BR9908036A - Processo aperfeiçoado para oxidar cicloalcano - Google Patents

Processo aperfeiçoado para oxidar cicloalcano

Info

Publication number
BR9908036A
BR9908036A BR9908036-2A BR9908036A BR9908036A BR 9908036 A BR9908036 A BR 9908036A BR 9908036 A BR9908036 A BR 9908036A BR 9908036 A BR9908036 A BR 9908036A
Authority
BR
Brazil
Prior art keywords
catalysts
sol
relates
combinations
cycloalkane
Prior art date
Application number
BR9908036-2A
Other languages
English (en)
Inventor
Joe Douglas Druliner
Norman Herron
Kostantinos Kourtakis
Original Assignee
Du Pont
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Du Pont filed Critical Du Pont
Publication of BR9908036A publication Critical patent/BR9908036A/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

<B>"PROCESSO APERFEIçOADO PARA OXIDAR CICLOALCANOS"<D> A invenção refere-se a um processo catalítico para oxidar cicloalcanos diretamente de modo a formar, em uma única etapa, uma mistura contendo álcool e a cetona correspondentes. Particularmente, a invenção refere-se à oxidação de um cicloalcano mediante o seu contato com uma fonte de oxigênio e uma quantidade catalítica de um catalisador heterogêneo. Os catalisadores da invenção incluem o ouro (inclusive os compostos de sol-gel de ouro) e os compostos de sol-gel contendo combinações particulares de Cr, Co, Zr, Ta, Si, Mg, Nb, Al e Ti, sendo que determinados desses metais foram combinados com um óxido, tal como uma matriz inorgânica de hidróxidos ou óxidos, ou as suas combinações. Os catalisadores também podem ser opcionalmente suportados em um membro de suporte apropriado.
BR9908036-2A 1998-02-10 1999-02-09 Processo aperfeiçoado para oxidar cicloalcano BR9908036A (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US7425998P 1998-02-10 1998-02-10
US09/245,754 US6160183A (en) 1998-02-10 1999-02-05 Direct oxidation of cycloalkanes
PCT/US1999/002477 WO1999040055A1 (en) 1998-02-10 1999-02-09 Direct oxidation of cycloalkanes

Publications (1)

Publication Number Publication Date
BR9908036A true BR9908036A (pt) 2000-11-28

Family

ID=26755431

Family Applications (1)

Application Number Title Priority Date Filing Date
BR9908036-2A BR9908036A (pt) 1998-02-10 1999-02-09 Processo aperfeiçoado para oxidar cicloalcano

Country Status (12)

Country Link
US (1) US6160183A (pt)
EP (1) EP1054854B1 (pt)
JP (1) JP2003524579A (pt)
KR (1) KR100611269B1 (pt)
CN (1) CN1295547A (pt)
BR (1) BR9908036A (pt)
CA (1) CA2318788A1 (pt)
DE (1) DE69907146T2 (pt)
PL (1) PL342319A1 (pt)
SK (1) SK283854B6 (pt)
TW (1) TW470738B (pt)
WO (1) WO1999040055A1 (pt)

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FR2802526B1 (fr) * 1999-12-17 2003-04-18 Rhodia Polyamide Intermediates Procede de preparation de melanges alcools/cetones
JP4580546B2 (ja) * 2000-12-22 2010-11-17 丸善石油化学株式会社 ２−ブタノン及び２−ブタノールの製造方法
TWI329630B (en) * 2002-04-03 2010-09-01 Sumitomo Chemical Co Method for oxidizing cycloalkane compound
US7081552B2 (en) * 2004-08-17 2006-07-25 Solutia Inc. Catalysts for cycloalkanes oxidation and decomposition of cycloalkyl hydroperoxide
JP4635571B2 (ja) * 2004-11-09 2011-02-23 住友化学株式会社 脂肪族環式炭化水素類の酸化反応に用いる触媒及びそれを用いる酸化方法
CN1305829C (zh) * 2004-11-12 2007-03-21 中国科学院兰州化学物理研究所 环己烷选择氧化制环己酮的方法
JP4765371B2 (ja) * 2005-03-30 2011-09-07 住友化学株式会社 シクロヘキサノール及び／又はシクロヘキサノンの製造方法
US7358401B2 (en) 2005-03-31 2008-04-15 Sumitomo Chemical Company, Limited Method for manufacturing cycloalkanol and/or cycloalkanone
JP2007223992A (ja) * 2006-02-27 2007-09-06 Sumitomo Chemical Co Ltd シクロアルカノール及び／又はシクロアルカノンの製造方法
CN100364663C (zh) * 2006-04-07 2008-01-30 浙江大学 负载型纳米金催化剂及制备方法
CN100435944C (zh) * 2007-03-13 2008-11-26 浙江大学 一种负载型纳米金催化剂及制备方法
JP5176426B2 (ja) * 2007-03-16 2013-04-03 住友化学株式会社 シクロアルカノール及び／又はシクロアルカノンの製造方法
JP2009035519A (ja) * 2007-08-03 2009-02-19 Sumitomo Chemical Co Ltd シクロアルカノール及び／又はシクロアルカノンの製造方法
JP5136017B2 (ja) 2007-11-21 2013-02-06 住友化学株式会社 シクロアルカノール及び／又はシクロアルカノンの製造方法
CN101862660B (zh) * 2010-06-04 2012-06-06 浙江大学 一种用于环己烷氧化的纳米金催化剂及其制备方法
GB201201866D0 (en) * 2012-02-03 2012-03-21 Invista Tech Sarl Oxidation reaction-I
CN102701905B (zh) * 2012-05-04 2015-03-18 华东理工大学 一种环己烷选择性氧化制备环己酮和环己醇的方法
CN107531567B (zh) * 2015-02-27 2020-06-09 Gcp应用技术有限公司 使用酮醇油废料改良水泥质组合物
CN109806863A (zh) * 2017-11-20 2019-05-28 中国科学院大连化学物理研究所 金催化剂的制备及其在环己烷氧化脱氢反应中的应用
RU2020128668A (ru) * 2018-01-30 2022-02-28 Басф Се Способ окисления циклоалканов

Family Cites Families (17)

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US2851496A (en) * 1954-07-27 1958-09-09 Du Pont Preparation of oxidation products of cyclohexane
US3530185A (en) * 1966-08-08 1970-09-22 Du Pont Oxidation process
NL174343C (nl) * 1973-10-09 1984-06-01 Stamicarbon Werkwijze voor het bereiden van cycloalkanonen en cycloalkanolen door omzetting van een cycloalkylhydroperoxide.
US4042630A (en) * 1973-10-19 1977-08-16 Stamicarbon B.V. Process for the preparation of cycloalkanones and cycloalkanols
US4326084A (en) * 1979-10-11 1982-04-20 E. I. Du Pont De Nemours And Company Process for producing a mixture containing cyclohexanol and cyclohexanone from cyclohexane
JPH01294646A (ja) * 1987-11-27 1989-11-28 Mitsubishi Kasei Corp シクロヘキサノール及びシクロヘキサノンの製造方法
NL8802592A (nl) * 1988-10-21 1990-05-16 Stamicarbon Werkwijze voor de bereiding van een k/a-mengsel.
NL9100521A (nl) * 1991-03-25 1992-10-16 Stamicarbon Werkwijze voor de bereiding van een alkanon en/of alkanol.
GB9113343D0 (en) * 1991-06-20 1991-08-07 Shell Int Research Catalytic oxidation of hydrocarbons
KR950010785B1 (ko) * 1992-03-13 1995-09-23 재단법인한국화학연구소 시클로헥산올 및 시클로헥산온의 제조방법과 그에 사용되는 촉매
BE1007904A3 (nl) * 1993-12-23 1995-11-14 Dsm Nv Werkwijze voor de bereiding van een alkanol en/of een alkanon.
JPH07309793A (ja) * 1994-03-22 1995-11-28 Mitsubishi Chem Corp 炭化水素類の酸化方法
JP2615432B2 (ja) * 1994-10-28 1997-05-28 工業技術院長 金−酸化チタン含有触媒による炭化水素の部分酸化方法
EP0827779A4 (en) * 1996-03-21 1999-06-30 Agency Ind Science Techn CATALYSTS AND METHOD FOR PARTIAL OXIDATION OF HYDROCARBONS
JP3777437B2 (ja) * 1996-03-21 2006-05-24 独立行政法人産業技術総合研究所 炭化水素の部分酸化方法および部分酸化用触媒
CA2279493A1 (en) * 1997-02-11 1998-08-13 E.I. Du Pont De Nemours And Company Hydroperoxide decomposition process
JP4000392B2 (ja) * 1997-11-05 2007-10-31 独立行政法人産業技術総合研究所 炭化水素の部分酸化用触媒及び含酸素有機化合物の製法

Also Published As

Publication number Publication date
KR100611269B1 (ko) 2006-08-10
CA2318788A1 (en) 1999-08-12
EP1054854A1 (en) 2000-11-29
PL342319A1 (en) 2001-06-04
US6160183A (en) 2000-12-12
SK11712000A3 (sk) 2001-11-06
WO1999040055A1 (en) 1999-08-12
DE69907146D1 (de) 2003-05-28
DE69907146T2 (de) 2004-01-29
JP2003524579A (ja) 2003-08-19
TW470738B (en) 2002-01-01
CN1295547A (zh) 2001-05-16
SK283854B6 (sk) 2004-03-02
EP1054854B1 (en) 2003-04-23
KR20010040729A (ko) 2001-05-15

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Legal Events

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B25A Requested transfer of rights approved

Owner name: INVISTA TECHNOLOGIES S.A.R.L. (US)

Free format text: TRANSFERIDO DE: E.I. DUPONT DE NEMOURS AND COMPANY

B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]

Free format text: REFERENTE A 8A,9A E 10A ANUIDADES.

B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

Free format text: REFERENTE AO DESPACHO PUBLICADO NA RPI 1990 DE 25/02/2009.