TWI251598B - Olefin polymerization catalyst component, its preparation and use - Google Patents
Olefin polymerization catalyst component, its preparation and use Download PDFInfo
- Publication number
- TWI251598B TWI251598B TW088105818A TW88105818A TWI251598B TW I251598 B TWI251598 B TW I251598B TW 088105818 A TW088105818 A TW 088105818A TW 88105818 A TW88105818 A TW 88105818A TW I251598 B TWI251598 B TW I251598B
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- Taiwan
- Prior art keywords
- formula
- magnesium
- patent application
- carrier
- alkyl
- Prior art date
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- 150000001336 alkenes Chemical class 0.000 title claims 2
- 238000002360 preparation method Methods 0.000 title abstract description 11
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title 1
- 239000002685 polymerization catalyst Substances 0.000 title 1
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 81
- 239000011777 magnesium Substances 0.000 claims abstract description 81
- 239000003054 catalyst Substances 0.000 claims abstract description 64
- -1 magnesium halide compound Chemical class 0.000 claims abstract description 64
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 54
- 239000000203 mixture Substances 0.000 claims abstract description 43
- 229910001507 metal halide Inorganic materials 0.000 claims abstract description 30
- 239000010936 titanium Substances 0.000 claims abstract description 23
- 230000000694 effects Effects 0.000 claims abstract description 21
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 20
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 17
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 12
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 9
- 125000005843 halogen group Chemical group 0.000 claims abstract 5
- 238000000034 method Methods 0.000 claims description 77
- 239000000047 product Substances 0.000 claims description 32
- 125000000217 alkyl group Chemical group 0.000 claims description 26
- 150000005309 metal halides Chemical class 0.000 claims description 26
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 22
- 229920000642 polymer Polymers 0.000 claims description 22
- 150000001875 compounds Chemical class 0.000 claims description 19
- 239000011148 porous material Substances 0.000 claims description 19
- 150000003609 titanium compounds Chemical class 0.000 claims description 19
- 239000010953 base metal Substances 0.000 claims description 15
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 15
- 150000002430 hydrocarbons Chemical class 0.000 claims description 14
- 238000004519 manufacturing process Methods 0.000 claims description 12
- 229920000573 polyethylene Polymers 0.000 claims description 12
- 239000004215 Carbon black (E152) Substances 0.000 claims description 10
- 239000004698 Polyethylene Substances 0.000 claims description 10
- 229910052751 metal Inorganic materials 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 229930195733 hydrocarbon Natural products 0.000 claims description 9
- 229910052809 inorganic oxide Inorganic materials 0.000 claims description 9
- 239000001301 oxygen Substances 0.000 claims description 9
- 229910052760 oxygen Inorganic materials 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 239000007789 gas Substances 0.000 claims description 8
- 150000002367 halogens Chemical class 0.000 claims description 7
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
- 239000007795 chemical reaction product Substances 0.000 claims description 6
- 238000001879 gelation Methods 0.000 claims description 6
- 239000012454 non-polar solvent Substances 0.000 claims description 6
- 150000001350 alkyl halides Chemical class 0.000 claims description 5
- 239000000460 chlorine Substances 0.000 claims description 5
- 239000003426 co-catalyst Substances 0.000 claims description 5
- 150000002681 magnesium compounds Chemical class 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 5
- 238000012360 testing method Methods 0.000 claims description 5
- 125000003545 alkoxy group Chemical group 0.000 claims description 4
- 229910000420 cerium oxide Inorganic materials 0.000 claims description 4
- 229910052801 chlorine Inorganic materials 0.000 claims description 4
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical group [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- 241000196324 Embryophyta Species 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- 238000012937 correction Methods 0.000 claims description 3
- 150000004820 halides Chemical class 0.000 claims description 3
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 3
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 claims description 2
- LASHFHLFDRTERB-UHFFFAOYSA-N 2-propylpentan-1-ol Chemical compound CCCC(CO)CCC LASHFHLFDRTERB-UHFFFAOYSA-N 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 238000007334 copolymerization reaction Methods 0.000 claims description 2
- 150000003608 titanium Chemical class 0.000 claims description 2
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 6
- 125000001309 chloro group Chemical group Cl* 0.000 claims 3
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 claims 2
- 229920005610 lignin Polymers 0.000 claims 2
- 238000002844 melting Methods 0.000 claims 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims 2
- NAWXUBYGYWOOIX-SFHVURJKSA-N (2s)-2-[[4-[2-(2,4-diaminoquinazolin-6-yl)ethyl]benzoyl]amino]-4-methylidenepentanedioic acid Chemical compound C1=CC2=NC(N)=NC(N)=C2C=C1CCC1=CC=C(C(=O)N[C@@H](CC(=C)C(O)=O)C(O)=O)C=C1 NAWXUBYGYWOOIX-SFHVURJKSA-N 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 229910052684 Cerium Inorganic materials 0.000 claims 1
- 235000019764 Soybean Meal Nutrition 0.000 claims 1
- 125000004104 aryloxy group Chemical group 0.000 claims 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims 1
- GPWDPLKISXZVIE-UHFFFAOYSA-N cyclo[18]carbon Chemical compound C1#CC#CC#CC#CC#CC#CC#CC#CC#C1 GPWDPLKISXZVIE-UHFFFAOYSA-N 0.000 claims 1
- 125000006003 dichloroethyl group Chemical group 0.000 claims 1
- 230000001747 exhibiting effect Effects 0.000 claims 1
- 239000007863 gel particle Substances 0.000 claims 1
- 230000026030 halogenation Effects 0.000 claims 1
- 238000005658 halogenation reaction Methods 0.000 claims 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 239000000395 magnesium oxide Substances 0.000 claims 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims 1
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 claims 1
- 210000002500 microbody Anatomy 0.000 claims 1
- RWFBQHICRCUQJJ-UHFFFAOYSA-N nicotine N(1')-oxide Chemical group C[N+]1([O-])CCCC1C1=CC=CN=C1 RWFBQHICRCUQJJ-UHFFFAOYSA-N 0.000 claims 1
- 239000003016 pheromone Substances 0.000 claims 1
- 239000002994 raw material Substances 0.000 claims 1
- 239000004071 soot Substances 0.000 claims 1
- 239000004455 soybean meal Substances 0.000 claims 1
- 239000007858 starting material Substances 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 abstract description 10
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 10
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract description 8
- 239000005977 Ethylene Substances 0.000 abstract description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract description 8
- 125000003710 aryl alkyl group Chemical group 0.000 abstract description 2
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 abstract 4
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 2
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 abstract 1
- 125000003860 C1-C20 alkoxy group Chemical group 0.000 abstract 1
- 239000000499 gel Substances 0.000 description 11
- 239000000463 material Substances 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 7
- 239000002131 composite material Substances 0.000 description 6
- 239000012041 precatalyst Substances 0.000 description 6
- 239000006185 dispersion Substances 0.000 description 5
- 238000009826 distribution Methods 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000012876 carrier material Substances 0.000 description 4
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 4
- 101100023124 Schizosaccharomyces pombe (strain 972 / ATCC 24843) mfr2 gene Proteins 0.000 description 3
- 241000519995 Stachys sylvatica Species 0.000 description 3
- KXDANLFHGCWFRQ-UHFFFAOYSA-N magnesium;butane;octane Chemical compound [Mg+2].CCC[CH2-].CCCCCCC[CH2-] KXDANLFHGCWFRQ-UHFFFAOYSA-N 0.000 description 3
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 238000007792 addition Methods 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 229920006158 high molecular weight polymer Polymers 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 150000002736 metal compounds Chemical class 0.000 description 2
- 239000008267 milk Substances 0.000 description 2
- 210000004080 milk Anatomy 0.000 description 2
- 235000013336 milk Nutrition 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- HGUFODBRKLSHSI-UHFFFAOYSA-N 2,3,7,8-tetrachloro-dibenzo-p-dioxin Chemical compound O1C2=CC(Cl)=C(Cl)C=C2OC2=C1C=C(Cl)C(Cl)=C2 HGUFODBRKLSHSI-UHFFFAOYSA-N 0.000 description 1
- MVECFARLYQAUNR-UHFFFAOYSA-N CCCC[Mg]CC Chemical compound CCCC[Mg]CC MVECFARLYQAUNR-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 239000004705 High-molecular-weight polyethylene Substances 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 241000208125 Nicotiana Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- 241000283973 Oryctolagus cuniculus Species 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910010066 TiC14 Inorganic materials 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000011358 absorbing material Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 125000005234 alkyl aluminium group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 1
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- 239000012320 chlorinating reagent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 150000004696 coordination complex Chemical class 0.000 description 1
- OENDOEZBSDLANK-UHFFFAOYSA-N dimagnesiomagnesium Chemical compound [Mg][Mg][Mg] OENDOEZBSDLANK-UHFFFAOYSA-N 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000002638 heterogeneous catalyst Substances 0.000 description 1
- UIZVMOZAXAMASY-UHFFFAOYSA-N hex-5-en-1-ol Chemical compound OCCCCC=C UIZVMOZAXAMASY-UHFFFAOYSA-N 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910012375 magnesium hydride Inorganic materials 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910001510 metal chloride Inorganic materials 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 239000011859 microparticle Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 150000002923 oximes Chemical class 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 230000037048 polymerization activity Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 229910001925 ruthenium oxide Inorganic materials 0.000 description 1
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- ZTBJFXYWWZPTFM-UHFFFAOYSA-N tellanylidenemagnesium Chemical compound [Te]=[Mg] ZTBJFXYWWZPTFM-UHFFFAOYSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- ZGYRTJADPPDDMY-UHFFFAOYSA-N titanium;tetrahydrate Chemical compound O.O.O.O.[Ti] ZGYRTJADPPDDMY-UHFFFAOYSA-N 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003623 transition metal compounds Chemical class 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/18—Applications used for pipes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/02—Ziegler natta catalyst
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI980788A FI111372B (fi) | 1998-04-06 | 1998-04-06 | Olefiinien polymerointiin tarkoitettu katalyyttikomponentti, sen valmistus ja käyttö |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TWI251598B true TWI251598B (en) | 2006-03-21 |
Family
ID=8551476
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW088105818A TWI251598B (en) | 1998-04-06 | 1999-04-13 | Olefin polymerization catalyst component, its preparation and use |
Country Status (14)
| Country | Link |
|---|---|
| US (3) | US6620758B1 (enExample) |
| EP (1) | EP0949274A3 (enExample) |
| JP (1) | JP4813657B2 (enExample) |
| KR (1) | KR100531509B1 (enExample) |
| CN (1) | CN1202140C (enExample) |
| AR (1) | AR018835A1 (enExample) |
| AU (1) | AU3334299A (enExample) |
| BR (1) | BR9909435B1 (enExample) |
| CA (1) | CA2325632A1 (enExample) |
| FI (1) | FI111372B (enExample) |
| MY (1) | MY121053A (enExample) |
| TW (1) | TWI251598B (enExample) |
| WO (1) | WO1999051646A1 (enExample) |
| ZA (1) | ZA200005015B (enExample) |
Families Citing this family (182)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
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| WO2024170344A1 (en) | 2023-02-14 | 2024-08-22 | Borealis Ag | Polyethylene blend for a film layer |
| WO2024170345A1 (en) | 2023-02-14 | 2024-08-22 | Borealis Ag | Polyethylene blend for a film layer |
| EP4417629A1 (en) | 2023-02-14 | 2024-08-21 | Borealis AG | Polyethylene blend for a film layer |
| EP4431552B1 (en) | 2023-03-14 | 2025-07-30 | Borealis GmbH | Biaxially oriented polyethylene film with improved stiffness |
| EP4455171A1 (en) | 2023-04-28 | 2024-10-30 | Borealis AG | Moulded articles |
| WO2025125458A1 (en) | 2023-12-12 | 2025-06-19 | Abu Dhabi Polymers Co. Ltd (Borouge) - Sole Proprietorship L.L.C. | Modified polyethylene having improved hydrostatic pressure resistance and slow crack growth resistance |
| EP4574891A1 (en) | 2023-12-19 | 2025-06-25 | Abu Dhabi Polymers Co. Ltd (Borouge) - Sole Proprietorship L.L.C. | Polyethylene compositions having improved rheological properties |
| WO2025219499A1 (en) | 2024-04-18 | 2025-10-23 | Borealis Gmbh | Processes for polymerising olefins |
| EP4650377A1 (en) | 2024-05-13 | 2025-11-19 | Borealis GmbH | Multimodal ethylene copolymer composition with medium density and film with improved toughness |
| EP4650376A1 (en) | 2024-05-13 | 2025-11-19 | Borealis GmbH | Multimodal ethylene copolymer composition, a recyclate-containing polymer composition containing the same and film being improved in toughness |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4414369A (en) | 1977-08-17 | 1983-11-08 | Nippon Oil Company, Limited | Continuous process for the preparation of polyolefins having widely distributed molecular weights |
| US4324691A (en) | 1980-01-10 | 1982-04-13 | Imperial Chemical Industries Limited | Catalyst component |
| US4766100A (en) * | 1984-08-06 | 1988-08-23 | Exxon Research & Engineering Co. | Polymerization catalyst, production and use (P-1063) |
| US4900706A (en) * | 1987-03-17 | 1990-02-13 | Sumitomo Chemical Company, Limited | Process for producing olefin polymers and catalyst used therein |
| US5192731A (en) * | 1988-05-13 | 1993-03-09 | Mitsui Petrochemical Industries, Ltd. | Titanium catalyst components, process for preparing same, catalysts containing same for preparing ethylene polymers and process for preparing said ethylene polymers |
| IT1246265B (it) * | 1990-09-07 | 1994-11-17 | Enimont Anic Srl | Componente solido di catalizzatore per la (co)polimerizzazione dell'etilene |
| JPH08503717A (ja) * | 1992-06-22 | 1996-04-23 | ボレアリス ポリマーズ オイ | マグネシウムアルコキシド、アルコキシチタンおよびアルコール溶液で担体を含浸させることによる主触媒組成物の製造方法 |
| US5330951A (en) * | 1992-12-09 | 1994-07-19 | Mobil Oil Corporation | Catalyst composition for polymerizing alpha-olefin |
| FI942949A0 (fi) * | 1994-06-20 | 1994-06-20 | Borealis Polymers Oy | Prokatalysator foer producering av etenpolymerer och foerfarande foer framstaellning daerav |
| US5661097A (en) | 1994-08-12 | 1997-08-26 | The Dow Chemical Company | Supported olefin polymerization catalyst |
| FI108452B (fi) * | 1996-06-07 | 2002-01-31 | Borealis Polymers Oy | Etyleenipolymeerituote, jolla on leveõ moolimassajakauma, sen valmistus ja kõytt÷ |
| PT837915E (pt) | 1995-07-10 | 2001-12-28 | Borealis Tech Oy | Composicao de revestimento |
| SE9504539D0 (sv) * | 1995-12-19 | 1995-12-19 | Borealis As | Procatalyst and process for the preparation of a multimodal ethylene homopolymer and/or ethylene/ 1-olefin copolymer by gas-phase polymerisation |
-
1998
- 1998-04-06 FI FI980788A patent/FI111372B/fi active
-
1999
- 1999-04-01 EP EP99660058A patent/EP0949274A3/en not_active Ceased
- 1999-04-05 MY MYPI99001301A patent/MY121053A/en unknown
- 1999-04-06 CN CNB998056995A patent/CN1202140C/zh not_active Expired - Lifetime
- 1999-04-06 AR ARP990101530A patent/AR018835A1/es active IP Right Grant
- 1999-04-06 CA CA002325632A patent/CA2325632A1/en not_active Abandoned
- 1999-04-06 WO PCT/FI1999/000286 patent/WO1999051646A1/en not_active Ceased
- 1999-04-06 BR BRPI9909435-5A patent/BR9909435B1/pt not_active IP Right Cessation
- 1999-04-06 AU AU33342/99A patent/AU3334299A/en not_active Abandoned
- 1999-04-06 KR KR10-2000-7011120A patent/KR100531509B1/ko not_active Expired - Lifetime
- 1999-04-06 US US09/286,437 patent/US6620758B1/en not_active Expired - Lifetime
- 1999-04-06 JP JP2000542367A patent/JP4813657B2/ja not_active Expired - Lifetime
- 1999-04-13 TW TW088105818A patent/TWI251598B/zh not_active IP Right Cessation
-
2000
- 2000-09-20 ZA ZA200005015A patent/ZA200005015B/xx unknown
-
2003
- 2003-04-24 US US10/423,771 patent/US20030208010A1/en not_active Abandoned
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2004
- 2004-06-14 US US10/868,509 patent/US6924343B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US20030208010A1 (en) | 2003-11-06 |
| US6924343B2 (en) | 2005-08-02 |
| US20050020785A1 (en) | 2005-01-27 |
| MY121053A (en) | 2005-12-30 |
| AU3334299A (en) | 1999-10-25 |
| CA2325632A1 (en) | 1999-10-14 |
| JP2002510719A (ja) | 2002-04-09 |
| BR9909435A (pt) | 2000-12-12 |
| CN1299375A (zh) | 2001-06-13 |
| FI980788A0 (fi) | 1998-04-06 |
| AR018835A1 (es) | 2001-12-12 |
| US6620758B1 (en) | 2003-09-16 |
| JP4813657B2 (ja) | 2011-11-09 |
| WO1999051646A1 (en) | 1999-10-14 |
| KR20010042494A (ko) | 2001-05-25 |
| ZA200005015B (en) | 2001-03-22 |
| KR100531509B1 (ko) | 2005-11-28 |
| CN1202140C (zh) | 2005-05-18 |
| EP0949274A3 (en) | 2007-10-03 |
| BR9909435B1 (pt) | 2011-07-12 |
| FI111372B (fi) | 2003-07-15 |
| FI980788A7 (fi) | 1999-10-07 |
| EP0949274A2 (en) | 1999-10-13 |
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