WO2008093567A1 - 洗濯耐久性に優れた含フッ素共重合体および汚れ脱離剤 - Google Patents

洗濯耐久性に優れた含フッ素共重合体および汚れ脱離剤 Download PDF

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Publication number
WO2008093567A1
WO2008093567A1 PCT/JP2008/050796 JP2008050796W WO2008093567A1 WO 2008093567 A1 WO2008093567 A1 WO 2008093567A1 JP 2008050796 W JP2008050796 W JP 2008050796W WO 2008093567 A1 WO2008093567 A1 WO 2008093567A1
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Prior art keywords
group
fluorine
carbon atoms
monomer
release agent
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PCT/JP2008/050796
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English (en)
French (fr)
Inventor
Norimasa Uesugi
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Daikin Industries, Ltd.
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Publication date
Application filed by Daikin Industries, Ltd. filed Critical Daikin Industries, Ltd.
Priority to JP2008556055A priority Critical patent/JP5245834B2/ja
Priority to CN200880003412.3A priority patent/CN101595142B/zh
Priority to ES08703640T priority patent/ES2421658T3/es
Priority to US12/525,434 priority patent/US20100093919A1/en
Priority to EP08703640.6A priority patent/EP2110391B1/en
Priority to CA2677192A priority patent/CA2677192C/en
Publication of WO2008093567A1 publication Critical patent/WO2008093567A1/ja

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/22—Esters containing halogen
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/27—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof of alkylpolyalkylene glycol esters of unsaturated carboxylic acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/285—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides
    • D06M15/295—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides containing fluorine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/11—Oleophobic properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/12—Hydrophobic properties

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

(a) フルオロアルキル基を有する含フッ素単量体、  (b) ポリアルキレングリコール（メタ）アクリレート、 (c) アセトアセチル基を有する単量体、および (d) カチオン供与基を有する単量体 を必須成分とする含フッ素共重合体と架橋剤を必須成分とする汚れ脱離剤組成物は、繊維織物等の基材に対して、洗濯耐久性を維持しながら、優れた撥油性、防汚性および汚れ脱離性を付与する。好ましい単量体(a)は、次式のものである。 　　CH2=C(－X)－C(=O)－Y－Z－Rf            (１) ［式中、Ｘは、水素原子、炭素数１～２１の直鎖状または分岐状のアルキル基、フッ素原子、塩素原子などであり；　Ｙは、－Ｏ－または－ＮＨ－であり；　Ｚは、炭素数１～１０の脂肪族基、炭素数６～１８の芳香族基または環状脂肪族基などであり；　Ｒｆは、炭素数１～２１の直鎖状または分岐状のフルオロアルキル基である。]
PCT/JP2008/050796 2007-02-02 2008-01-22 洗濯耐久性に優れた含フッ素共重合体および汚れ脱離剤 WO2008093567A1 (ja)

Priority Applications (6)

Application Number Priority Date Filing Date Title
JP2008556055A JP5245834B2 (ja) 2007-02-02 2008-01-22 汚れ脱離剤組成物
CN200880003412.3A CN101595142B (zh) 2007-02-02 2008-01-22 洗涤耐久性优异的含氟共聚物和去污剂
ES08703640T ES2421658T3 (es) 2007-02-02 2008-01-22 Copolímero que contiene flúor que tiene una excelente resistencia al lavado y agente de eliminación de la suciedad
US12/525,434 US20100093919A1 (en) 2007-02-02 2008-01-22 Fluorine-containing copolymer having excellent washing resistance and soil release agent
EP08703640.6A EP2110391B1 (en) 2007-02-02 2008-01-22 Fluorine-containing copolymer having excellent washing resistance and soil release agent
CA2677192A CA2677192C (en) 2007-02-02 2008-01-22 Fluorine-containing copolymer having excellent washing resistance and soil release agent

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007023666 2007-02-02
JP2007-023666 2007-02-02

Publications (1)

Publication Number Publication Date
WO2008093567A1 true WO2008093567A1 (ja) 2008-08-07

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PCT/JP2008/050796 WO2008093567A1 (ja) 2007-02-02 2008-01-22 洗濯耐久性に優れた含フッ素共重合体および汚れ脱離剤

Country Status (9)

Country Link
US (1) US20100093919A1 (ja)
EP (1) EP2110391B1 (ja)
JP (2) JP5245834B2 (ja)
KR (1) KR20090116774A (ja)
CN (1) CN101595142B (ja)
CA (1) CA2677192C (ja)
ES (1) ES2421658T3 (ja)
TW (1) TWI437010B (ja)
WO (1) WO2008093567A1 (ja)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009014039A1 (ja) * 2007-07-20 2009-01-29 Daikin Industries, Ltd. 撥アルコール性および汚れ脱離性を有する含フッ素繊維加工剤
WO2010110339A1 (ja) 2009-03-25 2010-09-30 ダイキン工業株式会社 含フッ素ポリマーから成る界面活性剤
WO2011152126A1 (ja) * 2010-06-02 2011-12-08 Dic株式会社 カチオン重合性組成物、それを含む接着剤、ならびに、それらを用いて得られた硬化物及び偏光板
WO2013077451A1 (ja) * 2011-11-25 2013-05-30 日産化学工業株式会社 反応性含フッ素高分岐ポリマー及びそれを含む硬化性組成物
JP2013223859A (ja) * 2012-03-19 2013-10-31 Toyo Ink Sc Holdings Co Ltd 硬化性分散剤とその製造方法、及びそれを用いた顔料組成物
WO2014003095A1 (ja) * 2012-06-29 2014-01-03 株式会社ネオス (メタ)アクリレート系共重合体、抗菌剤、抗菌性付与樹脂組成物及び帯電防止性付与樹脂組成物

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20120040609A (ko) * 2010-10-19 2012-04-27 현대자동차주식회사 고내구성을 가지는 시트 원단의 방오처리 방법
CN102153902B (zh) * 2011-03-11 2013-05-29 安徽嘉智信诺化工有限公司 一种涂料油墨用氟碳抗缩孔流平剂
WO2013115196A1 (ja) * 2012-01-31 2013-08-08 旭硝子株式会社 含フッ素共重合体およびその製造方法、ならびに撥水撥油剤組成物
CN103694429B (zh) * 2014-01-15 2017-01-25 太仓中化环保化工有限公司 含氟嵌段共聚物及其制备方法和应用
JP6713796B2 (ja) * 2015-03-28 2020-06-24 株式会社日本触媒 塗料用水性樹脂組成物
MX2018000740A (es) * 2015-07-20 2018-05-15 Dow Global Technologies Llc Aditivo de recubrimiento.
EP3287009A1 (en) 2016-08-26 2018-02-28 Green Impact Holding AG Non-leaching surface sanitizer and wipe with improved washability and/or absorbency
US11919986B2 (en) 2019-03-01 2024-03-05 Nanyang Technological University Fouling prevention ability-imparting agent and water treatment membrane manufactured using same
CN110820336A (zh) * 2019-10-31 2020-02-21 江苏箭鹿毛纺股份有限公司 一种防水面料及其生产方法
CN113881002B (zh) * 2021-11-17 2023-08-22 湘潭大学 一种两亲性嵌段共聚物及其制备和纳米胶束的制备与应用

Citations (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS53134786A (en) 1977-04-28 1978-11-24 Asahi Glass Co Ltd Water-and oil-repelling agents having improved stain-removing properties
JPS59204980A (ja) 1983-05-04 1984-11-20 旭硝子株式会社 耐久性の優れた防汚加工剤
JPS627782A (ja) 1985-03-12 1987-01-14 Daikin Ind Ltd 防汚剤
JPH03103411A (ja) * 1989-06-21 1991-04-30 Daikin Ind Ltd 新規共重合体
JPH03126771A (ja) * 1989-10-12 1991-05-29 Showa Highpolymer Co Ltd 防汚塗料組成物
JPH059414A (ja) * 1991-07-04 1993-01-19 Showa Highpolymer Co Ltd 防汚塗料組成物
JPH07238118A (ja) * 1994-02-28 1995-09-12 Daicel Chem Ind Ltd 樹脂組成物およびその製造方法
JPH09165420A (ja) * 1995-12-15 1997-06-24 Showa Highpolymer Co Ltd ポリマーエマルジョンの製造方法
JPH09188727A (ja) * 1996-01-08 1997-07-22 Toyo Ink Mfg Co Ltd 自己架橋性樹脂および架橋性樹脂組成物
JPH1045993A (ja) * 1996-05-22 1998-02-17 Nippon Paint Co Ltd 硬化性樹脂組成物および塗料
JPH10109034A (ja) * 1996-05-22 1998-04-28 Nippon Paint Co Ltd マロネート基を結合したアクリル単量体およびその製造法
JP2000290640A (ja) 1999-02-04 2000-10-17 Daikin Ind Ltd 撥水撥油剤
US6326447B1 (en) 1998-06-19 2001-12-04 E. I. Du Pont De Nemours And Company Polymeric compositions for soil release on fabrics
WO2002090402A2 (en) 2001-05-08 2002-11-14 3M Innovative Properties Company Novel fluoroalkyl polymers containing cationic segment
WO2005090423A1 (ja) 2004-03-23 2005-09-29 Asahi Glass Company, Limited 耐水耐油剤組成物
WO2007007743A1 (ja) * 2005-07-14 2007-01-18 Daikin Industries, Ltd. 含フッ素重合体および汚れ脱離剤

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4529658A (en) * 1982-10-13 1985-07-16 Minnesota Mining And Manufacturing Company Fluorochemical copolymers and ovenable paperboard and textile fibers treated therewith
US4900615A (en) * 1986-03-11 1990-02-13 Union Oil Company Of California Textile materials and compositions for use therein
US4791166A (en) * 1988-03-23 1988-12-13 Hoechst Celanese Corporation Fluorocarbon polymer compositions and methods
US5143991A (en) * 1989-06-21 1992-09-01 Daikin Industries, Ltd. Copolymer desoiling agent
US5387640A (en) * 1992-01-22 1995-02-07 Bayer Aktiengesellschaft Fluorine-containing copolymers and aqueous dispersions prepared therefrom
DE4201604A1 (de) * 1992-01-22 1993-07-29 Bayer Ag Fluorhaltige copolymerisate und daraus hergestellte waessrige dispersionen
DE4338910C1 (de) * 1993-11-15 1995-02-16 Bernstein Hans Spezialfabrik Sicherheitsschalter
JP3575043B2 (ja) * 1994-02-21 2004-10-06 大日本インキ化学工業株式会社 フッ素系共重合体の製造方法及び撥水撥油剤
CA2205765A1 (en) * 1996-05-22 1997-11-22 Nippon Paint Co., Ltd. Curable resin composition for coating use
CA2205753A1 (en) * 1996-05-22 1997-11-22 Kei Aoki Method for preparing malonate group-containing acrylate monomers
JP3820694B2 (ja) * 1997-08-06 2006-09-13 ダイキン工業株式会社 新規共重合体および防汚加工剤
JP2000212549A (ja) * 1999-01-25 2000-08-02 Asahi Glass Co Ltd 撥水撥油剤組成物およびその製造方法
US6274060B1 (en) * 1999-02-04 2001-08-14 Daikin Industries, Ltd. Water- and oil-repellent
JP4967190B2 (ja) * 2000-12-26 2012-07-04 旭硝子株式会社 水性塗料組成物、塗装方法及び塗装物品
US6479605B1 (en) * 2001-05-15 2002-11-12 E. I. Du Pont De Nemours And Company High-durability, low-yellowing repellent for textiles
US7186769B2 (en) * 2003-08-12 2007-03-06 Hexion Specialty Chemicals, Inc. Water-dispersible polyester stabilized fluoroalkyl compositions
CN101506257B (zh) * 2006-08-25 2012-08-08 克莱里安特财务(Bvi)有限公司 防油、防水和防污的甲基丙烯酸全氟烷基乙酯共聚物

Patent Citations (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS53134786A (en) 1977-04-28 1978-11-24 Asahi Glass Co Ltd Water-and oil-repelling agents having improved stain-removing properties
JPS59204980A (ja) 1983-05-04 1984-11-20 旭硝子株式会社 耐久性の優れた防汚加工剤
JPS627782A (ja) 1985-03-12 1987-01-14 Daikin Ind Ltd 防汚剤
JPH03103411A (ja) * 1989-06-21 1991-04-30 Daikin Ind Ltd 新規共重合体
JPH03126771A (ja) * 1989-10-12 1991-05-29 Showa Highpolymer Co Ltd 防汚塗料組成物
JPH059414A (ja) * 1991-07-04 1993-01-19 Showa Highpolymer Co Ltd 防汚塗料組成物
JPH07238118A (ja) * 1994-02-28 1995-09-12 Daicel Chem Ind Ltd 樹脂組成物およびその製造方法
JPH09165420A (ja) * 1995-12-15 1997-06-24 Showa Highpolymer Co Ltd ポリマーエマルジョンの製造方法
JPH09188727A (ja) * 1996-01-08 1997-07-22 Toyo Ink Mfg Co Ltd 自己架橋性樹脂および架橋性樹脂組成物
JPH1045993A (ja) * 1996-05-22 1998-02-17 Nippon Paint Co Ltd 硬化性樹脂組成物および塗料
JPH10109034A (ja) * 1996-05-22 1998-04-28 Nippon Paint Co Ltd マロネート基を結合したアクリル単量体およびその製造法
US6326447B1 (en) 1998-06-19 2001-12-04 E. I. Du Pont De Nemours And Company Polymeric compositions for soil release on fabrics
JP2000290640A (ja) 1999-02-04 2000-10-17 Daikin Ind Ltd 撥水撥油剤
WO2002090402A2 (en) 2001-05-08 2002-11-14 3M Innovative Properties Company Novel fluoroalkyl polymers containing cationic segment
JP2004526042A (ja) 2001-05-08 2004-08-26 スリーエム イノベイティブ プロパティズ カンパニー カチオン部分を含む新規なフルオロアルキルポリマー
WO2005090423A1 (ja) 2004-03-23 2005-09-29 Asahi Glass Company, Limited 耐水耐油剤組成物
EP1728806A1 (en) 2004-03-23 2006-12-06 Asahi Glass Company, Limited Waterproofing/oilproofing agent composition
WO2007007743A1 (ja) * 2005-07-14 2007-01-18 Daikin Industries, Ltd. 含フッ素重合体および汚れ脱離剤

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
"EPA INTENSIFIES SCIENTIFIC INVESTIGATION OF A CHEMICAL PROCESSING AID", EPA ENVIRONMENTAL NEWS FOR RELEASE MONDAY, April 2003 (2003-04-01), Retrieved from the Internet <URL:http://www.epa.gov/opptintr/pfoa/pfoaprs.pdf>
EPA OPPT FACT SHEET, 14 April 2003 (2003-04-14), Retrieved from the Internet <URL:http://www.epa.gov/opptintr/pfoa/pfoafacts.pdf>
FEDERAL REGISTER, vol. 68, no. 73, 16 April 2003 (2003-04-16), Retrieved from the Internet <URL:http://www.epa.gov/opptintr/pfoa/pfoafr.pdf>
P. SHERMAN; S. SMITH; B, JOHANNESSEN, TEXTILE RESEARCH JOURNAL, vol. 39, 1969, pages 499

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JP5392081B2 (ja) * 2007-07-20 2014-01-22 ダイキン工業株式会社 撥アルコール性および汚れ脱離性を有する含フッ素繊維加工剤
WO2009014039A1 (ja) * 2007-07-20 2009-01-29 Daikin Industries, Ltd. 撥アルコール性および汚れ脱離性を有する含フッ素繊維加工剤
WO2010110339A1 (ja) 2009-03-25 2010-09-30 ダイキン工業株式会社 含フッ素ポリマーから成る界面活性剤
JPWO2010110339A1 (ja) * 2009-03-25 2012-10-04 ダイキン工業株式会社 含フッ素ポリマーから成る界面活性剤
JP2015145511A (ja) * 2009-03-25 2015-08-13 ダイキン工業株式会社 含フッ素ポリマーから成る界面活性剤
WO2011152126A1 (ja) * 2010-06-02 2011-12-08 Dic株式会社 カチオン重合性組成物、それを含む接着剤、ならびに、それらを用いて得られた硬化物及び偏光板
JP4947244B2 (ja) * 2010-06-02 2012-06-06 Ｄｉｃ株式会社 カチオン重合性組成物、それを含む接着剤、ならびに、それらを用いて得られた硬化物及び偏光板
US20140308503A1 (en) * 2011-11-25 2014-10-16 Nissan Chemical Industries, Ltd. Reactive fluorine-containing hghly branched polymer and curable composition containing same
JPWO2013077451A1 (ja) * 2011-11-25 2015-04-27 日産化学工業株式会社 反応性含フッ素高分岐ポリマー及びそれを含む硬化性組成物
WO2013077451A1 (ja) * 2011-11-25 2013-05-30 日産化学工業株式会社 反応性含フッ素高分岐ポリマー及びそれを含む硬化性組成物
US9546298B2 (en) 2011-11-25 2017-01-17 Nissan Chemical Industries, Ltd. Reactive fluorine-containing highly branched polymer and curable composition containing the same
JP2013223859A (ja) * 2012-03-19 2013-10-31 Toyo Ink Sc Holdings Co Ltd 硬化性分散剤とその製造方法、及びそれを用いた顔料組成物
WO2014003095A1 (ja) * 2012-06-29 2014-01-03 株式会社ネオス (メタ)アクリレート系共重合体、抗菌剤、抗菌性付与樹脂組成物及び帯電防止性付与樹脂組成物
JPWO2014003095A1 (ja) * 2012-06-29 2016-06-02 株式会社ネオス （メタ）アクリレート系共重合体、抗菌剤、抗菌性付与樹脂組成物及び帯電防止性付与樹脂組成物
KR101730274B1 (ko) * 2012-06-29 2017-04-25 네오스 컴파니 리미티드 (메트)아크릴레이트계 공중합체, 항균제, 항균성 부여 수지 조성물 및 대전 방지성 부여 수지 조성물

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JP5245834B2 (ja) 2013-07-24
JPWO2008093567A1 (ja) 2010-05-20
EP2110391B1 (en) 2013-07-10
EP2110391A1 (en) 2009-10-21
CN101595142A (zh) 2009-12-02
JP5621858B2 (ja) 2014-11-12
US20100093919A1 (en) 2010-04-15
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CA2677192C (en) 2011-12-20
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