WO2009034773A1 - 含フッ素重合体およびこれを有効成分とする表面改質剤 - Google Patents

含フッ素重合体およびこれを有効成分とする表面改質剤 Download PDF

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Publication number
WO2009034773A1
WO2009034773A1 PCT/JP2008/062783 JP2008062783W WO2009034773A1 WO 2009034773 A1 WO2009034773 A1 WO 2009034773A1 JP 2008062783 W JP2008062783 W JP 2008062783W WO 2009034773 A1 WO2009034773 A1 WO 2009034773A1
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WIPO (PCT)
Prior art keywords
integer
fluorine
containing polymer
surface modifier
active ingredient
Prior art date
Application number
PCT/JP2008/062783
Other languages
English (en)
French (fr)
Inventor
Satoshi Kurihara
Seiichiro Murata
Katsuyuki Sato
Masayosi Horiuti
Sumiko Mouri
Hideki Abe
Ji-Shan Jin
Original Assignee
Unimatec Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unimatec Co., Ltd. filed Critical Unimatec Co., Ltd.
Priority to JP2009532100A priority Critical patent/JP5493860B2/ja
Priority to CA2697402A priority patent/CA2697402C/en
Priority to CN2008801064484A priority patent/CN101802028B/zh
Priority to US12/677,187 priority patent/US8501888B2/en
Priority to EP08778200.9A priority patent/EP2189481B1/en
Priority to KR1020107005998A priority patent/KR101131428B1/ko
Publication of WO2009034773A1 publication Critical patent/WO2009034773A1/ja

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/22—Esters containing halogen
    • C08F220/24—Esters containing halogen containing perhaloalkyl radicals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1807—C7-(meth)acrylate, e.g. heptyl (meth)acrylate or benzyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)

Abstract

　一般式　CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cOCOCR=CH2(ここで、Rは水素原子またはメチル基であり、nは1～6、好ましくは2～4の整数であり、aは1～4の整数であり、bは0～3の整数であり、cは1～3の整数である)で表されるフルオロアルキルアルコール(メタ)アクリル酸誘導体を重合単位で5～100重量％含有する含フッ素重合体。この含フッ素重合体の有機溶剤溶液または水性分散液は、例えば撥水撥油剤、オイルバリヤなどの表面改質剤として有効に用いられる。
PCT/JP2008/062783 2007-09-10 2008-07-16 含フッ素重合体およびこれを有効成分とする表面改質剤 WO2009034773A1 (ja)

Priority Applications (6)

Application Number Priority Date Filing Date Title
JP2009532100A JP5493860B2 (ja) 2007-09-10 2008-07-16 含フッ素重合体およびこれを有効成分とする表面改質剤
CA2697402A CA2697402C (en) 2007-09-10 2008-07-16 Fluorine-containing polymer and surface-modifying agent containing the same as active ingredient
CN2008801064484A CN101802028B (zh) 2007-09-10 2008-07-16 含氟聚合物及以其为有效成分的表面改性剂
US12/677,187 US8501888B2 (en) 2007-09-10 2008-07-16 Fluorine-containing polymer and surface-modifying agent containing the same as active ingredient
EP08778200.9A EP2189481B1 (en) 2007-09-10 2008-07-16 Fluorine-containing polymer and surface modifier containing the same as active ingredient
KR1020107005998A KR101131428B1 (ko) 2007-09-10 2008-07-16 함불소 중합체 및 이것을 유효성분으로 하는 표면개질제

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2007233555 2007-09-10
JP2007-233555 2007-09-10
JP2007233554 2007-09-10
JP2007-233554 2007-09-10

Publications (1)

Publication Number Publication Date
WO2009034773A1 true WO2009034773A1 (ja) 2009-03-19

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PCT/JP2008/062783 WO2009034773A1 (ja) 2007-09-10 2008-07-16 含フッ素重合体およびこれを有効成分とする表面改質剤

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Country Link
US (1) US8501888B2 (ja)
EP (1) EP2189481B1 (ja)
JP (1) JP5493860B2 (ja)
KR (1) KR101131428B1 (ja)
CN (1) CN101802028B (ja)
CA (1) CA2697402C (ja)
WO (1) WO2009034773A1 (ja)

Cited By (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010189449A (ja) * 2006-03-10 2010-09-02 Unimatec Co Ltd ポリフルオロアルキルアイオダイドおよびその製造法
JP2011098250A (ja) * 2009-11-04 2011-05-19 Unimatec Co Ltd ポリフルオロアルキルホスホン酸塩乳化剤
WO2012020735A1 (ja) * 2010-08-11 2012-02-16 旭硝子株式会社 撥水剤組成物、その製造方法、疎水性基材処理剤組成物および物品
WO2012036036A1 (ja) 2010-09-13 2012-03-22 ユニマテック株式会社 含フッ素共重合体
WO2013058337A1 (ja) * 2011-10-19 2013-04-25 ダイキン工業株式会社 含フッ素組成物および含フッ素重合体
WO2013058156A1 (ja) 2011-10-18 2013-04-25 ユニマテック株式会社 含フッ素共重合体およびこれを有効成分とする表面改質剤
WO2013058336A1 (ja) * 2011-10-19 2013-04-25 ダイキン工業株式会社 含フッ素組成物および表面処理剤
WO2013058335A1 (ja) * 2011-10-19 2013-04-25 ダイキン工業株式会社 含フッ素組成物およびその用途
JP2013091753A (ja) * 2011-10-27 2013-05-16 Shin-Etsu Chemical Co Ltd 硬化性樹脂組成物
WO2013088902A1 (ja) 2011-12-12 2013-06-20 ユニマテック株式会社 含フッ素共重合体およびそれを有効成分とする撥水撥油剤
JP2013216747A (ja) * 2012-04-06 2013-10-24 Nitto Denko Corp 撥油性が付与された通気フィルム
JP2014084404A (ja) * 2012-10-24 2014-05-12 Shin Etsu Chem Co Ltd 粘着剤用離型性組成物
WO2014136892A1 (ja) 2013-03-06 2014-09-12 ユニマテック株式会社 含フッ素オリゴマー、それを用いたナノシリカコンポジット粒子およびそれらの製造法
WO2014136895A1 (ja) 2013-03-06 2014-09-12 ユニマテック株式会社 含フッ素オリゴマー、それを用いたナノシリカコンポジット粒子およびそれらの製造法
JP2014172952A (ja) * 2013-03-07 2014-09-22 Unimatec Co Ltd 含フッ素重合体およびこれを有効成分とする表面改質剤
WO2015064360A1 (ja) 2013-11-01 2015-05-07 ユニマテック株式会社 含フッ素重合体およびこれを有効成分とする表面改質剤
WO2015098850A1 (ja) * 2013-12-25 2015-07-02 ユニマテック株式会社 含フッ素２ブロック共重合体
JP2015224187A (ja) * 2014-05-26 2015-12-14 ユニマテック株式会社 含フッ素ウレタン（メタ）アクリレートの製造法
JP2016018008A (ja) * 2014-07-04 2016-02-01 旭化成イーマテリアルズ株式会社 ペリクル、ペリクル付フォトマスク、及び半導体素子の製造方法
KR20170116057A (ko) 2015-02-13 2017-10-18 유니마테크 가부시키가이샤 함불소 공중합체 및 이것을 유효 성분으로 하는 표면개질제
WO2018084086A1 (ja) 2016-11-01 2018-05-11 ユニマテック株式会社 含フッ素重合体およびこれを有効成分とする防錆剤
WO2018174041A1 (ja) 2017-03-22 2018-09-27 ユニマテック株式会社 ポリフルオロアルキルリン酸エステルまたはその塩およびそれらを有効成分とする離型剤
WO2021065137A1 (ja) 2019-10-03 2021-04-08 ユニマテック株式会社 非粘着性組成物
WO2023286402A1 (ja) 2021-07-12 2023-01-19 ユニマテック株式会社 含フッ素共重合体およびこれを用いた表面改質基材

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US9290596B2 (en) * 2010-05-27 2016-03-22 The Chemours Company Fc, Llc Solvent-based fluoropolymer additives and their use in coating compositions
US9029452B2 (en) * 2010-05-27 2015-05-12 E I Du Pont De Nemours And Company Fluoropolymer additive for coatings
WO2013150781A1 (ja) * 2012-04-06 2013-10-10 日東電工株式会社 撥油性が付与された通気シート
KR102008301B1 (ko) * 2013-01-18 2019-08-07 엘지디스플레이 주식회사 투명기판 표면처리방법 및 표면처리된 투명기판을 포함하는 표시소자

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Cited By (53)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010189449A (ja) * 2006-03-10 2010-09-02 Unimatec Co Ltd ポリフルオロアルキルアイオダイドおよびその製造法
JP2011098250A (ja) * 2009-11-04 2011-05-19 Unimatec Co Ltd ポリフルオロアルキルホスホン酸塩乳化剤
WO2012020735A1 (ja) * 2010-08-11 2012-02-16 旭硝子株式会社 撥水剤組成物、その製造方法、疎水性基材処理剤組成物および物品
JPWO2012020735A1 (ja) * 2010-08-11 2013-10-28 旭硝子株式会社 撥水剤組成物、その製造方法、疎水性基材処理剤組成物および物品
CN103052698A (zh) * 2010-08-11 2013-04-17 旭硝子株式会社 拒水剂组合物、其制造方法、疏水性基材处理剂组合物和物品
JP5962507B2 (ja) * 2010-08-11 2016-08-03 旭硝子株式会社 撥水剤組成物、その製造方法、疎水性基材処理剤組成物、物品およびその製造方法
US8921482B2 (en) 2010-08-11 2014-12-30 Asahi Glass Company, Limited Water repellent composition, its production method, hydrophobic substrate treating agent composition and article
US9803120B2 (en) 2010-08-11 2017-10-31 Asahi Glass Company, Limited Water repellent composition, its production method, hydrophobic substrate treating agent composition and article
US8987397B2 (en) 2010-09-13 2015-03-24 Unimatec Co., Ltd. Fluorine-containing copolymer
US20130172502A1 (en) * 2010-09-13 2013-07-04 Unimatec Co., Ltd. Fluorine-containing copolymer
WO2012036036A1 (ja) 2010-09-13 2012-03-22 ユニマテック株式会社 含フッ素共重合体
KR20130088151A (ko) 2010-09-13 2013-08-07 유니마테크 가부시키가이샤 함불소 공중합체
WO2013058156A1 (ja) 2011-10-18 2013-04-25 ユニマテック株式会社 含フッ素共重合体およびこれを有効成分とする表面改質剤
WO2013058335A1 (ja) * 2011-10-19 2013-04-25 ダイキン工業株式会社 含フッ素組成物およびその用途
JP2013100497A (ja) * 2011-10-19 2013-05-23 Daikin Industries Ltd 含フッ素組成物および含フッ素重合体
JP2013100495A (ja) * 2011-10-19 2013-05-23 Daikin Industries Ltd 含フッ素組成物およびその用途
WO2013058337A1 (ja) * 2011-10-19 2013-04-25 ダイキン工業株式会社 含フッ素組成物および含フッ素重合体
JP2013100496A (ja) * 2011-10-19 2013-05-23 Daikin Industries Ltd 含フッ素組成物および表面処理剤
WO2013058336A1 (ja) * 2011-10-19 2013-04-25 ダイキン工業株式会社 含フッ素組成物および表面処理剤
JP2013091753A (ja) * 2011-10-27 2013-05-16 Shin-Etsu Chemical Co Ltd 硬化性樹脂組成物
KR20140101784A (ko) 2011-12-12 2014-08-20 유니마테크 가부시키가이샤 함불소 공중합체 및 그것을 유효 성분으로 하는 발수발유제
WO2013088902A1 (ja) 2011-12-12 2013-06-20 ユニマテック株式会社 含フッ素共重合体およびそれを有効成分とする撥水撥油剤
JP2013216747A (ja) * 2012-04-06 2013-10-24 Nitto Denko Corp 撥油性が付与された通気フィルム
JP2014084404A (ja) * 2012-10-24 2014-05-12 Shin Etsu Chem Co Ltd 粘着剤用離型性組成物
EP3243853A1 (en) 2013-03-06 2017-11-15 Unimatec Co., Ltd. Fluorine-containing oligomer, nano-silica composite particles using the same, and methods for producing both
US9695263B2 (en) 2013-03-06 2017-07-04 Unimatec Co., Ltd. Fluorine-containing oligomer, nano-silica composite particles using the same, and methods for producing both
WO2014136895A1 (ja) 2013-03-06 2014-09-12 ユニマテック株式会社 含フッ素オリゴマー、それを用いたナノシリカコンポジット粒子およびそれらの製造法
WO2014136892A1 (ja) 2013-03-06 2014-09-12 ユニマテック株式会社 含フッ素オリゴマー、それを用いたナノシリカコンポジット粒子およびそれらの製造法
US9803044B2 (en) 2013-03-06 2017-10-31 Unimatec Co., Ltd. Fluorine-containing oligomer, nano-silica composite particles using the same, and methods for producing both
JPWO2014136895A1 (ja) * 2013-03-06 2017-02-16 ユニマテック株式会社 含フッ素オリゴマー、それを用いたナノシリカコンポジット粒子およびそれらの製造法
JP2014172952A (ja) * 2013-03-07 2014-09-22 Unimatec Co Ltd 含フッ素重合体およびこれを有効成分とする表面改質剤
WO2015064360A1 (ja) 2013-11-01 2015-05-07 ユニマテック株式会社 含フッ素重合体およびこれを有効成分とする表面改質剤
KR20160083006A (ko) 2013-11-01 2016-07-11 유니마테크 가부시키가이샤 함불소 중합체 및 이것을 유효 성분으로 하는 표면개질제
JPWO2015064360A1 (ja) * 2013-11-01 2017-03-09 ユニマテック株式会社 含フッ素重合体およびこれを有効成分とする表面改質剤
WO2015098850A1 (ja) * 2013-12-25 2015-07-02 ユニマテック株式会社 含フッ素２ブロック共重合体
US10196473B2 (en) 2013-12-25 2019-02-05 Unimatec Co., Ltd. Fluorine-containing diblock copolymer
JP2015124233A (ja) * 2013-12-25 2015-07-06 ユニマテック株式会社 含フッ素２ブロック共重合体
JP2015224187A (ja) * 2014-05-26 2015-12-14 ユニマテック株式会社 含フッ素ウレタン（メタ）アクリレートの製造法
JP2016018008A (ja) * 2014-07-04 2016-02-01 旭化成イーマテリアルズ株式会社 ペリクル、ペリクル付フォトマスク、及び半導体素子の製造方法
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US10344172B2 (en) 2015-02-13 2019-07-09 Unimatec Co., Ltd. Fluorine-containing copolymer and surface-modifying agent comprising the same as active ingredient
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JPWO2018084086A1 (ja) * 2016-11-01 2019-07-25 ユニマテック株式会社 含フッ素重合体およびこれを有効成分とする防錆剤
EP3536719B1 (en) * 2016-11-01 2022-10-12 Unimatec Co., Ltd. Fluoropolymer and rust preventive containing same as active ingredient
WO2018174041A1 (ja) 2017-03-22 2018-09-27 ユニマテック株式会社 ポリフルオロアルキルリン酸エステルまたはその塩およびそれらを有効成分とする離型剤
KR20190132417A (ko) 2017-03-22 2019-11-27 유니마테크 가부시키가이샤 폴리플루오로알킬인산에스테르 또는 그 염 및 그것들을 유효 성분으로 하는 이형제
US10836780B2 (en) 2017-03-22 2020-11-17 Unimatec Co., Ltd Polyfluoroalkyl phosphoric acid ester or salt thereof, and mold-releasing agent comprising the same as an active ingredient
WO2021065137A1 (ja) 2019-10-03 2021-04-08 ユニマテック株式会社 非粘着性組成物
JPWO2021065137A1 (ja) * 2019-10-03 2021-04-08
KR20220046646A (ko) 2019-10-03 2022-04-14 유니마테크 가부시키가이샤 비점착성 조성물
WO2023286402A1 (ja) 2021-07-12 2023-01-19 ユニマテック株式会社 含フッ素共重合体およびこれを用いた表面改質基材
KR20240032079A (ko) 2021-07-12 2024-03-08 유니마테크 가부시키가이샤 함불소 공중합체 및 이것을 사용한 표면개질 기재

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EP2189481A4 (en) 2010-12-15
JPWO2009034773A1 (ja) 2010-12-24
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CA2697402C (en) 2013-01-22
US20110009555A1 (en) 2011-01-13
KR20100059881A (ko) 2010-06-04
CA2697402A1 (en) 2009-03-19
CN101802028B (zh) 2012-08-29
EP2189481A1 (en) 2010-05-26
CN101802028A (zh) 2010-08-11
EP2189481B1 (en) 2014-02-12
US8501888B2 (en) 2013-08-06

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