WO2009054176A1 - 撥水撥油剤 - Google Patents

撥水撥油剤 Download PDF

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Publication number
WO2009054176A1
WO2009054176A1 PCT/JP2008/064277 JP2008064277W WO2009054176A1 WO 2009054176 A1 WO2009054176 A1 WO 2009054176A1 JP 2008064277 W JP2008064277 W JP 2008064277W WO 2009054176 A1 WO2009054176 A1 WO 2009054176A1
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WO
WIPO (PCT)
Prior art keywords
repellent
meth
fluorine
water
benzyl
Prior art date
Application number
PCT/JP2008/064277
Other languages
English (en)
French (fr)
Inventor
Ji-Shan Jin
Sumiko Mouri
Katsuyuki Sato
Original Assignee
Unimatec Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unimatec Co., Ltd. filed Critical Unimatec Co., Ltd.
Priority to EP08792334A priority Critical patent/EP2208770B9/en
Priority to CN200880112526A priority patent/CN101835868A/zh
Priority to CA2702687A priority patent/CA2702687C/en
Priority to US12/739,028 priority patent/US8796368B2/en
Priority to KR1020107010638A priority patent/KR101456864B1/ko
Publication of WO2009054176A1 publication Critical patent/WO2009054176A1/ja

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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1807—C7-(meth)acrylate, e.g. heptyl (meth)acrylate or benzyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/22—Esters containing halogen
    • C08F220/24—Esters containing halogen containing perhaloalkyl radicals
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
    • C09D133/16—Homopolymers or copolymers of esters containing halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
    • D06M15/256—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons containing fluorine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/273—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof of unsaturated carboxylic esters having epoxy groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • D06M15/576—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C08F220/285—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing a polyether chain in the alcohol moiety
    • C08F220/286—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing a polyether chain in the alcohol moiety and containing polyethylene oxide in the alcohol moiety, e.g. methoxy polyethylene glycol (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/205—Compounds containing groups, e.g. carbamates
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    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/11—Oleophobic properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/12—Hydrophobic properties

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

　(a)一般式 CnF2n+1CmH2mOCOCR=CH2(ここで、Rは水素原子またはメチル基であり、nは4、5または6であり、mは1、2、3または4である)で表わされるパーフルオロアルキルアルキル(メタ)アクリレート、(b)ベンジル(メタ)アクリレート、(c)ベンジル(メタ)アクリレート以外の非フッ素系重合性単量体および(d)架橋性基含有重合性単量体を共重合単位として含有する含フッ素共重合体の水性分散液に、該水性分散液中の固形分重量に対して重量比で0.05～3.0となる量のブロックドイソシアネートが添加された撥水撥油剤。
PCT/JP2008/064277 2007-10-22 2008-08-08 撥水撥油剤 WO2009054176A1 (ja)

Priority Applications (5)

Application Number Priority Date Filing Date Title
EP08792334A EP2208770B9 (en) 2007-10-22 2008-08-08 Water-repellent oil-repellent agent
CN200880112526A CN101835868A (zh) 2007-10-22 2008-08-08 拒水拒油剂
CA2702687A CA2702687C (en) 2007-10-22 2008-08-08 Water- and oil-repellent
US12/739,028 US8796368B2 (en) 2007-10-22 2008-08-08 Water-and oil-repellent
KR1020107010638A KR101456864B1 (ko) 2007-10-22 2008-08-08 발수발유제

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007273280A JP5315663B2 (ja) 2007-10-22 2007-10-22 撥水撥油剤
JP2007-273280 2007-10-22

Publications (1)

Publication Number Publication Date
WO2009054176A1 true WO2009054176A1 (ja) 2009-04-30

Family

ID=40579283

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/064277 WO2009054176A1 (ja) 2007-10-22 2008-08-08 撥水撥油剤

Country Status (7)

Country Link
US (1) US8796368B2 (ja)
EP (1) EP2208770B9 (ja)
JP (1) JP5315663B2 (ja)
KR (1) KR101456864B1 (ja)
CN (1) CN101835868A (ja)
CA (1) CA2702687C (ja)
WO (1) WO2009054176A1 (ja)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009108296A (ja) * 2007-10-11 2009-05-21 Yunimatekku Kk 撥水撥油剤
WO2011062292A1 (en) * 2009-11-20 2011-05-26 Daikin Industries, Ltd. Fluoropolymers and treatment agent
WO2011062294A1 (en) * 2009-11-20 2011-05-26 Daikin Industries, Ltd. Fluoropolymers and surface treatment agent
US20110281483A1 (en) * 2010-01-13 2011-11-17 Hirschmann Franz Von Waterproofing Compound and Waterproofing-Processing Method for Waterproofing a Wide Variety of Natual and Synthetic Fabrics and Materials
WO2011153048A1 (en) 2010-05-31 2011-12-08 Corning Incorporated Microreactor device having an essentially vertical or inclined upper portion comprising means for collection and removal of gas formed in situ during a liquid-medium reaction and method
WO2013115196A1 (ja) * 2012-01-31 2013-08-08 旭硝子株式会社 含フッ素共重合体およびその製造方法、ならびに撥水撥油剤組成物

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KR101578243B1 (ko) * 2008-06-04 2015-12-16 아사히 가라스 가부시키가이샤 공중합체, 그 제조 방법 및 발수 발유제 조성물
US9096695B2 (en) 2008-06-12 2015-08-04 Unimatec Co., Ltd. Method for producing an aqueous emulsion
CN102149738B (zh) * 2008-09-15 2016-02-10 大金工业株式会社 拒水和拒油组合物
JP5413508B2 (ja) * 2009-09-01 2014-02-12 ダイキン工業株式会社 紙用耐水耐油剤、紙処理方法および加工紙
CN103052698A (zh) * 2010-08-11 2013-04-17 旭硝子株式会社 拒水剂组合物、其制造方法、疏水性基材处理剂组合物和物品
JP5480930B2 (ja) * 2011-03-31 2014-04-23 ダイキン工業株式会社 含フッ素共重合体を含有する組成物
US8852693B2 (en) * 2011-05-19 2014-10-07 Liquipel Ip Llc Coated electronic devices and associated methods
JP5541272B2 (ja) * 2011-12-12 2014-07-09 ユニマテック株式会社 含フッ素共重合体およびそれを有効成分とする撥水撥油剤
WO2013115197A1 (ja) * 2012-01-31 2013-08-08 旭硝子株式会社 含フッ素共重合体およびその製造方法、ならびに撥水撥油剤組成物
WO2014208338A1 (ja) 2013-06-25 2014-12-31 ユニマテック株式会社 含フッ素共重合体の水性分散液
JPWO2015064360A1 (ja) * 2013-11-01 2017-03-09 ユニマテック株式会社 含フッ素重合体およびこれを有効成分とする表面改質剤
CN104727147A (zh) * 2013-12-19 2015-06-24 上海伊贝纳纺织品有限公司 拒水防油整理剂及其应用
WO2015194049A1 (ja) * 2014-06-20 2015-12-23 日華化学株式会社 撥水撥油剤組成物及び撥水撥油性繊維製品の製造方法
WO2017083193A1 (en) * 2015-11-09 2017-05-18 Milliken & Company Flame resistant and chemical protective textile material
CN110761074B (zh) * 2018-07-26 2023-08-08 乳源东阳光氟有限公司 一种环保低温型拒水拒油组合物
JP2021050300A (ja) * 2019-09-26 2021-04-01 第一工業製薬株式会社 樹脂用添加剤
JP7422972B2 (ja) * 2020-02-17 2024-01-29 明成化学工業株式会社 吸水性及び撥水性を併せ持つ繊維製品
WO2021200646A1 (ja) * 2020-03-31 2021-10-07 東レ株式会社 フッ素含有重合体粒子およびそれを含む分散液
CN113564930A (zh) * 2021-07-09 2021-10-29 福可新材料(上海)有限公司 一种全棉纺织品水性无氟防水整理液及其应用
CN117642438A (zh) * 2021-07-12 2024-03-01 优迈特株式会社 含氟共聚物以及使用其的表面改性基材
CN115850562A (zh) * 2021-09-27 2023-03-28 中国科学院上海有机化学研究所 含氟丙烯酸酯类聚合物及其制备方法和应用、整理剂

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WO2005105872A1 (en) * 2003-07-02 2005-11-10 3M Innovative Properties Company Fluoropolymer of fluorinated short chain acrylates or methacrylates and oil,- and water rellent compositions based thereon
JP2005344032A (ja) * 2004-06-04 2005-12-15 Yunimatekku Kk 撥水撥油剤の製造法
WO2006022122A1 (ja) * 2004-08-25 2006-03-02 Daikin Industries, Ltd. 撥水撥油剤組成物

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US4742140A (en) * 1986-01-23 1988-05-03 E. I. Du Pont De Nemours And Company Oil- and water-repellent copolymers
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US6121372A (en) * 1998-03-06 2000-09-19 Nippon Mektron Limited Aqueous emulsion component for a water- and oil-repellant agent
JP2000212549A (ja) * 1999-01-25 2000-08-02 Asahi Glass Co Ltd 撥水撥油剤組成物およびその製造方法
JP4613420B2 (ja) 1999-03-29 2011-01-19 旭硝子株式会社 水分散型撥水撥油剤組成物
EP1553151B1 (en) 2002-10-15 2010-01-20 Asahi Glass Company, Limited Water-and-oil repellant composition
JP4329559B2 (ja) 2003-05-02 2009-09-09 ダイキン工業株式会社 含フッ素重合体を含んでなる表面処理剤
CN101006149A (zh) * 2004-08-25 2007-07-25 大金工业株式会社 防水防油剂组合物
JP5351023B2 (ja) * 2006-08-25 2013-11-27 クラリアント ファイナンス （ビーブイアイ） リミティド 撥油性、撥水性及び撥汚物性メタクリル酸ペルフルオロアルキルエチルコポリマー

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005105872A1 (en) * 2003-07-02 2005-11-10 3M Innovative Properties Company Fluoropolymer of fluorinated short chain acrylates or methacrylates and oil,- and water rellent compositions based thereon
JP2005344032A (ja) * 2004-06-04 2005-12-15 Yunimatekku Kk 撥水撥油剤の製造法
WO2006022122A1 (ja) * 2004-08-25 2006-03-02 Daikin Industries, Ltd. 撥水撥油剤組成物

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009108296A (ja) * 2007-10-11 2009-05-21 Yunimatekku Kk 撥水撥油剤
JP2013511575A (ja) * 2009-11-20 2013-04-04 ダイキン工業株式会社 含フッ素重合体および表面処理剤
JP2013511574A (ja) * 2009-11-20 2013-04-04 ダイキン工業株式会社 含フッ素重合体および処理剤
US9677220B2 (en) 2009-11-20 2017-06-13 Daikin Industries, Ltd. Fluoropolymers and treatment agent
US9365714B2 (en) 2009-11-20 2016-06-14 Daikin Industries, Ltd. Fluoropolymers and surface treatment agent
CN102666971A (zh) * 2009-11-20 2012-09-12 大金工业株式会社 含氟聚合物和处理剂
CN102666970A (zh) * 2009-11-20 2012-09-12 大金工业株式会社 含氟聚合物和表面处理剂
US20130078880A1 (en) * 2009-11-20 2013-03-28 Norimasa Uesugi Fluoropolymers And Surface Treatment Agent
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CA2702687A1 (en) 2009-04-30
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JP2009102463A (ja) 2009-05-14
KR101456864B1 (ko) 2014-11-03
EP2208770B9 (en) 2012-10-31
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EP2208770A4 (en) 2011-06-01
US20100249312A1 (en) 2010-09-30

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