ES2653868T3 - Procatalizador de Ziegler Natta soportado para la polimerización de etileno - Google Patents

Procatalizador de Ziegler Natta soportado para la polimerización de etileno Download PDF

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Publication number
ES2653868T3
ES2653868T3 ES12198801.8T ES12198801T ES2653868T3 ES 2653868 T3 ES2653868 T3 ES 2653868T3 ES 12198801 T ES12198801 T ES 12198801T ES 2653868 T3 ES2653868 T3 ES 2653868T3
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weight
group
metal
polymerization
ethylene
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ES12198801.8T
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English (en)
Inventor
Kumudini Jayaratne
Elina Hämäläinen
Kalle Kallio
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Borealis GmbH
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Borealis GmbH
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Un procatalizador de Ziegler-Natta soportado para la polimerización de etileno, donde dicho procatalizador comprende a) un metal de los Grupos 1 a 3, preferiblemente un metal del Grupo 2, más preferiblemente Mg cuyo contenido (determinado mediante análisis por ICP) se encuentra dentro el rango entre 5.0 y 22.0 % en peso, preferiblemente entre 6.0 y 20 % en peso, más preferiblemente entre 6.5 y 18 % en peso b) un metal del Grupo 13 o 14, preferiblemente un metal del Grupo 13, más preferiblemente Al cuyo contenido (determinado mediante análisis por ICP) se encuentra dentro el rango entre 0.1 y 5.0 % en peso, preferiblemente entre 0.2 y 4.0% en peso, más preferiblemente entre 0.3 y 3.5 % en peso c) y un donante interno que se selecciona entre compuestos de bi-(anillo oxigenado) de fórmula (I) X es C o Si, Los R1 pueden ser el mismo o diferentes y pueden ser hidrógeno, un grupo C1-C8 alquilo lineal o ramificado, o un grupo C3-C8 alquileno, y R2 a R5 son el mismo o son diferentes y pueden ser hidrógeno, o un grupo C1-C8 alquilo lineal o ramificado, o C3- C8 alquileno, mediante lo cual dos o más de R1 a R5 pueden formar un anillo, n es el mismo para ambos anillos oxigenados y puede ser 0, 1 o 2, preferiblemente 1 o 2, donde los dos anillos oxigenados pueden ser, individualmente, saturados o insaturados, o una mezcla de isómeros de los mismos, d) un metal de los Grupos 4 a 6, preferiblemente un metal del Grupo 4, más preferiblemente Ti cuyo contenido (determinado mediante análisis por ICP) se encuentra dentro el rango entre 1.0 y 10.0 % en peso, preferiblemente entre 1.5 y 8.5 % en peso, más preferiblemente entre 2.0 y 7.0 % en peso

Description

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Claims (1)

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ES12198801.8T 2012-12-21 2012-12-21 Procatalizador de Ziegler Natta soportado para la polimerización de etileno Active ES2653868T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP12198801.8A EP2746306B1 (en) 2012-12-21 2012-12-21 Supported Ziegler Natta procatalyst for ethylene polymerisation

Publications (1)

Publication Number Publication Date
ES2653868T3 true ES2653868T3 (es) 2018-02-09

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ES12198801.8T Active ES2653868T3 (es) 2012-12-21 2012-12-21 Procatalizador de Ziegler Natta soportado para la polimerización de etileno

Country Status (6)

Country Link
US (1) US10457758B2 (es)
EP (1) EP2746306B1 (es)
CN (1) CN104870495B (es)
ES (1) ES2653868T3 (es)
SA (1) SA515360595B1 (es)
WO (1) WO2014096296A1 (es)

Families Citing this family (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2799456B1 (en) * 2013-04-30 2018-11-21 Borealis AG Supported donor modified Ziegler-Natta catalysts
US10118977B2 (en) * 2014-12-18 2018-11-06 Borealis Ag Ziegler-natta catalyst and preparation thereof
EP3253807B1 (en) * 2015-02-05 2023-04-26 Borealis AG Process for producing polyethylene
EP3053936A1 (en) 2015-02-06 2016-08-10 Borealis AG Process for producing copolymers of ethylene with alpha-olefins
ES2707391T3 (es) 2015-06-23 2019-04-03 Borealis Ag Procedimiento para la producción de resinas de LLDPE
US10961334B2 (en) * 2016-05-31 2021-03-30 Borealis Ag Polymer composition and a process for production of the polymer composition
PL3385958T3 (pl) * 2017-04-06 2023-08-07 Borealis Ag Kompozycja płaszcza kabla
EP3385959A1 (en) * 2017-04-06 2018-10-10 Borealis AG Cable jacket composition
WO2019129797A1 (en) 2017-12-27 2019-07-04 Borealis Ag Ziegler-natta catalyst and preparation thereof
EP3732209A1 (en) 2017-12-28 2020-11-04 Borealis AG Catalyst and preparation thereof
PT3746492T (pt) 2018-01-30 2022-11-25 Borealis Ag Agente de acoplamento
WO2020016370A1 (en) 2018-07-19 2020-01-23 Borealis Ag Process for the preparation of an uhmwpe homopolymer
WO2020064484A1 (en) 2018-09-28 2020-04-02 Borealis Ag A multi-stage process for producing a c2 to c8 olefin polymer composition
EP3647645A1 (en) 2018-10-31 2020-05-06 Borealis AG Polyethylene composition for high pressure resistant pipes
KR102593922B1 (ko) 2018-10-31 2023-10-25 보레알리스 아게 개선된 균질성을 갖는 고압력 저항성 파이프용 폴리에틸렌 조성물
US12146019B2 (en) 2018-11-30 2024-11-19 Borealis Ag Washing process
JP7365503B2 (ja) 2019-10-04 2023-10-19 ボレアリス エージー オレフィン重合用チーグラー・ナッタ触媒
EP4038116A1 (en) 2019-10-04 2022-08-10 Borealis AG Ziegler-natta catalysts for olefin polymerization
WO2021064081A1 (en) 2019-10-04 2021-04-08 Borealis Ag Ziegler-natta catalysts for olefin polymerization
US12359005B2 (en) 2019-10-04 2025-07-15 Borealis Ag Ziegler-Natta catalysts for olefin polymerization
EP4179020B1 (en) 2020-07-10 2024-12-25 Borealis AG Polyethylene pipe resin with high resistance to slow crack growth
WO2022008608A1 (en) 2020-07-10 2022-01-13 Borealis Ag Polyolefin composition with improved resistance to high temperature
EP3988587B1 (en) 2020-10-26 2025-09-17 Borealis GmbH Polyolefin pipe resin with very good sagging and slow crack growth resistance
CN116601177A (zh) 2020-11-27 2023-08-15 博里利斯股份公司 工艺
EP4151677A1 (en) 2021-09-21 2023-03-22 Borealis AG Biaxially oriented film
EP4163323B1 (en) 2021-10-07 2024-05-29 Borealis AG Biaxially oriented film
EP4201969A1 (en) 2021-12-23 2023-06-28 Borealis AG Polyethylene composition for pipes having very good impact properties and slow crack growth resistance
WO2023117558A1 (en) 2021-12-23 2023-06-29 Borealis Ag Polymer composition for pipes having very good impact properties and slow crack growth resistance
EP4209546A1 (en) 2022-01-10 2023-07-12 Abu Dhabi Polymers Co. Ltd (Borouge) LLC Polyethylene pipe resin with improved long term hydrostatic strength
US11845814B2 (en) 2022-02-01 2023-12-19 Chevron Phillips Chemical Company Lp Ethylene polymerization processes and reactor systems for the production of multimodal polymers using combinations of a loop reactor and a fluidized bed reactor
EP4234614A1 (en) 2022-02-25 2023-08-30 Borealis AG A film comprising a polyethylene composition having improved gloss
EP4234627B1 (en) 2022-02-25 2024-12-04 Borealis AG A polyethylene composition with improved stiffness and toughness
EP4234626B1 (en) 2022-02-25 2024-07-03 Borealis AG A polyethylene composition with improved stiffness and toughness
EP4239014A1 (en) 2022-03-02 2023-09-06 Borealis AG Film comprising a polyethylene composition
EP4239015B1 (en) 2022-03-02 2024-05-22 Borealis AG Monoaxially oriented film comprising a polyethylene composition
EP4245805B1 (en) 2022-03-18 2024-09-18 Borealis AG Polyethylene blend for a film layer
EP4306442B1 (en) 2022-07-14 2025-05-07 Borealis AG Composition
EP4306444B1 (en) 2022-07-14 2025-03-05 Borealis AG Composition
EP4386046A1 (en) 2022-12-16 2024-06-19 Borealis AG Composition
CN120693367A (zh) 2023-02-14 2025-09-23 北欧化工有限责任公司 用于膜层的聚乙烯共混物
EP4417629A1 (en) 2023-02-14 2024-08-21 Borealis AG Polyethylene blend for a film layer
EP4665795A1 (en) 2023-02-14 2025-12-24 Borealis GmbH Polyethylene blend for a film layer
EP4431552B1 (en) 2023-03-14 2025-07-30 Borealis GmbH Biaxially oriented polyethylene film with improved stiffness
EP4455171A1 (en) 2023-04-28 2024-10-30 Borealis AG Moulded articles
EP4520722A1 (en) 2023-09-05 2025-03-12 LANXESS Organometallics GmbH Sustainable ziegler-natta catalysts

Family Cites Families (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3696398A (en) 1969-06-23 1972-10-03 Olivetti & Co Spa Analog to digital converters having multiple units of measurement
EP0044735A3 (en) 1980-07-21 1982-08-25 Imperial Chemical Industries Plc Transition metal composition, production and use
US4577035A (en) 1984-11-28 1986-03-18 Huffman George W 2,2'-Isopropylidine bis(tetrahydrofuran)
US4647635A (en) 1986-03-25 1987-03-03 The Firestone Tire & Rubber Company Initiator systems for polymerization of 1,3-dienes or copolymers containing 1,3-dienes
IT1198222B (it) * 1986-12-02 1988-12-21 Ausimont Spa Catalizzatori per la preparazione di polietilene a larga distribuzione dei pesi molecolari
FR2640273B1 (fr) 1988-12-14 1992-09-04 Atochem Procede de polymerisation en phase gazeuse de l'ethylene permettant la fabrication de polyethylene lineaire de distribution etroite de masse moleculaire
FI86867C (fi) 1990-12-28 1992-10-26 Neste Oy Flerstegsprocess foer framstaellning av polyeten
FI89929C (fi) 1990-12-28 1993-12-10 Neste Oy Foerfarande foer homo- eller sampolymerisering av eten
FI942949A0 (fi) 1994-06-20 1994-06-20 Borealis Polymers Oy Prokatalysator foer producering av etenpolymerer och foerfarande foer framstaellning daerav
JP3471099B2 (ja) 1994-11-25 2003-11-25 昭和電工株式会社 オレフィン重合用触媒担体の製造方法
FI96216C (fi) 1994-12-16 1996-05-27 Borealis Polymers Oy Prosessi polyeteenin valmistamiseksi
US7049377B1 (en) 1995-02-21 2006-05-23 Basell Poliolefine Italia S.R.L. 1,3-diethers and components and catalysts for the polymerization of olefins, containing said diethers
US5955396A (en) 1995-10-17 1999-09-21 Bp Amoco Corporation Morphology-controlled olefin polymerization catalyst formed from an emulsion
FI111372B (fi) 1998-04-06 2003-07-15 Borealis Polymers Oy Olefiinien polymerointiin tarkoitettu katalyyttikomponentti, sen valmistus ja käyttö
FI981717A7 (fi) 1998-08-07 2000-02-08 Borealis As Katalysaattorikomponentti, joka käsittää magnesiumia, titaania, halogeenia ja elektronidonorin, sen valmistus ja käyttö
FI981718L (fi) 1998-08-07 2000-02-08 Borealis As Katalysaattorikomponentti, joka käsittää magnesiumia, titaania, halogeenia ja elektrodonorin, sen valmistus ja käyttö
FI982388A7 (fi) 1998-11-04 2000-05-05 Borealis Polymers Oy Menetelmä staattisen sähkön eliminoimiseksi
FI990140A0 (fi) 1999-01-26 1999-01-26 Borealis Polymers Oy Korkea-aktiivinen olefiinipolymerointikatalysaattori, sen valmistus, katalysaattorisysteemi ja käyttö
MXPA01009833A (es) 1999-03-30 2002-11-04 Eastman Chem Co Proceso para producir poliolefinas.
GB0001914D0 (en) 2000-01-27 2000-03-22 Borealis Polymers Oy Catalyst
ES2266053T3 (es) 2001-06-20 2007-03-01 Borealis Technology Oy Preparacion de un componente de catalizador para la polimerizacion de olefina.
EP1403292B1 (en) 2002-09-30 2016-04-13 Borealis Polymers Oy Process for preparing an olefin polymerisation catalyst component with improved high temperature activity
EP1415999B1 (en) 2002-10-30 2007-12-05 Borealis Technology Oy Process and apparatus for producing olefin polymers
EP1572760B1 (en) 2002-12-18 2016-12-07 Borealis Technology Oy Method for the preparation of olefin polymerisation catalyst support and an olefin polymerisation catalyst
ES2377948T3 (es) 2003-06-20 2012-04-03 Borealis Polymers Oy Procedimiento para la preparación de una composición de un catalizador para la polimerización de olefinas
US7135531B2 (en) 2004-01-28 2006-11-14 Basf Catalysts Llc Spherical catalyst for olefin polymerization
EP1780225A1 (en) 2005-11-01 2007-05-02 Borealis Technology Oy Ziegler-Natta catalyst and its use to prepare multimodal polyolefin
EP2845868A1 (en) 2006-05-31 2015-03-11 Borealis Technology Oy Oxidation state of Ti as means for increasing catalyst activity
EP1862481B1 (en) 2006-05-31 2016-08-31 Borealis Technology Oy Catalyst with al-alkoxy component
EP2228395A1 (en) 2009-02-24 2010-09-15 Borealis AG Improved multi-stage process for producing multi-modal ethylene polymer composition
EP2246368A1 (en) 2009-04-30 2010-11-03 Borealis AG Improved ethylene polymerization catalyst composition
JP5596174B2 (ja) 2009-12-22 2014-09-24 株式会社ブリヂストン 改良されたビニル変性剤組成物および当該組成物の利用方法
TW201211083A (en) 2010-06-15 2012-03-16 Styron Europe Gmbh Low vinyl styrene-butadiene polymers and methods of making the same
EP2415790B1 (en) 2010-07-13 2014-09-24 Borealis AG Catalyst component
EP2495266A1 (en) 2011-03-04 2012-09-05 Styron Deutschland GmbH High styrene high vinyl styrene-butadiene rubber and methods for preparation thereof
EP2610273B1 (en) * 2011-12-30 2018-02-07 Borealis AG Catalyst component
US8575283B1 (en) * 2012-06-28 2013-11-05 Formosa Plastics Corporation, U.S.A. Heterocyclic organic compounds as electron donors for polyolefin catalysts
EP2799456B1 (en) 2013-04-30 2018-11-21 Borealis AG Supported donor modified Ziegler-Natta catalysts

Also Published As

Publication number Publication date
CN104870495B (zh) 2018-04-06
SA515360595B1 (ar) 2017-06-22
EP2746306B1 (en) 2017-10-04
CN104870495A (zh) 2015-08-26
US10457758B2 (en) 2019-10-29
WO2014096296A1 (en) 2014-06-26
EP2746306A1 (en) 2014-06-25
US20150315316A1 (en) 2015-11-05

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