BR0011184A - Processo para a hidro-oxidação de olefinas a óxidos de olefinas usando catalisador de ouro oxidado, composição de catalisador e método para preparar uma composição de catalisador - Google Patents

Processo para a hidro-oxidação de olefinas a óxidos de olefinas usando catalisador de ouro oxidado, composição de catalisador e método para preparar uma composição de catalisador

Info

Publication number
BR0011184A
BR0011184A BR0011184-8A BR0011184A BR0011184A BR 0011184 A BR0011184 A BR 0011184A BR 0011184 A BR0011184 A BR 0011184A BR 0011184 A BR0011184 A BR 0011184A
Authority
BR
Brazil
Prior art keywords
catalyst
catalyst composition
olefin
hydro
oxidation
Prior art date
Application number
BR0011184-8A
Other languages
English (en)
Other versions
BR0011184B1 (pt
Inventor
Alex Kuperman
Robert G Bownan
Howard W Clark
George E Hartwell
Brian J Schoeman
Henridk E Tuinstra
Garmt R Meima
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of BR0011184A publication Critical patent/BR0011184A/pt
Publication of BR0011184B1 publication Critical patent/BR0011184B1/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C27/00Processes involving the simultaneous production of more than one class of oxygen-containing compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063Titanium; Oxides or hydroxides thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48Silver or gold
    • B01J23/52Gold
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/89Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/40Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0203Impregnation the impregnation liquid containing organic compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D301/00Preparation of oxiranes
    • C07D301/02Synthesis of the oxirane ring
    • C07D301/03Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D301/00Preparation of oxiranes
    • C07D301/02Synthesis of the oxirane ring
    • C07D301/03Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66Silver or gold
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Epoxy Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

"PROCESSO PARA A HIDRO-OXIDAçãO DE OLEFINAS A óXIDOS DE OLEFINAS USANDO CATALISADOR DE OURO OXIDADO, COMPOSIçãO DE CATALISADOR E MéTODO PARA PREPARAR UMA COMPOSIçãO DE CATALISADOR". A presente invenção refere-se a um processo e um catalisador para a hidro-oxidação de uma olefina tendo três ou mais átomos de carbono, tais como propileno, para formar um óxido de olefina, tal como óxido de propileno. O processo envolve contatar a olefina com oxigênio sob condições de reação na presença de hidrogênio e um catalisador. O catalisador contêm ouro oxidado disperso em um suporte contendo titânio, preferivelmente, um suporte tendo uma pluralidade de ambientes de coordenação de titânio, por exemplo, titânio enxertado sobre um titanossilicato. A seletividade ao óxido de olefina é alta a uma boa conversão de olefina. O catalisador usa hidrogênio eficientemente e exibe uma longa vida útil.
BRPI0011184-8A 1999-04-08 2000-04-07 processo para a hidro-oxidaÇço de olefinas a àxidos de olefinas usando catalisador de ouro oxidado, composiÇço de catalisador e mÉtodo para preparar uma composiÇço de catalisador. BR0011184B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12839499P 1999-04-08 1999-04-08
PCT/US2000/009419 WO2000059632A1 (en) 1999-04-08 2000-04-07 Process for the hydro-oxidation of olefins to olefin oxides using oxidized gold catalyst

Publications (2)

Publication Number Publication Date
BR0011184A true BR0011184A (pt) 2002-03-05
BR0011184B1 BR0011184B1 (pt) 2011-06-14

Family

ID=22435162

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0011184-8A BR0011184B1 (pt) 1999-04-08 2000-04-07 processo para a hidro-oxidaÇço de olefinas a àxidos de olefinas usando catalisador de ouro oxidado, composiÇço de catalisador e mÉtodo para preparar uma composiÇço de catalisador.

Country Status (13)

Country Link
US (1) US6255499B1 (pt)
EP (2) EP1384506A3 (pt)
JP (2) JP4646409B2 (pt)
KR (1) KR100704141B1 (pt)
CN (1) CN1122566C (pt)
AT (1) ATE259258T1 (pt)
AU (1) AU4335100A (pt)
BR (1) BR0011184B1 (pt)
DE (1) DE60008235T2 (pt)
ES (1) ES2211535T3 (pt)
ID (1) ID30342A (pt)
RU (1) RU2234369C2 (pt)
WO (1) WO2000059632A1 (pt)

Families Citing this family (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0917532B1 (en) 1996-07-01 2002-02-13 The Dow Chemical Company Process for the direct oxidation of olefins to olefin oxides
US6562986B2 (en) * 1997-06-30 2003-05-13 Dow Global Technologies, Inc. Process for the direct oxidation of olefins to olefin oxides
KR100565026B1 (ko) 1998-04-15 2006-03-30 다우 글로벌 테크놀로지스 인크. 올레핀을 올레핀 옥사이드로 직접 산화시키는 방법
US6646142B1 (en) 1998-12-16 2003-11-11 Dow Global Technologies Inc. Process for the direct oxidation of olefins to olefin oxides
US6821923B1 (en) * 1999-04-08 2004-11-23 Dow Global Technologies Inc. Method of preparing a catalyst containing gold and titanium
AU770334B2 (en) 1999-12-09 2004-02-19 Dow Global Technologies Inc. Activation and regeneration of a hydro-oxidation catalyst
MY131860A (en) * 2000-06-21 2007-09-28 Shell Int Research Process for preparation of catalyst and use there of
IL137208A0 (en) * 2000-07-06 2001-07-24 Yeda Res & Dev Method for depth profiling of a sample
US6307073B1 (en) 2000-07-25 2001-10-23 Arco Chemical Technology, L.P. Direct epoxidation process using a mixed catalyst system
US6281369B1 (en) 2000-12-07 2001-08-28 Arco Chemical Technology, L.P. Epoxidation catalyst and process
US6310224B1 (en) * 2001-01-19 2001-10-30 Arco Chemical Technology, L.P. Epoxidation catalyst and process
DE10107777A1 (de) 2001-02-16 2002-09-05 Bayer Ag Kontinuierlicher Prozess für die Synthese von nanoskaligen Edelmetallpartikeln
JP4307253B2 (ja) 2001-08-01 2009-08-05 ダウ グローバル テクノロジーズ インコーポレーテッド 水素化−酸化触媒の寿命を増加する方法
DE10137784A1 (de) * 2001-08-02 2003-02-13 Bayer Ag Verfahren zur Herstellung von Alkenoxiden aus Alkenen
DE10137826A1 (de) * 2001-08-02 2003-02-13 Bayer Ag Verfahren zur Herstellung und Isolierung von Alkenoxiden aus Alkenen
DE10201241A1 (de) 2002-01-15 2003-07-24 Bayer Ag Katalysator
ES2741123T3 (es) * 2002-12-02 2020-02-10 Shell Int Research Proceso para preparar un catalizador de epoxidación y proceso para preparar epóxidos
EP1977816B1 (en) 2003-09-26 2011-08-31 3M Innovative Properties Company Nanoscale gold catalysts, activating agents, support media, and related methodologies useful for making such catalyst systems especially when the gold is deposited onto the support media using physical vapor deposition
WO2005102525A1 (en) * 2004-04-01 2005-11-03 Dow Global Technologies Inc. Hydro-oxidation of hydrocarbons using catalyst prepared by microwave heating
US8058202B2 (en) * 2005-01-04 2011-11-15 3M Innovative Properties Company Heterogeneous, composite, carbonaceous catalyst system and methods that use catalytically active gold
CN101098755B (zh) 2005-01-14 2010-06-09 陶氏环球技术公司 钛硅酸盐的回收和活性氧化催化剂的再生
US7837977B2 (en) * 2005-09-13 2010-11-23 Chevron U.S.A. Inc. Preparation of titanosilicate zeolite TS-1
JP5067942B2 (ja) * 2005-09-28 2012-11-07 Jx日鉱日石エネルギー株式会社 触媒及びその製造方法
US8137750B2 (en) 2006-02-15 2012-03-20 3M Innovative Properties Company Catalytically active gold supported on thermally treated nanoporous supports
EP1988994A2 (en) 2006-02-28 2008-11-12 3M Innovative Properties Company Low pressure drop, highly active catalyst systems using catalytically active gold
BRPI0716682A2 (pt) * 2006-11-17 2013-09-24 Dow Global Technologies Inc "composiÇço de catalisador, processo para preparar um àxido de olefina e composiÇço de precursor de catalisador."
WO2008108398A1 (ja) * 2007-03-05 2008-09-12 National Institute Of Advanced Industrial Science And Technology 炭化水素の酸化による含酸素有機化合物の製造方法及びそれに用いる酸化用触媒
RU2458906C2 (ru) * 2007-03-20 2012-08-20 Дау Текнолоджи Инвестментс Ллс Способ гидроформилирования с усовершенствованным контролем над изомерами продуктов
CN101274765B (zh) * 2007-03-30 2011-11-30 中国石油化工股份有限公司 一种含贵金属的微孔钛硅材料及其制备方法
US8183399B2 (en) * 2007-04-05 2012-05-22 Dow Global Technologies Llc Integrated hydro-oxidation process with separation of an olefin oxide product stream
WO2009061623A2 (en) * 2007-11-07 2009-05-14 Dow Global Technologies Inc. Hydro-oxidation process using a catalyst containing gold and a halogen-containing compound
US8236725B2 (en) 2008-01-14 2012-08-07 3M Innovative Properties Company Gold carbon monoxide oxidation catalysts with etched substrate
KR20110030472A (ko) 2008-05-22 2011-03-23 다우 글로벌 테크놀로지스 엘엘씨 실리카 지지체상 금속 백금 촉매 및 그 제조 방법
JP2010159245A (ja) * 2008-09-19 2010-07-22 Sumitomo Chemical Co Ltd 酸化化合物の製造方法
WO2012047514A1 (en) 2010-10-05 2012-04-12 Dow Technology Investments Llc Hydroformylation process
JP6621281B2 (ja) * 2015-09-18 2019-12-18 国立大学法人横浜国立大学 チタノシリケートの製造方法
CN111389457B (zh) * 2020-04-22 2022-08-30 陕西延长石油(集团)有限责任公司 一种异丁烷与丙烯共氧化制备甲基丙烯酸及环氧丙烷的催化剂及方法
CN113912569B (zh) * 2020-07-10 2024-04-26 中国石油化工股份有限公司 可降低稀释气用量的丙烯直接环氧化的方法

Family Cites Families (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1338901A (en) 1970-10-30 1973-11-28 Bp Chem Int Ltd Production of propylene oxide
GB1327497A (en) 1972-05-25 1973-08-22 Bp Chem Int Ltd Propylene oxide
GB1409421A (en) 1972-07-17 1975-10-08 Bryce Smith Derek Gold compounds
GB1491447A (en) 1973-12-05 1977-11-09 Ici Ltd Alkylene oxide production and catalysts therefor
FR2412538A1 (fr) 1977-12-22 1979-07-20 Ugine Kuhlmann Catalyseurs a base d'argent pour la production d'oxyde d'ethylene
US4391756A (en) 1978-06-05 1983-07-05 The Standard Oil Company Organo-monovalent aurus complex catalysts for the manufacture of olefin oxides
IT1127311B (it) 1979-12-21 1986-05-21 Anic Spa Materiale sintetico,cristallino,poroso costituito da ossidi di silicio e titanio,metodo per la sua preparazione e suoi usi
IT1187661B (it) 1985-04-23 1987-12-23 Enichem Sintesi Catalizzatore a base di silicio e titanio ad elevata resistenza meccanica
JPS63252908A (ja) 1987-04-08 1988-10-20 Agency Of Ind Science & Technol 金超微粒子固定化酸化物、その製造法、酸化触媒、還元触媒、可燃性ガスセンサ素子、及び電極用触媒
JPS6483513A (en) 1987-09-24 1989-03-29 Agency Ind Science Techn Ultrafine gold particle immobilized alkaline earth metallic compound, production thereof, oxidation catalyst, reduction catalyst and combustible gas sensor element
US4845253A (en) 1987-11-23 1989-07-04 The Dow Chemical Company Silver-based catalyst for vapor phase oxidation of olefins to epoxides
US5008414A (en) 1988-12-08 1991-04-16 The Boc Group, Inc. Process for the production of oxides
JPH02252610A (ja) 1989-03-24 1990-10-11 Agency Of Ind Science & Technol 金超微粒子固定化酸化物の製造法
US5162283A (en) 1991-01-22 1992-11-10 Mobil Oil Corporation Highly porous amorphous titania and titania/silica phases
JP3044836B2 (ja) 1991-05-28 2000-05-22 東ソー株式会社 プロピレンオキシドの製法
US5506273A (en) 1991-12-06 1996-04-09 Agency Of Industrial Science And Technology Catalyst for hydrogenation and method for hydrogenation therewith
US5262550A (en) 1992-04-30 1993-11-16 Arco Chemical Technology, L.P. Epoxidation process using titanium-rich silicalite catalysts
JPH0639284A (ja) * 1992-07-24 1994-02-15 Mitsui Mining Co Ltd 窒素酸化物分解触媒及び脱硝方法
FR2704159B1 (fr) 1993-04-22 1995-06-09 Atochem Elf Sa Catalyseur solide à base de silice particulaire, comportant du titane, Procédé d'obtention, et utilisation dans l'époxydation d'oléfines.
JP3351583B2 (ja) 1993-08-10 2002-11-25 花王株式会社 リン酸エステル塩の精製法
EP0638362B1 (en) 1993-08-11 2001-03-21 Mitsubishi Gas Chemical Company, Inc. Titanosilicate catalyst particle
US5354875A (en) 1993-12-23 1994-10-11 Uop Epoxidation of olefins using a titania-supported titanosilicate
JP2615418B2 (ja) 1994-03-10 1997-05-28 工業技術院長 金超微粒子固定化チタン系金属酸化物からなる酸化触媒、還元触媒、可燃性ガスセンサ素子および電極用触媒
DE4425672A1 (de) 1994-07-20 1996-01-25 Basf Ag Oxidationskatalysator, Verfahren zu seiner Herstellung und Oxidationsverfahren unter Verwendung des Oxidationskatalysators
US5935895A (en) * 1994-09-22 1999-08-10 Roche Vitamins Inc. Heterogeneous catalysts
JP2615432B2 (ja) 1994-10-28 1997-05-28 工業技術院長 金−酸化チタン含有触媒による炭化水素の部分酸化方法
DE19501891C1 (de) 1995-01-23 1996-09-26 Degussa Verfahren zur Herstellung eines Trägerkatalysators und seine Verwendung für die Produktion von Vinylacetat
JPH08269029A (ja) 1995-03-29 1996-10-15 Tosoh Corp プロピレンオキシドの製造方法
DE19600708A1 (de) 1996-01-11 1997-07-17 Basf Ag Oxidationskatalysator mit einem Gehalt an Lanthanoidmetallen, Verfahren zu seiner Herstellung und Oxidationsverfahren unter Verwendung des Oxidationskatalysators
DE19600709A1 (de) 1996-01-11 1997-07-17 Basf Ag Verfahren zur Herstellung von Epoxiden aus Olefinen, Wasserstoff und Sauerstoff
JP3777437B2 (ja) * 1996-03-21 2006-05-24 独立行政法人産業技術総合研究所 炭化水素の部分酸化方法および部分酸化用触媒
KR100255480B1 (ko) 1996-03-21 2000-05-01 사또 다께오 탄화수소의 부분산화용촉매 및 탄화수소의 부분산화방법
DE19623609A1 (de) 1996-06-13 1997-12-18 Basf Ag Oxidationskatalysator und Verfahren zur Herstellung von Epoxiden aus Olefinen, Wasserstoff und Sauerstoff unter Verwendung des Oxidationskatalysators
EP0917532B1 (en) 1996-07-01 2002-02-13 The Dow Chemical Company Process for the direct oxidation of olefins to olefin oxides
JPH1099646A (ja) * 1996-09-27 1998-04-21 Mitsubishi Chem Corp 塩素化有機化合物の分解方法
US5703254A (en) 1996-10-02 1997-12-30 Arco Chemical Technology, L.P. Propylene oxide process using mixed precious metal catalyst supported on alkaline earth metal carbonate
JPH10237055A (ja) * 1996-12-25 1998-09-08 Agency Of Ind Science & Technol エポキシドの製造方法およびエポキシド製造用触媒
EP0850936B1 (en) * 1996-12-25 2004-10-27 Agency Of Industrial Science And Technology Method of manufacturing epoxide and catalyst for use therein
US5759945A (en) * 1997-03-26 1998-06-02 Arco Chemical Technology, L.P. Preparation of titanium-containing catalysts using titanosiloxane polymers
EP1314473B1 (en) * 1997-06-30 2007-03-21 Dow Global Technologies Inc. Catalyst composition and process for the direct oxidation of propylene to propylene oxide
JP4016121B2 (ja) * 1997-09-05 2007-12-05 独立行政法人産業技術総合研究所 炭化水素部分酸化用触媒及び含酸素有機化合物の製造方法
JP4000392B2 (ja) 1997-11-05 2007-10-31 独立行政法人産業技術総合研究所 炭化水素の部分酸化用触媒及び含酸素有機化合物の製法
US6252095B1 (en) 1998-02-24 2001-06-26 Director-General Of Agency Of Industrial Science And Technology Catalyst for partially oxidizing unsaturated hydrocarbon
KR100565026B1 (ko) 1998-04-15 2006-03-30 다우 글로벌 테크놀로지스 인크. 올레핀을 올레핀 옥사이드로 직접 산화시키는 방법
NO982818L (no) 1998-06-18 2000-03-15 Pemby Ltd Syntetisk fremstilt preparat for behandling og/eller profylakse av overvekt, samt anvendelse derav

Also Published As

Publication number Publication date
JP2002541127A (ja) 2002-12-03
AU4335100A (en) 2000-10-23
KR100704141B1 (ko) 2007-04-09
DE60008235T2 (de) 2004-12-02
EP1177041A1 (en) 2002-02-06
JP4646409B2 (ja) 2011-03-09
DE60008235D1 (de) 2004-03-18
EP1384506A3 (en) 2004-02-04
JP2011031243A (ja) 2011-02-17
CN1122566C (zh) 2003-10-01
RU2234369C2 (ru) 2004-08-20
EP1384506A9 (en) 2004-03-31
ES2211535T3 (es) 2004-07-16
BR0011184B1 (pt) 2011-06-14
CN1349429A (zh) 2002-05-15
US6255499B1 (en) 2001-07-03
JP5419844B2 (ja) 2014-02-19
EP1177041B1 (en) 2004-02-11
WO2000059632A1 (en) 2000-10-12
ID30342A (id) 2001-11-22
EP1384506A2 (en) 2004-01-28
ATE259258T1 (de) 2004-02-15
KR20010102581A (ko) 2001-11-15

Similar Documents

Publication Publication Date Title
BR0011184A (pt) Processo para a hidro-oxidação de olefinas a óxidos de olefinas usando catalisador de ouro oxidado, composição de catalisador e método para preparar uma composição de catalisador
BR9710995A (pt) Processo para preparar um óxido de olefina, processo para preparar óxido de propileno, composição de catalisador e processo para regenerar uma composição de catalisador
MY112878A (en) Improvements in catalysts.
ES2190280T3 (es) Procedimiento para la oxidacion directa de olefinas a oxidos de olefina.
BR0014995A (pt) Processo de oxidação parcial catalìtica
BR9909604A (pt) Processo para a oxidação direta de olefinas a óxidos de olefinas.
BR9714951A (pt) Processo para preparar um óxido de olefina, composição de catalisador e processo para regenerar um composição.
BR9711924A (pt) Processo para a preparação de uma solução de peróxido de hidrogênio
BR9913599A (pt) Processos para preparação de um catalisador e para epoxidação catalìtica de um alqueno com um gás contendo oxigênio
MX168704B (es) Procedimiento para la preparacion de un catalizador que contiene plata
BR0200448A (pt) Combinação de catalisadores, catalisador, processo de produção de um poliéster, e, poliéster
BR0213339A (pt) Processo de epoxidação direta usando um sistema misto de catalisador
NO944550L (no) Fremgangsmåte for katalytisk, delvis oksidasjon av hydrokarboner
BR9507663A (pt) Processo para a oxidação de um alceno delta-5-esteroidal para o correspondente alceno delta-5-7-ceto-esteroidal e composto
DE69419849T2 (de) Verfahren zur Umsetzung einer chlorierten Alkanbeschickung
BRPI0008181B8 (pt) processo de preparação de cloro.
DE69839728D1 (de) Ethylenoxid-katalysatoren
AU586511B2 (en) Supported metal catalysts and use thereof
BR8503204A (pt) Processo para a preparacao de hidrocarbonetos por reacao catalitica de monoxido de carbono com hidrogenio
KR890009824A (ko) 시클로헥세논 탈 수소 방법
BR9813466A (pt) Processo para a produção de acetato de vinila por reação de etileno, oxigênio e ácido acético como reagentes, em presença de um catalisador
BR0011158A (pt) Método para preparar um catalisador e composição de catalisador compreendendo ouro sobre um suporte contendo titânio
BR9709386A (pt) Catalisador para uso na catálise da oxidação do monóxido de carbono e hidrocarbonetos
MY127878A (en) Vinyl acetate catalyst comprising palladium, gold, and any of certain third metals
ES516353A0 (es) "un procedimiento para hidroxilar al menos un compuesto olefinico que posee por lo menos una insaturacion etilenica".

Legal Events

Date Code Title Description
B25A Requested transfer of rights approved

Free format text: DOW GLOBAL TECHNOLOGIES INC (US)

B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B15K Others concerning applications: alteration of classification

Free format text: ALTERADA DA INT.CL: B01J 23/52, B01J 21/06, B01J 29/04, C07D 301/04, C07D 301/10

Ipc: B01J 23/52 (2010.01), B01J 21/06 (2010.01), B01J 2

B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 14/06/2011, OBSERVADAS AS CONDICOES LEGAIS.

B21A Patent or certificate of addition expired [chapter 21.1 patent gazette]

Free format text: PATENTE EXTINTA EM 14.06.2021