SG11202008654WA - Highly soluble bis-borate as binuclear co-catalysts for olefin polymerizations - Google Patents
Highly soluble bis-borate as binuclear co-catalysts for olefin polymerizationsInfo
- Publication number
- SG11202008654WA SG11202008654WA SG11202008654WA SG11202008654WA SG11202008654WA SG 11202008654W A SG11202008654W A SG 11202008654WA SG 11202008654W A SG11202008654W A SG 11202008654WA SG 11202008654W A SG11202008654W A SG 11202008654WA SG 11202008654W A SG11202008654W A SG 11202008654WA
- Authority
- SG
- Singapore
- Prior art keywords
- binuclear
- borate
- catalysts
- highly soluble
- olefin polymerizations
- Prior art date
Links
- 150000001336 alkenes Chemical class 0.000 title 1
- 239000003426 co-catalyst Substances 0.000 title 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title 1
- 238000006116 polymerization reaction Methods 0.000 title 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/64003—Titanium, zirconium, hafnium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
- C08F4/64006—Bidentate ligand
- C08F4/64041—Monoanionic ligand
- C08F4/64048—NO
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic System
- C07F5/02—Boron compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/14—Monomers containing five or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/14—Monomers containing five or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/64003—Titanium, zirconium, hafnium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
- C08F4/64082—Tridentate ligand
- C08F4/64141—Dianionic ligand
- C08F4/64144—NN(R)C
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/03—Multinuclear procatalyst, i.e. containing two or more metals, being different or not
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/02—Cp or analog bridged to a non-Cp X anionic donor
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/03—Narrow molecular weight distribution, i.e. Mw/Mn < 3
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/04—Broad molecular weight distribution, i.e. Mw/Mn > 6
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/09—Long chain branches
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/10—Short chain branches
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201862650437P | 2018-03-30 | 2018-03-30 | |
PCT/US2019/024599 WO2019191440A1 (en) | 2018-03-30 | 2019-03-28 | Highly soluble bis-borate as binuclear co-catalysts for olefin polymerizations |
Publications (1)
Publication Number | Publication Date |
---|---|
SG11202008654WA true SG11202008654WA (en) | 2020-10-29 |
Family
ID=66286978
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
SG11202008654WA SG11202008654WA (en) | 2018-03-30 | 2019-03-28 | Highly soluble bis-borate as binuclear co-catalysts for olefin polymerizations |
Country Status (8)
Country | Link |
---|---|
US (1) | US20210108005A1 (en) |
EP (1) | EP3774934A1 (en) |
JP (1) | JP7364585B2 (en) |
KR (1) | KR20200141452A (en) |
CN (1) | CN112041351B (en) |
BR (1) | BR112020019339A2 (en) |
SG (1) | SG11202008654WA (en) |
WO (1) | WO2019191440A1 (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114478605B (en) * | 2022-03-07 | 2023-10-20 | 万华化学集团股份有限公司 | Trinuclear borate and preparation method thereof, catalyst system and olefin polymerization method |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3189175B2 (en) * | 1993-07-02 | 2001-07-16 | 出光興産株式会社 | Method for producing aromatic vinyl compound copolymer |
BR9708232A (en) | 1996-03-27 | 1999-08-03 | Dow Chemical Co | Catalyst activator catalyst system for polymerization of alpha-olefins and polymerization process |
ATE202365T1 (en) * | 1996-08-13 | 2001-07-15 | Basell Polyolefine Gmbh | SUPPORTED CATALYST SYSTEM, METHOD FOR THE PRODUCTION THEREOF AND ITS USE FOR THE POLYMERIZATION OF OLEFINS |
DE19703478A1 (en) * | 1997-01-31 | 1998-08-06 | Hoechst Ag | Process for the preparation of a matallocene catalyst system |
DE69812106T2 (en) * | 1997-08-01 | 2003-12-18 | Dow Global Technologies Inc | catalyst activator |
EP1228109B1 (en) * | 1999-09-27 | 2006-02-01 | Dow Global Technologies Inc. | Supported catalyst comprising expanded anions |
ES2263497T3 (en) * | 1999-10-22 | 2006-12-16 | Exxonmobil Chemical Patents Inc. | CAUTIONIC CARBEN COMPLEX ADEQUATE FOR POLYMERIZATION CATALYSTS. |
JP2002348343A (en) | 2001-05-28 | 2002-12-04 | Idemitsu Petrochem Co Ltd | Olefin polymer, its manufacturing method and thermoplastic resin composition comprising the polymer |
JP2002348336A (en) | 2001-05-28 | 2002-12-04 | Idemitsu Petrochem Co Ltd | Olefin polymer, method for producing the same and thermoplastic resin composition |
AU2002310315A1 (en) * | 2001-07-23 | 2003-02-17 | Dow Global Technologies, Inc. | Salt of lewis acid/acid adducts and catalyst activators therefrom |
US7196149B2 (en) * | 2003-04-17 | 2007-03-27 | The University Of Akron | Polymerization of i-butane in hydrocarbon media using bis(borane) co-initiators |
JP5133050B2 (en) | 2004-03-17 | 2013-01-30 | ダウ グローバル テクノロジーズ エルエルシー | Catalyst composition comprising a shuttling agent for forming an ethylene multiblock copolymer |
JP5311805B2 (en) | 2007-11-21 | 2013-10-09 | 日本ポリエチレン株式会社 | Olefin polymerization catalyst and olefin polymerization method using the same |
JP5769711B2 (en) * | 2009-08-18 | 2015-08-26 | エルジー・ケム・リミテッド | NOVEL COMPOUND, CATALYST COMPOSITION CONTAINING THE SAME AND METHOD FOR PRODUCING CYCLIC OLEFIN POLYMER USING THE SAME |
ES2711081T3 (en) * | 2012-10-18 | 2019-04-30 | Borealis Ag | Catalyst for the polymerization of olefins |
CN105339327B (en) | 2013-06-28 | 2020-01-21 | 陶氏环球技术有限责任公司 | Hyperbranched ethylene-based oligomers |
WO2019157002A1 (en) * | 2018-02-06 | 2019-08-15 | Northwestern University | Highly branched, low molecular weight polyolefins and methods for their production |
-
2019
- 2019-03-28 EP EP19719682.7A patent/EP3774934A1/en active Pending
- 2019-03-28 US US17/043,029 patent/US20210108005A1/en active Pending
- 2019-03-28 CN CN201980022077.XA patent/CN112041351B/en active Active
- 2019-03-28 SG SG11202008654WA patent/SG11202008654WA/en unknown
- 2019-03-28 WO PCT/US2019/024599 patent/WO2019191440A1/en active Application Filing
- 2019-03-28 JP JP2020551431A patent/JP7364585B2/en active Active
- 2019-03-28 BR BR112020019339-9A patent/BR112020019339A2/en active Search and Examination
- 2019-03-28 KR KR1020207029422A patent/KR20200141452A/en not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
EP3774934A1 (en) | 2021-02-17 |
WO2019191440A1 (en) | 2019-10-03 |
KR20200141452A (en) | 2020-12-18 |
CN112041351B (en) | 2023-12-29 |
US20210108005A1 (en) | 2021-04-15 |
CN112041351A (en) | 2020-12-04 |
BR112020019339A2 (en) | 2021-01-05 |
JP2021519357A (en) | 2021-08-10 |
JP7364585B2 (en) | 2023-10-18 |
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