KR900017991A - 니트로벤젠류의 제조방법 - Google Patents
니트로벤젠류의 제조방법 Download PDFInfo
- Publication number
- KR900017991A KR900017991A KR1019890006635A KR890006635A KR900017991A KR 900017991 A KR900017991 A KR 900017991A KR 1019890006635 A KR1019890006635 A KR 1019890006635A KR 890006635 A KR890006635 A KR 890006635A KR 900017991 A KR900017991 A KR 900017991A
- Authority
- KR
- South Korea
- Prior art keywords
- oxide
- acidic
- tio
- nitric acid
- benzene
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C201/00—Preparation of esters of nitric or nitrous acid or of compounds containing nitro or nitroso groups bound to a carbon skeleton
- C07C201/06—Preparation of nitro compounds
- C07C201/08—Preparation of nitro compounds by substitution of hydrogen atoms by nitro groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
- C07C205/06—Compounds containing nitro groups bound to a carbon skeleton having nitro groups bound to carbon atoms of six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
- C07C205/07—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by halogen atoms
- C07C205/11—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by halogen atoms having nitro groups bound to carbon atoms of six-membered aromatic rings
- C07C205/12—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by halogen atoms having nitro groups bound to carbon atoms of six-membered aromatic rings the six-membered aromatic ring or a condensed ring system containing that ring being substituted by halogen atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (7)
- 니트로화제로서 질산을 이용하여, 벤젠류를 기상에서 니트로화하여 니트로 벤젠류를 제조함에 있어서, 촉매로서 (A) 다가금속으로 이온 교환된 산성의 층상점토 광물 또는 (B) 멘델레프의 주기율표의 IVA족에 속하는 금속의 산화물과 산화 턴스텐, 산화 몰리브덴, 산화 니오브 또는 산화 아연으로 구성되는 산성 복합 산화물을 사용하는 니트로 벤젠류의 제조방법.
- 제1항에 있어서, 상기 산성의 층상점토 광물들은, Al3+,Ti4+,Zr4+,Fe3+,Cr3+,Bi3+또는 La3+와 이온 교환된 몬모릴로 나이트인 방법.
- 제1항에 있어서, 상기 산성 복합 산화물들은 TiO2-MoO3,TiO2-WO3,TiO|2-ZnO 또는 ZrO2-WO3인 방법.
- 제1항에 있어서, 상기 벤젠류들은 벤젠, 클로로 벤젠 또는 톨루엔인 방법.
- 제1항에 있어서, 상기 질산은 희석 질산인 방법.
- 제1항에 있어서, 상기 산성 층상 점토 광물들은 +1.5이하의 산성도(H0)를 가지는 방법.
- 제1항에 있어서, 상기 산성 복합산화물들은 +1.5이하의 산성도(H0)를 가지는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP12267188 | 1988-05-18 | ||
JP63-122671 | 1988-05-18 |
Publications (1)
Publication Number | Publication Date |
---|---|
KR900017991A true KR900017991A (ko) | 1990-12-20 |
Family
ID=14841757
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019890006635A KR900017991A (ko) | 1988-05-18 | 1989-05-18 | 니트로벤젠류의 제조방법 |
Country Status (8)
Country | Link |
---|---|
US (1) | US5004846A (ko) |
EP (1) | EP0343048B1 (ko) |
JP (1) | JPH0249755A (ko) |
KR (1) | KR900017991A (ko) |
CS (1) | CS276381B6 (ko) |
DE (1) | DE68904594T2 (ko) |
ES (1) | ES2044164T3 (ko) |
PT (1) | PT90593B (ko) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH03294884A (ja) * | 1990-04-13 | 1991-12-26 | Asahi Optical Co Ltd | 電子写真プリンタのスキュー防止構造 |
JP2648047B2 (ja) * | 1991-06-27 | 1997-08-27 | ジューキ株式会社 | 玉縁縫い装置 |
CH683918A5 (de) * | 1991-12-04 | 1994-06-15 | Uetikon Chemie Ag | Verfahren zur Herstellung von Nitrobenzol. |
CH683919A5 (de) * | 1992-01-15 | 1994-06-15 | Uetikon Chemie Ag | Verfahren zur Herstellung von Nitrobenzol. |
US5510309A (en) * | 1994-05-02 | 1996-04-23 | Mobil Oil Corporation | Method for preparing a modified solid oxide |
US6376726B1 (en) * | 1997-10-14 | 2002-04-23 | Council Of Scientific & Industrial Research | Process for the production of nitroaromatic compounds from aromatic hydrocarbons using modified clay catalysts |
DE69810892T2 (de) * | 1998-03-25 | 2003-12-24 | Council Scient Ind Res | Verfahren zur Herstellung von nitroaromatischen Verbindungen aus aromatischen Kohlenwasserstoffen durch Verwendung von modifizierten Tonkatalysatoren |
FR2780308B1 (fr) | 1998-06-25 | 2000-08-11 | Inst Francais Du Petrole | Catalyseur comprenant une argile et un element du groupe vb, et son utilisation en hydrocraquage de charges petrolieres hydrocarbonees |
US6034287A (en) * | 1998-09-25 | 2000-03-07 | Coucil Of Scientific And Industrial Research | Process for the production of nitroarenes with high para-selectivity from monosubstituted aromatic hydrocarbons using alumino-silicates as catalysts |
WO2003086049A2 (en) | 2002-04-10 | 2003-10-23 | Devi Pesticides Private Limited | Flowering stimulant composition using nitrobenzene |
CN101679200A (zh) * | 2007-06-27 | 2010-03-24 | Hrd有限公司 | 生产硝基苯的方法和系统 |
WO2010061382A2 (en) * | 2008-11-25 | 2010-06-03 | Magal Saphier | A process for substitution on aromatic rings |
CN109400482B (zh) * | 2018-11-27 | 2021-04-20 | 浙江工业大学上虞研究院有限公司 | 一种甲苯硝化制备对硝基甲苯的方法 |
CN115245819B (zh) * | 2021-06-28 | 2024-01-09 | 荆楚理工学院 | 一种用于芳烃硝化反应的催化剂制备方法及应用 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3966830A (en) * | 1974-03-08 | 1976-06-29 | Teijin Limited | Process for the nitration of halogenated benzene derivatives |
DE2632234C3 (de) * | 1976-07-17 | 1978-12-21 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Herstellung von Nitrotoluolgemischen mit einem überwiegenden Gehalt an Nitrotoluol |
SE7707089L (sv) * | 1977-06-20 | 1978-12-21 | Bofors Ab | Sett for gasfasnitrering av aromater |
US4418230A (en) * | 1978-06-21 | 1983-11-29 | Aktiebolaget Bofors | Method for gaseous phase nitration of aromatics |
US4426543A (en) * | 1980-11-26 | 1984-01-17 | Monsanto Company | Vapor phase nitration of aromatic hydrocarbons |
JPS58180460A (ja) * | 1982-04-16 | 1983-10-21 | Sumitomo Chem Co Ltd | ニトロ化方法 |
US4600702A (en) * | 1984-11-14 | 1986-07-15 | Monsanto Company | Vapor phase nitration catalysts |
US4618733A (en) * | 1984-11-14 | 1986-10-21 | Monsanto Company | Vapor phase nitration of aromatic compounds |
-
1989
- 1989-04-26 JP JP1108223A patent/JPH0249755A/ja active Pending
- 1989-05-12 ES ES89401325T patent/ES2044164T3/es not_active Expired - Lifetime
- 1989-05-12 DE DE8989401325T patent/DE68904594T2/de not_active Expired - Fee Related
- 1989-05-12 EP EP89401325A patent/EP0343048B1/en not_active Expired - Lifetime
- 1989-05-15 US US07/352,022 patent/US5004846A/en not_active Expired - Fee Related
- 1989-05-17 CS CS892955A patent/CS276381B6/cs unknown
- 1989-05-17 PT PT90593A patent/PT90593B/pt not_active IP Right Cessation
- 1989-05-18 KR KR1019890006635A patent/KR900017991A/ko not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
JPH0249755A (ja) | 1990-02-20 |
EP0343048A1 (en) | 1989-11-23 |
ES2044164T3 (es) | 1994-01-01 |
DE68904594T2 (de) | 1993-08-19 |
US5004846A (en) | 1991-04-02 |
PT90593B (pt) | 1995-01-31 |
DE68904594D1 (de) | 1993-03-11 |
CS295589A3 (en) | 1992-05-13 |
CS276381B6 (en) | 1992-05-13 |
EP0343048B1 (en) | 1993-01-27 |
PT90593A (pt) | 1989-11-30 |
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Legal Events
Date | Code | Title | Description |
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WITN | Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid |