NL8001764A - Bereiding van hoogmoleculair polytramethyleenadipamide. - Google Patents
Bereiding van hoogmoleculair polytramethyleenadipamide. Download PDFInfo
- Publication number
- NL8001764A NL8001764A NL8001764A NL8001764A NL8001764A NL 8001764 A NL8001764 A NL 8001764A NL 8001764 A NL8001764 A NL 8001764A NL 8001764 A NL8001764 A NL 8001764A NL 8001764 A NL8001764 A NL 8001764A
- Authority
- NL
- Netherlands
- Prior art keywords
- prepolymer
- prepared
- molecular weight
- polyamide
- condensation
- Prior art date
Links
- GVNWZKBFMFUVNX-UHFFFAOYSA-N Adipamide Chemical compound NC(=O)CCCCC(N)=O GVNWZKBFMFUVNX-UHFFFAOYSA-N 0.000 title claims description 13
- 238000002360 preparation method Methods 0.000 title description 5
- 238000009833 condensation Methods 0.000 claims description 25
- 239000004952 Polyamide Substances 0.000 claims description 18
- 229920002647 polyamide Polymers 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 17
- -1 polytetramethylene Polymers 0.000 claims description 15
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 239000012298 atmosphere Substances 0.000 claims description 8
- GHWVXCQZPNWFRO-UHFFFAOYSA-N butane-2,3-diamine Chemical compound CC(N)C(C)N GHWVXCQZPNWFRO-UHFFFAOYSA-N 0.000 claims description 8
- 239000001361 adipic acid Substances 0.000 claims description 5
- 235000011037 adipic acid Nutrition 0.000 claims description 5
- 239000007790 solid phase Substances 0.000 claims description 5
- 230000002378 acidificating effect Effects 0.000 claims description 2
- 229920001519 homopolymer Polymers 0.000 claims description 2
- 239000003054 catalyst Substances 0.000 claims 1
- 238000006068 polycondensation reaction Methods 0.000 claims 1
- 150000004985 diamines Chemical class 0.000 description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- DRXQIWUATHHZSU-UHFFFAOYSA-N C(CCCCC(=O)O)(=O)O.NC(C(C)N)C Chemical compound C(CCCCC(=O)O)(=O)O.NC(C(C)N)C DRXQIWUATHHZSU-UHFFFAOYSA-N 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 239000004677 Nylon Substances 0.000 description 5
- 230000005494 condensation Effects 0.000 description 5
- 229920001778 nylon Polymers 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 239000001273 butane Substances 0.000 description 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- HITFWOWDAHZDPG-UHFFFAOYSA-N CCCCN.OC(=O)CCCCC(O)=O Chemical compound CCCCN.OC(=O)CCCCC(O)=O HITFWOWDAHZDPG-UHFFFAOYSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- AVKNGPAMCBSNSO-UHFFFAOYSA-O aminomethylcyclohexane Chemical compound [NH3+]CC1CCCCC1 AVKNGPAMCBSNSO-UHFFFAOYSA-O 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- QFNNDGVVMCZKEY-UHFFFAOYSA-N azacyclododecan-2-one Chemical compound O=C1CCCCCCCCCCN1 QFNNDGVVMCZKEY-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 150000003951 lactams Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 238000002074 melt spinning Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 150000003003 phosphines Chemical class 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- XUWHAWMETYGRKB-UHFFFAOYSA-N piperidin-2-one Chemical compound O=C1CCCCN1 XUWHAWMETYGRKB-UHFFFAOYSA-N 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000004826 seaming Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000010129 solution processing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
- C08G69/28—Preparatory processes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyamides (AREA)
Priority Applications (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL8001764A NL8001764A (nl) | 1980-03-26 | 1980-03-26 | Bereiding van hoogmoleculair polytramethyleenadipamide. |
CA000373818A CA1165941A (en) | 1980-03-26 | 1981-03-25 | Preparation of high molecular polytetramethylene adipamide |
EP81200327A EP0038094B1 (en) | 1980-03-26 | 1981-03-25 | Preparation of high molecular polytetramethylene adipamide |
DE8181200327T DE3164518D1 (en) | 1980-03-26 | 1981-03-25 | Preparation of high molecular polytetramethylene adipamide |
US06/247,545 US4460762A (en) | 1980-03-26 | 1981-03-25 | Preparation of high molecular polytetramethylene adipamide |
ES500687A ES500687A0 (es) | 1980-03-26 | 1981-03-25 | Metodo para la preparacion de una poliamida blanca de alto peso molecular |
JP56044669A JPS608248B2 (ja) | 1980-03-26 | 1981-03-26 | 高分子量ポリテトラメチレンアジプアミドの製造方法 |
BR8101816A BR8101816A (pt) | 1980-03-26 | 1981-03-26 | Processo para preparacao de poliamida branca de alto peso molecular, e objeto consistindo total ou parcialmente tal poliamida |
IN334/CAL/81A IN154657B (OSRAM) | 1980-03-26 | 1981-03-26 | |
MX10052281U MX6549E (es) | 1980-03-26 | 1981-03-26 | Metodo para preparar adipamida de politetrametileno de gran pesomolecular |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL8001764A NL8001764A (nl) | 1980-03-26 | 1980-03-26 | Bereiding van hoogmoleculair polytramethyleenadipamide. |
NL8001764 | 1980-03-26 |
Publications (1)
Publication Number | Publication Date |
---|---|
NL8001764A true NL8001764A (nl) | 1981-10-16 |
Family
ID=19835060
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NL8001764A NL8001764A (nl) | 1980-03-26 | 1980-03-26 | Bereiding van hoogmoleculair polytramethyleenadipamide. |
Country Status (9)
Country | Link |
---|---|
US (1) | US4460762A (OSRAM) |
EP (1) | EP0038094B1 (OSRAM) |
JP (1) | JPS608248B2 (OSRAM) |
BR (1) | BR8101816A (OSRAM) |
CA (1) | CA1165941A (OSRAM) |
DE (1) | DE3164518D1 (OSRAM) |
ES (1) | ES500687A0 (OSRAM) |
IN (1) | IN154657B (OSRAM) |
NL (1) | NL8001764A (OSRAM) |
Families Citing this family (153)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3276758D1 (en) * | 1982-11-12 | 1987-08-20 | Stamicarbon | Use of (co)polytetramethylene-adipamide articles |
JPS60220731A (ja) * | 1984-04-17 | 1985-11-05 | Unitika Ltd | ポリアミドフィルムおよびその製造方法 |
NL8401271A (nl) * | 1984-04-19 | 1985-11-18 | Stamicarbon | Werkwijze voor het bereiden van polytetramethyleenadipamide. |
JPS61232902A (ja) * | 1985-04-08 | 1986-10-17 | Bridgestone Corp | 空気入りタイヤ |
US4722997A (en) * | 1985-05-31 | 1988-02-02 | Stamicarbon, B.V. | Process for the preparation of nylon 4,6 |
JPH0781007B2 (ja) * | 1985-05-31 | 1995-08-30 | デーエスエム ナムローゼ フェンノートシャップ | 白色の高分子量ポリ(テトラメチレンアジパミド)の製法 |
DE3526931A1 (de) * | 1985-07-27 | 1987-02-05 | Bayer Ag | Verfahren zur herstellung von poly(tetramethylenadipamid) |
GB8615268D0 (en) * | 1986-06-23 | 1986-07-30 | Domnick Hunter Filters Ltd | Polyamide membranes |
NL8601893A (nl) * | 1986-07-22 | 1988-02-16 | Stamicarbon | Bereiding van hoog-moleculair polytetramethyleenadipamide. |
NL8602729A (nl) * | 1986-10-30 | 1988-05-16 | Stamicarbon | Copolyamide en een werkwijze voor de bereiding ervan. |
NL8603138A (nl) * | 1986-12-10 | 1988-07-01 | Stamicarbon | Meerlagen polyamide vormlichaam. |
DE3804392A1 (de) * | 1988-02-12 | 1989-08-24 | Basf Ag | Fuellstoffhaltige polyamid-formmassen mit verbesserter oberflaeche und lackierbarkeit |
US5215662A (en) * | 1988-12-16 | 1993-06-01 | Micron Separations Inc. | Heat resistant microporous material production and products |
EP0410230A3 (en) * | 1989-07-26 | 1992-02-26 | Bayer Ag | Process for preparing high molecular weight polyamides |
US5332778A (en) * | 1990-08-21 | 1994-07-26 | Basf Aktiengesellschaft | Production of reinforced polytetramethyleneadipamide |
DE4026404A1 (de) * | 1990-08-21 | 1992-02-27 | Basf Ag | Verfahren zur herstellung von verstaerktem polytetramethylenadipamid |
JP2700116B2 (ja) * | 1992-05-29 | 1998-01-19 | 矢崎総業株式会社 | コネクタ |
DE4430480A1 (de) | 1994-08-27 | 1996-02-29 | Basf Ag | Hochmolekulare Polyamide aus Nitrilen |
JP3412657B2 (ja) * | 1994-09-08 | 2003-06-03 | 三菱瓦斯化学株式会社 | ポリアミドの乾燥方法および固相重合方法 |
DE19526855A1 (de) * | 1995-07-22 | 1997-01-23 | Basf Ag | Verfahren zur Herstellung von Polyarylenethern mit Anhydridendgruppen |
IT1285524B1 (it) * | 1996-10-18 | 1998-06-08 | Sinco Eng Spa | Procedimento per il raffreddamento di resine poliestere e/o poliammidiche |
IT1286041B1 (it) * | 1996-10-25 | 1998-07-07 | Sinco Eng Spa | Procedimento per la policondensazione allo stato solido di resine poliammidiche |
DE19648436A1 (de) | 1996-11-22 | 1998-05-28 | Basf Ag | Langleinen |
EP1029883B1 (en) | 1999-02-16 | 2003-10-29 | Mitsubishi Gas Chemical Company, Inc. | Solid phase-polymerized polyamide polymer and method for producing the same |
NL1011637C2 (nl) | 1999-03-22 | 2000-09-27 | Dsm Nv | Werkwijze voor de bereiding van polyamide perskorrels. |
DE19961040A1 (de) | 1999-12-16 | 2001-06-21 | Basf Ag | Thermoplastische Formmassen mit verbessertem Verarbeitungsverhalten auf Basis von Polyarylenethersulfonen und Polyamiden |
KR100911744B1 (ko) * | 2001-07-09 | 2009-08-13 | 디에스엠 아이피 어셋츠 비.브이. | 호모폴리아미드-4,6 섬유의 제조 방법 |
US6703479B1 (en) | 2001-12-03 | 2004-03-09 | Uop Llc | Process and apparatus for cooling polymer in a reactor |
US6749821B1 (en) | 2001-12-03 | 2004-06-15 | Uop Llc | Process for the purification of inert gases |
US20060135725A1 (en) * | 2004-12-21 | 2006-06-22 | Scimed Life Systems, Inc. | New balloon materials |
JP4857634B2 (ja) | 2005-07-22 | 2012-01-18 | 三菱瓦斯化学株式会社 | ポリアミド樹脂 |
US7585104B2 (en) * | 2005-09-12 | 2009-09-08 | Uop Llc | Rotary processor |
JP5431168B2 (ja) | 2006-12-13 | 2014-03-05 | ビーエーエスエフ ソシエタス・ヨーロピア | アクリレートゴムを含むポリアミド |
DE102006062269A1 (de) | 2006-12-22 | 2008-06-26 | Eckart Gmbh & Co. Kg | Verwendung von sphärischen Metallpartikeln als Lasermarkierungs- oder Laserschweißbarkeitsmittel sowie lasermarkierbarer und/oder laserschweißbarer Kunststoff |
DE502008001478D1 (de) | 2007-02-19 | 2010-11-18 | Basf Se | Formmassen mit reduzierter anisotropie der schlagzähigkeit |
DE102007038578A1 (de) | 2007-08-16 | 2009-02-19 | Evonik Degussa Gmbh | Verfahren zur Dekorierung von Oberflächen |
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DE502007001931D1 (de) | 2007-11-30 | 2009-12-17 | Eckart Gmbh | Verwendung einer Mischung mit sphärischen Metallpartikeln und Metallflakes als Lasermarkierungs- oder Laserschweissbarkeitsmittel sowie lasermarkierbarer und/oder laserschweissbarer Kunststoff |
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US2130948A (en) * | 1937-04-09 | 1938-09-20 | Du Pont | Synthetic fiber |
GB614625A (en) * | 1944-07-04 | 1948-12-20 | Geoffrey William Ison Sheavyn | Improvements in the production of condensation polymers |
GB1044128A (en) * | 1964-06-03 | 1966-09-28 | British Nylon Spinners Ltd | Polyamides and a process and apparatus for their production |
US3840500A (en) * | 1970-08-05 | 1974-10-08 | Inventa Ag | Process for the preparation of high molecular weight polyamides |
US3676400A (en) * | 1970-11-13 | 1972-07-11 | Du Pont | Thermoplastic blends of high-amine-end poly-amides and acid-containing olefin polymers |
JPS4917036A (OSRAM) * | 1972-06-12 | 1974-02-15 | ||
DE2417003C2 (de) * | 1974-04-08 | 1983-09-22 | Basf Ag, 6700 Ludwigshafen | Verfahren zum kontinuierlichen Herstellen von Polyamiden |
-
1980
- 1980-03-26 NL NL8001764A patent/NL8001764A/nl not_active Application Discontinuation
-
1981
- 1981-03-25 CA CA000373818A patent/CA1165941A/en not_active Expired
- 1981-03-25 US US06/247,545 patent/US4460762A/en not_active Expired - Fee Related
- 1981-03-25 DE DE8181200327T patent/DE3164518D1/de not_active Expired
- 1981-03-25 ES ES500687A patent/ES500687A0/es active Granted
- 1981-03-25 EP EP81200327A patent/EP0038094B1/en not_active Expired
- 1981-03-26 IN IN334/CAL/81A patent/IN154657B/en unknown
- 1981-03-26 JP JP56044669A patent/JPS608248B2/ja not_active Expired
- 1981-03-26 BR BR8101816A patent/BR8101816A/pt not_active IP Right Cessation
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EP0038094B1 (en) | 1984-07-04 |
JPS608248B2 (ja) | 1985-03-01 |
ES8202041A1 (es) | 1982-01-01 |
US4460762A (en) | 1984-07-17 |
JPS56149431A (en) | 1981-11-19 |
ES500687A0 (es) | 1982-01-01 |
CA1165941A (en) | 1984-04-17 |
DE3164518D1 (en) | 1984-08-09 |
IN154657B (OSRAM) | 1984-12-01 |
EP0038094A2 (en) | 1981-10-21 |
BR8101816A (pt) | 1981-09-29 |
EP0038094A3 (en) | 1981-11-04 |
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