WO2009014039A1 - 撥アルコール性および汚れ脱離性を有する含フッ素繊維加工剤 - Google Patents

撥アルコール性および汚れ脱離性を有する含フッ素繊維加工剤 Download PDF

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WO2009014039A1
WO2009014039A1 PCT/JP2008/062825 JP2008062825W WO2009014039A1 WO 2009014039 A1 WO2009014039 A1 WO 2009014039A1 JP 2008062825 W JP2008062825 W JP 2008062825W WO 2009014039 A1 WO2009014039 A1 WO 2009014039A1
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monomer
fluorine
group
weight
parts
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PCT/JP2008/062825
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English (en)
French (fr)
Inventor
Kouji Kubota
Masashi Nanri
Hirotoshi Sakashita
Takashi Enomoto
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Daikin Industries, Ltd.
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Priority to EP20080791220 priority Critical patent/EP2177550B1/en
Priority to ES08791220.0T priority patent/ES2524063T3/es
Priority to JP2009524457A priority patent/JP5392081B2/ja
Priority to US12/669,731 priority patent/US20100216363A1/en
Priority to KR1020107003646A priority patent/KR101185652B1/ko
Publication of WO2009014039A1 publication Critical patent/WO2009014039A1/ja

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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C08F214/186—Monomers containing fluorine with non-fluorinated comonomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
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    • C08F220/22—Esters containing halogen
    • C08F220/24—Esters containing halogen containing perhaloalkyl radicals
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    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
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    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/285—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides
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    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/285—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides
    • D06M15/29—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides containing a N-methylol group or an etherified N-methylol group; containing a N-aminomethylene group; containing a N-sulfidomethylene group
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    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/285—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides
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    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
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    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C08F220/282—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing two or more oxygen atoms
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
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    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C08F220/283—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing one or more carboxylic moiety in the chain, e.g. acetoacetoxyethyl(meth)acrylate
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    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Abstract

（ａ）フルオロアルキル基またはフルオロアルケニル基を有する単量体、および （ｂ）アルキレンオキサイド基を有する単量体、および （ｃ）アセトアセチル基を有する単量体、および （ｄ）-CH(OH)-CH2-Cl基を有する単量体、および （ｅ）-CH(OH)-CH2-OH基を有する単量体 から誘導された繰返単位を必須成分とし、 　単量体（ａ）と単量体（ｂ）と単量体（ｃ）と単量体（ｄ）と単量体（ｅ）の量がそれぞれ３０～８０重量部と１～３０重量部と０．５～２０重量部と０．５～２０重量部と０．５～２０重量部である含フッ素共重合体は、繊維製品などの基材に対して、洗濯耐久性を維持しながら、優れた撥アルコール性と撥油性と防汚性と汚れ脱離性を付与する。含フッ素共重合体は、汚れ脱離性を有する含フッ素繊維加工剤の活性成分として機能する。
PCT/JP2008/062825 2007-07-20 2008-07-16 撥アルコール性および汚れ脱離性を有する含フッ素繊維加工剤 WO2009014039A1 (ja)

Priority Applications (5)

Application Number Priority Date Filing Date Title
EP20080791220 EP2177550B1 (en) 2007-07-20 2008-07-16 Fluorine-containing fiber processing agent having alcohol repellency and soil release properties
ES08791220.0T ES2524063T3 (es) 2007-07-20 2008-07-16 Agente de procesamiento de fibras que contiene flúor que tiene repelencia a los alcoholes y propiedades de eliminación de suciedad
JP2009524457A JP5392081B2 (ja) 2007-07-20 2008-07-16 撥アルコール性および汚れ脱離性を有する含フッ素繊維加工剤
US12/669,731 US20100216363A1 (en) 2007-07-20 2008-07-16 Fluorine-containing fiber processing agent having alcohol repellency and soil release properties
KR1020107003646A KR101185652B1 (ko) 2007-07-20 2008-07-16 발알코올성 및 오염 탈리성을 갖는 불소 함유 섬유 가공제

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007189437 2007-07-20
JP2007-189437 2007-07-20

Publications (1)

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WO2009014039A1 true WO2009014039A1 (ja) 2009-01-29

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PCT/JP2008/062825 WO2009014039A1 (ja) 2007-07-20 2008-07-16 撥アルコール性および汚れ脱離性を有する含フッ素繊維加工剤

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US (1) US20100216363A1 (ja)
EP (1) EP2177550B1 (ja)
JP (1) JP5392081B2 (ja)
KR (1) KR101185652B1 (ja)
ES (1) ES2524063T3 (ja)
TW (1) TWI450909B (ja)
WO (1) WO2009014039A1 (ja)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPWO2010110339A1 (ja) * 2009-03-25 2012-10-04 ダイキン工業株式会社 含フッ素ポリマーから成る界面活性剤

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CN102153902B (zh) * 2011-03-11 2013-05-29 安徽嘉智信诺化工有限公司 一种涂料油墨用氟碳抗缩孔流平剂
CA2992498C (en) * 2015-07-20 2022-11-22 Dow Global Technologies Llc A coating additive
JP6953548B2 (ja) * 2017-10-27 2021-10-27 富士フイルム株式会社 高分子化合物、液晶組成物、位相差層、光学フィルム、偏光板および画像表示装置
KR102508178B1 (ko) * 2022-07-08 2023-03-10 이정현 방오 코팅된 바지의 제조방법 및 이로부터 제조된 기능성 바지

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Publication number Priority date Publication date Assignee Title
JPH1149825A (ja) * 1997-08-06 1999-02-23 Daikin Ind Ltd 新規共重合体および防汚加工剤
WO2005092997A1 (ja) * 2004-03-26 2005-10-06 Daikin Industries, Ltd. 表面処理剤と、含フッ素単量体および含フッ素重合体
WO2007007743A1 (ja) * 2005-07-14 2007-01-18 Daikin Industries, Ltd. 含フッ素重合体および汚れ脱離剤
WO2008093567A1 (ja) * 2007-02-02 2008-08-07 Daikin Industries, Ltd. 洗濯耐久性に優れた含フッ素共重合体および汚れ脱離剤

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPWO2010110339A1 (ja) * 2009-03-25 2012-10-04 ダイキン工業株式会社 含フッ素ポリマーから成る界面活性剤
JP2015145511A (ja) * 2009-03-25 2015-08-13 ダイキン工業株式会社 含フッ素ポリマーから成る界面活性剤

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EP2177550A1 (en) 2010-04-21
US20100216363A1 (en) 2010-08-26
EP2177550B1 (en) 2014-11-05
JPWO2009014039A1 (ja) 2010-09-30
KR101185652B1 (ko) 2012-09-24
JP5392081B2 (ja) 2014-01-22
KR20100044221A (ko) 2010-04-29
TWI450909B (zh) 2014-09-01
TW200911850A (en) 2009-03-16
EP2177550A4 (en) 2011-02-16
ES2524063T3 (es) 2014-12-03

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