TW201304239A - 包括氟化碳電解質添加物之鋰離子電化學電池 - Google Patents
包括氟化碳電解質添加物之鋰離子電化學電池 Download PDFInfo
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- TW201304239A TW201304239A TW101120346A TW101120346A TW201304239A TW 201304239 A TW201304239 A TW 201304239A TW 101120346 A TW101120346 A TW 101120346A TW 101120346 A TW101120346 A TW 101120346A TW 201304239 A TW201304239 A TW 201304239A
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- Prior art keywords
- lithium
- lithium ion
- electrolyte
- ion electrochemical
- electrochemical cell
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- 229910001416 lithium ion Inorganic materials 0.000 title claims abstract description 93
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 title claims abstract description 91
- 239000002000 Electrolyte additive Substances 0.000 title description 6
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 title 1
- 239000003792 electrolyte Substances 0.000 claims abstract description 110
- 239000000654 additive Substances 0.000 claims abstract description 74
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 49
- 230000000996 additive effect Effects 0.000 claims abstract description 47
- 150000001450 anions Chemical class 0.000 claims abstract description 42
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 35
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 23
- 229910021450 lithium metal oxide Inorganic materials 0.000 claims abstract description 19
- 125000001153 fluoro group Chemical group F* 0.000 claims abstract description 16
- 125000003709 fluoroalkyl group Chemical group 0.000 claims abstract description 16
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 14
- 125000005842 heteroatom Chemical group 0.000 claims abstract description 14
- 238000009830 intercalation Methods 0.000 claims abstract description 14
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 14
- 239000010452 phosphate Substances 0.000 claims abstract description 14
- 229910021481 rutherfordium Inorganic materials 0.000 claims abstract description 12
- 125000004122 cyclic group Chemical group 0.000 claims abstract description 6
- -1 ethyl dimethyl carbonate Chemical compound 0.000 claims description 24
- 229910013870 LiPF 6 Inorganic materials 0.000 claims description 23
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 claims description 22
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 17
- VAYTZRYEBVHVLE-UHFFFAOYSA-N 1,3-dioxol-2-one Chemical compound O=C1OC=CO1 VAYTZRYEBVHVLE-UHFFFAOYSA-N 0.000 claims description 15
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- 229910052760 oxygen Inorganic materials 0.000 claims description 13
- 239000007787 solid Substances 0.000 claims description 13
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 12
- 239000001301 oxygen Chemical group 0.000 claims description 12
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 11
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 10
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 claims description 10
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 9
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- DEUISMFZZMAAOJ-UHFFFAOYSA-N lithium dihydrogen borate oxalic acid Chemical compound B([O-])(O)O.C(C(=O)O)(=O)O.C(C(=O)O)(=O)O.[Li+] DEUISMFZZMAAOJ-UHFFFAOYSA-N 0.000 claims description 6
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- QEWYKACRFQMRMB-UHFFFAOYSA-N fluoroacetic acid Chemical compound OC(=O)CF QEWYKACRFQMRMB-UHFFFAOYSA-N 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- 229910021385 hard carbon Inorganic materials 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
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- 150000002500 ions Chemical class 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 238000006138 lithiation reaction Methods 0.000 description 1
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 1
- 229910052808 lithium carbonate Inorganic materials 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- QLOAVXSYZAJECW-UHFFFAOYSA-N methane;molecular fluorine Chemical compound C.FF QLOAVXSYZAJECW-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- YKYONYBAUNKHLG-UHFFFAOYSA-N n-Propyl acetate Natural products CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
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- 229920000867 polyelectrolyte Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 229940090181 propyl acetate Drugs 0.000 description 1
- FOWDZVNRQHPXDO-UHFFFAOYSA-N propyl hydrogen carbonate Chemical compound CCCOC(O)=O FOWDZVNRQHPXDO-UHFFFAOYSA-N 0.000 description 1
- 238000000425 proton nuclear magnetic resonance spectrum Methods 0.000 description 1
- 239000005297 pyrex Substances 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
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- 230000009467 reduction Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000002390 rotary evaporation Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
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- 238000004544 sputter deposition Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
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- 239000007858 starting material Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
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- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 150000004685 tetrahydrates Chemical class 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
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- 230000007704 transition Effects 0.000 description 1
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- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
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- 238000003911 water pollution Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0565—Polymeric materials, e.g. gel-type or solid-type
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0567—Liquid materials characterised by the additives
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0025—Organic electrolyte
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0085—Immobilising or gelification of electrolyte
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/60—Other road transportation technologies with climate change mitigation effect
- Y02T10/70—Energy storage systems for electromobility, e.g. batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Dispersion Chemistry (AREA)
- Secondary Cells (AREA)
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| US10615456B2 (en) | 2015-11-06 | 2020-04-07 | Sumitomo Seika Chemicals Co., Ltd. | Additive for nonaqueous electrolyte solutions, nonaqueous electrolyte solution and electricity storage device |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2844796C (en) | 2011-09-02 | 2020-12-29 | E. I. Du Pont De Nemours And Company | Lithium ion battery with nonaqueous electrolyte comprising fluorinated acyclic carboxylic acid ester and/or fluorinated acyclic carbonate |
| EP2751866B1 (en) | 2011-09-02 | 2016-12-14 | E. I. du Pont de Nemours and Company | Fluorinated electrolyte compositions |
| WO2013180781A1 (en) | 2012-06-01 | 2013-12-05 | E. I. Du Pont De Nemours And Company | Lithium- ion battery |
| WO2013180783A1 (en) | 2012-06-01 | 2013-12-05 | E. I. Du Pont De Nemours And Company | Fluorinated electrolyte compositions |
| EP3588657A1 (en) | 2013-04-04 | 2020-01-01 | Solvay SA | Nonaqueous electrolyte compositions |
| US10168389B2 (en) * | 2014-08-06 | 2019-01-01 | Samsung Electronics Co., Ltd. | All-solid secondary battery, method of controlling all-solid secondary battery and method of evaluating all-solid secondary battery |
| US20160087307A1 (en) * | 2014-09-19 | 2016-03-24 | E I Du Pont De Nemours And Company | Nonaqueous electrolyte compositions |
| KR101828127B1 (ko) | 2014-10-02 | 2018-02-09 | 주식회사 엘지화학 | 젤 폴리머 전해질 및 이를 포함하는 리튬 이차전지 |
| JP2016149312A (ja) * | 2015-02-13 | 2016-08-18 | ソニー株式会社 | 二次電池、電池パック、電動車両、電力貯蔵システム、電動工具および電子機器 |
| WO2016160703A1 (en) | 2015-03-27 | 2016-10-06 | Harrup Mason K | All-inorganic solvents for electrolytes |
| JP6927038B2 (ja) * | 2015-05-29 | 2021-08-25 | 日本電気株式会社 | リチウムイオン二次電池 |
| FR3038455B1 (fr) * | 2015-07-01 | 2020-03-13 | Renault S.A.S. | Compose utilise en tant qu'additif dans un electrolyte pour batterie a circulation d'ions |
| KR101898240B1 (ko) * | 2015-12-24 | 2018-10-29 | 주식회사 포스코 | 리튬 이차 전지용 양극 활물질의 제조 방법 및 이를 포함하는 리튬 이차 전지 |
| US10707531B1 (en) | 2016-09-27 | 2020-07-07 | New Dominion Enterprises Inc. | All-inorganic solvents for electrolytes |
| KR102160709B1 (ko) | 2017-04-14 | 2020-09-28 | 주식회사 엘지화학 | 고분자 고체 전해질 및 이를 포함하는 리튬 이차전지 |
| JP2019021622A (ja) * | 2017-07-13 | 2019-02-07 | Tdk株式会社 | 二次電池用電解質および二次電池 |
| CN109428081A (zh) * | 2017-08-31 | 2019-03-05 | 宁德时代新能源科技股份有限公司 | 一种电池、正极浆料及极片以及清除杂质锂的方法 |
| JP2019096610A (ja) | 2017-11-21 | 2019-06-20 | 三星電子株式会社Ｓａｍｓｕｎｇ Ｅｌｅｃｔｒｏｎｉｃｓ Ｃｏ．，Ｌｔｄ． | 全固体二次電池およびその充電方法 |
| US11043705B1 (en) * | 2018-05-25 | 2021-06-22 | The United States Government Of America As Represented By The Secretary Of The Navy | Cell having implanted electronic circuit |
| US11824155B2 (en) | 2019-05-21 | 2023-11-21 | Samsung Electronics Co., Ltd. | All-solid lithium secondary battery and method of charging the same |
| US11881558B2 (en) | 2020-01-09 | 2024-01-23 | Apple Inc. | Electrolytes for lithium-containing battery cells |
| JPWO2023120688A1 (enExample) * | 2021-12-24 | 2023-06-29 | ||
| CN118382950A (zh) * | 2021-12-24 | 2024-07-23 | 株式会社村田制作所 | 二次电池 |
| WO2023119946A1 (ja) * | 2021-12-24 | 2023-06-29 | 株式会社村田製作所 | 二次電池用電解液および二次電池 |
| WO2023119949A1 (ja) * | 2021-12-24 | 2023-06-29 | 株式会社村田製作所 | 二次電池 |
| WO2023162432A1 (ja) * | 2022-02-25 | 2023-08-31 | 株式会社村田製作所 | 二次電池 |
| WO2023162430A1 (ja) * | 2022-02-25 | 2023-08-31 | 株式会社村田製作所 | 二次電池用電解液および二次電池 |
| WO2023220857A1 (zh) * | 2022-05-16 | 2023-11-23 | 宁德时代新能源科技股份有限公司 | 电解液及包含其的二次电池、电池模块、电池包和用电装置 |
| CN117175145B (zh) * | 2023-11-01 | 2024-01-30 | 柔电（武汉）科技有限公司 | 一种纤维素基全固态聚合物电解质隔膜及制备方法及应用 |
Family Cites Families (91)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3476753A (en) | 1965-05-03 | 1969-11-04 | Minnesota Mining & Mfg | Tertiaryamino perfluoro alkylene sulfonic acid fluorides |
| JPS61289614A (ja) | 1985-06-18 | 1986-12-19 | 旭硝子株式会社 | 電気二重層コンデンサ |
| DE3883630T2 (de) | 1987-06-24 | 1994-02-17 | Hitachi Maxell | Nichtwässrige elektrochemische Zelle. |
| US4857423A (en) | 1987-11-30 | 1989-08-15 | Eic Labotatories, Inc. | Overcharge protection of secondary, non-aqueous batteries |
| US4935316A (en) | 1989-07-25 | 1990-06-19 | The United States Of America As Represented By The United States Department Of Energy | Overdischarge protection in high-temperature cells and batteries |
| JP2803332B2 (ja) | 1990-06-22 | 1998-09-24 | 日本板硝子株式会社 | 溝型枠材とガラスとの接着方法 |
| JPH0536439A (ja) | 1991-07-31 | 1993-02-12 | Sony Corp | 非水電解液二次電池 |
| JP3016447B2 (ja) | 1991-08-29 | 2000-03-06 | 株式会社ユアサコーポレーション | 非水電解液電池 |
| JP3043175B2 (ja) | 1992-03-13 | 2000-05-22 | 富士電気化学株式会社 | リチウム二次電池 |
| US5278000A (en) | 1992-09-02 | 1994-01-11 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Overcharge and overdischarge protection of ambient temperature secondary lithium cells |
| JP3259436B2 (ja) | 1993-05-31 | 2002-02-25 | ソニー株式会社 | 非水電解液二次電池 |
| JP3809657B2 (ja) | 1994-03-07 | 2006-08-16 | ソニー株式会社 | 非水電解液二次電池 |
| US5536599A (en) | 1994-05-16 | 1996-07-16 | Eic Laboratories Inc. | Solid polymer electrolyte batteries containing metallocenes |
| JP3404929B2 (ja) | 1994-10-13 | 2003-05-12 | 日本電池株式会社 | 非水電解液電池 |
| US5514493A (en) * | 1995-03-06 | 1996-05-07 | Minnesota Mining And Manufacturing Company | Perfluoroalkylsulfonates, sulfonimides, and sulfonyl methides, and electrolytes containing them |
| JP3493873B2 (ja) | 1995-04-28 | 2004-02-03 | ソニー株式会社 | 非水電解液二次電池 |
| JP3669024B2 (ja) | 1995-05-26 | 2005-07-06 | ソニー株式会社 | 非水電解液二次電池 |
| CA2156800C (en) | 1995-08-23 | 2003-04-29 | Huanyu Mao | Polymerizable aromatic additives for overcharge protection in non-aqueous rechargeable lithium batteries |
| CA2163187C (en) | 1995-11-17 | 2003-04-15 | Huanyu Mao | Aromatic monomer gassing agents for protecting non-aqueous lithium batteries against overcharge |
| JP3669064B2 (ja) | 1996-08-01 | 2005-07-06 | ソニー株式会社 | 非水電解質二次電池 |
| US5858573A (en) | 1996-08-23 | 1999-01-12 | Eic Laboratories, Inc. | Chemical overcharge protection of lithium and lithium-ion secondary batteries |
| US5882812A (en) | 1997-01-14 | 1999-03-16 | Polyplus Battery Company, Inc. | Overcharge protection systems for rechargeable batteries |
| JP3575735B2 (ja) | 1997-05-16 | 2004-10-13 | Ｎｅｃトーキン栃木株式会社 | 非水系の再充電可能なリチウム電池 |
| CA2205683C (en) | 1997-05-16 | 2001-05-15 | Moli Energy (1990) Limited | Polymerizable additives for making non-aqueous rechargeable lithium batteries safe after overcharge |
| EP0886334B1 (en) | 1997-06-19 | 2001-08-29 | Sanyo Electric Co., Ltd. | Lithium secondary battery |
| DE19733948A1 (de) * | 1997-08-06 | 1999-02-11 | Merck Patent Gmbh | Verfahren zur Herstellung von Perfluoralkan-1-sulfonyl(perfluoralkylsulfonyl) imid-N-sulfonyl enthaltende Methanide, Imide und Sulfonate, und Perfluoralkan-1-N-(sulfonylbis(perfluoralkylsulfonyl)methaniden) |
| GB9717220D0 (en) | 1997-08-15 | 1997-10-22 | Aea Technology Plc | Eklectrolyte for a rechargeable cell |
| US6004698A (en) | 1997-08-21 | 1999-12-21 | The United States Of America As Represented By The United States Department Of Energy | Solid polymer electrolyte electrochemical storage cell containing a redox shuttle additive for overcharge protection |
| JPH1167274A (ja) | 1997-08-22 | 1999-03-09 | Daikin Ind Ltd | リチウム二次電池及び高分子ゲル電解質並びにリチウム二次電池用結着剤 |
| CA2216898C (en) | 1997-09-26 | 2005-03-22 | Moli Energy (1990) Limited | Improved additives for overcharge protection in non-aqueous rechargeable lithium batteries |
| US6045952A (en) | 1998-03-23 | 2000-04-04 | The United States Of America As Represented By The United States Department Of Energy | Electrochemical storage cell containing a substituted anisole or di-anisole redox shuttle additive for overcharge protection and suitable for use in liquid organic and solid polymer electrolytes |
| US6063522A (en) * | 1998-03-24 | 2000-05-16 | 3M Innovative Properties Company | Electrolytes containing mixed fluorochemical/hydrocarbon imide and methide salts |
| US6203944B1 (en) | 1998-03-26 | 2001-03-20 | 3M Innovative Properties Company | Electrode for a lithium battery |
| US6228516B1 (en) | 1998-04-02 | 2001-05-08 | Motorola, Inc. | Self-switching electrochemical cells and method of making same |
| JPH11307122A (ja) | 1998-04-24 | 1999-11-05 | Yuasa Corp | リチウム二次電池 |
| US6255017B1 (en) | 1998-07-10 | 2001-07-03 | 3M Innovative Properties Co. | Electrode material and compositions including same |
| JP2983205B1 (ja) | 1998-07-31 | 1999-11-29 | 三洋電機株式会社 | 非水系二次電池 |
| JP2939469B1 (ja) | 1998-07-31 | 1999-08-25 | 三洋電機株式会社 | 非水系電池用電解液およびこの電解液を用いた二次電池 |
| JP2000195554A (ja) | 1998-11-11 | 2000-07-14 | Sanyo Electric Co Ltd | リチウム二次電池 |
| JP4296620B2 (ja) | 1998-11-18 | 2009-07-15 | ソニー株式会社 | 非水電解液電池 |
| JP2000228215A (ja) | 1999-02-04 | 2000-08-15 | Sanyo Electric Co Ltd | リチウム二次電池 |
| JP2000251932A (ja) | 1999-02-24 | 2000-09-14 | Sony Corp | 非水電解質二次電池 |
| JP2000277147A (ja) | 1999-03-25 | 2000-10-06 | Sony Corp | 非水電解質二次電池 |
| DE19919347A1 (de) * | 1999-04-28 | 2000-11-02 | Merck Patent Gmbh | Verfahren zur Aufreinigung von Methanid-Elektrolyten (II) |
| JP4020571B2 (ja) | 1999-06-25 | 2007-12-12 | 三洋電機株式会社 | リチウム二次電池 |
| JP3670895B2 (ja) | 1999-08-04 | 2005-07-13 | 三洋電機株式会社 | リチウム二次電池 |
| JP3831550B2 (ja) | 1999-08-16 | 2006-10-11 | 三洋電機株式会社 | 非水電解質電池 |
| JP3558007B2 (ja) | 1999-09-30 | 2004-08-25 | 宇部興産株式会社 | 非水電解液およびそれを用いたリチウム二次電池 |
| US6372829B1 (en) | 1999-10-06 | 2002-04-16 | 3M Innovative Properties Company | Antistatic composition |
| WO2001029920A1 (en) | 1999-10-18 | 2001-04-26 | The Regents Of The University Of California | Shutdown and redox shuttle additives for batteries |
| JP3617447B2 (ja) | 1999-12-01 | 2005-02-02 | 松下電器産業株式会社 | リチウム二次電池 |
| WO2001052341A1 (en) | 2000-01-11 | 2001-07-19 | 3M Innovative Properties Company | Perfluoroalkanesulfonate salts in electrochemical systems |
| JP2001210364A (ja) | 2000-01-26 | 2001-08-03 | Mitsubishi Chemicals Corp | 非水系電解液およびこれを用いた二次電池 |
| US6596439B1 (en) | 2000-04-26 | 2003-07-22 | Quallion Llc | Lithium ion battery capable of being discharged to zero volts |
| KR100337889B1 (ko) | 2000-06-22 | 2002-05-24 | 김순택 | 리튬 2차전지 |
| JP3475911B2 (ja) | 2000-05-25 | 2003-12-10 | 宇部興産株式会社 | 非水電解液およびそれを用いたリチウム二次電池 |
| JP4843832B2 (ja) | 2000-05-26 | 2011-12-21 | 三菱化学株式会社 | 非水系電解液及びこれを用いた二次電池 |
| US6660432B2 (en) | 2000-09-14 | 2003-12-09 | Ilion Technology Corporation | Lithiated oxide materials and methods of manufacture |
| EP1324417B1 (en) | 2000-10-03 | 2012-11-28 | Ube Industries, Ltd. | Lithium secondary cell and nonaqueous electrolyte |
| JP2002134166A (ja) | 2000-10-20 | 2002-05-10 | Matsushita Electric Ind Co Ltd | 非水電解液とそれを用いた非水電解液二次電池 |
| ITMI20010008A1 (it) * | 2001-01-03 | 2002-07-03 | Ausimont Spa | Additivi per fluoropolieterei per applicazioni elettromagnetiche |
| HU228326B1 (en) | 2001-01-24 | 2013-03-28 | Ube Industries | Nonaqueous electrolytic solution and lithium secondary batteries |
| JP5011606B2 (ja) | 2001-04-13 | 2012-08-29 | パナソニック株式会社 | 有機電解液電池 |
| US6964828B2 (en) | 2001-04-27 | 2005-11-15 | 3M Innovative Properties Company | Cathode compositions for lithium-ion batteries |
| US6680145B2 (en) | 2001-08-07 | 2004-01-20 | 3M Innovative Properties Company | Lithium-ion batteries |
| JP4190188B2 (ja) | 2002-01-24 | 2008-12-03 | 三洋電機株式会社 | リチウム二次電池 |
| WO2003081697A1 (en) | 2002-03-22 | 2003-10-02 | Lg Chem, Ltd. | Lithium secondary battery comprising overdischarge-preventing agent |
| JP4367648B2 (ja) | 2003-02-14 | 2009-11-18 | ダイキン工業株式会社 | フルオロスルホン酸化合物、その製法及びその用途 |
| WO2004100293A1 (ja) | 2003-05-09 | 2004-11-18 | Sony Corporation | 負極活物質及びその製造方法、これを用いた非水電解質二次電池 |
| US7498100B2 (en) | 2003-08-08 | 2009-03-03 | 3M Innovative Properties Company | Multi-phase, silicon-containing electrode for a lithium-ion battery |
| CN1894822B (zh) * | 2003-12-15 | 2010-06-02 | 日本电气株式会社 | 二次电池 |
| WO2005057714A1 (ja) * | 2003-12-15 | 2005-06-23 | Nec Corporation | 二次電池用電解液およびそれを用いた二次電池 |
| JP4345641B2 (ja) * | 2003-12-15 | 2009-10-14 | 日本電気株式会社 | 二次電池 |
| WO2005099025A2 (en) | 2004-04-01 | 2005-10-20 | 3M Innovative Properties Company | Redox shuttle for overdischarge protection in rechargeable lithium-ion batteries |
| ATE491240T1 (de) | 2004-04-01 | 2010-12-15 | 3M Innovative Properties Co | Redox-shuttle für eine wiederaufladbare lithiumionenzelle |
| US20060046144A1 (en) | 2004-09-01 | 2006-03-02 | 3M Innovative Properties Company | Anode composition for lithium ion battery |
| CN100438197C (zh) * | 2004-09-24 | 2008-11-26 | 比亚迪股份有限公司 | 一种非水电解液及其锂离子二次电池 |
| US7615317B2 (en) | 2005-05-17 | 2009-11-10 | 3M Innovative Properties Company | N-oxide redox shuttles for rechargeable lithium-ion cell |
| US7615312B2 (en) | 2005-05-17 | 2009-11-10 | 3M Innovative Properties Company | Substituted phenothiazine redox shuttles for rechargeable lithium-ion cell |
| US7851085B2 (en) | 2005-07-25 | 2010-12-14 | 3M Innovative Properties Company | Alloy compositions for lithium ion batteries |
| US7767349B2 (en) | 2005-07-25 | 2010-08-03 | 3M Innovative Properties Company | Alloy compositions for lithium ion batteries |
| US7871727B2 (en) | 2005-07-25 | 2011-01-18 | 3M Innovative Properties Company | Alloy composition for lithium ion batteries |
| US7517604B2 (en) | 2005-09-19 | 2009-04-14 | 3M Innovative Properties Company | Fuel cell electrolyte membrane with acidic polymer |
| JP5155172B2 (ja) | 2005-10-13 | 2013-02-27 | スリーエム イノベイティブ プロパティズ カンパニー | 電気化学セルの使用方法 |
| KR101354336B1 (ko) | 2005-12-01 | 2014-01-22 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 규소 함량이 높은 비결정성 합금을 기재로 하는 전극조성물 |
| KR20080093054A (ko) | 2006-02-17 | 2008-10-17 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 트라이페닐아민 산화환원 셔틀을 가진 재충전가능한 리튬 이온 전지 |
| JP5117730B2 (ja) * | 2006-03-27 | 2013-01-16 | 日立マクセルエナジー株式会社 | 非水二次電池およびその使用方法 |
| US20070269718A1 (en) | 2006-05-22 | 2007-11-22 | 3M Innovative Properties Company | Electrode composition, method of making the same, and lithium ion battery including the same |
| US20090053589A1 (en) | 2007-08-22 | 2009-02-26 | 3M Innovative Properties Company | Electrolytes, electrode compositions, and electrochemical cells made therefrom |
| CN101990721B (zh) | 2008-02-12 | 2013-06-19 | 3M创新有限公司 | 用于高电压阴极的氧化还原梭 |
| JP2011096492A (ja) | 2009-10-29 | 2011-05-12 | Sony Corp | リチウム空気電池 |
-
2012
- 2012-05-30 KR KR1020147000064A patent/KR20140039254A/ko not_active Ceased
- 2012-05-30 EP EP12726983.5A patent/EP2719009B1/en not_active Not-in-force
- 2012-05-30 US US14/122,596 patent/US9455472B2/en not_active Expired - Fee Related
- 2012-05-30 JP JP2014514493A patent/JP6054956B2/ja not_active Expired - Fee Related
- 2012-05-30 CN CN201280026782.5A patent/CN103563155B/zh not_active Expired - Fee Related
- 2012-05-30 WO PCT/US2012/039908 patent/WO2012170240A1/en not_active Ceased
- 2012-06-06 TW TW101120346A patent/TW201304239A/zh unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10615456B2 (en) | 2015-11-06 | 2020-04-07 | Sumitomo Seika Chemicals Co., Ltd. | Additive for nonaqueous electrolyte solutions, nonaqueous electrolyte solution and electricity storage device |
| TWI694630B (zh) * | 2015-11-06 | 2020-05-21 | 日商住友精化股份有限公司 | 非水電解液用添加劑、非水電解液及蓄電裝置 |
Also Published As
| Publication number | Publication date |
|---|---|
| JP6054956B2 (ja) | 2016-12-27 |
| WO2012170240A1 (en) | 2012-12-13 |
| CN103563155A (zh) | 2014-02-05 |
| EP2719009A1 (en) | 2014-04-16 |
| KR20140039254A (ko) | 2014-04-01 |
| JP2014516201A (ja) | 2014-07-07 |
| EP2719009B1 (en) | 2017-06-21 |
| US9455472B2 (en) | 2016-09-27 |
| US20140093783A1 (en) | 2014-04-03 |
| CN103563155B (zh) | 2017-07-21 |
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