited, and may be the same as the substituent that R 1 , R 2 , and R 3 in the general formula (1) may have.
- the bonding position of the substituent bonded to Ar and the number of substituents are not particularly limited.
- the substituent bonded to Ar is an electron withdrawing group; for example, —F, —Cl, —Br, —I, —NO 2 , or —CN, Ar in the general formula (1) and a methylene group
- the substituent is bonded to the meta position or the para position with respect to the bonding position with.
- an electron withdrawing group is bonded to this position, the curing reaction of the cationic polymerizable compound is easily promoted.
- the number of electron withdrawing groups bonded to Ar is preferably 2 or less.
- the substituent bonded to Ar is an electron donating group; for example, an alkyl group, an alkoxy group, or a group represented by the general formula (2), a bond between Ar in the general formula (1) and a methylene group It is preferred that the substituent is bonded to the para position relative to the position. When an electron donating group is bonded to this position, the curing reaction of the cationic polymerizable compound is easily promoted. When the substituent bonded to Ar is an electron donating group, the curing reaction of the cationically polymerizable compound is more easily promoted than when the substituent is an electron withdrawing group.
- an electron donating group for example, an alkyl group, an alkoxy group, or a group represented by the general formula (2)
- Preferred examples of the quaternary ammonium ion represented by the general formula (1) include the following ions.
- Examples of the counter anion constituting the salt (B1) include [CF 3 SO 3 ] ⁇ , [C 4 F 9 SO 3 ] ⁇ , [PF 6 ] ⁇ , [AsF 6 ] ⁇ and [Ph 4 B] ⁇ .
- R 16 represents an alkyl group having 1 to 10 carbon atoms
- R 16 represents an alkyl group having 1 to 10 carbon atoms
- an anion having a small logarithm (pKa) of the reciprocal of the acid dissociation constant is preferable. The smaller the pKa, the easier the salt (B1) is ionized and the curing reaction of the epoxy resin is promoted.
- Preferred examples of the salt (B1) include the following compounds.
- the salt (B1) When the salt (B1) is heated to a certain temperature or higher, the proton at the benzyl position of the quaternary ammonium ion of the salt (B1) is eliminated, and the proton is donated to the epoxy group of the epoxy resin. In the epoxy resin to which protons are donated, the epoxy group is ring-opened and polymerized with other epoxy resins to be cured. Thus, the salt (B1) can start the polymerization reaction of the epoxy resin by being heated to a certain temperature or higher. On the other hand, since such a reaction hardly occurs at a low temperature, the storage stability of the thermosetting composition can be improved.
- the reactivity of the quaternary ammonium ion can be adjusted by the substituent of the aryl group adjacent to the methylene group.
- the reactivity of a quaternary ammonium ion can be enhanced by using an aryl group substituent as an electron donating group.
- the content of the thermal cationic polymerization initiator is preferably 0.1 to 5 parts by mass, and preferably 0.1 to 3 parts by mass with respect to 100 parts by mass of the cationic polymerizable compound (component (A)). More preferred.
- the content of the thermal cationic polymerization initiator is a certain level or more, the cationically polymerizable compound is easily cured sufficiently.
- the content of the thermal cationic polymerization initiator is below a certain level, not only is the stability of the resin composition during storage difficult to impair, but the residual amount of unreacted thermal cationic polymerization initiator in the cured product is also reduced. It can be reduced, and the heat resistance of the cured product is hardly impaired.
- the thermal cationic polymerization initiator may be composed of only one kind of compound, or may be a combination of two or more kinds of compounds.
- Ratio of the amount of ammonium ions in the thermal cationic polymerization initiator to the amount of the cationic polymerizable functional group contained in the thermosetting composition is preferably 0.5 to 10%, more preferably 0.5 to 1%.
- thermosetting composition in particular, the thermosetting process, the present inventors may combine (C) a polyether compound and (D) a leveling agent. I found it effective.
- thermosetting composition in the heat curing process of the thermosetting composition, (C) the ether bond portion of the polyether compound does not interfere with the surface tension adjusting function of (D) the leveling agent, and (B) the thermal cationic polymerization initiator
- the cation can be captured and the polymerization of the (A) cationic polymerizable compound can be delayed. Thereby, the time during which the thermosetting composition can flow during the heat curing process can be lengthened; during this period, (D) the leveling agent can sufficiently act.
- polyether compound is a compound which contains the repeating unit which has an ether bond, and does not contain the above-mentioned cation polymerizable functional group.
- Such polyether compounds can be polyalkylene oxides, crown ethers, and the like.
- the number of carbon atoms in the alkylene chain of the alkylene oxide which is a structural unit of the polyalkylene oxide, is 2 to 4, preferably 2 to 3.
- the polyalkylene oxide include polyethylene glycol, polypropylene glycol, polyoxytetramethylene glycol and the like, and preferably polyethylene glycol.
- the molecular terminal of the polyalkylene oxide may be a hydroxyl group, or may be etherified or esterified with another compound.
- crown ethers examples include 12-crown-4, 15-crown-5, 18-crown-6 and the like.
- polyethylene glycol and crown ether are particularly preferable. This is because they are easily mixed with the (A) cationic polymerizable compound.
- the weight average molecular weight of the polyether compound is preferably 150 to 10,000, more preferably 250 to 10,000, and further preferably 400 to 10,000.
- the ether compound portion is sufficiently contained in the polyether compound, so that the cation of the thermal cationic polymerization initiator can be easily captured, and (A) polymerization of the cationic polymerizable compound It is easy to obtain a delayed reaction effect. As a result, it is easy to lengthen the time during which the thermosetting composition can flow in the heat curing process, and a sufficient leveling effect can be easily obtained.
- the molecular weight of the polyether compound is below a certain level, it is difficult to cause a decrease in solubility in the thermosetting composition and an increase in viscosity.
- the content of the polyether compound is preferably less than 10 parts by mass and more preferably 0.05 parts by mass or more and 8 parts by mass or less with respect to 100 parts by mass of the cationically polymerizable compound (component (A)). More preferably, it is 0.5 parts by mass or more and 5 parts by mass or less.
- the content of the polyether compound is not less than a certain value, the cation of the thermal cationic polymerization initiator is easily captured by the ether bond portion, and the effect of delaying the polymerization reaction of the cationic polymerizable compound is easily obtained. As a result, it is easy to sufficiently level the thermosetting composition.
- the content of the polyether compound is less than a certain value, it is easy to dissolve sufficiently in the thermosetting composition, and further, it is difficult to solidify when the composition is stored at room temperature, and the storage stability of the composition is not easily impaired. .
- the polyether compound can be added for the purpose of trapping the cation of the thermal cationic polymerization initiator in the heat curing process. Therefore, the content of the polyether compound is preferably set according to the content (molar amount) of the thermal cationic polymerization initiator. Specifically, by preventing the content of the thermal cationic polymerization initiator from increasing excessively (relative to the polyether compound), a sufficient polymerization delay effect can be easily obtained. On the other hand, by preventing the content of the polyether compound from excessively increasing (relative to the thermal cationic polymerization initiator), poor curing can be suppressed.
- the leveling agent has a surface tension ( ⁇ A) that is smaller than the surface tension ( ⁇ v) of the coating film of the thermosetting composition in the heat curing step, and the interfacial tension ( ⁇ I) between the thermosetting composition and the leveling agent is also It can be selected to be smaller.
- the leveling agent is preferably incompatible with the cationic polymerizable compound.
- Leveling agents improve the wettability of the composition to the coating object by adjusting the surface tension of the coating surface, and improve the fluidity and defoaming property of the coating surface to smooth the surface. These effects are often manifested in small additions. For this reason, for example, a silicone polymer or an acrylate polymer having a smaller surface modifying action than a fluorine polymer or the like is preferable.
- the silicone polymer is preferably a polymer containing a structure derived from polydimethylsiloxane represented by the following formula.
- N in the following formula is preferably 2 or more, more preferably 2 to 140.
- silicone-based polymer examples include polydimethylsiloxane, polyether-modified polydimethylsiloxane, and polymethylalkylsiloxane.
- the acrylate polymer is preferably an acrylic acid alkyl ester polymer.
- the number of carbon atoms in the alkyl chain of the acrylic acid alkyl ester is preferably 4 or more, and more preferably 6 or more.
- the upper limit of the number of carbon atoms of the alkyl chain of the acrylic acid alkyl ester can be 12, for example.
- Examples of the acrylic acid alkyl ester include butyl acrylate, 2-ethylhexyl acrylate, and the like.
- the acrylate polymer preferably does not contain a fluorine atom.
- the alkyl acrylate ester may be one type or two or more types.
- acrylate polymer examples include a copolymer of butyl acrylate and 2-ethylhexyl acrylate.
- the molecular weight of the silicone polymer or acrylate polymer can be about 1000 to 10,000.
- the leveling agent may be difficult to exude from the cured product.
- the leveling agent is easily oriented on the coating film surface of the thermosetting composition, and a sufficient leveling effect is easily obtained.
- the content of the leveling agent is preferably 0.01 to 1 part by mass, more preferably 0.05 to 0.5 part by mass with respect to 100 parts by mass of the cationically polymerizable compound (component (A)). preferable.
- component (A) cationically polymerizable compound
- the content of the leveling agent is a certain level or more, a sufficient amount of the leveling agent is easily oriented on the coating film surface of the curable resin composition, and a sufficient leveling effect is easily obtained.
- the content of the leveling agent is below a certain level, the compatibility between the leveling agent and the cationic polymerizable compound and the transparency of the cured product are difficult to be impaired.
- the content ratio (D) / (C) (mass ratio) of the leveling agent (D) to the polyether compound (C) is preferably 0.002 to 20, more preferably 0.01 to 10. Even more preferably, 0.03 to 5.
- thermosetting composition of the present invention may further contain (E) other optional components as long as the effects of the present invention are not impaired.
- other optional components include resin components other than the above (A), coupling agents, fillers, modifiers, antioxidants, stabilizers, solvents, and the like.
- Examples of other resin components include solid cationic polymerizable compounds (eg, solid epoxy resins), polyamide, polyamideimide, polyurethane, polybutadiene, polychloroprene, polyether, polyester, styrene-butadiene-styrene block Copolymers, petroleum resins, xylene resins, ketone resins, cellulose resins, fluorine-based oligomers, silicon-based oligomers, polysulfide-based oligomers and the like are included.
- solid cationic polymerizable compounds eg, solid epoxy resins
- polyamide polyamideimide
- polyurethane polybutadiene
- polychloroprene polyether
- polyester styrene-butadiene-styrene block Copolymers
- petroleum resins xylene resins
- ketone resins ketone resins
- cellulose resins fluorine-based oligomers
- coupling agents examples include silane coupling agents, titanium coupling agents, zirconium coupling agents, aluminum coupling agents and the like.
- the coupling agent can enhance the adhesion with the substrate of the organic EL device.
- silane coupling agents include 1) a silane coupling agent having an epoxy group, 2) a silane coupling agent having a functional group capable of reacting with an epoxy group, and 3) other silane coupling agents.
- the silane coupling agent is preferably a silane coupling agent that reacts with the epoxy resin in the thermosetting composition from the viewpoint of preventing the low molecular weight component from remaining in the cured film.
- the silane coupling agent that reacts with the epoxy resin is preferably 1) a silane coupling agent having an epoxy group, or 2) a silane coupling agent having a functional group capable of reacting with an epoxy group. Reacting with an epoxy group means an addition reaction with an epoxy group.
- Examples of the silane coupling agent having an epoxy group include ⁇ -glycidoxypropyltrimethoxysilane, ⁇ - (3,4-epoxycyclohexyl) ethyltrimethoxysilane, and the like.
- Functional groups capable of reacting with epoxy groups include amino groups such as primary amino groups and secondary amino groups; carboxyl groups and the like, and groups that can be converted into functional groups capable of reacting with epoxy groups (for example, Methacryloyl group, isocyanate group, etc.).
- silane coupling agent having a functional group capable of reacting with an epoxy group examples include N-2- (aminoethyl) -3-aminopropylmethyldimethoxysilane, N-2- (aminoethyl) -3- Aminopropylmethyltrimethoxysilane and the like are included. 3)
- silane coupling agents include vinyltriacetoxysilane and vinyltrimethoxysilane.
- One kind of these silane coupling agents may be contained in the thermosetting composition, or two or more kinds thereof may be contained.
- the molecular weight of the silane coupling agent is preferably 80 to 800. When the molecular weight of the silane coupling agent exceeds 800, the adhesion may be lowered.
- the content of the silane coupling agent is preferably 0.05 to 30 parts by mass, more preferably 0.1 to 20 parts by mass, with respect to 100 parts by mass of the thermosetting composition. More preferably, it is 3 to 10 parts by mass.
- Examples of the filler include glass beads, styrene polymer particles, methacrylate polymer particles, ethylene polymer particles, propylene polymer particles, and the like.
- Examples of the modifier include polymerization initiation assistants, antiaging agents, surfactants, plasticizers, and the like.
- Examples of stabilizers include ultraviolet absorbers, preservatives, antibacterial agents and the like.
- Antioxidants refer to those that deactivate radicals generated by plasma irradiation or sunlight irradiation (Hindered Amine Light Stabilizer, HALS) and those that decompose peroxides. Discoloration of the cured product of the thermosetting composition containing the antioxidant can be suppressed.
- antioxidants include Tinuvin 123 (bis (1-octyloxy-2,2,6,6-tetramethyl-4-piperidyl) sebacic acid), Tinuvin 765 (bis (1,2,2,6,6-pentamethyl). -4-piperidyl) sebacic acid and methyl, a mixture of 1,2,2,6,6-pentamethyl-4-piperidyl sebacic acid).
- Solvent can uniformly disperse or dissolve each component.
- the solvent is an organic solvent.
- examples thereof include ketone solvents such as acetone, methyl ethyl ketone, and methyl isobutyl ketone; ethers such as ethylene glycol monoalkyl ether, ethylene glycol dialkyl ether, propylene glycol, and dialkyl ether; Examples include aprotic polar solvents such as N-methylpyrrolidone; esters such as ethyl acetate and butyl acetate.
- the viscosity of the thermosetting composition of the present invention measured by an E-type viscometer at 25 ° C. and 2.5 rpm is preferably 50 to 30000 mPa ⁇ s, and preferably 100 to 10000 mPa ⁇ s. More preferably, it is s.
- coatability for example, screen printability
- the viscosity of the thermosetting composition is measured with an E-type viscometer (RC-500 manufactured by Toki Sangyo).
- the water content of the thermosetting composition of the present invention is preferably 0.1% by mass or less, and more preferably 0.06% by mass or less.
- Organic EL elements are easily degraded by moisture. Therefore, it is preferable to reduce the water content of the thermosetting composition as much as possible.
- the moisture content of the thermosetting composition can be obtained by weighing about 0.1 g of a sample sample, heating to 150 ° C. with a Karl Fischer moisture meter, and measuring the amount of water generated at that time (solid vaporization method). ).
- the reaction activity expression temperature of the thermosetting composition of the present invention is appropriately adjusted depending on the heat resistance temperature of the element to be surface-sealed, and is preferably 70 to 150 ° C., more preferably 80 to 110 ° C., 90 More preferably, the temperature is ⁇ 100 ° C.
- the reaction activity expression temperature is closely related to the curing temperature of the thermosetting composition. If the reaction activity expression temperature is 150 ° C. or lower, the thermosetting composition can be heat-cured at 150 ° C. or lower, and there is little possibility of affecting the organic EL element during surface sealing. On the other hand, when the reaction activity expression temperature is 70 ° C. or higher, an unnecessary curing reaction of the cationic polymerizable compound (component (A)) hardly occurs during storage of the composition, and storage stability is improved.
- the reaction activity expression temperature can be measured as a rising value of an exothermic peak measured by differential scanning calorimetry (DSC).
- the reaction activation temperature can be adjusted by the structure of the quaternary ammonium ion contained in (A) the cationic polymerizable compound or (B) the thermal cationic polymerization initiator, preferably (B) the thermal cationic polymerization initiator.
- the cured product of the thermosetting composition of the present invention preferably has high visible light permeability.
- a cured film obtained by curing a thermosetting composition having a thickness of 10 ⁇ m at 100 ° C. for 30 minutes has a parallel light transmittance in a wavelength region of 380 nm (visible / ultraviolet light) of 80% or more, more preferably 90% or more, More preferably, it is 95% or more.
- the parallel light transmittance is 80% or more, light emitted from the organic EL element can be efficiently extracted through the cured product of the thermosetting composition.
- the transparency of the cured product is not particularly limited.
- the parallel light transmittance of the cured product can be measured by a fully automatic haze meter TC-H III DPK manufactured by Tokyo Denshoku Co., Ltd.
- thermosetting composition of the present invention can be produced, for example, through a step of mixing each of the above components at a temperature lower than the reaction activity expression temperature (for example, 60 ° C. or lower) in an inert gas environment.
- the mixing of each component can be performed by a method of charging each component in a flask and stirring, or a method of kneading with a three roll mill.
- thermosetting composition of the present invention can be preferably used as an optical semiconductor surface sealant.
- An optical semiconductor is, for example, an element that converts electricity into light and emits light. Examples thereof include inorganic LED elements, organic EL elements, and the like, and preferably organic EL elements. That is, the thermosetting composition of the present invention is preferably used as a surface sealing agent for organic EL devices.
- FIG. 1 is a schematic diagram showing an example of an organic EL device that can constitute an organic EL panel.
- the organic EL device 20 is disposed between a display substrate 22 on which an organic EL element 24 is disposed, a counter substrate 26, and at least the organic EL element 24 and the counter substrate 26.
- a sealing member 28 for sealing the element 24 covers the periphery of the organic EL element 24 (surface-sealed), and is composed of a cured product of the surface sealing agent (thermosetting composition) of the present invention.
- the display substrate 22 and the counter substrate 26 are usually glass substrates or resin films, and at least one of the display substrate 22 and the counter substrate 26 is a transparent glass substrate or a transparent resin film.
- transparent resin films include aromatic polyester resins such as polyethylene terephthalate.
- the organic EL element 24 When the organic EL element 24 is a top emission type, the organic EL element 24 includes a pixel electrode layer 30 (made of aluminum or silver), an organic EL layer 32, and a counter electrode layer 34 (ITO) from the display substrate 22 side. (Indium and tin oxide) and IZO (indium and zinc oxide).
- the pixel electrode layer 30, the organic EL layer 32, and the counter electrode layer 34 can be formed by vacuum evaporation, sputtering, or the like.
- An organic EL device is, for example, 1) a step of preparing an organic EL element disposed on a substrate, 2) a step of covering the organic EL element with a surface sealing agent, and 3) a step of heating and curing the surface sealing agent. It can be manufactured through.
- the step of covering the organic EL element with the surface sealing agent can be performed by applying a liquid surface sealing agent or by thermocompression bonding a solid (sheet-like) surface sealing agent. It is preferable to carry out by applying a sealant.
- FIG. 2 is a schematic diagram showing an example of a manufacturing process of an organic EL device.
- the organic EL device 20 includes 1) a step of preparing the display substrate 22 on which the organic EL element 24 is laminated (FIG. 2A), and 2) applying the surface sealing agent of the present invention onto the organic EL element 24. And the step of forming the coating film 28A of the surface sealing agent (FIG. 2B) and 3) the counter substrate 26 is disposed on the coating film 28A of the surface sealing agent, and the coating film 28A of the surface sealing agent Is cured by heating to form the seal member 28, and the counter substrate 26 is attached (FIG. 2C). In this way, the organic EL device 20 can be obtained.
- the surface sealant can be applied by techniques such as screen printing, dispenser application, slit coating, and spray coating.
- the heat curing of the surface sealant can be performed at a relatively low temperature.
- the heat curing temperature may be any temperature at which (B) the thermal cationic polymerization initiator in the surface sealing agent is activated, preferably 70 to 150 ° C., more preferably 80 to 110 ° C., and still more preferably 90 ⁇ 100 ° C.
- the heat curing temperature is 70 ° C. or higher, (B) the thermal cationic polymerization initiator is sufficiently activated, and (A) the cationic polymerizable compound is sufficiently cured.
- the heat curing temperature is 150 ° C. or lower, the possibility of affecting the organic EL element during heat curing can be reduced.
- the heat curing can be performed by a known method such as heating with an oven or a hot plate.
- the heating time is preferably 10 to 120 minutes, more preferably 20 to 90 minutes, and further preferably 30 to 60 minutes.
- the thickness of the seal member 28 may be a thickness that can sufficiently cover the organic EL element 24, and may be, for example, about 0.1 to 20 ⁇ m.
- a passivation film may be further formed on the seal member 28 as necessary.
- the passivation film may cover the entire surface of the seal member 28 or may cover only a part thereof.
- the passivation film may be an inorganic compound film formed by a plasma CVD method, for example.
- the material of the passivation film is preferably a transparent inorganic compound, and examples thereof include silicon nitride, silicon oxide, SiONF, and SiON, but are not particularly limited.
- the thickness of the passivation film is preferably 0.1 to 5 ⁇ m.
- the surface sealing agent of the present invention contains (C) a polyether compound
- the time during which the surface sealing agent can flow without impairing the effect of the (D) leveling agent in the heat curing process of the surface sealing agent. Can be lengthened.
- the time during which (D) the leveling agent acts can be lengthened.
- thermosetting composition Cationic polymerizable compound Bisphenol F type epoxy resin (weight average molecular weight 338, epoxy equivalent 165 to 175 g / eq, E type viscosity (@ 25 ° C., 2.5 rpm) 3000 to 4000 mPa ⁇ s 1) Number of cationically polymerizable functional groups in one molecule: 2): YL983U, manufactured by Japan Epoxy Resin Co., Ltd.
- thermosetting composition (Example 1) In a flask substituted with nitrogen, 100 parts by mass of epoxy resin (YL983U), 2 parts by mass of a quaternary ammonium salt (CXC-1612), 2 parts by mass of a polyether compound (PEG # 400), 0.3 parts by mass Part of a leveling agent (LS-460) and 1 part by weight of a silane coupling agent (KBM-403) were mixed by stirring at 50 ° C. to obtain a thermosetting composition.
- epoxy resin YL983U
- CXC-1612 quaternary ammonium salt
- PEG # 400 polyether compound
- LS-460 leveling agent
- KBM-403 silane coupling agent
- thermosetting composition was obtained in the same manner as in Example 1 except that the composition of the thermosetting composition was changed as shown in Table 1.
- thermosetting composition The viscosity, storage stability, and smoothness of the cured product surface of the obtained thermosetting composition were evaluated by the following methods.
- thermosetting composition The viscosity of the obtained thermosetting composition was measured at 25 ° C. and 2.5 rpm using an E-type viscometer (RC-500 manufactured by Toki Sangyo).
- thermosetting composition (Storage stability) A predetermined amount of the obtained thermosetting composition was collected and stored at 23 ° C. for 24 hours, and then the presence or absence of white turbidity and fluidity of the thermosetting composition was observed. “No” if the thermosetting composition after storage was not cloudy and fluidity was not reduced; “Yes” if the thermosetting composition after storage was cloudy and fluidity was significantly reduced did.
- thermosetting composition (Smoothness of cured product layer surface)
- the obtained thermosetting composition was printed on a glass substrate (7 cm ⁇ 7 cm ⁇ 0.7 mm thickness) previously cleaned by ozone treatment using a screen printer (Screen Printer Model 2200, manufactured by MITANI).
- coating of the thermosetting composition was performed so that it might become 5 cm x 5 cm x 10 micrometers thickness in a dry state.
- the printed glass substrate was heated on a hot plate heated to 100 ° C. for 30 minutes to obtain a cured product layer. And the obtained hardened
- the cured product layer had no coating defects (repels) or irregularities, and the surface was smooth.
- thermosetting compositions of Examples 1 to 9 including both the polyether compound and the leveling agent are free from coating defects (repels) and unevenness, and have a smooth surface. It turns out that the nature is high.
- thermosetting composition of Comparative Example 1 that does not contain a polyether compound and the cured product layer of the thermosetting composition of Comparative Example 2 that does not contain a leveling agent both have coating defects (repellency) and It can be seen that there are irregularities and the surface smoothness is low.
- thermosetting the thermosetting composition captures the cation of the thermal cationic polymerization initiator, delays the cationic polymerization reaction of the epoxy resin, and the thermosetting composition flows. The possible time can be lengthened. This is considered to be because the leveling agent was able to sufficiently act in the heat curing process of the thermosetting composition.
- thermosetting composition capable of forming a cured product layer with less surface irregularities and repellency and high surface smoothness on an object to be coated such as an organic EL element.
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2017186521A (ja) * | 2016-03-31 | 2017-10-12 | 三井化学株式会社 | 熱硬化性組成物、これを含む封止剤、有機el素子用枠封止剤、及び有機el素子用面封止剤、並びにその硬化物 |
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---|---|---|---|---|
CN107079542B (zh) * | 2014-12-09 | 2019-03-01 | 三井化学株式会社 | 有机el元件用面密封材及其固化物 |
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KR20210118289A (ko) | 2020-03-19 | 2021-09-30 | 삼성디스플레이 주식회사 | 전자 소자용 밀봉 또는 충전 조성물 및 전자 장치 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008031424A (ja) * | 2006-07-06 | 2008-02-14 | Daicel Chem Ind Ltd | 脂環式ジエポキシ化合物、エポキシ樹脂組成物及び硬化物 |
JP2009203431A (ja) * | 2008-02-29 | 2009-09-10 | Kyocera Chemical Corp | 注形用エポキシ樹脂組成物および高熱伝導コイル |
JP2013018921A (ja) * | 2011-07-13 | 2013-01-31 | Daicel Corp | 硬化性エポキシ樹脂組成物 |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4397998A (en) | 1981-12-14 | 1983-08-09 | Shell Oil Company | Curable epoxy compositions suitable for use in RIM processes |
US6306926B1 (en) * | 1998-10-07 | 2001-10-23 | 3M Innovative Properties Company | Radiopaque cationically polymerizable compositions comprising a radiopacifying filler, and method for polymerizing same |
JP2003246850A (ja) | 2001-12-19 | 2003-09-05 | Sekisui Chem Co Ltd | 光硬化組成物、及び、光硬化組成物を用いた塗装物品、接着物品又は封入物品 |
JP3820147B2 (ja) | 2001-12-26 | 2006-09-13 | 積水化学工業株式会社 | 光硬化可能組成物 |
JP2004067828A (ja) | 2002-08-05 | 2004-03-04 | Nippon Perunotsukusu Kk | エポキシ樹脂粉体塗料 |
JP4384509B2 (ja) | 2003-01-09 | 2009-12-16 | 積水化学工業株式会社 | 有機エレクトロルミネッセンス素子の封止方法及び有機エレクトロルミネッセンス素子 |
KR101121671B1 (ko) * | 2003-08-12 | 2012-03-14 | 미쓰이 가가쿠 가부시키가이샤 | 광경화형 수지 조성물 및 그것을 이용한 플랫 패널디스플레이용 실링제 |
CN100404578C (zh) * | 2003-08-12 | 2008-07-23 | 三井化学株式会社 | 光固化型树脂组合物和用其的平板显示器用密封剂 |
US7192991B2 (en) * | 2003-11-26 | 2007-03-20 | 3M Innovative Properties Company | Cationically curable composition |
JP4687027B2 (ja) * | 2004-01-30 | 2011-05-25 | Dic株式会社 | 硬化性樹脂組成物、転写材及び保護層の形成方法 |
EP1893704B1 (en) * | 2005-04-22 | 2010-03-31 | Sun Chemical B.V. | An ink jet ink |
JP4795779B2 (ja) * | 2005-11-09 | 2011-10-19 | 株式会社アルバック | 有機エレクトロルミネッセンス表示パネル |
JP2010100736A (ja) * | 2008-10-24 | 2010-05-06 | Toyo Ink Mfg Co Ltd | 紫外線硬化型缶用塗料組成物及びその利用 |
JP2010248387A (ja) * | 2009-04-16 | 2010-11-04 | Sekisui Chem Co Ltd | 光学部材用光硬化性樹脂組成物、接着剤、及び、タッチパネル |
JP5612406B2 (ja) * | 2010-09-13 | 2014-10-22 | Jsr株式会社 | 光ファイバ素線の最外層被覆用液状硬化性樹脂組成物及び光ファイバ素線 |
JP5348341B1 (ja) * | 2012-04-27 | 2013-11-20 | Jsr株式会社 | 基材の処理方法、仮固定用組成物および半導体装置 |
JP5697048B2 (ja) | 2012-06-15 | 2015-04-08 | 古河電気工業株式会社 | 有機エレクトロルミネッセンス素子封止用樹脂組成物、有機エレクトロルミネッセンス素子用封止フィルム、有機エレクトロルミネッセンス素子用ガスバリアフィルムおよびこれを用いた有機エレクトロルミネッセンス素子 |
-
2014
- 2014-06-10 JP JP2014547612A patent/JP5763280B2/ja active Active
- 2014-06-10 TW TW103120041A patent/TWI601783B/zh active
- 2014-06-10 WO PCT/JP2014/003074 patent/WO2014199626A1/ja active Application Filing
- 2014-06-10 KR KR1020157025702A patent/KR101697892B1/ko active IP Right Grant
- 2014-06-10 CN CN201480012025.1A patent/CN105026493B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008031424A (ja) * | 2006-07-06 | 2008-02-14 | Daicel Chem Ind Ltd | 脂環式ジエポキシ化合物、エポキシ樹脂組成物及び硬化物 |
JP2009203431A (ja) * | 2008-02-29 | 2009-09-10 | Kyocera Chemical Corp | 注形用エポキシ樹脂組成物および高熱伝導コイル |
JP2013018921A (ja) * | 2011-07-13 | 2013-01-31 | Daicel Corp | 硬化性エポキシ樹脂組成物 |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102015212058A1 (de) | 2015-06-29 | 2016-12-29 | Tesa Se | Klebemasse insbesondere zur Kapselung einer elektronischen Anordnung |
WO2017001126A1 (de) | 2015-06-29 | 2017-01-05 | Tesa Se | Klebemasse insbesondere zur kapselung einer elektronischen anordnung |
JP2018527425A (ja) * | 2015-06-29 | 2018-09-20 | テーザ・ソシエタス・ヨーロピア | 特に電子的装置のカプセル化のための接着剤 |
KR102064332B1 (ko) * | 2015-06-29 | 2020-01-09 | 테사 소시에타스 유로파에아 | 접착제 조성물, 특히, 전자 장치를 캡슐화하기 위한 접착제 조성물. |
JP2017186521A (ja) * | 2016-03-31 | 2017-10-12 | 三井化学株式会社 | 熱硬化性組成物、これを含む封止剤、有機el素子用枠封止剤、及び有機el素子用面封止剤、並びにその硬化物 |
JP2018193480A (ja) * | 2017-05-17 | 2018-12-06 | 東京応化工業株式会社 | 硬化性組成物、硬化膜、表示パネル、及び硬化物の製造方法 |
WO2019162035A1 (de) | 2018-02-20 | 2019-08-29 | Tesa Se | Zusammensetzung zur erzeugung einer klebemasse insbesondere zur kapselung einer elektronischen anordnung |
DE102018202545A1 (de) | 2018-02-20 | 2019-08-22 | Tesa Se | Zusammensetzung zur Erzeugung einer Klebemasse insbesondere zur Kapselung einer elektronischen Anordnung |
JP2020066643A (ja) * | 2018-10-22 | 2020-04-30 | アイカ工業株式会社 | 光カチオン硬化型エポキシ樹脂組成物 |
JP7128716B2 (ja) | 2018-10-22 | 2022-08-31 | アイカ工業株式会社 | 光カチオン硬化型エポキシ樹脂組成物 |
KR20210098943A (ko) | 2018-11-28 | 2021-08-11 | 세키스이가가쿠 고교가부시키가이샤 | 경화성 수지 조성물, 경화물, 및, 유기 el 표시 소자 |
WO2021006070A1 (ja) * | 2019-07-05 | 2021-01-14 | 三井化学株式会社 | 有機el表示素子用封止剤および有機el表示装置 |
JPWO2021006070A1 (zh) * | 2019-07-05 | 2021-01-14 | ||
JP7412430B2 (ja) | 2019-07-05 | 2024-01-12 | 三井化学株式会社 | 有機el表示素子用封止剤および有機el表示装置 |
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JPWO2014199626A1 (ja) | 2017-02-23 |
CN105026493A (zh) | 2015-11-04 |
TWI601783B (zh) | 2017-10-11 |
TW201502193A (zh) | 2015-01-16 |
KR20150119935A (ko) | 2015-10-26 |
KR101697892B1 (ko) | 2017-01-18 |
JP5763280B2 (ja) | 2015-08-12 |
CN105026493B (zh) | 2017-07-07 |
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