ES2107201T3 - Preparacion de catalizadores de polimerizacion por adicion mediante oxidacion de un centro metalico atenuado con un acido de lewis. - Google Patents
Preparacion de catalizadores de polimerizacion por adicion mediante oxidacion de un centro metalico atenuado con un acido de lewis.Info
- Publication number
- ES2107201T3 ES2107201T3 ES94911386T ES94911386T ES2107201T3 ES 2107201 T3 ES2107201 T3 ES 2107201T3 ES 94911386 T ES94911386 T ES 94911386T ES 94911386 T ES94911386 T ES 94911386T ES 2107201 T3 ES2107201 T3 ES 2107201T3
- Authority
- ES
- Spain
- Prior art keywords
- oxidation
- lewis acid
- polymerization catalysts
- attenuated
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/14—Monomers containing five or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
CATALIZADORES DE POLIMERIZACION DE ADICION QUE COMPRENDE UN DERIVADO DE UN TITANIO O ZIRCONIO EN EL ESTADO DE OXIDACION +4 PREPARADO POR OXIDACION CENTRAL DE METAL Y FORMACION DE COMPLEJO DE CATION DE UN COMPLEJO PRECURSOR DE METAL REDUCIDO POR TRANSFERENCIA DE ELECTRONES EN UNA UNICA ETAPA USANDO UN OXIDANTES ORGANICO NEUTRO, OPCIONALMENTE EN PRESENCIA DE UN MITIGADOR DE ACIDO LEWIS.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/034,434 US5347024A (en) | 1993-03-19 | 1993-03-19 | Preparation of addition polymerization catalysts via Lewis acid mitigated metal center oxidation |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2107201T3 true ES2107201T3 (es) | 1997-11-16 |
Family
ID=21876391
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES94911386T Expired - Lifetime ES2107201T3 (es) | 1993-03-19 | 1994-02-10 | Preparacion de catalizadores de polimerizacion por adicion mediante oxidacion de un centro metalico atenuado con un acido de lewis. |
Country Status (12)
Country | Link |
---|---|
US (1) | US5347024A (es) |
EP (1) | EP0641360B1 (es) |
JP (1) | JP3547440B2 (es) |
KR (1) | KR950701651A (es) |
CA (1) | CA2134890A1 (es) |
DE (1) | DE69405952T2 (es) |
ES (1) | ES2107201T3 (es) |
FI (1) | FI945435A0 (es) |
HK (1) | HK1003598A1 (es) |
NO (1) | NO944420D0 (es) |
TW (1) | TW273557B (es) |
WO (1) | WO1994021693A1 (es) |
Families Citing this family (41)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1273753B (it) * | 1994-02-11 | 1997-07-10 | Eniriceche Spa | Sistema catalitico e processo per la produzione di polidiolefine |
US6111020A (en) * | 1994-09-02 | 2000-08-29 | The Dow Chemical Company | Crosslinked foams from blends of ethylene vinyl acetate and ethylene-styrene interpolymers |
FI104825B (fi) | 1996-01-26 | 2000-04-14 | Borealis As | Olefiinien polymerointikatalysaattorisysteemi, sen valmistus ja käyttö |
DE19622207A1 (de) * | 1996-06-03 | 1997-12-04 | Hoechst Ag | Chemische Verbindung |
AU718884B2 (en) | 1996-06-17 | 2000-04-20 | Exxon Chemical Patents Inc. | Mixed transition metal catalyst systems for olefin polymerization |
US5811379A (en) | 1996-06-17 | 1998-09-22 | Exxon Chemical Patents Inc. | Polymers derived from olefins useful as lubricant and fuel oil additives, processes for preparation of such polymers and additives and use thereof (PT-1267) |
US6066603A (en) * | 1996-06-17 | 2000-05-23 | Exxon Chemical Patents Inc. | Polar monomer containing copolymers derived from olefins useful as lubricant and useful as lubricant and fuel oil additivies process for preparation of such copolymers and additives and use thereof |
US5939503A (en) * | 1996-08-09 | 1999-08-17 | California Institute Of Technology | Group IV zwitterion ansa metallocene (ZAM) catalysts for α-olefin polymerization |
EP0824112B1 (de) | 1996-08-13 | 2006-05-10 | Basell Polyolefine GmbH | Geträgerte chemische Verbindung |
ES2160289T3 (es) * | 1996-08-13 | 2001-11-01 | Basell Polyolefine Gmbh | Sistema catalizador soportado, un procedimiento para su obtencion y su empleo para la polimerizacion de olefinas. |
ZA977909B (en) | 1996-09-04 | 1999-03-03 | Dow Chemical Co | Compositions comprising a substantially random interpolymer of at least one alpha-olefin and at least one vinylidene aromatic monomer or hindered aliphatic vinylidene monomer |
BR9712009A (pt) | 1996-09-04 | 2000-01-18 | Dow Chemical Co | Revestimento para piso, parede ou teto. |
US6262161B1 (en) | 1997-06-26 | 2001-07-17 | The Dow Chemical Company | Compositions having improved ignition resistance |
US6319969B1 (en) | 1997-06-26 | 2001-11-20 | The Dow Chemical Company | Interpolymer compositions for use in sound management |
US6172015B1 (en) | 1997-07-21 | 2001-01-09 | Exxon Chemical Patents, Inc | Polar monomer containing copolymers derived from olefins useful as lubricant and fuel oil additives, processes for preparation of such copolymers and additives and use thereof |
CA2304674A1 (en) * | 1997-10-17 | 1999-04-29 | The Dow Chemical Company | Compositions of interpolymers of alpha-olefin monomers with one or more vinyl or vinylidene aromatic monomers |
ID26115A (id) | 1998-03-11 | 2000-11-23 | Dow Chemical Co | Komposisi-komposisi termoplastik interpolimer pada monomer alfa-olefin dengan satu beberapa monomer vinil viniliden beraroma dan beberapa alifatik berpenghalang monomer monomer sikloalifatik vinil viniliden yang dicampur dengan termoplastik rekayasa |
US6403773B1 (en) | 1998-09-30 | 2002-06-11 | Exxon Mobil Chemical Patents Inc. | Cationic group 3 catalyst system |
US5993707A (en) * | 1998-12-04 | 1999-11-30 | The Dow Chemical Company | Enlarged cell size foams made from blends of alkenyl aromatic polymers and alpha-olefin/vinyl or vinylidene aromatic and/or sterically hindered aliphatic or cycloaliphatic vinyl or vinylidene interpolymers |
US6187232B1 (en) | 1998-12-04 | 2001-02-13 | The Dow Chemical Company | Acoustical insulation foams |
US6048909A (en) * | 1998-12-04 | 2000-04-11 | The Dow Chemical Company | Foams having increased heat distortion temperature made from blends of alkenyl aromatic polymers and alpha-olefin/vinyl or vinylidene aromatic and/or sterically hindered aliphatic or cycloaliphatic vinyl or vinylidene interpolymers |
US6231795B1 (en) | 1998-12-04 | 2001-05-15 | The Dow Chemical Company | Soft and flexible foams made from blends of alkenyl aromatic polymers and alpha-olefin/vinyl or vinylidene aromatic and/or sterically hindered aliphatic or cycloaliphatic vinyl or vinylidene interpolymers |
CA2353884A1 (en) | 1998-12-08 | 2000-06-15 | Edward N. Knickerbocker | Mel-bondable polypropylene/ethylene polymer fiber and composition for making the same |
US6331597B1 (en) | 1999-08-09 | 2001-12-18 | The Dow Chemical Company | Azidosilane-modified, moisture-curable polyolefin polymers, process for making, and articles obtained therefrom |
US6362270B1 (en) | 1999-08-12 | 2002-03-26 | The Dow Chemical Company | Thermoplastic compositions for durable goods applications |
US6524702B1 (en) | 1999-08-12 | 2003-02-25 | Dow Global Technologies Inc. | Electrical devices having polymeric members |
ES2570753T3 (es) | 1999-08-17 | 2016-05-20 | Dow Global Technologies Llc | Composición polimérica fluida |
US6239062B1 (en) | 1999-09-02 | 2001-05-29 | Equistar Chemicals, L.P. | Olefin polymerization catalysts containing indolyl-amido ligands |
US6417276B2 (en) | 2000-01-07 | 2002-07-09 | The Dow Chemical Company | Thermoformable ethylene/styrene interpolymer-based polymer blend film for three-dimensional transfer finish foil |
US6160029A (en) * | 2000-03-08 | 2000-12-12 | The Dow Chemical Company | Olefin polymer and α-olefin/vinyl or α-olefin/vinylidene interpolymer blend foams |
US6649671B2 (en) | 2000-03-13 | 2003-11-18 | Dow Global Technologies Inc. | Concrete and process to make same |
KR20030028805A (ko) | 2000-07-20 | 2003-04-10 | 다우 글로벌 테크놀로지스 인크. | 알케닐 방향족 중합체와 알파-올레핀/비닐 또는 비닐리덴방향족 인터폴리머와의 블렌드로부터의 발포체 조성물 |
WO2002068529A2 (en) * | 2001-02-27 | 2002-09-06 | Dow Global Technologies Inc. | Fabricated articles prepared from blends of substantially random ethylene/propylene/vinyl aromatic interpolymers with polypropylene |
WO2003013806A1 (en) | 2001-08-10 | 2003-02-20 | Dow Global Technologies Inc. | Wood treatment composition and method of use |
US20040106739A1 (en) * | 2002-02-19 | 2004-06-03 | Cheung Yunwa Wilson | Blends of substantially random interpolymers with enhanced thermal performance |
DE102007057854A1 (de) * | 2007-11-28 | 2009-06-04 | Philipps-Universität Marburg | Cyclopentadienylphosphazen-Komplexe (CpPN-Komplexe) von Metallen der 3. und 4. Gruppe und der Lanthanoide |
JP7304880B2 (ja) | 2018-03-30 | 2023-07-07 | ダウ グローバル テクノロジーズ エルエルシー | 二核オレフィン重合活性化剤 |
WO2019191098A1 (en) | 2018-03-30 | 2019-10-03 | Dow Global Technologies Llc | Olefin polymerization activators |
CN112041351B (zh) | 2018-03-30 | 2023-12-29 | 陶氏环球技术有限责任公司 | 高度可溶的双硼酸盐作为烯烃聚合的双核助催化剂 |
US11787880B2 (en) | 2018-03-30 | 2023-10-17 | Dow Global Technologies Llc | Highly soluble alkyl substituted carbenium borate as co-catalysts for olefin polymerizations |
KR20200138271A (ko) | 2018-03-30 | 2020-12-09 | 다우 글로벌 테크놀로지스 엘엘씨 | 올레핀 중합 활성화제 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5064802A (en) * | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
US5189192A (en) * | 1991-01-16 | 1993-02-23 | The Dow Chemical Company | Process for preparing addition polymerization catalysts via metal center oxidation |
-
1993
- 1993-03-19 US US08/034,434 patent/US5347024A/en not_active Expired - Fee Related
-
1994
- 1994-02-10 ES ES94911386T patent/ES2107201T3/es not_active Expired - Lifetime
- 1994-02-10 CA CA002134890A patent/CA2134890A1/en not_active Abandoned
- 1994-02-10 JP JP52102794A patent/JP3547440B2/ja not_active Expired - Fee Related
- 1994-02-10 DE DE69405952T patent/DE69405952T2/de not_active Expired - Fee Related
- 1994-02-10 KR KR1019940704130A patent/KR950701651A/ko not_active Application Discontinuation
- 1994-02-10 EP EP94911386A patent/EP0641360B1/en not_active Expired - Lifetime
- 1994-02-10 WO PCT/US1994/001647 patent/WO1994021693A1/en active IP Right Grant
- 1994-03-18 TW TW083102388A patent/TW273557B/zh active
- 1994-11-18 NO NO944420A patent/NO944420D0/no unknown
- 1994-11-18 FI FI945435A patent/FI945435A0/fi unknown
-
1998
- 1998-03-31 HK HK98102704A patent/HK1003598A1/xx not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
FI945435A (fi) | 1994-11-18 |
DE69405952T2 (de) | 1998-04-16 |
US5347024A (en) | 1994-09-13 |
NO944420L (no) | 1994-11-18 |
NO944420D0 (no) | 1994-11-18 |
HK1003598A1 (en) | 1998-10-30 |
KR950701651A (ko) | 1995-04-28 |
EP0641360A1 (en) | 1995-03-08 |
CA2134890A1 (en) | 1994-09-29 |
EP0641360B1 (en) | 1997-10-01 |
JP3547440B2 (ja) | 2004-07-28 |
FI945435A0 (fi) | 1994-11-18 |
DE69405952D1 (de) | 1997-11-06 |
JPH07507099A (ja) | 1995-08-03 |
TW273557B (es) | 1996-04-01 |
WO1994021693A1 (en) | 1994-09-29 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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