KR101716609B1 - 조절된 알루미늄 대 ｓｃａ 비를 갖는 자기-제한성 촉매 시스템 및 방법 - Google Patents

조절된 알루미늄 대 ｓｃａ 비를 갖는 자기-제한성 촉매 시스템 및 방법 Download PDF

Info

Publication number
KR101716609B1
KR101716609B1 KR1020157033656A KR20157033656A KR101716609B1 KR 101716609 B1 KR101716609 B1 KR 101716609B1 KR 1020157033656 A KR1020157033656 A KR 1020157033656A KR 20157033656 A KR20157033656 A KR 20157033656A KR 101716609 B1 KR101716609 B1 KR 101716609B1
Authority
KR
South Korea
Prior art keywords
catalyst composition
sca
compound
propylene
aluminum
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
KR1020157033656A
Other languages
English (en)
Korean (ko)
Other versions
KR20150140854A (ko
Inventor
린펭 첸
리처드 이 캠벨
에그몬드 잰 더블유 반
Original Assignee
더블유.알. 그레이스 앤드 캄파니-콘.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=39768748&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=KR101716609(B1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by 더블유.알. 그레이스 앤드 캄파니-콘. filed Critical 더블유.알. 그레이스 앤드 캄파니-콘.
Publication of KR20150140854A publication Critical patent/KR20150140854A/ko
Application granted granted Critical
Publication of KR101716609B1 publication Critical patent/KR101716609B1/ko
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/656—Pretreating with metals or metal-containing compounds with silicon or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1809—Controlling processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1872—Details of the fluidised bed reactor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
    • C08F4/6465—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64 containing silicium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/651—Pretreating with non-metals or metal-free compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
    • B01J31/0212—Alkoxylates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/128—Mixtures of organometallic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2213—At least two complexing oxygen atoms present in an at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2400/00—Characteristics for processes of polymerization
    • C08F2400/02—Control or adjustment of polymerization parameters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Emergency Medicine (AREA)
KR1020157033656A 2007-08-24 2008-08-21 조절된 알루미늄 대 ｓｃａ 비를 갖는 자기-제한성 촉매 시스템 및 방법 Active KR101716609B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US95788807P 2007-08-24 2007-08-24
US60/957,888 2007-08-24
PCT/US2008/073882 WO2009029487A1 (en) 2007-08-24 2008-08-21 Self-limiting catalyst system with controlled aluminum rto sca ratio and method

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
KR1020107006325A Division KR101576308B1 (ko) 2007-08-24 2008-08-21 조절된 알루미늄 대 ｓｃａ 비를 갖는 자기-제한성 촉매 시스템 및 방법

Publications (2)

Publication Number Publication Date
KR20150140854A KR20150140854A (ko) 2015-12-16
KR101716609B1 true KR101716609B1 (ko) 2017-03-14

Family

ID=39768748

Family Applications (2)

Application Number Title Priority Date Filing Date
KR1020157033656A Active KR101716609B1 (ko) 2007-08-24 2008-08-21 조절된 알루미늄 대 ｓｃａ 비를 갖는 자기-제한성 촉매 시스템 및 방법
KR1020107006325A Active KR101576308B1 (ko) 2007-08-24 2008-08-21 조절된 알루미늄 대 ｓｃａ 비를 갖는 자기-제한성 촉매 시스템 및 방법

Family Applications After (1)

Application Number Title Priority Date Filing Date
KR1020107006325A Active KR101576308B1 (ko) 2007-08-24 2008-08-21 조절된 알루미늄 대 ｓｃａ 비를 갖는 자기-제한성 촉매 시스템 및 방법

Country Status (11)

Country Link
US (3) US10647788B2 (enExample)
EP (2) EP2185599B1 (enExample)
JP (1) JP5576281B2 (enExample)
KR (2) KR101716609B1 (enExample)
CN (3) CN101848946B (enExample)
BR (2) BRPI0815290A2 (enExample)
ES (1) ES2711342T3 (enExample)
MX (3) MX2010002118A (enExample)
PL (2) PL2185609T3 (enExample)
RU (1) RU2470947C2 (enExample)
WO (2) WO2009029487A1 (enExample)

Families Citing this family (46)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101716609B1 (ko) 2007-08-24 2017-03-14 더블유.알. 그레이스 앤드 캄파니-콘. 조절된 알루미늄 대 ｓｃａ 비를 갖는 자기-제한성 촉매 시스템 및 방법
WO2009141831A2 (en) * 2008-05-21 2009-11-26 Reliance Industries Limited A catalyst system for polymerization of olefins
CN102186889B (zh) * 2008-08-21 2013-11-06 陶氏环球技术有限责任公司 具有混合的选择性控制剂的催化剂组合物和使用它的聚合反应方法
BRPI0912920B1 (pt) 2008-08-21 2019-07-09 W. R. Grace & Co. -Conn Processo de polimerização e copolímero de impacto de propileno
US8507717B2 (en) 2008-12-31 2013-08-13 Dow Global Technologies Llc Production of substituted phenylene aromatic diesters
CN102325808B (zh) 2008-12-31 2014-03-12 陶氏环球技术有限责任公司 包含取代的1,2-亚苯基芳族二酯内给体的前催化剂组合物及方法
CN101554595B (zh) 2009-05-18 2011-02-02 中国石油化工股份有限公司 一种烯烃聚合用催化剂载体及其制备方法和应用
KR101784537B1 (ko) 2009-12-02 2017-10-11 더블유.알. 그레이스 앤드 캄파니-콘. 폴리프로필렌 제조를 위한 촉매 중 내부 공여체로서 2개의 원자로 브릿지된 디카르보네이트 화합물
MY158466A (en) 2009-12-02 2016-10-14 Grace W R & Co Three and four atom bridged dicarbonate compounds as internal donors in catalysts for polypropylene manufacture
MY156361A (en) * 2009-12-21 2016-02-15 Grace W R & Co Gas-phase polymerization process having multiple flow regimes
US20120116029A1 (en) * 2010-11-08 2012-05-10 Van Egmond Jan W Method for polymerizing polypropylene
US20120157295A1 (en) 2010-12-21 2012-06-21 Linfeng Chen Process for Producing Procatalyst Composition with Alkoxyalkyl Ester Internal Electron Donor and Product
US9382342B2 (en) 2010-12-21 2016-07-05 W. R. Grace & Co.-Conn. Procatalyst composition with alkoxyalkyl 2-propenoate internal electron donor and polymer from same
US9382343B2 (en) 2010-12-21 2016-07-05 W. R. Grace & Co.-Conn. Procatalyst composition with alkoxypropyl ester internal electron donor and polymer from same
US20120157645A1 (en) * 2010-12-21 2012-06-21 Linfeng Chen Procatalyst Composition with Alkoxypropyl Ester Internal Electron Donor and Polymer From Same
CN102174134B (zh) * 2011-01-27 2013-07-24 大唐国际化工技术研究院有限公司 制备高熔融指数聚丙烯的催化剂组合物、制备方法和用途
US10647790B2 (en) 2011-06-30 2020-05-12 W. R. Grace & Co.-Conn. Process for gas-phase polymerization having high bed bulk density
CN103044583B (zh) * 2011-10-13 2015-10-28 中国石油化工股份有限公司 烯烃聚合物及其制备方法
CN104066755B (zh) * 2011-11-15 2017-07-14 格雷斯公司 用于聚合聚丙烯的方法
EP2607384A1 (en) 2011-12-21 2013-06-26 Basell Poliolefine Italia S.r.l. Catalyst system for the polymerization of olefins
JP6466395B2 (ja) * 2013-03-14 2019-02-06 ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット プロピレン／ブテンインターポリマー生成システム及び方法
ES2963034T3 (es) * 2013-08-19 2024-03-25 Dow Global Technologies Llc Método para producir un polímero a base de etileno en un procedimiento de polimerización usando un agente de autolimitación
TWI639626B (zh) * 2013-09-30 2018-11-01 中國石油化工科技開發有限公司 Catalyst composition for olefin polymerization and application thereof
WO2015073221A1 (en) * 2013-11-15 2015-05-21 Dow Global Technologies Llc A polyolefin composition and method of producing the same
RU2702633C1 (ru) * 2013-11-15 2019-10-09 У.Р. Грейс Энд Ко.-Конн Полимер на основе пропилена с уменьшенной высокомолекулярной частью
RU2731442C2 (ru) 2013-11-21 2020-09-02 У.Р. Грейс Энд Ко.-Конн Получение полимеров на основе пропилена с высоким содержанием сомономера
EP3074429B1 (en) 2013-11-26 2024-01-24 W.R. Grace & CO. - CONN. Producing propylene impact copolymers and products
CN104774281A (zh) * 2014-01-09 2015-07-15 金成豪 用于烯烃聚合的催化剂组合物及其应用
US11236222B2 (en) * 2016-08-30 2022-02-01 W.R. Grace & Co.-Conn. Catalyst system for the production of polyolefins and method of making and using same
RU2692246C1 (ru) * 2017-06-15 2019-06-24 Индийская Нефтяная Корпорация Лимитэд Внешний донор для полимеризации олефинов
CN109096420B (zh) * 2017-06-21 2021-05-11 中国石油化工股份有限公司 一种用于烯烃聚合的催化剂和烯烃聚合方法
CN109096424A (zh) * 2017-06-21 2018-12-28 中国石油化工股份有限公司 一种用于烯烃聚合的催化剂和烯烃聚合方法
CN109096421A (zh) * 2017-06-21 2018-12-28 中国石油化工股份有限公司 一种用于烯烃聚合的催化剂和烯烃聚合方法
CN109096418A (zh) * 2017-06-21 2018-12-28 中国石油化工股份有限公司 一种用于烯烃聚合的催化剂和烯烃聚合方法
CN109096417A (zh) * 2017-06-21 2018-12-28 中国石油化工股份有限公司 一种用于烯烃聚合的催化剂和烯烃聚合方法
US11613592B2 (en) 2018-02-07 2023-03-28 Reliance Industries Limited Ziegler-Natta catalyst system with self-extinguishing properties suitable for olefin polymerization
CN108409896B (zh) * 2018-04-04 2021-02-05 朴蓝聚烯烃科技发展（上海）有限公司 齐格勒-纳塔催化剂组合物及其应用
US11990859B2 (en) 2018-05-28 2024-05-21 Borealis Ag Devices for a photovoltaic (PV) module
WO2020064190A1 (en) 2018-09-26 2020-04-02 Borealis Ag Propylene copolymer composition with excellent optical and mechanical properties
CN109517099B (zh) * 2018-11-27 2021-07-30 山东鲁晶化工科技有限公司 一种外给电子体、烯烃聚合催化剂体系及其应用
WO2020190681A1 (en) * 2019-03-15 2020-09-24 W.R. Grace & Co.-Conn. Catalyst system for producing olefin polymers with no fines
US20230312782A1 (en) 2020-06-29 2023-10-05 W.R. Grace & Co.-Conn. Phthalate-free polypropylene homopolymer having high stiffness properties
EP4384556A4 (en) * 2021-08-09 2025-07-09 Grace W R & Co METHOD FOR PRODUCING A GRANULAR POLYOLEFIN RESIN HAVING AN INCREASED CONTROLLED APPARENT DENSITY
CN118339199A (zh) * 2021-10-06 2024-07-12 格雷斯公司 用于制备聚丙烯无规共聚物的气相方法
CN116228676A (zh) * 2023-01-09 2023-06-06 上海烟草集团有限责任公司 一种烟草检测用流化床内气体流速的调整方法
WO2025124978A1 (en) * 2023-12-11 2025-06-19 Sabic Global Technologies B.V. Self-extinguishing catalyst system for propylene polymerization

Family Cites Families (71)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1209255B (it) * 1980-08-13 1989-07-16 Montedison Spa Catalizzatori per la polimerizzazione di olefine.
DE3247919A1 (de) * 1982-12-24 1984-06-28 Basf Ag, 6700 Ludwigshafen Verfahren zum herstellen von homo- und copolymerisaten von (alpha)-monoolefinen mittels einer ziegler-natta-katalysatorsystems
US4746762A (en) 1985-01-17 1988-05-24 Mobil Oil Corporation Upgrading light olefins in a turbulent fluidized catalyst bed reactor
IN168393B (enExample) 1986-02-28 1991-03-23 Shell Oil Co
EP0284005B1 (en) * 1987-03-23 1991-12-18 Idemitsu Petrochemical Co. Ltd. Method of production of polyolefins
JPH0796573B2 (ja) 1987-03-31 1995-10-18 出光石油化学株式会社 プロピレン重合体の製造方法
US5093415A (en) 1987-05-19 1992-03-03 Union Carbide Chemicals & Plastics Technology Corporation Process for producing stereoregular polymers having a narrow molecular weight distribution
US4882380A (en) 1987-07-07 1989-11-21 Union Carbide Chemicals And Plastics Company Inc. Process for the production of impact polypropylene copolymers
DE69019046T2 (de) 1989-03-02 1995-09-07 Mitsui Petrochemical Ind Verfahren zur Polymerisation von Olefinen und Katalysator für Olefinpolymerisation.
JPH07119290B2 (ja) 1989-11-28 1995-12-20 出光石油化学株式会社 軟質ポリプロピレンフィルム及びその製造方法
FR2669639A1 (fr) 1990-11-27 1992-05-29 Atochem Cocatalyseur de polymerisation du propylene a base de silane et de monoether.
US5432244A (en) 1990-12-12 1995-07-11 Union Carbide Chemicals & Plastics Technology Corporation Process for the production of polypropylene
US5218052A (en) 1991-02-04 1993-06-08 Amoco Corporation Olefin polymerization and copolymerization process
JP3443848B2 (ja) 1992-11-04 2003-09-08 東ソー株式会社 プロピレンブロック共重合体の製造方法
TW300235B (enExample) * 1992-12-04 1997-03-11 Mitsui Petroleum Chemicals Ind
GB9300318D0 (en) 1993-01-08 1993-03-03 Oxford Analytical Instr Ltd Improvements relating to sample monitoring
US5462999A (en) * 1993-04-26 1995-10-31 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
TW354792B (en) 1993-08-13 1999-03-21 Mitsui Petrochemical Ind Olefin polymerization catalyst and process for preparing polypropylene and propylene block copolymer
IT1271420B (it) 1993-08-30 1997-05-28 Himont Inc Composizioni poliolefiniche aventi un elevato bilancio di rigidita' e resilienza
JP3508187B2 (ja) 1993-11-10 2004-03-22 チッソ株式会社 プロピレン・エチレンブロック共重合体の連続製造法
JPH07149812A (ja) 1993-12-02 1995-06-13 Tonen Corp α−オレフィン重合用触媒
US6133385A (en) 1994-04-06 2000-10-17 Fina Technology, Inc. Catalyst systems for improved stereoselectivity and broader molecular weight distribution in polymerization of olefins
JPH0812717A (ja) * 1994-07-01 1996-01-16 Mitsubishi Chem Corp プロピレン−エチレン系ブロック共重合体の製造方法
US5529850A (en) 1994-07-05 1996-06-25 Montell North America Inc. Fibers produced from crystalline propylene polymers having high melt flow rate values and a narrow molecular weight distribution
JP3354729B2 (ja) * 1994-11-28 2002-12-09 サンアロマー株式会社 オレフィン重合用触媒およびオレフィン重合体の製造方法
IL117114A (en) 1995-02-21 2000-02-17 Montell North America Inc Components and catalysts for the polymerization ofolefins
IT1275573B (it) 1995-07-20 1997-08-07 Spherilene Spa Processo ed apparecchiatura per la pomimerizzazione in fase gas delle alfa-olefine
CN1119364C (zh) 1995-08-31 2003-08-27 智索公司 丙烯－乙烯共聚物组合物及其制备方法
US6087459A (en) 1998-05-14 2000-07-11 Exxon Chemical Patents Inc. Polymeric materials formed using blends of electron donors
WO1999058585A1 (en) 1998-05-14 1999-11-18 Exxon Chemical Patents Inc. Polymeric materials formed using blends of electron donors
US6576697B1 (en) 1998-09-02 2003-06-10 Thayer A. Brown, Jr. Malleable high density polymer material
JP3182130B2 (ja) 1999-01-25 2001-07-03 出光石油化学株式会社 オレフィン重合体の製造方法
ES2267504T3 (es) 1999-03-15 2007-03-16 Basell Poliolefine Italia S.R.L. Componentes y catalizadores para la polimerizacion de olefinas.
WO2000063261A1 (en) * 1999-04-15 2000-10-26 Basell Technology Company B.V. Components and catalysts for the polymerization of olefins
AU6512100A (en) 1999-08-03 2001-02-19 Union Carbide Chemicals & Plastics Technology Corporation Method of detecting and correcting local defluidization and channeling in fluidized-bed reactors for polymerization
US6391985B1 (en) 1999-10-21 2002-05-21 Union Carbide Chemicals & Plastics Technology Corporation High condensing mode polyolefin production under turbulent conditions in a fluidized bed
ES2214070T5 (es) 1999-11-12 2010-09-06 Borealis Technology Oy Copolimeros heterofasicos.
US6815512B2 (en) 2000-02-28 2004-11-09 Union Carbide Chemicals & Plastics Technology Corporation Polyolefin production using condensing mode in fluidized beds, with liquid phase enrichment and bed injection
US6460412B1 (en) 2000-10-27 2002-10-08 Union Carbide Chemicals & Plastics Technology Corporation Detection of dynamic fluidized bed level in a fluidized bed polymerization reactor using ultrasonic waves or microwaves
US6825146B2 (en) 2001-05-29 2004-11-30 Union Carbide Chemicals & Plastics Technology Corporation Olefin polymerization catalyst compositions and method of preparation
EP1444276A1 (en) 2001-11-06 2004-08-11 Dow Global Technologies, Inc. Isotactic propylene copolymers, their preparation and use
US6906160B2 (en) 2001-11-06 2005-06-14 Dow Global Technologies Inc. Isotactic propylene copolymer fibers, their preparation and use
AU2002358255A1 (en) 2002-01-03 2003-07-30 Bp Corporation North America Inc. Gas phase olefin polymerizations using dual donor catalyst systems
CN1169845C (zh) 2002-02-07 2004-10-06 中国石油化工股份有限公司 用于烯烃聚合的固体催化剂组分和含该催化剂组分的催化剂及其应用
EP1515996A2 (en) * 2002-06-14 2005-03-23 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition and polymerization process using mixtures of electron donors
BRPI0313639B1 (pt) 2002-08-19 2016-03-15 Toho Titanium Co Ltd constituinte de catalisador, seu catalisador para polimerização ou copolimerização de alfa-olefina, método para polimerizar alfa-olefina, e método para produzir copolímeros em blocos ou aleatórios da alfa-olefina
US6753390B2 (en) 2002-09-04 2004-06-22 Univation Technologies, Llc Gas phase polymerization process
US6818711B2 (en) 2003-01-01 2004-11-16 Fina Technology, Inc. Polymerization of olefins using a ziegler-natta catalyst system having an external electron donor
US6759489B1 (en) 2003-05-20 2004-07-06 Eastern Petrochemical Co. Fluidized bed methods for making polymers
RU2345094C2 (ru) 2003-09-23 2009-01-27 Дау Глобал Текнолоджиз Инк. Композиция катализатора с самоограничением реакции, включающая внутренний донор в виде сложного эфира дикарбоновой кислоты, и способ полимеризации пропилена
KR101146472B1 (ko) 2003-09-23 2012-05-21 유니온 카바이드 케미칼즈 앤드 플라스틱스 테크날러지 엘엘씨 모노카르복실산 에스테르 내부 공여체를 갖는 자가-소멸촉매 조성물 및 프로필렌 중합 방법
KR101114748B1 (ko) * 2003-09-23 2012-03-05 다우 글로벌 테크놀로지스 엘엘씨 자가 제한 촉매 조성물 및 프로필렌 중합 방법
EP1548054B1 (en) 2003-12-26 2016-03-23 Japan Polypropylene Corporation Polypropylene-based resin composition and molded article thereof
JP3953466B2 (ja) 2004-02-23 2007-08-08 日本ポリプロ株式会社 ポリプロピレン系樹脂組成物及びその成形体
JP2005232395A (ja) * 2004-02-23 2005-09-02 Toho Catalyst Co Ltd オレフィン類重合用触媒およびこれを用いたオレフィン類重合体の製造方法
WO2005103094A1 (en) 2004-04-07 2005-11-03 Union Carbide Chemicals & Plastics Technology Corporation Olefin polymerization procatalyst compositions and method of preparation
US7226977B2 (en) 2004-04-19 2007-06-05 Sunoco, Inc. ( R&M) High melt flow rate thermoplastic polyolefins produced in-reactor
US20070224641A1 (en) 2004-06-16 2007-09-27 Campbell Richard E Apparatus and method for ziegler-natta research
EP1827673B1 (en) 2004-12-20 2012-02-01 Basell Poliolefine Italia S.r.l. Process and apparatus for the polymerization of propylene
WO2007035885A2 (en) 2005-09-20 2007-03-29 Emerge Medsystems, Llc Embolic filter device and related systems and methods
JP2007254671A (ja) 2006-03-24 2007-10-04 Japan Polypropylene Corp ポリプロピレンの製造方法
CN102351966B (zh) 2006-02-03 2014-04-09 日本聚丙烯公司 丙烯类聚合物及其制备方法、丙烯类聚合物组合物以及由该组合物制成的成型制品
US20070270558A1 (en) * 2006-05-16 2007-11-22 Paul Keith Scherrer Pulsing olefin polymerization fluidized-bed reactors
MX2008015361A (es) 2006-06-01 2008-12-16 Sunoco Inc R&M Polipropileno de alta cristalinidad de indice de flujo de fusion alto.
EP1935938A1 (en) 2006-12-18 2008-06-25 Borealis Technology Oy Improved high melt flow heterophasic polypropylene copolymers
KR101716609B1 (ko) 2007-08-24 2017-03-14 더블유.알. 그레이스 앤드 캄파니-콘. 조절된 알루미늄 대 ｓｃａ 비를 갖는 자기-제한성 촉매 시스템 및 방법
BRPI0912920B1 (pt) 2008-08-21 2019-07-09 W. R. Grace & Co. -Conn Processo de polimerização e copolímero de impacto de propileno
KR101510775B1 (ko) 2008-11-24 2015-04-10 삼성전자주식회사 동기식 펄스 플라즈마 에칭 장비
US8507717B2 (en) 2008-12-31 2013-08-13 Dow Global Technologies Llc Production of substituted phenylene aromatic diesters
CN102325808B (zh) * 2008-12-31 2014-03-12 陶氏环球技术有限责任公司 包含取代的1,2-亚苯基芳族二酯内给体的前催化剂组合物及方法
KR101906621B1 (ko) * 2010-12-21 2018-10-10 더블유.알. 그레이스 앤드 캄파니-콘. 고 용융 유동 프로필렌-기재 중합체의 생산 공정 및 이로부터의 생산물

Also Published As

Publication number Publication date
US10926234B2 (en) 2021-02-23
CN103467630A (zh) 2013-12-25
EP2185609A2 (en) 2010-05-19
PL2185609T3 (pl) 2021-06-14
CN101835812B (zh) 2013-10-02
KR101576308B1 (ko) 2015-12-09
MX351199B (es) 2017-10-05
RU2010111113A (ru) 2011-09-27
MX347799B (es) 2017-05-15
EP2185609B1 (en) 2021-01-27
US8324327B2 (en) 2012-12-04
EP2185599A1 (en) 2010-05-19
CN101848946A (zh) 2010-09-29
US10647788B2 (en) 2020-05-12
US20110152067A1 (en) 2011-06-23
EP2185599B1 (en) 2018-12-26
WO2009029487A1 (en) 2009-03-05
KR20100061502A (ko) 2010-06-07
JP2010537005A (ja) 2010-12-02
BRPI0815290A2 (pt) 2019-09-24
ES2711342T3 (es) 2019-05-03
PL2185599T3 (pl) 2019-07-31
JP5576281B2 (ja) 2014-08-20
RU2470947C2 (ru) 2012-12-27
WO2009029486A2 (en) 2009-03-05
WO2009029487A4 (en) 2009-06-04
CN101835812A (zh) 2010-09-15
CN103467630B (zh) 2016-08-10
BRPI0815326B1 (pt) 2019-10-08
CN101848946B (zh) 2013-06-12
WO2009029486A4 (en) 2009-11-05
KR20150140854A (ko) 2015-12-16
US20190247818A1 (en) 2019-08-15
US20110172377A1 (en) 2011-07-14
BRPI0815326A2 (pt) 2015-02-10
RU2010111142A (ru) 2011-09-27
MX2010002118A (es) 2010-08-09
WO2009029486A3 (en) 2009-08-20

Similar Documents

Publication Publication Date Title
KR101716609B1 (ko) 조절된 알루미늄 대 ｓｃａ 비를 갖는 자기-제한성 촉매 시스템 및 방법
JP6244389B2 (ja) 高メルトフローレートを有する高剛性のプロピレン系ポリマー
KR101787927B1 (ko) 두자리 내부 공여체를 가진 자기-제한성 촉매 조성물
CN102203140B (zh) 高熔体流动速率的抗冲丙烯共聚物和方法
KR102267271B1 (ko) 프로필렌 충격 공중합체의 제조 및 생성물
JP5248774B2 (ja) ジカルボン酸エステル内部供与体を有する自己制限性触媒組成物及びプロピレン重合方法
JP2015501857A (ja) ポリプロピレンの重合法
JP2007505984A (ja) モノカルボン酸エステル内部供与体を有する自己消滅性触媒組成物及びプロピレン重合方法
KR102243786B1 (ko) 고 공단량체 함량 프로필렌계 중합체의 제조
KR20060099512A (ko) 혼합된 선택성 조절제를 갖는 촉매 조성물 및 프로필렌중합 방법

Legal Events

Date Code Title Description
A107 Divisional application of patent
A201 Request for examination
PA0104 Divisional application for international application

Comment text: Divisional Application for International Patent

Patent event code: PA01041R01D

Patent event date: 20151125

Application number text: 1020107006325

Filing date: 20100323

PA0201 Request for examination
PG1501 Laying open of application
E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

Comment text: Notification of reason for refusal

Patent event date: 20160114

Patent event code: PE09021S01D

E90F Notification of reason for final refusal
PE0902 Notice of grounds for rejection

Comment text: Final Notice of Reason for Refusal

Patent event date: 20160812

Patent event code: PE09021S02D

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

Patent event code: PE07011S01D

Comment text: Decision to Grant Registration

Patent event date: 20170124

GRNT Written decision to grant
PR0701 Registration of establishment

Comment text: Registration of Establishment

Patent event date: 20170308

Patent event code: PR07011E01D

PR1002 Payment of registration fee

Payment date: 20170308

End annual number: 3

Start annual number: 1

PG1601 Publication of registration
FPAY Annual fee payment

Payment date: 20200226

Year of fee payment: 4

PR1001 Payment of annual fee

Payment date: 20200226

Start annual number: 4

End annual number: 4

PR1001 Payment of annual fee

Payment date: 20210225

Start annual number: 5

End annual number: 5

PR1001 Payment of annual fee

Payment date: 20230228

Start annual number: 7

End annual number: 7

PR1001 Payment of annual fee

Payment date: 20240227

Start annual number: 8

End annual number: 8

PR1001 Payment of annual fee

Payment date: 20250305

Start annual number: 9

End annual number: 9