NO20080008L - Fremstilling av hydrogen ved anvendelse av elektrokjemisk reformering and regenerering av elektrolytt - Google Patents

Fremstilling av hydrogen ved anvendelse av elektrokjemisk reformering and regenerering av elektrolytt

Info

Publication number
NO20080008L
NO20080008L NO20080008A NO20080008A NO20080008L NO 20080008 L NO20080008 L NO 20080008L NO 20080008 A NO20080008 A NO 20080008A NO 20080008 A NO20080008 A NO 20080008A NO 20080008 L NO20080008 L NO 20080008L
Authority
NO
Norway
Prior art keywords
electrolyte
preparation
regenerated
hydrogen
regeneration
Prior art date
Application number
NO20080008A
Other languages
English (en)
Inventor
Patrick G Grimes
Richard J Bellows
Original Assignee
Grdc Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Grdc Llc filed Critical Grdc Llc
Publication of NO20080008L publication Critical patent/NO20080008L/no

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/323—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/248—Reactors comprising multiple separated flow channels
    • B01J19/2485—Monolithic reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J3/00—Processes of utilising sub-atmospheric or super-atmospheric pressure to effect chemical or physical change of matter; Apparatus therefor
    • B01J3/04—Pressure vessels, e.g. autoclaves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0242—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical
    • B01J8/025—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical in a cylindrical shaped bed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0285—Heating or cooling the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
    • B01J8/222—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid in the presence of a rotating device only
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
    • B01J8/224—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement
    • B01J8/226—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement internally, i.e. the particles rotate within the vessel
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D7/00—Carbonates of sodium, potassium or alkali metals in general
    • C01D7/10—Preparation of bicarbonates from carbonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00203—Coils
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00212—Plates; Jackets; Cylinders
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00389—Controlling the temperature using electric heating or cooling elements
    • B01J2208/00407—Controlling the temperature using electric heating or cooling elements outside the reactor bed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00389—Controlling the temperature using electric heating or cooling elements
    • B01J2208/00415—Controlling the temperature using electric heating or cooling elements electric resistance heaters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00004—Scale aspects
    • B01J2219/00006—Large-scale industrial plants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00027—Process aspects
    • B01J2219/00029—Batch processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00027—Process aspects
    • B01J2219/00033—Continuous processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/0009—Coils
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00094—Jackets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00132—Controlling the temperature using electric heating or cooling elements
    • B01J2219/00135—Electric resistance heaters
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/86—Carbon dioxide sequestration
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/32—Hydrogen storage
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Fluid Mechanics (AREA)
  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Catalysts (AREA)
  • Fuel Cell (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)

Abstract

En fremgangsmåte, foretrukket kontinuerlig, for fremstilling av hydrogengass som omfatter å kontakte i den flytende fasen minst én oksiderbar organisk substans i nærvær av en blanding som omfatter minst én ledende katalysator og en vandig alkalisk karbonatelektrolytt, hvori minst én bikarbonatsammensetning fremstilt ved reaksjon av elektrolytten regenereres og den minst ene oksiderbare organiske substansen omfatter et oksygenert hydrokarbon, for eksempel metanol og/eller dimetyleter. I en foretrukken utførelsesform regenereres den alkaliske elektrolytten ved anvendelse av damp. Forskjellige fordelaktige reaksjonsskjemaer er beskrevet, som utnytter f.eks. strømningsflyt i medstrøm og motstrøm og alternative tårnsekvensarrangementer.
NO20080008A 2005-06-23 2008-01-02 Fremstilling av hydrogen ved anvendelse av elektrokjemisk reformering and regenerering av elektrolytt NO20080008L (no)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US69331605P 2005-06-23 2005-06-23
PCT/US2006/024645 WO2007002503A1 (en) 2005-06-23 2006-06-23 Hydrogen production using electrochemical reforming and electrolyte regeneration

Publications (1)

Publication Number Publication Date
NO20080008L true NO20080008L (no) 2008-03-17

Family

ID=37595464

Family Applications (2)

Application Number Title Priority Date Filing Date
NO20080009A NO20080009L (no) 2005-06-23 2008-01-02 Effektiv fremstilling av hydrogen
NO20080008A NO20080008L (no) 2005-06-23 2008-01-02 Fremstilling av hydrogen ved anvendelse av elektrokjemisk reformering and regenerering av elektrolytt

Family Applications Before (1)

Application Number Title Priority Date Filing Date
NO20080009A NO20080009L (no) 2005-06-23 2008-01-02 Effektiv fremstilling av hydrogen

Country Status (12)

Country Link
US (3) US8828216B2 (no)
EP (2) EP1904399A4 (no)
JP (2) JP4785920B2 (no)
KR (2) KR101014157B1 (no)
CN (2) CN101248005A (no)
AU (2) AU2006261880B2 (no)
BR (2) BRPI0612832A2 (no)
CA (3) CA2613497C (no)
NO (2) NO20080009L (no)
RU (2) RU2008102379A (no)
WO (3) WO2007002503A1 (no)
ZA (2) ZA200800562B (no)

Families Citing this family (61)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4785920B2 (ja) 2005-06-23 2011-10-05 シーオーピー エナジー テクノロジーズ エルエルシー 電気化学的な改質及び電解質の再生を使用する水素の生産
WO2007140441A2 (en) * 2006-05-31 2007-12-06 The Trustees Of Columbia University In The City Of New York Methods and systems for generating hydrogen from a biomass
WO2009024185A1 (en) * 2007-08-21 2009-02-26 Acta S.P.A. On-board continuous hydrogen production via ammonia electrolysis, corresponding electrolyzers and a method of operating the same
EP2268572B1 (en) 2008-04-23 2017-06-21 Her Majesty The Queen In Right Of Canada As Represented By The Minister Of Natural Resources Canada Production of hydrogen from oxygenated hydrocarbons
ATE534022T1 (de) * 2008-07-29 2011-12-15 Powerspan Corp Verfahren zur reinigung der verteilerplatte in einem flüssigbettreaktorsystem
US8082890B2 (en) * 2008-11-25 2011-12-27 Common Sense Technologies, LLC Method and apparatus for efficient generation of hydrogen
DK2387478T3 (en) * 2009-01-15 2018-10-29 Clene Nanomedicine Inc CONTINUOUS PROCESS AND APPARATUS FOR THE CREATION OF GOLD-BASED NANOPARTICLES
EP2399865A4 (en) * 2009-01-20 2012-10-24 Yasuo Ishikawa CATALYST FOR HYDROGEN GENERATION, METHOD FOR HYDROGEN GENERATION AND HYDROGEN GENERATOR
US8313634B2 (en) * 2009-01-29 2012-11-20 Princeton University Conversion of carbon dioxide to organic products
US11214486B2 (en) 2009-02-20 2022-01-04 Marine Power Products Incorporated Desalination methods and devices using geothermal energy
US9415363B2 (en) * 2009-02-20 2016-08-16 Marine Power Products Corporation Method and apparatus for efficient on-demand production of H2 and O2 from water using waste heat and environmentally safe metals
US9067186B2 (en) 2009-02-20 2015-06-30 Marine Power Products Incorporated Stability control of a hydrogen generating system and method
US10145015B2 (en) 2012-12-05 2018-12-04 Marine Power Products Incorporated Hydrogen generating system and method using geothermal energy
US9206043B2 (en) 2009-02-20 2015-12-08 Marine Power Products Incorporated Method of and device for optimizing a hydrogen generating system
US20130210155A1 (en) * 2009-09-17 2013-08-15 Chandrashekhar Khandekar Methods For Selection Of A Naphthenate Solids Inhibitor And Test Kit, And Method For Precipitating Naphthenate Solids
KR101157141B1 (ko) * 2009-12-28 2012-06-22 한국에너지기술연구원 입체장애 시클릭 아민이 첨가된 알칼리탄산염계 이산화탄소 흡수제 및 이를 이용한 이산화탄소 제거방법
US9376317B2 (en) 2010-01-06 2016-06-28 Yasuo Ishikawa Method of generating hydrogen
US8500987B2 (en) 2010-03-19 2013-08-06 Liquid Light, Inc. Purification of carbon dioxide from a mixture of gases
US8845877B2 (en) 2010-03-19 2014-09-30 Liquid Light, Inc. Heterocycle catalyzed electrochemical process
US8721866B2 (en) 2010-03-19 2014-05-13 Liquid Light, Inc. Electrochemical production of synthesis gas from carbon dioxide
US8524066B2 (en) * 2010-07-29 2013-09-03 Liquid Light, Inc. Electrochemical production of urea from NOx and carbon dioxide
US8845878B2 (en) 2010-07-29 2014-09-30 Liquid Light, Inc. Reducing carbon dioxide to products
US20120037510A1 (en) * 2010-08-12 2012-02-16 Advanced Combustion Technologies,Inc. Process and apparatus for the preparation of combustible fluid
US8961774B2 (en) 2010-11-30 2015-02-24 Liquid Light, Inc. Electrochemical production of butanol from carbon dioxide and water
US8568581B2 (en) 2010-11-30 2013-10-29 Liquid Light, Inc. Heterocycle catalyzed carbonylation and hydroformylation with carbon dioxide
US9090976B2 (en) 2010-12-30 2015-07-28 The Trustees Of Princeton University Advanced aromatic amine heterocyclic catalysts for carbon dioxide reduction
CN102153049A (zh) * 2011-02-15 2011-08-17 浙江工业大学 一种甘油催化裂解制备氢气方法
US20120216759A1 (en) * 2011-02-25 2012-08-30 Wallace Taylor Irvin Hydroxy booster system
US8562811B2 (en) 2011-03-09 2013-10-22 Liquid Light, Inc. Process for making formic acid
CN102530858B (zh) * 2011-04-29 2015-01-07 中国科学技术大学 一种用醇制氢气的方法
CN102249184A (zh) * 2011-05-06 2011-11-23 北京恒源基业新能源投资有限公司 用于产生氢气的组合物和制备氢气的方法
CA2839004A1 (en) 2011-07-06 2013-01-10 Liquid Light, Inc. Carbon dioxide capture and conversion to organic products
CA2841062A1 (en) 2011-07-06 2013-01-10 Liquid Light, Inc. Reduction of carbon dioxide to carboxylic acids, glycols, and carboxylates
US8596047B2 (en) * 2011-07-25 2013-12-03 King Fahd University Of Petroleum And Minerals Vehicle electrocatalyzer for recycling carbon dioxide to fuel hydrocarbons
RU2480399C1 (ru) * 2011-11-16 2013-04-27 Федеральное государственное бюджетное учреждение "Национальный исследовательский центр "Курчатовский институт" Способ получения водорода из воды
JP5646524B2 (ja) * 2012-02-27 2014-12-24 株式会社東芝 二酸化炭素分離回収システムおよびその運転方法
US10370595B2 (en) 2012-03-13 2019-08-06 Marine Power Products Incorporated System for and method of using on-site excess heat to convert CO2 emissions into hydrocarbons income at coal-fired power plants
US20140110271A1 (en) * 2012-10-19 2014-04-24 Phillips 66 Company Electrochemical reforming of oxygenate mixtures
KR101412015B1 (ko) * 2012-10-29 2014-07-01 한국과학기술연구원 고체산을 이용한 합성가스 제조 방법
CN103011072B (zh) * 2012-12-16 2015-03-04 天津大学 利用生物质制取高纯度氢气的方法及装置
US20140224663A1 (en) * 2013-02-14 2014-08-14 Phillips 66 Company Method of electrochemically depositing high-activity electrocatalysts
WO2015103391A1 (en) * 2013-12-31 2015-07-09 Mcalister Technologies, Llc Processes and apparatus for production and use of fuels sourced from organic wastes
KR102259107B1 (ko) * 2015-10-28 2021-06-01 금오공과대학교 산학협력단 수소 제조방법 및 무격막형 수소 제조 시스템
WO2017124112A1 (en) * 2016-01-15 2017-07-20 Sustainable Innovations, LLC Hydrogen system and method of operation
US9981896B2 (en) 2016-07-01 2018-05-29 Res Usa, Llc Conversion of methane to dimethyl ether
WO2018004994A1 (en) 2016-07-01 2018-01-04 Res Usa, Llc Fluidized bed membrane reactor
US10189763B2 (en) 2016-07-01 2019-01-29 Res Usa, Llc Reduction of greenhouse gas emission
US10536992B2 (en) * 2016-10-12 2020-01-14 John Arthur Cobb, JR. Resistance method
US11268875B2 (en) * 2016-11-22 2022-03-08 Redline Detection, Llc Method and apparatus for fluid leak detection
KR101976007B1 (ko) * 2017-09-27 2019-05-09 한국과학기술원 메탄올 직접 전환용 귀금속 담지 촉매, 그 제조방법 및 이를 이용한 메탄올 제조방법
JP7158672B2 (ja) * 2018-03-09 2022-10-24 株式会社Soken 水素生成装置
CN111086973B (zh) * 2019-12-30 2023-07-18 广东蓝玖新能源科技有限公司 一种制氢工艺及其应用
EP4085022A4 (en) * 2020-01-03 2024-02-14 Cornell University METHODS AND PROCESSES FOR THE USE OF OXIDES, HYDROXIDES AND SILICATES CONTAINING CALCIUM AND MAGNESIUM; AQUEOUS STREAMS CONTAINING CALCIUM AND MAGNESIUM TO CAPTURE, CONVERT AND STORAGE CARBON DIOXIDE AND PRODUCE HYDROGEN
JP7506481B2 (ja) * 2020-02-03 2024-06-26 日本スピンドル製造株式会社 スラリー保管装置、スラリー製造システム及びスラリー保管方法
WO2021162800A1 (en) * 2020-02-12 2021-08-19 Maceda Joseph Peter Novel electrochemical cells, stacks, modules and systems
EP4204355A1 (en) * 2020-08-26 2023-07-05 GTI Energy Liquid phase reforming of oxygenates for hydrogen production
KR20220055987A (ko) * 2020-10-27 2022-05-04 현대자동차주식회사 바이오매스를 이용한 수소 생산방법
WO2022221954A1 (en) * 2021-04-22 2022-10-27 Iogen Corporation Process and system for producing fuel
WO2023167663A1 (en) * 2022-03-02 2023-09-07 Alpha Portfolio LLC Processes for producing reactant chemical substances for fuel cells
KR20230132644A (ko) * 2022-03-08 2023-09-18 (주)바이오프랜즈 스마트 농장 및 발전소를 위한 dme 개질 시스템
CN114717600B (zh) * 2022-05-17 2023-09-26 中国科学院兰州化学物理研究所 一种碳载小颗粒纳米金属铼催化剂的制备及其在电解水制氢中的应用

Family Cites Families (62)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE162655C (no)
CA787831A (en) 1968-06-18 Allis-Chalmers Manufacturing Company Process and apparatus for thermal hydrogen reformation
FR685992A (fr) * 1930-10-07 1930-07-21 Girdler Corp Perfectionnements à la séparation des gaz entre eux
DE1000357B (de) 1954-12-06 1957-01-10 Iavetrocokeia Spa Verfahren zur Abtrennung und Wiedergewinnung von Kohlensaeure aus Gasgemischen
GB725000A (en) 1955-03-01 1955-03-02 Benson Homer Edwin Improvements in or relating to method for separating carbon dioxide and hydrogen sulphide from gas mixtures
US2886405A (en) * 1956-02-24 1959-05-12 Benson Homer Edwin Method for separating co2 and h2s from gas mixtures
BE572576A (no) * 1957-11-02
US3144301A (en) 1961-04-21 1964-08-11 Girdler Corp Removal of carbon dioxde from gaseous mixtures
US3520823A (en) * 1967-04-24 1970-07-21 Texaco Inc Synthesis gas process
US3965253A (en) * 1972-05-01 1976-06-22 Shell Oil Company Process for producing hydrogen
US3799884A (en) * 1972-06-29 1974-03-26 Union Oil Co Preparations of sulfur suspensions
US3959094A (en) 1975-03-13 1976-05-25 The United States Of America As Represented By The United States Energy Research And Development Administration Electrolytic synthesis of methanol from CO2
JPS5244802A (en) * 1975-10-06 1977-04-08 Osaka Gas Co Ltd Preparation of high calorific value fuel gas
GB1577723A (en) 1976-06-11 1980-10-29 Exxon Research Engineering Co Removal of a gas component present in a gaseous stream
JPS56146883A (en) 1980-04-15 1981-11-14 Mitsui Eng & Shipbuild Co Ltd Recovering method for hydrogen
JPS5767003A (en) 1980-10-14 1982-04-23 Toshiba Corp Feeding apparatus for hydrogen
US4661422A (en) 1985-03-04 1987-04-28 Institute Of Gas Technology Electrochemical production of partially oxidized organic compounds
US4609440A (en) * 1985-12-18 1986-09-02 Gas Research Institute Electrochemical synthesis of methane
US4609441A (en) * 1985-12-18 1986-09-02 Gas Research Institute Electrochemical reduction of aqueous carbon dioxide to methanol
NO162660C (no) 1987-01-27 1990-01-31 Onsager Olav T Fremgangsmaate for konvertering av karbonmonoksyd og vann til hydrogen og karbondioksyd.
US4793904A (en) * 1987-10-05 1988-12-27 The Standard Oil Company Process for the electrocatalytic conversion of light hydrocarbons to synthesis gas
US5248566A (en) * 1991-11-25 1993-09-28 The United States Of America As Represented By The United States Department Of Energy Fuel cell system for transportation applications
US5417817A (en) 1994-06-15 1995-05-23 Dammann; Wilbur A. Biomass gasification process and apparatus
GB9412786D0 (en) 1994-06-24 1994-08-17 Johnson Matthey Plc Improved reformer
JP2700052B2 (ja) * 1995-03-08 1998-01-19 工業技術院長 水素化物の製造方法
US6048458A (en) * 1995-12-01 2000-04-11 Eastern Power Limited Apparatus and method for waste recycling and conversion
PT914203E (pt) 1996-05-20 2001-08-30 Dinex As Metodo e reactor para a conversao electroquimica de um material que e insoluvel num fluido por exemplo as particulas de fuligem
US5904880A (en) * 1996-12-31 1999-05-18 Exxon Chemical Patents Inc. One step conversion of methanol to hydrogen and carbon dioxide
WO1998041313A1 (en) * 1997-03-14 1998-09-24 Exxon Research And Engineering Company Membranes comprising aminoacid salts in polyamine polymers and blends
US6035089A (en) * 1997-06-11 2000-03-07 Lockheed Martin Energy Research Corporation Integrated narrowband optical filter based on embedded subwavelength resonant grating structures
US6299744B1 (en) * 1997-09-10 2001-10-09 California Institute Of Technology Hydrogen generation by electrolysis of aqueous organic solutions
CN1502546A (zh) * 1997-10-07 2004-06-09 JFE�عɹ�˾ 制造氢或合成气体用的催化剂及制造氢或合成气体的方法
CA2253161A1 (en) 1998-04-16 1999-10-16 Karl Tze-Tang Chuang Electrochemical oxidation of hydrogen sulfide
GR1003235B (el) * 1998-05-22 1999-10-13 Διεργασια παραγωγης υδρογονου και ηλεκτρικης ενεργειας απο αναμορφωση βιο-αιθανολης, με χρηση κυψελιδων καυσιμου και με μηδενικη εκπομπη ρυπων
DE19835481A1 (de) * 1998-08-07 2000-02-17 Bayer Ag Verfahren zur Oxidation von Kohlenwasserstoffen
JP2001019402A (ja) * 1999-07-05 2001-01-23 Center For Coal Utilization Japan 熱化学的分解による水素の製造方法
EP1278700B1 (en) 2000-04-21 2005-11-09 Institut Francais Du Petrole Hydrogen derived from methanol cracking is used as a clean fuel for power generation while reinjecting co-product carbon dioxide
JP4284829B2 (ja) * 2000-05-09 2009-06-24 三菱マテリアル株式会社 水素ガスの製造方法及びその装置
US6811913B2 (en) * 2000-11-15 2004-11-02 Technology Management, Inc. Multipurpose reversible electrochemical system
US6596423B2 (en) * 2001-03-26 2003-07-22 Brookhaven Science Associates, Llc Method for low temperature catalytic production of hydrogen
US6834623B2 (en) 2001-08-07 2004-12-28 Christopher T. Cheng Portable hydrogen generation using metal emulsions
US6607707B2 (en) * 2001-08-15 2003-08-19 Ovonic Battery Company, Inc. Production of hydrogen from hydrocarbons and oxygenated hydrocarbons
US20050163704A1 (en) 2004-01-23 2005-07-28 Ovonic Battery Company Base-facilitated production of hydrogen from biomass
US6994839B2 (en) * 2001-08-15 2006-02-07 Ovonic Battery Company, Inc. Carbonate recycling in a hydrogen producing reaction
BR0214560A (pt) 2001-11-29 2004-11-09 Wisconsin Alumni Res Found Produção de hidrogênio à baixa temperatura a partir de hidrocarbonetos oxigenados
US6699457B2 (en) 2001-11-29 2004-03-02 Wisconsin Alumni Research Foundation Low-temperature hydrogen production from oxygenated hydrocarbons
US6998188B2 (en) 2002-02-19 2006-02-14 Petillo Phillip J Fuel cell components
US7132188B2 (en) 2002-04-04 2006-11-07 The Board Of Trustees Of The University Of Illinois Fuel cells and fuel cell catalysts
US20030194368A1 (en) * 2002-04-16 2003-10-16 Devos John A. Hydrogen production system
AU2003299488B2 (en) 2002-05-10 2008-05-08 Wisconsin Alumni Research Foundation Low-temperature hydrocarbon production from oxygenated hydrocarbons
US6853669B2 (en) * 2002-12-10 2005-02-08 Ut-Battelle, Llc Nanocrystal waveguide (NOW) laser
WO2004076721A2 (en) 2003-02-21 2004-09-10 Avalence Llc Electrolyzer apparatus and method for hydrogen production
JP4041422B2 (ja) * 2003-03-26 2008-01-30 ニッポン高度紙工業株式会社 固体電解質及び該固体電解質を使用した電気化学システム
JP2004307295A (ja) * 2003-04-09 2004-11-04 Nissan Motor Co Ltd 水素製造方法
WO2005028372A2 (en) 2003-06-10 2005-03-31 The C & M Group, Llc Apparatus and process for mediated electrochemical oxidation of materials
US7588676B2 (en) * 2004-01-23 2009-09-15 Ovonic Battery Company, Inc. Base-facilitated production of hydrogen from carbonaceous matter
US20060188436A1 (en) * 2005-02-18 2006-08-24 Linnard Griffin Apparatus and method for the production of hydrogen
WO2005035444A2 (en) * 2003-10-10 2005-04-21 Ohio University Electro-catalysts for the oxidation of ammonia in alkaline media
US7700071B2 (en) * 2004-01-23 2010-04-20 Ovonic Battery Company, Inc. Production of hydrogen via a base-facilitated reaction of carbon monoxide
JP2005240064A (ja) 2004-02-24 2005-09-08 Seiko Epson Corp 改質器、燃料電池システムおよび機器
JP4814537B2 (ja) * 2004-03-09 2011-11-16 ハビックス株式会社 水素製造方法およびその装置
JP4785920B2 (ja) * 2005-06-23 2011-10-05 シーオーピー エナジー テクノロジーズ エルエルシー 電気化学的な改質及び電解質の再生を使用する水素の生産

Also Published As

Publication number Publication date
WO2007002504A1 (en) 2007-01-04
ZA200800562B (en) 2008-12-31
AU2006261880A1 (en) 2007-01-04
AU2006261880B2 (en) 2011-03-24
KR101014157B1 (ko) 2011-02-14
BRPI0612693A2 (pt) 2010-11-30
US20090277799A1 (en) 2009-11-12
CA2613097A1 (en) 2007-01-04
US20090277800A1 (en) 2009-11-12
CA2613483A1 (en) 2007-01-04
CN101248005A (zh) 2008-08-20
RU2415074C2 (ru) 2011-03-27
AU2006261881A1 (en) 2007-01-04
RU2008102379A (ru) 2009-07-27
WO2007002502A3 (en) 2007-08-30
CA2613497C (en) 2013-01-22
CA2613483C (en) 2012-02-07
US8828216B2 (en) 2014-09-09
CA2613497A1 (en) 2007-01-04
WO2007002502A2 (en) 2007-01-04
EP1904399A1 (en) 2008-04-02
EP1907317A1 (en) 2008-04-09
KR20080031309A (ko) 2008-04-08
NO20080009L (no) 2008-02-20
EP1904399A4 (en) 2013-09-18
CN101248004A (zh) 2008-08-20
WO2007002503A1 (en) 2007-01-04
US20090266717A1 (en) 2009-10-29
JP2008546626A (ja) 2008-12-25
KR20080027873A (ko) 2008-03-28
RU2008102365A (ru) 2009-07-27
CN101248004B (zh) 2015-11-25
JP4785920B2 (ja) 2011-10-05
US8318130B2 (en) 2012-11-27
BRPI0612832A2 (pt) 2010-11-30
CA2613097C (en) 2013-01-08
ZA200800563B (en) 2008-12-31
US8419922B2 (en) 2013-04-16
JP2008543719A (ja) 2008-12-04

Similar Documents

Publication Publication Date Title
NO20080008L (no) Fremstilling av hydrogen ved anvendelse av elektrokjemisk reformering and regenerering av elektrolytt
ES2421261T3 (es) Materiales depuradores en cartucho de combustible
NO20075881L (no) Fremgangsmate til behandling av en brukt svovelholdig kaustisk raffineristrom ved anvendelse av en membranelektrolysator drevet av en brenselcelle
CA2647525A1 (en) Process for preparing liquid hydrocarbons
KR101426112B1 (ko) 탄화수소계 연료의 탈황 시스템
WO2007114859A3 (en) Method and apparatus for generating hydrogen
WO2006120981A1 (ja) Ｌｐガス型燃料電池用液化石油ガス、その脱硫方法及び燃料電池システム
BRPI0621335A2 (pt) processo para a geração de um gás contendo h2
US20220396480A1 (en) Hydrogen generation assemblies
JP4284028B2 (ja) 一酸化炭素除去方法及びこれを用いた燃料電池システムの運転方法
RU2010105046A (ru) Способ производства диоксида хлора
RU2010114521A (ru) Совмещенное производство углеводородов и электрической энергии
JP4969091B2 (ja) 炭化水素系燃料の脱硫方法
RU2008142177A (ru) Способ получения синтез-газа и продуктов органического синтеза конверсий диоксида углерода и воды
JP4969090B2 (ja) 炭化水素系燃料の脱硫方法
GB2447817A (en) Thermal siphon reactor and hydrogen generator having the same
JP5334358B2 (ja) 炭化水素系燃料の脱硫方法
JP2008031306A (ja) 炭化水素系燃料の脱硫方法
JP4728846B2 (ja) 電解セル及び水素供給システム
JP2006167501A (ja) 改質触媒、水素生成装置および燃料電池システム
JP2006100141A (ja) 付臭剤、燃料電池用液体燃料及び燃料電池
JP2005190995A (ja) 燃料電池システム
JP2005166486A (ja) 直接型燃料電池システム
JP5421857B2 (ja) 吸着剤及びその製造方法、並びに燃料の脱硫方法
JP2007167828A (ja) 一酸化炭素を選択的に酸化する触媒、一酸化炭素濃度を低減する方法および燃料電池システム

Legal Events

Date Code Title Description
FC2A Withdrawal, rejection or dismissal of laid open patent application