KR100611269B1 - 시클로알칸의 직접 산화 - Google Patents

시클로알칸의 직접 산화 Download PDF

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Publication number
KR100611269B1
KR100611269B1 KR1020007008613A KR20007008613A KR100611269B1 KR 100611269 B1 KR100611269 B1 KR 100611269B1 KR 1020007008613 A KR1020007008613 A KR 1020007008613A KR 20007008613 A KR20007008613 A KR 20007008613A KR 100611269 B1 KR100611269 B1 KR 100611269B1
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South Korea
Prior art keywords
catalyst
gold
sol
solution
component
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Expired - Fee Related
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KR1020007008613A
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English (en)
Korean (ko)
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KR20010040729A (ko
Inventor
조우 더글라스 드룰리너
노만 헤론
코스탄티노스 쿠어타키스
Original Assignee
이 아이 듀폰 디 네모아 앤드 캄파니
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020007008613A 1998-02-10 1999-02-09 시클로알칸의 직접 산화 Expired - Fee Related KR100611269B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US7425998P 1998-02-10 1998-02-10
US60/074,259 1998-02-10
US09/245,754 US6160183A (en) 1998-02-10 1999-02-05 Direct oxidation of cycloalkanes
US09/245,754 1999-02-05

Publications (2)

Publication Number Publication Date
KR20010040729A KR20010040729A (ko) 2001-05-15
KR100611269B1 true KR100611269B1 (ko) 2006-08-10

Family

ID=26755431

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020007008613A Expired - Fee Related KR100611269B1 (ko) 1998-02-10 1999-02-09 시클로알칸의 직접 산화

Country Status (12)

Country Link
US (1) US6160183A (https=)
EP (1) EP1054854B1 (https=)
JP (1) JP2003524579A (https=)
KR (1) KR100611269B1 (https=)
CN (1) CN1295547A (https=)
BR (1) BR9908036A (https=)
CA (1) CA2318788A1 (https=)
DE (1) DE69907146T2 (https=)
PL (1) PL342319A1 (https=)
SK (1) SK283854B6 (https=)
TW (1) TW470738B (https=)
WO (1) WO1999040055A1 (https=)

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FR2802526B1 (fr) * 1999-12-17 2003-04-18 Rhodia Polyamide Intermediates Procede de preparation de melanges alcools/cetones
JP4580546B2 (ja) * 2000-12-22 2010-11-17 丸善石油化学株式会社 ２−ブタノン及び２−ブタノールの製造方法
TWI329630B (en) * 2002-04-03 2010-09-01 Sumitomo Chemical Co Method for oxidizing cycloalkane compound
US7081552B2 (en) * 2004-08-17 2006-07-25 Solutia Inc. Catalysts for cycloalkanes oxidation and decomposition of cycloalkyl hydroperoxide
JP4635571B2 (ja) * 2004-11-09 2011-02-23 住友化学株式会社 脂肪族環式炭化水素類の酸化反応に用いる触媒及びそれを用いる酸化方法
CN1305829C (zh) * 2004-11-12 2007-03-21 中国科学院兰州化学物理研究所 环己烷选择氧化制环己酮的方法
JP4765371B2 (ja) * 2005-03-30 2011-09-07 住友化学株式会社 シクロヘキサノール及び／又はシクロヘキサノンの製造方法
US7358401B2 (en) 2005-03-31 2008-04-15 Sumitomo Chemical Company, Limited Method for manufacturing cycloalkanol and/or cycloalkanone
JP2007223992A (ja) * 2006-02-27 2007-09-06 Sumitomo Chemical Co Ltd シクロアルカノール及び／又はシクロアルカノンの製造方法
CN100364663C (zh) * 2006-04-07 2008-01-30 浙江大学 负载型纳米金催化剂及制备方法
CN100435944C (zh) * 2007-03-13 2008-11-26 浙江大学 一种负载型纳米金催化剂及制备方法
JP5176426B2 (ja) * 2007-03-16 2013-04-03 住友化学株式会社 シクロアルカノール及び／又はシクロアルカノンの製造方法
JP2009035519A (ja) 2007-08-03 2009-02-19 Sumitomo Chemical Co Ltd シクロアルカノール及び／又はシクロアルカノンの製造方法
JP5136017B2 (ja) 2007-11-21 2013-02-06 住友化学株式会社 シクロアルカノール及び／又はシクロアルカノンの製造方法
CN101862660B (zh) * 2010-06-04 2012-06-06 浙江大学 一种用于环己烷氧化的纳米金催化剂及其制备方法
GB201201866D0 (en) * 2012-02-03 2012-03-21 Invista Tech Sarl Oxidation reaction-I
CN102701905B (zh) * 2012-05-04 2015-03-18 华东理工大学 一种环己烷选择性氧化制备环己酮和环己醇的方法
ES3035113T3 (en) * 2015-02-27 2025-08-28 Gcp Applied Tech Inc Modifying cementitious compositions using ketone alcohol oil waste
CN109806863A (zh) * 2017-11-20 2019-05-28 中国科学院大连化学物理研究所 金催化剂的制备及其在环己烷氧化脱氢反应中的应用
RU2020128668A (ru) * 2018-01-30 2022-02-28 Басф Се Способ окисления циклоалканов
CN118871410A (zh) * 2022-04-06 2024-10-29 切弗朗菲利浦化学公司 紫外光存在下铬催化的一氧化碳与烃的反应
KR20250070912A (ko) * 2023-11-14 2025-05-21 에스케이이노베이션 주식회사 암모니아 산화 촉매, 촉매 시스템 및 암모니아 산화 촉매의 제조방법

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0709360A1 (en) * 1994-10-28 1996-05-01 AGENCY OF INDUSTRIAL SCIENCE & TECHNOLOGY MINISTRY OF INTERNATIONAL TRADE & INDUSTRY Method for production of alcohol, ketone, and alderhyde by oxidation of hydrocarbon

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US2851496A (en) * 1954-07-27 1958-09-09 Du Pont Preparation of oxidation products of cyclohexane
US3530185A (en) * 1966-08-08 1970-09-22 Du Pont Oxidation process
NL174343C (nl) * 1973-10-09 1984-06-01 Stamicarbon Werkwijze voor het bereiden van cycloalkanonen en cycloalkanolen door omzetting van een cycloalkylhydroperoxide.
US4042630A (en) * 1973-10-19 1977-08-16 Stamicarbon B.V. Process for the preparation of cycloalkanones and cycloalkanols
US4326084A (en) * 1979-10-11 1982-04-20 E. I. Du Pont De Nemours And Company Process for producing a mixture containing cyclohexanol and cyclohexanone from cyclohexane
JPH01294646A (ja) * 1987-11-27 1989-11-28 Mitsubishi Kasei Corp シクロヘキサノール及びシクロヘキサノンの製造方法
NL8802592A (nl) * 1988-10-21 1990-05-16 Stamicarbon Werkwijze voor de bereiding van een k/a-mengsel.
NL9100521A (nl) * 1991-03-25 1992-10-16 Stamicarbon Werkwijze voor de bereiding van een alkanon en/of alkanol.
GB9113343D0 (en) * 1991-06-20 1991-08-07 Shell Int Research Catalytic oxidation of hydrocarbons
KR950010785B1 (ko) * 1992-03-13 1995-09-23 재단법인한국화학연구소 시클로헥산올 및 시클로헥산온의 제조방법과 그에 사용되는 촉매
BE1007904A3 (nl) * 1993-12-23 1995-11-14 Dsm Nv Werkwijze voor de bereiding van een alkanol en/of een alkanon.
JPH07309793A (ja) * 1994-03-22 1995-11-28 Mitsubishi Chem Corp 炭化水素類の酸化方法
JP3777437B2 (ja) * 1996-03-21 2006-05-24 独立行政法人産業技術総合研究所 炭化水素の部分酸化方法および部分酸化用触媒
KR100255480B1 (ko) * 1996-03-21 2000-05-01 사또 다께오 탄화수소의 부분산화용촉매 및 탄화수소의 부분산화방법
CN1102923C (zh) * 1997-02-11 2003-03-12 纳幕尔杜邦公司 氢过氧化物的分解方法
JP4000392B2 (ja) * 1997-11-05 2007-10-31 独立行政法人産業技術総合研究所 炭化水素の部分酸化用触媒及び含酸素有機化合物の製法

Patent Citations (1)

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Publication number Priority date Publication date Assignee Title
EP0709360A1 (en) * 1994-10-28 1996-05-01 AGENCY OF INDUSTRIAL SCIENCE & TECHNOLOGY MINISTRY OF INTERNATIONAL TRADE & INDUSTRY Method for production of alcohol, ketone, and alderhyde by oxidation of hydrocarbon

Also Published As

Publication number Publication date
BR9908036A (pt) 2000-11-28
DE69907146T2 (de) 2004-01-29
JP2003524579A (ja) 2003-08-19
EP1054854A1 (en) 2000-11-29
SK11712000A3 (sk) 2001-11-06
KR20010040729A (ko) 2001-05-15
TW470738B (en) 2002-01-01
PL342319A1 (en) 2001-06-04
EP1054854B1 (en) 2003-04-23
US6160183A (en) 2000-12-12
CN1295547A (zh) 2001-05-16
SK283854B6 (sk) 2004-03-02
WO1999040055A1 (en) 1999-08-12
DE69907146D1 (de) 2003-05-28
CA2318788A1 (en) 1999-08-12

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