WO2008053843A1 - Heat conducting sheet, process for producing the same, and radiator utilizing the sheet - Google Patents
Heat conducting sheet, process for producing the same, and radiator utilizing the sheet Download PDFInfo
- Publication number
- WO2008053843A1 WO2008053843A1 PCT/JP2007/071038 JP2007071038W WO2008053843A1 WO 2008053843 A1 WO2008053843 A1 WO 2008053843A1 JP 2007071038 W JP2007071038 W JP 2007071038W WO 2008053843 A1 WO2008053843 A1 WO 2008053843A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- conductive sheet
- heat conductive
- heat
- graphite particles
- sheet
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/08—Materials not undergoing a change of physical state when used
- C09K5/14—Solid materials, e.g. powdery or granular
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F21/00—Constructions of heat-exchange apparatus characterised by the selection of particular materials
- F28F21/02—Constructions of heat-exchange apparatus characterised by the selection of particular materials of carbon, e.g. graphite
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0066—Flame-proofing or flame-retarding additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/34—Arrangements for cooling, heating, ventilating or temperature compensation ; Temperature sensing arrangements
- H01L23/36—Selection of materials, or shaping, to facilitate cooling or heating, e.g. heatsinks
- H01L23/373—Cooling facilitated by selection of materials for the device or materials for thermal expansion adaptation, e.g. carbon
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/34—Arrangements for cooling, heating, ventilating or temperature compensation ; Temperature sensing arrangements
- H01L23/36—Selection of materials, or shaping, to facilitate cooling or heating, e.g. heatsinks
- H01L23/373—Cooling facilitated by selection of materials for the device or materials for thermal expansion adaptation, e.g. carbon
- H01L23/3737—Organic materials with or without a thermoconductive filler
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K7/00—Constructional details common to different types of electric apparatus
- H05K7/20—Modifications to facilitate cooling, ventilating, or heating
- H05K7/2039—Modifications to facilitate cooling, ventilating, or heating characterised by the heat transfer by conduction from the heat generating element to a dissipating body
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
- C08J2333/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C08J2333/10—Homopolymers or copolymers of methacrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/08—Homopolymers or copolymers of acrylic acid esters
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/0001—Technical content checked by a classifier
- H01L2924/0002—Not covered by any one of groups H01L24/00, H01L24/00 and H01L2224/00
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T428/24851—Intermediate layer is discontinuous or differential
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
Definitions
- the present invention provides: (8) the composition contains a flame retardant in a range of 5% by volume to 50% by volume.
- the thermal conductive sheet according to any one of (7),
- the present invention is (26) the heat conductive sheet according to any one of (1) to (; 12) or the above (13) to (; 18). And a heat conductive sheet obtained by the manufacturing method, wherein the heat conductive sheet dissipates heat generated from a semiconductor.
- the shape of the graphite particles (A) in the present invention is scaly, oval or rod-like, and scaly is preferred.
- the shape of the graphite particles (A) is spherical or indefinite, the conductivity is inferior, and when it is fibrous, it is difficult to form into a sheet and the productivity tends to be inferior.
- the adhesive surface of the heat conductive sheet before use is covered with a protective film in order to protect the adhesive surface.
- a protective film in order to protect the adhesive surface.
- polyethylene, polyester, polypropylene, polyethylene terephthalate, polyimide, polyetherimide, polyether naphthalate, methyl pentene film, etc., metals such as coated paper, coated cloth, and aluminum are used as the protective film material. It can. Two or more types of these protective films can be combined to form a multilayer film.
- the surface of the protective film is preferably treated with a release agent such as silicone or silica. It is used well.
- the method for producing a heat conductive sheet of the present invention includes a step of producing a primary sheet, a step of laminating or winding the primary sheet to obtain a formed body, and a step of slicing the formed body.
- the method for producing a heat conductive sheet of the present invention is, first, scaly, oval or rod-shaped, and the six-membered ring surface in the crystal is the surface direction of the scaly, the major axis of the ellipse or the major axis of the rod.
- a composition containing graphite particles (A) oriented in the direction and an organic polymer compound (B) having a Tg of 50 ° C. or less is 20 times the average value of the major axis of the graphite particles (A).
- Rolling, pressing, extrusion or coating is performed to the following thickness to produce a primary sheet in which the graphite particles (A) are oriented in a direction substantially parallel to the main surface.
- the heat dissipating device of the present invention is established by bringing each surface of the heat conducting sheet of the present invention or the heat conducting sheet obtained by the production method of the present invention into contact with the heat generating body and the heat radiating body.
- the contact method There is no limitation on the contact method as long as the heating element, the heat conductive sheet, and the heat dissipation element can be fixed in a sufficiently intimate contact state, but from the viewpoint of maintaining the close contact, a method of screwing through a spring, A contact method that maintains the pressing force, such as a method of pinching with a clip, is preferred.
- the heat conductive sheet of the present invention or the heat conductive sheet obtained by the production method of the present invention is attached to either the heat generating body or the heat radiating body, thermal contact with the adherend is easily ensured. It becomes an excellent article in that it can be done.
- the heat conductivity of the heat conductive sheet (IX) was measured in the same manner as in Example 1. As a result, it was as low as 1.2 W / mK. The adhesion of the heat conductive sheet (IX) to the transistor and the aluminum heat dissipation block was good.
- the heat conductive sheet according to (10) is excellent in workability during shell occupancy, in addition to the effect of the invention according to any one of (1) to (9)! /.
- the heat conductive sheet described in (11) can achieve long-term adhesion maintenance and high film strength.
- the thermal conductive sheet according to (12) described above is characterized in that in addition to the effects of the invention according to any one of (1) to (; It can be used for applications that require electrical insulation such as sideways.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Power Engineering (AREA)
- Thermal Sciences (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Cooling Or The Like Of Semiconductors Or Solid State Devices (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Laminated Bodies (AREA)
- Carbon And Carbon Compounds (AREA)
- Cooling Or The Like Of Electrical Apparatus (AREA)
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2007800406278A CN101535383B (zh) | 2006-11-01 | 2007-10-29 | 导热片、其制造方法以及使用了导热片的散热装置 |
JP2008542104A JP5381102B2 (ja) | 2006-11-01 | 2007-10-29 | 熱伝導シート、その製造方法及び熱伝導シートを用いた放熱装置 |
KR1020097008006A KR101449075B1 (ko) | 2006-11-01 | 2007-10-29 | 열전도 시트, 그 제조방법 및 열전도 시트를 이용한 방열장치 |
US12/513,194 US20100073882A1 (en) | 2006-11-01 | 2007-10-29 | Thermally conductive sheet, process for producing the same, and radiator utilizing thermally conductive sheet |
US14/304,116 US20140293626A1 (en) | 2006-11-01 | 2014-06-13 | Thermally conductive sheet, process for producing the same, and radiator utilizing thermally conductive sheet |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2006-297730 | 2006-11-01 | ||
JP2006297730 | 2006-11-01 | ||
JP2007-187119 | 2007-07-18 | ||
JP2007187119 | 2007-07-18 |
Related Child Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US12/513,194 A-371-Of-International US20100073882A1 (en) | 2006-11-01 | 2007-10-29 | Thermally conductive sheet, process for producing the same, and radiator utilizing thermally conductive sheet |
US14/304,116 Continuation US20140293626A1 (en) | 2006-11-01 | 2014-06-13 | Thermally conductive sheet, process for producing the same, and radiator utilizing thermally conductive sheet |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2008053843A1 true WO2008053843A1 (en) | 2008-05-08 |
Family
ID=39344185
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2007/071038 WO2008053843A1 (en) | 2006-11-01 | 2007-10-29 | Heat conducting sheet, process for producing the same, and radiator utilizing the sheet |
Country Status (6)
Country | Link |
---|---|
US (2) | US20100073882A1 (ja) |
JP (4) | JP5381102B2 (ja) |
KR (1) | KR101449075B1 (ja) |
CN (2) | CN102433105B (ja) |
TW (1) | TWI470010B (ja) |
WO (1) | WO2008053843A1 (ja) |
Cited By (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009055021A (ja) * | 2007-08-01 | 2009-03-12 | Hitachi Chem Co Ltd | 熱伝導シート及びその製造方法 |
JP2009149831A (ja) * | 2007-11-26 | 2009-07-09 | Hitachi Chem Co Ltd | 熱伝導シート、その製造方法及び熱伝導シートを用いた放熱装置 |
JP2010132856A (ja) * | 2008-10-28 | 2010-06-17 | Hitachi Chem Co Ltd | 熱伝導シート、熱伝導シートの製造方法及び熱伝導シートを用いた放熱装置 |
JP2010132866A (ja) * | 2008-10-28 | 2010-06-17 | Hitachi Chem Co Ltd | 熱伝導シート、この熱伝導シートの製造方法及び熱伝導シートを用いた放熱装置 |
JP2011088946A (ja) * | 2009-10-20 | 2011-05-06 | Sumitomo Chemical Co Ltd | アクリル樹脂フィルム |
JP2011516633A (ja) * | 2008-03-20 | 2011-05-26 | ディーエスエム アイピー アセッツ ビー.ブイ. | 熱伝導性プラスチック材料のヒートシンク |
JP2011162642A (ja) * | 2010-02-09 | 2011-08-25 | Hitachi Chem Co Ltd | 熱伝導シート、その製造方法及び熱伝導シートを用いた放熱装置 |
JP2011184663A (ja) * | 2010-03-11 | 2011-09-22 | Hitachi Chem Co Ltd | 熱伝導シート、その製造方法及びこれを用いた放熱装置 |
JP2011208024A (ja) * | 2010-03-30 | 2011-10-20 | Hitachi Chem Co Ltd | 熱伝導シート、その製造方法及びこれを用いた放熱装置 |
JP2012515836A (ja) * | 2009-01-22 | 2012-07-12 | インターナショナル・ビジネス・マシーンズ・コーポレーション | 熱界面材料用の低圧縮力非シリコーン高熱伝導性配合物及びパッケージ |
JP2012158695A (ja) * | 2011-02-01 | 2012-08-23 | Hitachi Chemical Co Ltd | 熱伝導シート及び放熱装置 |
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JPWO2011001760A1 (ja) * | 2009-06-30 | 2012-12-13 | 日本ゼオン株式会社 | 熱伝導性感圧接着剤組成物、熱伝導性感圧接着性シート、及び電子部品 |
WO2013077178A1 (ja) * | 2011-11-24 | 2013-05-30 | 積水化学工業株式会社 | 樹脂複合材料及び樹脂複合材料の製造方法 |
JP2013225636A (ja) * | 2011-09-14 | 2013-10-31 | Nippon Shokubai Co Ltd | 熱伝導性材料 |
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Also Published As
Publication number | Publication date |
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JPWO2008053843A1 (ja) | 2010-02-25 |
KR20090074772A (ko) | 2009-07-07 |
JP2014001388A (ja) | 2014-01-09 |
JP5381102B2 (ja) | 2014-01-08 |
TW200829633A (en) | 2008-07-16 |
JP2017141443A (ja) | 2017-08-17 |
JP2015156490A (ja) | 2015-08-27 |
KR101449075B1 (ko) | 2014-10-08 |
TWI470010B (zh) | 2015-01-21 |
CN102433105B (zh) | 2014-07-30 |
US20140293626A1 (en) | 2014-10-02 |
CN101535383A (zh) | 2009-09-16 |
US20100073882A1 (en) | 2010-03-25 |
CN101535383B (zh) | 2012-02-22 |
JP6341303B2 (ja) | 2018-06-13 |
CN102433105A (zh) | 2012-05-02 |
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