KR100692775B1 - 일사 차폐용 적층 구조체 - Google Patents
일사 차폐용 적층 구조체 Download PDFInfo
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- KR100692775B1 KR100692775B1 KR1020057010175A KR20057010175A KR100692775B1 KR 100692775 B1 KR100692775 B1 KR 100692775B1 KR 1020057010175 A KR1020057010175 A KR 1020057010175A KR 20057010175 A KR20057010175 A KR 20057010175A KR 100692775 B1 KR100692775 B1 KR 100692775B1
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- fine particles
- solar
- resin
- fine
- particles
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Landscapes
- Chemical & Material Sciences (AREA)
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- Joining Of Glass To Other Materials (AREA)
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Abstract
Description
Claims (19)
- 일사 차폐 기능을 갖는 미립자를 포함하는 중간층을 판유리, 플라스틱, 일사 차폐 기능을 갖는 미립자를 포함하는 플라스틱으로부터 선택된 2개의 적층판 사이에 개재시켜 이루어지는 일사 차폐용 적층 구조체에 있어서,상기 일사 차폐 기능을 갖는 미립자가, 일반식 WyOz(단, W는 텅스텐, O는 산소, 2.0<z/y<3.0)로 표기되는 텅스텐 산화물의 미립자, 일반식 MxWyOz(단, M은 H, He, 알칼리 금속, 알칼리 토류 금속, 희토류 원소, Mg, Zr, Cr, Mn, Fe, Ru, Co, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au, Zn, Cd, Al, Ga, In, Tl, Si, Ge, Sn, Pb, Sb, B, F, P, S, Se, Br, Te, Ti, Nb, V, Mo, Ta, Re 중에서 선택되는 1종 이상의 원소, W는 텅스텐, O는 산소, 0.001≤x/y≤1, 2.0<z/y≤3.0)로 표기되는 복합 텅스텐 산화물의 미립자 및 이들의 혼합물로부터 선택되는 미립자로 구성되며,상기 플라스틱이, 폴리카보네이트 수지, 아크릴 수지, 폴리에틸렌테레프탈레이트 수지, PET 수지, 폴리아미드 수지, 염화 비닐 수지, 올레핀 수지, 에폭시 수지, 폴리이미드 수지, 불소 수지 중에서 선택되고,상기 텅스텐 산화물의 미립자, 복합 텅스텐 산화물의 미립자 및 이들의 혼합물로부터 선택된 미립자의 L*a*b* 표색계에서의 분체색에 있어서, L*이 25~80, a*가 -10~10, b*가 -15~15의 범위 내에 있는 것을 특징으로 하는 일사 차폐용 적층 구조체.
- 일사 차폐 기능을 갖는 미립자를 포함하지 않는 중간층을,일사 차폐 기능을 갖는 미립자를 포함하는 플라스틱의 적층판과,판유리, 플라스틱, 일사 차폐 기능을 갖는 미립자를 포함하는 플라스틱으로부터 선택된 적층판과의 사이에 개재시켜 이루어지는 일사 차폐용 적층 구조체에 있어서,일사 차폐 기능을 갖는 미립자가, 일반식 WyOz(단, W는 텅스텐, O는 산소, 2.0<z/y<3.0)로 표기되는 텅스텐 산화물의 미립자, 일반식 MxWyOz(단, M은 H, He, 알칼리 금속, 알칼리 토류 금속, 희토류 원소, Mg, Zr, Cr, Mn, Fe, Ru, Co, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au, Zn, Cd, Al, Ga, In, Tl, Si, Ge, Sn, Pb, Sb, B, F, P, S, Se, Br, Te, Ti, Nb, V, Mo, Ta, Re 중에서 선택되는 1종 이상의 원소, W는 텅스텐, O는 산소, 0.001≤x/y≤1, 2.0<z/y≤3.0)로 표기되는 복합 텅스텐 산화물의 미립자 및 이들의 혼합물로부터 선택되는 미립자로 구성되며,상기 플라스틱이, 폴리카보네이트 수지, 아크릴 수지, 폴리에틸렌테레프탈레이트 수지, PET 수지, 폴리아미드 수지, 염화 비닐 수지, 올레핀 수지, 에폭시 수지, 폴리이미드 수지, 불소 수지 중에서 선택되고,상기 텅스텐 산화물의 미립자, 복합 텅스텐 산화물의 미립자 및 이들의 혼합물로부터 선택된 미립자의 L*a*b* 표색계에서의 분체색에 있어서, L*이 25~80, a*가 -10~10, b*가 -15~15의 범위 내에 있는 것을 특징으로 하는 일사 차폐용 적층 구조체.
- 제1항 또는 제2항에 있어서,상기 일사 차폐 기능을 갖는 미립자의 직경이, 1nm 이상 800nm 이하인 것을 특징으로 하는 일사 차폐용 적층 구조체.
- 삭제
- 제1항 또는 제2항에 있어서,상기 일사 차폐 기능을 갖는 미립자가, 육방정 또는 단사정의 결정 구조를 갖는 복합 텅스텐 산화물의 미립자를 포함하는 것을 특징으로 하는 일사 차폐용 적층 구조체.
- 제1항 또는 제2항에 있어서,상기 일사 차폐 기능을 갖는 미립자로서,상기 텅스텐 산화물의 미립자, 상기 복합 텅스텐 산화물의 미립자 및 이들의 혼합물로부터 선택되는 미립자와,Sb, V, Nb, Ta, W, Zr, F, Zn, Al, Ti, Pb, Ga, Re, Ru, P, Ge, In, Sn, La, Ce, Pr, Nd, Gd, Tb, Dy, Ho, Y, Sm, Eu, Er, Tm, Tb, Lu, Sr, Ca로 이루어지는 군으로부터 선택된 2종 이상의 원소로 이루어지는 산화물의 미립자, 복합 산화물의 미립자, 붕화물의 미립자로부터 선택되는 적어도 1종의 미립자와의 혼합체를 이용하는 것을 특징으로 하는 일사 차폐용 적층 구조체.
- 일사 차폐 기능을 갖는 미립자를 포함하는 중간층을 판유리, 플라스틱, 일사 차폐 기능을 갖는 미립자를 포함하는 플라스틱으로부터 선택된 2개의 적층판 사이에 개재시켜 이루어지는 일사 차폐용 적층 구조체에 있어서,상기 일사 차폐 기능을 갖는 미립자가, 일반식 WyOz(단, W는 텅스텐, O는 산소, 2.0<z/y<3.0)로 표기되는 텅스텐 산화물의 미립자, 일반식 MxWyOz(단, M은 H, He, 알칼리 금속, 알칼리 토류 금속, 희토류 원소, Mg, Zr, Cr, Mn, Fe, Ru, Co, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au, Zn, Cd, Al, Ga, In, Tl, Si, Ge, Sn, Pb, Sb, B, F, P, S, Se, Br, Te, Ti, Nb, V, Mo, Ta, Re 중에서 선택되는 1종 이상의 원소, W는 텅스텐, O는 산소, 0.001≤x/y≤1, 2.0<z/y≤3.0)로 표기되는 복합 텅스텐 산화물의 미립자 및 이들의 혼합물로부터 선택되는 미립자와,Sb, V, Nb, Ta, W, Zr, F, Zn, Al, Ti, Pb, Ga, Re, Ru, P, Ge, In, Sn, La, Ce, Pr, Nd, Gd, Tb, Dy, Ho, Y, Sm, Eu, Er, Tm, Tb, Lu, Sr, Ca로 이루어지는 군으로부터 선택된 2종 이상의 원소로 이루어지는 산화물의 미립자, 복합 산화물의 미립자, 붕화물의 미립자로부터 선택되는 적어도 1종의 미립자와의 혼합체를 이용하고,상기 플라스틱이, 폴리카보네이트 수지, 아크릴 수지, 폴리에틸렌테레프탈레이트 수지, PET 수지, 폴리아미드 수지, 염화 비닐 수지, 올레핀 수지, 에폭시 수지, 폴리이미드 수지, 불소 수지 중에서 선택되며,상기 텅스텐 산화물의 미립자, 복합 텅스텐 산화물의 미립자 및 이들의 혼합물로부터 선택되는 미립자와,상기 Sb, V, Nb, Ta, W, Zr, F, Zn, Al, Ti, Pb, Ga, Re, Ru, P, Ge, In, Sn, La, Ce, Pr, Nd, Gd, Tb, Dy, Ho, Y, Sm, Eu, Er, Tm, Tb, Lu, Sr, Ca로 이루어지는 군으로부터 선택된 2종 이상의 원소로 이루어지는 산화물의 미립자, 복합 산화물의 미립자, 붕화물의 미립자로부터 선택되는 적어도 1종의 미립자와의 혼합 비율이, 중량비로 95:5~5:95의 범위에 있는 것을 특징으로 하는 일사 차폐용 적층 구조체.
- 일사 차폐 기능을 갖는 미립자를 포함하지 않는 중간층을,일사 차폐 기능을 갖는 미립자를 포함하는 플라스틱의 적층판과,판유리, 플라스틱, 일사 차폐 기능을 갖는 미립자를 포함하는 플라스틱으로부터 선택된 적층판과의 사이에 개재시켜 이루어지는 일사 차폐용 적층 구조체에 있어서,상기 일사 차폐 기능을 갖는 미립자가, 일반식 WyOz(단, W는 텅스텐, O는 산소, 2.0<z/y<3.0)로 표기되는 텅스텐 산화물의 미립자, 일반식 MxWyOz(단, M은 H, He, 알칼리 금속, 알칼리 토류 금속, 희토류 원소, Mg, Zr, Cr, Mn, Fe, Ru, Co, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au, Zn, Cd, Al, Ga, In, Tl, Si, Ge, Sn, Pb, Sb, B, F, P, S, Se, Br, Te, Ti, Nb, V, Mo, Ta, Re 중에서 선택되는 1종 이상의 원소, W는 텅스텐, O는 산소, 0.001≤x/y≤1, 2.0<z/y≤3.0)로 표기되는 복합 텅스텐 산화물의 미립자 및 이들의 혼합물로부터 선택되는 미립자와,Sb, V, Nb, Ta, W, Zr, F, Zn, Al, Ti, Pb, Ga, Re, Ru, P, Ge, In, Sn, La, Ce, Pr, Nd, Gd, Tb, Dy, Ho, Y, Sm, Eu, Er, Tm, Tb, Lu, Sr, Ca로 이루어지는 군으로부터 선택된 2종 이상의 원소로 이루어지는 산화물의 미립자, 복합 산화물의 미립자, 붕화물의 미립자로부터 선택되는 적어도 1종의 미립자와의 혼합체를 이용하고,상기 플라스틱이, 폴리카보네이트 수지, 아크릴 수지, 폴리에틸렌테레프탈레이트 수지, PET 수지, 폴리아미드 수지, 염화 비닐 수지, 올레핀 수지, 에폭시 수지, 폴리이미드 수지, 불소 수지 중에서 선택되며,상기 텅스텐 산화물의 미립자, 복합 텅스텐 산화물의 미립자 및 이들의 혼합물로부터 선택되는 미립자와,상기 Sb, V, Nb, Ta, W, Zr, F, Zn, Al, Ti, Pb, Ga, Re, Ru, P, Ge, In, Sn, La, Ce, Pr, Nd, Gd, Tb, Dy, Ho, Y, Sm, Eu, Er, Tm, Tb, Lu, Sr, Ca로 이루어지는 군으로부터 선택된 2종 이상의 원소로 이루어지는 산화물의 미립자, 복합 산화물의 미립자, 붕화물의 미립자로부터 선택되는 적어도 1종의 미립자와의 혼합 비율이, 중량비로 95:5~5:95의 범위에 있는 것을 특징으로 하는 일사 차폐용 적층 구조체.
- 제1항, 제2항, 제7항 및 제8항 중 어느 한 항에 있어서,상기 플라스틱이, 폴리카보네이트 수지 또는 아크릴 수지 또는 폴리에틸렌테레프탈레이트 수지의 시트 또는 필름인 것을 특징으로 하는 일사 차폐용 적층 구조체.
- 일사 차폐 기능을 갖는 미립자를 포함하는 중간층을 판유리, 플라스틱, 일사 차폐 기능을 갖는 미립자를 포함하는 플라스틱으로부터 선택된 2개의 적층판 사이에 개재시켜 이루어지는 일사 차폐용 적층 구조체에 있어서,상기 일사 차폐 기능을 갖는 미립자가, 일반식 WyOz(단, W는 텅스텐, O는 산소, 2.0<z/y<3.0)로 표기되는 텅스텐 산화물의 미립자, 일반식 MxWyOz(단, M은 H, He, 알칼리 금속, 알칼리 토류 금속, 희토류 원소, Mg, Zr, Cr, Mn, Fe, Ru, Co, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au, Zn, Cd, Al, Ga, In, Tl, Si, Ge, Sn, Pb, Sb, B, F, P, S, Se, Br, Te, Ti, Nb, V, Mo, Ta, Re 중에서 선택되는 1종 이상의 원소, W는 텅스텐, O는 산소, 0.001≤x/y≤1, 2.0<z/y≤3.0)로 표기되는 복합 텅스텐 산화물의 미립자 및 이들의 혼합물로부터 선택되는 미립자로 구성되며,상기 플라스틱이, 폴리카보네이트 수지, 아크릴 수지, 폴리에틸렌테레프탈레이트 수지, PET 수지, 폴리아미드 수지, 염화 비닐 수지, 올레핀 수지, 에폭시 수지, 폴리이미드 수지, 불소 수지 중에서 선택되고,상기 중간층은, 중간막을 갖고, 상기 중간막 중에 상기 일사 차폐 기능을 갖는 미립자가 분산되어 있는 것을 특징으로 하는 일사 차폐용 적층 구조체.
- 일사 차폐 기능을 갖는 미립자를 포함하는 중간층을 판유리, 플라스틱, 일사 차폐 기능을 갖는 미립자를 포함하는 플라스틱으로부터 선택된 2개의 적층판 사이에 개재시켜 이루어지는 일사 차폐용 적층 구조체에 있어서,상기 일사 차폐 기능을 갖는 미립자가, 일반식 WyOz(단, W는 텅스텐, O는 산소, 2.0<z/y<3.0)로 표기되는 텅스텐 산화물의 미립자, 일반식 MxWyOz(단, M은 H, He, 알칼리 금속, 알칼리 토류 금속, 희토류 원소, Mg, Zr, Cr, Mn, Fe, Ru, Co, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au, Zn, Cd, Al, Ga, In, Tl, Si, Ge, Sn, Pb, Sb, B, F, P, S, Se, Br, Te, Ti, Nb, V, Mo, Ta, Re 중에서 선택되는 1종 이상의 원소, W는 텅스텐, O는 산소, 0.001≤x/y≤1, 2.0<z/y≤3.0)로 표기되는 복합 텅스텐 산화물의 미립자 및 이들의 혼합물로부터 선택되는 미립자와,Sb, V, Nb, Ta, W, Zr, F, Zn, Al, Ti, Pb, Ga, Re, Ru, P, Ge, In, Sn, La, Ce, Pr, Nd, Gd, Tb, Dy, Ho, Y, Sm, Eu, Er, Tm, Tb, Lu, Sr, Ca로 이루어지는 군으로부터 선택된 2종 이상의 원소로 이루어지는 산화물의 미립자, 복합 산화물의 미립자, 붕화물의 미립자로부터 선택되는 적어도 1종의 미립자와의 혼합체를 이용하고,상기 플라스틱이, 폴리카보네이트 수지, 아크릴 수지, 폴리에틸렌테레프탈레이트 수지, PET 수지, 폴리아미드 수지, 염화 비닐 수지, 올레핀 수지, 에폭시 수지, 폴리이미드 수지, 불소 수지 중에서 선택되며,상기 텅스텐 산화물의 미립자, 복합 텅스텐 산화물의 미립자 및 이들의 혼합물로부터 선택되는 미립자와,상기 Sb, V, Nb, Ta, W, Zr, F, Zn, Al, Ti, Pb, Ga, Re, Ru, P, Ge, In, Sn, La, Ce, Pr, Nd, Gd, Tb, Dy, Ho, Y, Sm, Eu, Er, Tm, Tb, Lu, Sr, Ca로 이루어지는 군으로부터 선택된 2종 이상의 원소로 이루어지는 산화물의 미립자, 복합 산화물의 미립자, 붕화물의 미립자로부터 선택되는 적어도 1종의 미립자와의 혼합 비율이, 중량비로 95:5~5:95의 범위이고,상기 중간층은, 중간막을 갖고, 상기 중간막 중에 상기 일사 차폐 기능을 갖는 미립자가 분산되어 있는 것을 특징으로 하는 일사 차폐용 적층 구조체.
- 일사 차폐 기능을 갖는 미립자를 포함하지 않는 중간층을,일사 차폐 기능을 갖는 미립자를 포함하는 플라스틱의 적층판과,판유리, 플라스틱, 일사 차폐 기능을 갖는 미립자를 포함하는 플라스틱으로부터 선택된 적층판과의 사이에 개재시켜 이루어지는 일사 차폐용 적층 구조체에 있어서,상기 일사 차폐 기능을 갖는 미립자가, 일반식 WyOz(단, W는 텅스텐, O는 산소, 2.0<z/y<3.0)로 표기되는 텅스텐 산화물의 미립자, 일반식 MxWyOz(단, M은 H, He, 알칼리 금속, 알칼리 토류 금속, 희토류 원소, Mg, Zr, Cr, Mn, Fe, Ru, Co, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au, Zn, Cd, Al, Ga, In, Tl, Si, Ge, Sn, Pb, Sb, B, F, P, S, Se, Br, Te, Ti, Nb, V, Mo, Ta, Re 중에서 선택되는 1종 이상의 원소, W는 텅스텐, O는 산소, 0.001≤x/y≤1, 2.0<z/y≤3.0)로 표기되는 복합 텅스텐 산화물의 미립자 및 이들의 혼합물로부터 선택되는 미립자와,Sb, V, Nb, Ta, W, Zr, F, Zn, Al, Ti, Pb, Ga, Re, Ru, P, Ge, In, Sn, La, Ce, Pr, Nd, Gd, Tb, Dy, Ho, Y, Sm, Eu, Er, Tm, Tb, Lu, Sr, Ca로 이루어지는 군으로부터 선택된 2종 이상의 원소로 이루어지는 산화물의 미립자, 복합 산화물의 미립자, 붕화물의 미립자로부터 선택되는 적어도 1종의 미립자와의 혼합체를 이용하고,상기 플라스틱이, 폴리카보네이트 수지, 아크릴 수지, 폴리에틸렌테레프탈레이트 수지, PET 수지, 폴리아미드 수지, 염화 비닐 수지, 올레핀 수지, 에폭시 수지, 폴리이미드 수지, 불소 수지 중에서 선택되며,상기 텅스텐 산화물의 미립자, 복합 텅스텐 산화물의 미립자 및 이들의 혼합물로부터 선택되는 미립자와,상기 Sb, V, Nb, Ta, W, Zr, F, Zn, Al, Ti, Pb, Ga, Re, Ru, P, Ge, In, Sn, La, Ce, Pr, Nd, Gd, Tb, Dy, Ho, Y, Sm, Eu, Er, Tm, Tb, Lu, Sr, Ca로 이루어지는 군으로부터 선택된 2종 이상의 원소로 이루어지는 산화물의 미립자, 복합 산화물의 미립자, 붕화물의 미립자로부터 선택되는 적어도 1종의 미립자와의 혼합 비율이, 중량비로 95:5~5:95의 범위이고,상기 중간층은, 중간막을 갖고, 상기 중간막 중에 상기 일사 차폐 기능을 갖는 미립자가 분산되어 있는 것을 특징으로 하는 일사 차폐용 적층 구조체.
- 제1항, 제7항 및 제8항 중 어느 한 항에 있어서,상기 중간층은, 2층 이상 적층된 중간막을 갖고, 상기 중간막의 적어도 1층에 상기 일사 차폐 기능을 갖는 미립자가 분산되어 있는 것을 특징으로 하는 일사 차폐용 적층 구조체.
- 제1항, 제7항 및 제8항 중 어느 한 항에 있어서,상기 중간층은, 상기 판유리, 플라스틱으로부터 선택된 2개의 적층판의 적어도 한쪽의 내측의 면에 형성된 상기 일사 차폐 기능을 갖는 미립자가 포함되는 일사 차폐층과, 상기 일사 차폐층에 겹치어지는 중간막을 갖는 것을 특징으로 하는 일사 차폐용 적층 구조체.
- 제1항, 제7항 및 제8항 중 어느 한 항에 있어서,상기 중간층은, 상기 일사 차폐 기능을 갖는 미립자가 포함되는 일사 차폐층이 연성의 수지 필름 기판의 편면상 또는 내부에 형성된 일사 차폐 연성의 필름기판이 2층 이상 적층된 중간막의 사이에 적층되는 것을 특징으로 하는 일사 차폐용 적층 구조체.
- 제1항, 제7항 및 제8항 중 어느 한 항에 있어서,상기 중간층은,중간막 또는 2층 이상 적층된 중간막과,접착제층, 상기 일사 차폐 기능을 갖는 미립자가 포함되는 일사 차폐층, 박리층의 순서로 적층된 적층체를 갖고,상기 적층체의 접착제층은, 상기 판유리, 플라스틱으로부터 선택된 한쪽의 적층판의 내측의 면에 접착되고,상기 적층체의 박리층은, 상기 중간막 또는 2층 이상 적층된 중간막과 접착하는 것을 특징으로 하는 일사 차폐용 적층 구조체.
- 제2항, 제7항 및 제8항 중 어느 한 항에 있어서,상기 중간층은, 일사 차폐 기능을 갖는 미립자를 포함하지 않는 중간막 또는 2층 이상 적층된 일사 차폐 기능을 갖는 미립자를 포함하지 않는 중간막을 갖는 것을 특징으로 하는 일사 차폐용 적층 구조체.
- 제10항, 제11항 및 제12항 중 어느 한 항에 있어서,상기 중간막은 폴리비닐아세탈, 폴리염화비닐, 염화비닐에틸렌 공중합체, 염화비닐에틸렌-글리시딜메타크릴레이트 공중합체, 염화비닐에틸렌-글리시딜아크릴레이트 공중합체, 염화비닐글리시딜메타크릴레이트 공중합체, 염화비닐글리시딜아크릴레이트 공중합체, 폴리염화비닐리덴, 염화비닐리덴아크릴로니트릴 공중합체, 폴리초산비닐에틸렌-초산비닐 공중합체, 에틸렌-초산비닐 공중합체, 폴리비닐아세탈-폴리비닐부티랄 혼합물 중에서 선택된 수지로 구성되는 것을 특징으로 하는 일사 차폐용 적층 구조체.
- 제18항에 있어서,상기 중간층은 폴리비닐부티랄 및 에틸렌-초산비닐 공중합체로 이루어진 군으로부터 선택된 비닐계 수지로 구성되는 것을 특징으로 하는 일사 차폐용 적층 구조체.
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JP3985193B2 (ja) | 2007-10-03 |
BRPI0406534A (pt) | 2005-12-13 |
TW200531949A (en) | 2005-10-01 |
BRPI0406534B1 (pt) | 2016-04-05 |
WO2005087680A1 (ja) | 2005-09-22 |
US7655301B2 (en) | 2010-02-02 |
DE602004014768D1 (de) | 2008-08-14 |
EP1640348A4 (en) | 2007-08-01 |
AU2004317197A1 (en) | 2005-09-22 |
TWI300405B (ko) | 2008-09-01 |
KR20060005995A (ko) | 2006-01-18 |
CN100368331C (zh) | 2008-02-13 |
CN1747908A (zh) | 2006-03-15 |
EP1640348A1 (en) | 2006-03-29 |
US20060008640A1 (en) | 2006-01-12 |
EP1640348B1 (en) | 2008-07-02 |
JPWO2005087680A1 (ja) | 2007-08-09 |
AU2004317197B2 (en) | 2010-09-09 |
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