WO2000019533A1 - Substrat plaque, destine a des cadres de montage, cadre de montage mettant en oeuvre un tel substrat, et procede de fabrication de ce cadre - Google Patents
Substrat plaque, destine a des cadres de montage, cadre de montage mettant en oeuvre un tel substrat, et procede de fabrication de ce cadre Download PDFInfo
- Publication number
- WO2000019533A1 WO2000019533A1 PCT/JP1999/005230 JP9905230W WO0019533A1 WO 2000019533 A1 WO2000019533 A1 WO 2000019533A1 JP 9905230 W JP9905230 W JP 9905230W WO 0019533 A1 WO0019533 A1 WO 0019533A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- foil material
- nickel
- lead frame
- clad plate
- copper
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 33
- 239000000463 material Substances 0.000 claims abstract description 106
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 90
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 71
- 239000011889 copper foil Substances 0.000 claims abstract description 51
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 38
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 38
- 239000011888 foil Substances 0.000 claims abstract description 37
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 30
- 229910052802 copper Inorganic materials 0.000 claims abstract description 20
- 239000010949 copper Substances 0.000 claims abstract description 20
- 238000000034 method Methods 0.000 claims description 31
- 238000005530 etching Methods 0.000 claims description 30
- 238000007747 plating Methods 0.000 claims description 21
- 238000003825 pressing Methods 0.000 claims description 14
- 238000005253 cladding Methods 0.000 claims description 8
- 238000005096 rolling process Methods 0.000 claims description 7
- 239000011261 inert gas Substances 0.000 claims description 4
- 238000000992 sputter etching Methods 0.000 claims description 3
- NPXOKRUENSOPAO-UHFFFAOYSA-N Raney nickel Chemical compound [Al].[Ni] NPXOKRUENSOPAO-UHFFFAOYSA-N 0.000 claims description 2
- 230000004913 activation Effects 0.000 claims description 2
- 238000010030 laminating Methods 0.000 claims description 2
- 230000003213 activating effect Effects 0.000 claims 1
- 238000003466 welding Methods 0.000 abstract description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 8
- 229920002120 photoresistant polymer Polymers 0.000 description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 239000004065 semiconductor Substances 0.000 description 5
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 4
- 229960003280 cupric chloride Drugs 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000004544 sputter deposition Methods 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000001994 activation Methods 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 238000005304 joining Methods 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 238000007740 vapor deposition Methods 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
- 229910000570 Cupronickel Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000003486 chemical etching Methods 0.000 description 1
- YOCUPQPZWBBYIX-UHFFFAOYSA-N copper nickel Chemical compound [Ni].[Cu] YOCUPQPZWBBYIX-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 229910000765 intermetallic Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/48—Manufacture or treatment of parts, e.g. containers, prior to assembly of the devices, using processes not provided for in a single one of the subgroups H01L21/06 - H01L21/326
- H01L21/4814—Conductive parts
- H01L21/4821—Flat leads, e.g. lead frames with or without insulating supports
- H01L21/4842—Mechanical treatment, e.g. punching, cutting, deforming, cold welding
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/48—Arrangements for conducting electric current to or from the solid state body in operation, e.g. leads, terminal arrangements ; Selection of materials therefor
- H01L23/488—Arrangements for conducting electric current to or from the solid state body in operation, e.g. leads, terminal arrangements ; Selection of materials therefor consisting of soldered or bonded constructions
- H01L23/495—Lead-frames or other flat leads
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K20/00—Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating
- B23K20/04—Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating by means of a rolling mill
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K20/00—Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating
- B23K20/22—Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating taking account of the properties of the materials to be welded
- B23K20/233—Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating taking account of the properties of the materials to be welded without ferrous layer
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/48—Arrangements for conducting electric current to or from the solid state body in operation, e.g. leads, terminal arrangements ; Selection of materials therefor
- H01L23/488—Arrangements for conducting electric current to or from the solid state body in operation, e.g. leads, terminal arrangements ; Selection of materials therefor consisting of soldered or bonded constructions
- H01L23/495—Lead-frames or other flat leads
- H01L23/49579—Lead-frames or other flat leads characterised by the materials of the lead frames or layers thereon
- H01L23/49582—Metallic layers on lead frames
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/02—Apparatus or processes for manufacturing printed circuits in which the conductive material is applied to the surface of the insulating support and is thereafter removed from such areas of the surface which are not intended for current conducting or shielding
- H05K3/06—Apparatus or processes for manufacturing printed circuits in which the conductive material is applied to the surface of the insulating support and is thereafter removed from such areas of the surface which are not intended for current conducting or shielding the conductive material being removed chemically or electrolytically, e.g. by photo-etch process
- H05K3/061—Etching masks
- H05K3/062—Etching masks consisting of metals or alloys or metallic inorganic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K2101/00—Articles made by soldering, welding or cutting
- B23K2101/34—Coated articles, e.g. plated or painted; Surface treated articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K2103/00—Materials to be soldered, welded or cut
- B23K2103/08—Non-ferrous metals or alloys
- B23K2103/10—Aluminium or alloys thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K2103/00—Materials to be soldered, welded or cut
- B23K2103/08—Non-ferrous metals or alloys
- B23K2103/12—Copper or alloys thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K2103/00—Materials to be soldered, welded or cut
- B23K2103/18—Dissimilar materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K2103/00—Materials to be soldered, welded or cut
- B23K2103/18—Dissimilar materials
- B23K2103/26—Alloys of Nickel and Cobalt and Chromium
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/42—Wire connectors; Manufacturing methods related thereto
- H01L2224/44—Structure, shape, material or disposition of the wire connectors prior to the connecting process
- H01L2224/45—Structure, shape, material or disposition of the wire connectors prior to the connecting process of an individual wire connector
- H01L2224/45001—Core members of the connector
- H01L2224/45099—Material
- H01L2224/451—Material with a principal constituent of the material being a metal or a metalloid, e.g. boron (B), silicon (Si), germanium (Ge), arsenic (As), antimony (Sb), tellurium (Te) and polonium (Po), and alloys thereof
- H01L2224/45138—Material with a principal constituent of the material being a metal or a metalloid, e.g. boron (B), silicon (Si), germanium (Ge), arsenic (As), antimony (Sb), tellurium (Te) and polonium (Po), and alloys thereof the principal constituent melting at a temperature of greater than or equal to 950°C and less than 1550°C
- H01L2224/45144—Gold (Au) as principal constituent
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L24/00—Arrangements for connecting or disconnecting semiconductor or solid-state bodies; Methods or apparatus related thereto
- H01L24/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L24/42—Wire connectors; Manufacturing methods related thereto
- H01L24/44—Structure, shape, material or disposition of the wire connectors prior to the connecting process
- H01L24/45—Structure, shape, material or disposition of the wire connectors prior to the connecting process of an individual wire connector
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/0001—Technical content checked by a classifier
- H01L2924/00014—Technical content checked by a classifier the subject-matter covered by the group, the symbol of which is combined with the symbol of this group, being disclosed without further technical details
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/01—Chemical elements
- H01L2924/01013—Aluminum [Al]
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/01—Chemical elements
- H01L2924/01019—Potassium [K]
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/01—Chemical elements
- H01L2924/01028—Nickel [Ni]
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/03—Conductive materials
- H05K2201/0332—Structure of the conductor
- H05K2201/0364—Conductor shape
- H05K2201/0367—Metallic bump or raised conductor not used as solder bump
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2203/00—Indexing scheme relating to apparatus or processes for manufacturing printed circuits covered by H05K3/00
- H05K2203/03—Metal processing
- H05K2203/0384—Etch stop layer, i.e. a buried barrier layer for preventing etching of layers under the etch stop layer
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/10—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern
- H05K3/20—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern by affixing prefabricated conductor pattern
- H05K3/202—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern by affixing prefabricated conductor pattern using self-supporting metal foil pattern
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/40—Forming printed elements for providing electric connections to or between printed circuits
- H05K3/4007—Surface contacts, e.g. bumps
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49117—Conductor or circuit manufacturing
- Y10T29/49204—Contact or terminal manufacturing
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12431—Foil or filament smaller than 6 mils
- Y10T428/12438—Composite
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12736—Al-base component
- Y10T428/1275—Next to Group VIII or IB metal-base component
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12861—Group VIII or IB metal-base component
- Y10T428/12903—Cu-base component
- Y10T428/1291—Next to Co-, Cu-, or Ni-base component
Definitions
- the present invention relates to a method for manufacturing a lead frame, particularly to a lead frame that can be manufactured by using a clad plate formed by cold pressing.
- a bump is formed at the tip of the lead, and is joined to the semiconductor chip via the bump. This also enables the package to be thinner.
- Japanese Patent Application Laid-Open No. 9-1115695 discloses a method for manufacturing a lead frame using such a three-layer clad plate.
- a clad plate is prepared by sandwiching a high-hardness copper plate with a pure copper plate.
- Also there is a method of manufacturing a lead frame using a three-layer clad plate using aluminum or an iron-based alloy as the etching stop layer. Since it is formed by the method, the rolling reduction must be high, which deteriorates the flatness of the joint surface. In addition, an alloy layer is formed at the interface between the copper plate and the etching stop layer during heat treatment. There was a problem that it was inferior to selective etching.
- Another method of manufacturing a lead frame is to deposit a thin metal film if by vapor deposition. In this method, if the film is thin (several im), pores are likely to occur and the thickness is large ( In this case, the workability is poor and the cost is high.
- the present invention is intended to solve such a problem, and a lead frame clad plate that can be manufactured at low cost and has good selective etching properties.
- the clad plate for a lead frame according to claim 1 is manufactured by pressing a copper foil material and a nickel foil material at a rolling reduction of 0.1 to 3%.
- the clad plate for a lead frame according to claim 2 is manufactured by pressing a copper foil material having nickel plating on one or both surfaces thereof with another copper foil material at a rolling reduction of 0.1 to 3%. It is characterized by.
- the clad plate for a lead frame according to claim 3 is characterized by being manufactured by pressing an aluminum foil material and a Nigger foil material at a reduction ratio of 0.1 to 3%.
- the clad plate for a lead frame according to claim 4 is manufactured by pressing a copper foil material provided with nickel plating on one surface and another aluminum foil material at a rolling reduction of 0.1 to 3%.
- the clad plate for a lead frame according to claim 5 is characterized in that it is formed of three layers of copper, nickel, and Z copper.
- the clad plate for a lead frame according to claim 6 is characterized in that it is formed of three layers of copper / nickel aluminum.
- a lead frame according to a seventh aspect is characterized in that the clad plate according to any one of the first to sixth aspects is selectively etched to form a bump.
- the lead frame manufacturing method wherein the copper foil material or the aluminum foil material and the nickel foil material forming the etch stop layer or the copper foil material laminated with nickel plating are reduced by 0.1 to 3%.
- FIG. 1 is an explanatory process diagram of a method for manufacturing a lead frame according to an embodiment of the present invention.
- FIG. 2 is a process explanatory diagram of a method for manufacturing a lead frame according to one embodiment of the present invention.
- FIG. 3 is a process explanatory view of a method for manufacturing a lead frame according to one embodiment of the present invention.
- FIG. 4 is a view showing the manufacture of a lead frame according to an embodiment of the present invention.
- FIG. 5 is a process explanatory diagram of a method for manufacturing a lead frame according to one embodiment of the present invention.
- FIG. 6 shows a lead according to an embodiment of the present invention. It is process explanatory drawing of the manufacturing method of a flame
- FIG. 7 is a process explanatory diagram of a method for manufacturing a lead frame according to one embodiment of the present invention.
- FIG. 8 is a cross-sectional front view of an apparatus for manufacturing a clad metal plate. BEST MODE FOR CARRYING OUT THE INVENTION
- one side of the outer lead layer 10 (thickness 10 to 100 m) consisting of copper foil material or aluminum foil material 20 has a nickel foil material (thickness 5 ID to 10 m) or Etching stop layer 1 1 with nickel plating (thickness 0.
- nickel plating 21 (thickness 5 to 10), which serves as an etching stop layer 11, is formed on one side of a copper foil material 20 (thickness 100 to 100 fi m) that becomes the outer lead layer 10 when the lead frame is manufactured. 3 // m) to produce nickel-plated copper foil material 22 (see Fig. 1).
- the nickel-plated copper foil material 22 is wound around the rewinding reel 23 in the clad plate manufacturing apparatus shown in FIG.
- the copper foil material 24 serving as the inner lead layer is rewound and wound around the reel 25.
- the nickel-plated copper foil material 22 and the copper foil material 24 are simultaneously rewound from the rewind reels 23, 25, and a part of them is fed to the electrode holes 27, 28 projecting into the etching chamber 26. It is wound and activated by a sputter etching process in the etching chamber 26.
- a copper or aluminum foil material 20 (thickness 10 to 100 m) that becomes an outer lead layer 10 when a lead frame is manufactured.
- the nickel foil material 21 (thickness 5 to 10 m) serving as the etching stop layer 11 is rewound on the reel 25.
- the copper or aluminum foil material 20 and the nickel foil material 21 are rewound simultaneously from the rewind reels 23, 25, and a part of them is rolled to the electrode rolls 27, 28 projecting into the etching chamber 26.
- a sputter etching process is performed to activate the bonding surface. Then, the activated surfaces are used as joining surfaces and cold pressed by a rolling unit 30 to form a copper foil with a nickel foil having a two-layer structure.
- the clad plate having the two-layer structure is wound around a wind-up roll 32 to produce the clad plate.
- the copper foil material with nickel foil or the aluminum foil material 22 having the two-layer structure is rewound and wound around the reel 23 again.
- a copper foil material 24 serving as an inner lead layer is wound around a rewind reel 25.
- Electrode rolls 27, 2 with copper foil material with nickel foil or aluminum foil material 22 and copper foil material 24 rewound from rewind reels 23, 25, respectively, and a part of which is projected into etching chamber 26 Then, it is sputter-etched and activated in the etching chamber 26.
- the activation processing is performed in the same manner as (1) 1 X 10— :! 1 X 10—4 Torr, in an extremely low-pressure inert gas atmosphere, (2) Copper foil material with nickel foil or aluminum foil material 22 with a bonding surface and one electrode of copper foil material 24 grounded respectively. A, and an AC of 1 to 50 MHz is applied between it and another electrode B, which is supported insulated, to cause a glow discharge, and 3 is exposed to the plasma generated by the glow discharge.
- the electrode area is 1 Z 3 or less of the area of the electrode B, and the etching is performed by sputtering.
- the cladding plate 31 for a lead frame having a three-layer structure is formed as shown in FIG. To manufacture.
- a clad plate having a multilayer structure can be manufactured by one press welding.
- a photoresist is applied to the surface of the copper foil material 24, and then exposed and developed to form a photoresist film 40.
- the copper foil material 24 is selectively etched using sulfuric acid + hydrogen peroxide, and the copper foil material 24 is removed while leaving the bumps 12 and the external terminals 13.
- the etching time is, for example, about 4 minutes.
- etching aluminum foil use sodium hydroxide solution.
- a photoresist film 41 is formed on the surface of the bumps 12 and the external terminals 13, and a photoresist film is formed on the surface of the copper or aluminum foil material 20 to be the outer lead layer 10. Is applied, and exposed and developed to form a photoresist film 42.
- the copper foil material 20 to be the outer lead layer 10 and the nickel plating or nickel foil material 21 are etched using ferric chloride or cupric chloride or the like. Thereafter, the photoresist films 41 and 42 are removed to form a conductor circuit 43.
- 5% D sodium hydroxide or potassium hydroxide 50 ° C.
- the etching time is, for example, about 2 minutes.
- nickel plating or nickel foil material 21 is etched using ferric chloride or cupric chloride or the like to form conductor circuit 43.
- bumps 12 and external I terminal The photoresist film 41 may be further formed on the surface of a copper foil material or an aluminum foil material 20 to be the outer lead layer 10.
- nickel plating or etching may be performed from the nickel foil material 21 side to the copper foil material 20 on the outer lead layer side using ferric chloride or cupric chloride or the like.
- nickel plating or nickel foil material 21 is first etched with ferric chloride or cupric chloride, etc., followed by 5% sodium hydroxide or potassium hydroxide. Etch the aluminum foil material 20 at (50 ° C).
- a copper foil material or an aluminum foil material is pressed against a nickel foil material, or a copper foil having nickel plating on one surface or both surfaces. Since the clad plate for lead frames is manufactured by pressing the foil material and another copper foil material in a laminated state, the generation of pores in the vapor deposition method can be eliminated and the quality can be improved. At the same time, since it can be manufactured only by laminating and pressing, the manufacturing cost of the clad plate for a lead frame can be reduced.
- a copper foil material or an aluminum foil material forming a lead layer and a nickel-plated or nickel foil material forming an etching stop layer are laminated. Since the lead frame is manufactured by forming a clad plate for a lead frame by pressing and pressing, and selectively etching the multilayer clad plate to form a bump made of copper or aluminum, the lead frame is manufactured uniformly. It is possible to efficiently and inexpensively manufacture a thin lead frame having such bumps.
- the bonding surface between the copper foil material or the aluminum foil material and the nickel plating or the nickel foil material is preliminarily activated in a vacuum chamber.
- the foil material and the nickel plating or the nickel foil material are formed by polymerizing and cold-welding at a reduction rate of 0.1 to 3%.
- a lead frame excellent in selective etching properties can be manufactured by using.
Landscapes
- Engineering & Computer Science (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Power Engineering (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Metallurgy (AREA)
- Lead Frames For Integrated Circuits (AREA)
- Laminated Bodies (AREA)
- Pressure Welding/Diffusion-Bonding (AREA)
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP99944820A EP1119048B1 (en) | 1998-09-30 | 1999-09-24 | Lead frame having bumps thereon and manufacturing method thereof |
KR1020017003919A KR20010089283A (ko) | 1998-09-30 | 1999-09-24 | 리드프레임용 클래드판, 그것을 이용한 리드프레임 및 그제조방법 |
JP2000572941A JP4110440B2 (ja) | 1998-09-30 | 1999-09-24 | リードフレーム用クラッド板の製造方法及びリードフレームの製造方法 |
AU57600/99A AU5760099A (en) | 1998-09-30 | 1999-09-24 | Clad plate for lead frames, lead frame using the same, and method of manufacturing the lead frame |
US09/806,532 US6663980B1 (en) | 1998-09-30 | 1999-09-24 | Clad plate for lead frames, lead frame using the same, and method of manufacturing the lead frame |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP29137898 | 1998-09-30 | ||
JP10/291378 | 1998-09-30 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2000019533A1 true WO2000019533A1 (fr) | 2000-04-06 |
Family
ID=17768153
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP1999/005230 WO2000019533A1 (fr) | 1998-09-30 | 1999-09-24 | Substrat plaque, destine a des cadres de montage, cadre de montage mettant en oeuvre un tel substrat, et procede de fabrication de ce cadre |
Country Status (9)
Country | Link |
---|---|
US (1) | US6663980B1 (ja) |
EP (1) | EP1119048B1 (ja) |
JP (1) | JP4110440B2 (ja) |
KR (1) | KR20010089283A (ja) |
CN (1) | CN1141739C (ja) |
AU (1) | AU5760099A (ja) |
MY (1) | MY126425A (ja) |
TW (1) | TW446627B (ja) |
WO (1) | WO2000019533A1 (ja) |
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KR100449156B1 (ko) * | 2002-05-09 | 2004-09-18 | 엘지전선 주식회사 | 솔더 범프용 동박의 제조방법 |
US7175919B2 (en) * | 2000-10-18 | 2007-02-13 | Toyo Kohan Co., Ltd. | Multilayered metal laminate and process for producing the same |
WO2007058005A1 (ja) * | 2005-11-16 | 2007-05-24 | Ain Co., Ltd. | 配線板の製造方法および配線板 |
KR100793644B1 (ko) * | 2007-05-02 | 2008-01-10 | (주)알오호일 | 금속 극박판 제조 방법 |
JP2008147237A (ja) * | 2006-12-06 | 2008-06-26 | Toyo Kohan Co Ltd | Qfn用金属積層板及びその製造方法、並びに該qfn用金属積層板を用いたqfnの製造方法 |
JP2011211248A (ja) * | 2011-07-29 | 2011-10-20 | Toyo Kohan Co Ltd | Qfn用金属積層板を用いたqfnの製造方法 |
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Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH03188660A (ja) * | 1989-12-19 | 1991-08-16 | Toppan Printing Co Ltd | 半導体装置用リードフレーム用材及び半導体装置用リードフレームの製造方法 |
Family Cites Families (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5868958A (ja) * | 1981-10-21 | 1983-04-25 | Toshiba Corp | リ−ドフレ−ム |
JPS59204547A (ja) * | 1983-05-10 | 1984-11-19 | 日立電線株式会社 | アルミニウム−銅クラツド材 |
US5001546A (en) * | 1983-07-27 | 1991-03-19 | Olin Corporation | Clad metal lead frame substrates |
US5243320A (en) * | 1988-02-26 | 1993-09-07 | Gould Inc. | Resistive metal layers and method for making same |
JPH0818145B2 (ja) * | 1988-02-26 | 1996-02-28 | 株式会社神戸製鋼所 | 電子部品用積層材の製造方法 |
JPH07120740B2 (ja) * | 1988-09-13 | 1995-12-20 | 株式会社三井ハイテック | 半導体用リードフレームとその製造法 |
US4896813A (en) * | 1989-04-03 | 1990-01-30 | Toyo Kohan Co., Ltd. | Method and apparatus for cold rolling clad sheet |
JP2797542B2 (ja) * | 1989-11-06 | 1998-09-17 | ソニー株式会社 | リードフレームの製造方法 |
JPH03204101A (ja) * | 1989-12-28 | 1991-09-05 | Daido Steel Co Ltd | リードフレーム材の圧延方法 |
JP2684259B2 (ja) * | 1991-04-22 | 1997-12-03 | 住友特殊金属株式会社 | クラッド材とその製造方法 |
JPH0575006A (ja) * | 1991-09-18 | 1993-03-26 | Fujitsu Ltd | リードフレーム及び樹脂封止型半導体装置 |
JPH0681172A (ja) * | 1992-09-01 | 1994-03-22 | Hitachi Cable Ltd | 微細パターンの形成方法 |
US5329159A (en) * | 1993-08-03 | 1994-07-12 | Motorola, Inc. | Semiconductor device employing an aluminum clad leadframe |
JP3559598B2 (ja) * | 1994-12-26 | 2004-09-02 | 日立化成工業株式会社 | 印刷配線板用金属箔とその製造法並びにこの金属箔を用いた配線板の製造法 |
JP3460410B2 (ja) * | 1995-10-20 | 2003-10-27 | ソニー株式会社 | バンプ付金属リード及びその製造方法 |
JP3108360B2 (ja) * | 1996-02-15 | 2000-11-13 | 福田金属箔粉工業株式会社 | 電池用安全弁素子および安全弁付き電池ケース蓋 |
TW355162B (en) * | 1996-02-15 | 1999-04-01 | Toyo Kohan Co Ltd | Clad material |
JPH09237865A (ja) * | 1996-02-28 | 1997-09-09 | Mitsubishi Shindoh Co Ltd | リードフレーム製造用素材 |
JPH09312374A (ja) * | 1996-05-24 | 1997-12-02 | Sony Corp | 半導体パッケージ及びその製造方法 |
JP3204101B2 (ja) | 1996-06-20 | 2001-09-04 | 住友金属工業株式会社 | 深絞り用鋼板及びその製造方法 |
JP3327396B2 (ja) * | 1996-08-06 | 2002-09-24 | 東洋鋼鈑株式会社 | コンデンサー用安全弁素子および安全弁付きコンデンサーケース蓋 |
US5937278A (en) * | 1996-10-15 | 1999-08-10 | Sony Corporation | Method of manufacturing lead frame having inner lead connected to outer lead by metal etch stop layer |
JP3026485B2 (ja) * | 1997-02-28 | 2000-03-27 | 日本電解株式会社 | リードフレーム材とその製法 |
JP3066952B2 (ja) * | 1997-02-03 | 2000-07-17 | 日本電解株式会社 | リードフレーム材 |
JP3003624B2 (ja) * | 1997-05-27 | 2000-01-31 | ソニー株式会社 | 半導体装置 |
JPH1174413A (ja) * | 1997-07-01 | 1999-03-16 | Sony Corp | リードフレームとリードフレームの製造方法と半導体装置と半導体装置の組立方法と電子機器 |
JP3188660B2 (ja) | 1997-10-16 | 2001-07-16 | 帝人株式会社 | 金属板貼合せ成形加工用ポリエステルフィルム |
-
1999
- 1999-09-22 TW TW088116268A patent/TW446627B/zh not_active IP Right Cessation
- 1999-09-24 JP JP2000572941A patent/JP4110440B2/ja not_active Expired - Fee Related
- 1999-09-24 KR KR1020017003919A patent/KR20010089283A/ko not_active Application Discontinuation
- 1999-09-24 AU AU57600/99A patent/AU5760099A/en not_active Abandoned
- 1999-09-24 US US09/806,532 patent/US6663980B1/en not_active Expired - Fee Related
- 1999-09-24 WO PCT/JP1999/005230 patent/WO2000019533A1/ja not_active Application Discontinuation
- 1999-09-24 CN CNB998114782A patent/CN1141739C/zh not_active Expired - Fee Related
- 1999-09-24 EP EP99944820A patent/EP1119048B1/en not_active Expired - Lifetime
- 1999-09-28 MY MYPI99004199A patent/MY126425A/en unknown
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH03188660A (ja) * | 1989-12-19 | 1991-08-16 | Toppan Printing Co Ltd | 半導体装置用リードフレーム用材及び半導体装置用リードフレームの製造方法 |
Non-Patent Citations (1)
Title |
---|
See also references of EP1119048A4 * |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7175919B2 (en) * | 2000-10-18 | 2007-02-13 | Toyo Kohan Co., Ltd. | Multilayered metal laminate and process for producing the same |
KR100449156B1 (ko) * | 2002-05-09 | 2004-09-18 | 엘지전선 주식회사 | 솔더 범프용 동박의 제조방법 |
WO2007058005A1 (ja) * | 2005-11-16 | 2007-05-24 | Ain Co., Ltd. | 配線板の製造方法および配線板 |
JP2008147237A (ja) * | 2006-12-06 | 2008-06-26 | Toyo Kohan Co Ltd | Qfn用金属積層板及びその製造方法、並びに該qfn用金属積層板を用いたqfnの製造方法 |
KR100793644B1 (ko) * | 2007-05-02 | 2008-01-10 | (주)알오호일 | 금속 극박판 제조 방법 |
JP2011211248A (ja) * | 2011-07-29 | 2011-10-20 | Toyo Kohan Co Ltd | Qfn用金属積層板を用いたqfnの製造方法 |
Also Published As
Publication number | Publication date |
---|---|
TW446627B (en) | 2001-07-21 |
EP1119048A4 (en) | 2007-07-04 |
CN1141739C (zh) | 2004-03-10 |
CN1320276A (zh) | 2001-10-31 |
JP4110440B2 (ja) | 2008-07-02 |
EP1119048A1 (en) | 2001-07-25 |
US6663980B1 (en) | 2003-12-16 |
MY126425A (en) | 2006-09-29 |
EP1119048B1 (en) | 2011-11-09 |
AU5760099A (en) | 2000-04-17 |
KR20010089283A (ko) | 2001-09-29 |
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