JPH09231821A - Luminaire and method for maintaining illuminance - Google Patents
Luminaire and method for maintaining illuminanceInfo
- Publication number
- JPH09231821A JPH09231821A JP8083499A JP8349996A JPH09231821A JP H09231821 A JPH09231821 A JP H09231821A JP 8083499 A JP8083499 A JP 8083499A JP 8349996 A JP8349996 A JP 8349996A JP H09231821 A JPH09231821 A JP H09231821A
- Authority
- JP
- Japan
- Prior art keywords
- surface layer
- arc tube
- light
- semiconductor particles
- covering
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F13/00—Arrangements for modifying heat-transfer, e.g. increasing, decreasing
- F28F13/18—Arrangements for modifying heat-transfer, e.g. increasing, decreasing by applying coatings, e.g. radiation-absorbing, radiation-reflecting; by surface treatment, e.g. polishing
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F8/00—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying
- F24F8/20—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by sterilisation
- F24F8/22—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by sterilisation using UV light
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F2245/00—Coatings; Surface treatments
- F28F2245/02—Coatings; Surface treatments hydrophilic
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Catalysts (AREA)
- Paints Or Removers (AREA)
- Surface Treatment Of Glass (AREA)
- Laminated Bodies (AREA)
- Surface Treatment Of Optical Elements (AREA)
- Finishing Walls (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
- Prevention Of Fouling (AREA)
- Optical Elements Other Than Lenses (AREA)
- Building Environments (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Refuge Islands, Traffic Blockers, Or Guard Fence (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Rear-View Mirror Devices That Are Mounted On The Exterior Of The Vehicle (AREA)
- Dental Tools And Instruments Or Auxiliary Dental Instruments (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Road Signs Or Road Markings (AREA)
- Illuminated Signs And Luminous Advertising (AREA)
- Devices For Indicating Variable Information By Combining Individual Elements (AREA)
- Greenhouses (AREA)
- Joining Of Glass To Other Materials (AREA)
- Detergent Compositions (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Mirrors, Picture Frames, Photograph Stands, And Related Fastening Devices (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Panels For Use In Building Construction (AREA)
- Aftertreatments Of Artificial And Natural Stones (AREA)
- Bridges Or Land Bridges (AREA)
- Devices Affording Protection Of Roads Or Walls For Sound Insulation (AREA)
- Optical Radar Systems And Details Thereof (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は清掃性及び自己浄化
性に優れた照明器具とその照度維持方法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a luminaire excellent in cleaning property and self-cleaning property and a method for maintaining illuminance thereof.
【0002】[0002]
【従来の技術】蛍光灯等の照明器具の表面に酸化チタン
(TiO2)膜を形成して、自己浄化性を高める提案が、
学会予稿集(第2回シンポジウム「光触媒の最近の展
開」、1995年12月25日 於:東京大学)、特開平6−2
5857号公報、特開平7−51646号公報及び特開
平7−111104号公報になされている。2. Description of the Related Art Proposals have been made to improve the self-cleaning property by forming a titanium oxide (TiO 2 ) film on the surface of lighting equipment such as a fluorescent lamp.
Proceedings of the conference (2nd symposium "Recent Developments of Photocatalysts", December 25, 1995 at the University of Tokyo), JP-A-6-2
5857, JP-A-7-51646 and JP-A-7-111104.
【0003】前記学会予稿集では、酸化チタン微粒子を
分散した液剤及びゾルゲル用液剤を蛍光ランプ外面に塗
布することで、ランプ表面に付着しているインクや油等
の汚れが分解され、また同時に悪臭成分も分解されるこ
とが報告されている。特開平6−25857号公報に
は、気体状のチタンイソプロポキシドを蛍光体粒子表面
に噴霧して表面に酸化チタン膜を形成することで、高湿
度下でも輝度低下の少ない蛍光灯を得ることが記載され
ている。特開平7−51646号公報には、酸化チタン
膜をガラス等の表面に形成し、この酸化チタン膜に紫外
線を照射することで、ヤニや油脂成分等の汚れを分解す
ることが開示されている。特開平7−111104号公
報には、照明カバーの内側面に酸化チタン膜を形成する
ことで、悪臭成分や有毒成分を分解するとともに、有害
な紫外線を蛍光灯から放出しないようにすることが開示
されている。In the above-mentioned proceedings of the academic conference, by applying a liquid agent in which fine particles of titanium oxide are dispersed and a liquid agent for sol-gel to the outer surface of the fluorescent lamp, stains such as ink and oil adhering to the lamp surface are decomposed, and at the same time, a foul odor is given. It has been reported that the components are also decomposed. Japanese Unexamined Patent Publication No. 6-25857 discloses a fluorescent lamp having a small brightness decrease even under high humidity by spraying gaseous titanium isopropoxide on the surface of phosphor particles to form a titanium oxide film on the surface. Is listed. Japanese Patent Application Laid-Open No. 7-51646 discloses that a titanium oxide film is formed on the surface of glass or the like, and the titanium oxide film is irradiated with ultraviolet rays to decompose stains such as tars and oil and fat components. . Japanese Patent Application Laid-Open No. 7-111104 discloses that a titanium oxide film is formed on the inner surface of a lighting cover to decompose odorous and toxic components and prevent harmful ultraviolet rays from being emitted from a fluorescent lamp. Has been done.
【0004】[0004]
【発明が解決しようとする課題】上記したいずれの先行
例にあっても、照明器具の発光管若しくはカバーに直接
酸化チタン膜を形成し、この酸化チタン膜に紫外線を照
射することによる光触媒作用或いは光半導体作用で汚れ
成分等を化学的に分解するものであり、汚れ成分の量が
多量であって光触媒分解作用が追い付かないような極め
て劣悪な環境下での使用には対処できない。更に、汚れ
が付着した場合の雨水や洗浄水等による洗浄を効果的に
行わせるものではない。In any of the above-mentioned prior art examples, a titanium oxide film is directly formed on the arc tube or the cover of the lighting equipment, and the titanium oxide film is irradiated with ultraviolet rays for photocatalytic action or The photo-semiconductor action chemically decomposes stain components and the like, and cannot be used in an extremely poor environment where the amount of stain components is large and the photocatalytic decomposition action cannot catch up. Further, when dirt is attached, cleaning with rainwater or cleaning water is not effectively performed.
【0005】[0005]
【課題を解決するための手段】上記課題を解決すべく本
発明に係る照明器具は、発光管または発光管を覆うカバ
ーの外表面に光半導体粒子を含有する表面層を形成し、
またこの表面層が形成される発光管または発光管を覆う
カバーの厚みを、発光源からの照明光が前記光半導体粒
子を励起して表面層に親水性を付与し得る厚さとした。In order to solve the above-mentioned problems, the luminaire according to the present invention has a surface layer containing photo-semiconductor particles formed on the outer surface of an arc tube or a cover covering the arc tube.
The thickness of the arc tube on which the surface layer is formed or the cover covering the arc tube is set so that the illumination light from the light emitting source excites the optical semiconductor particles to impart hydrophilicity to the surface layer.
【0006】ここで、前記表面層としては、例えばSi
−O結合を有する樹脂(SiO2)中に酸化チタンが分散
して存在する構造が考えられる。Here, as the surface layer, for example, Si
A structure in which titanium oxide is dispersed and present in a resin (SiO 2 ) having an —O bond is considered.
【0007】また、上記の構造の他に、発光管または発
光管を覆うカバー類の表面に、アルカリ金属(Na等)
の拡散を防止する下地層を形成し、この下地層を介して
光半導体粒子からなる表面層を形成する構造でもよい。
尚プラスチック等の基材上に形成する下地層としてはS
i−O結合を有する樹脂が好ましく、ガラス等の基材上
に形成する下地層としては二酸化ケイ素が好ましい。In addition to the above structure, an alkali metal (Na or the like) is formed on the surface of the arc tube or covers covering the arc tube.
It is also possible to have a structure in which an underlayer for preventing the diffusion of the above is formed and a surface layer made of optical semiconductor particles is formed through this underlayer.
In addition, as an underlayer formed on a substrate such as plastic, S
A resin having an i-O bond is preferable, and silicon dioxide is preferable as an underlayer formed on a substrate such as glass.
【0008】もともと酸化チタン単独でも多少の親水性
を有するのであるが、下地層を形成することで、発光管
または発光管を覆うカバー類中に含まれる不純物が酸化
チタンに拡散し表面層の親水化を阻害することを防ぐ効
果がある。Originally, titanium oxide alone has some hydrophilicity, but by forming a base layer, the impurities contained in the arc tube or the covers covering the arc tube diffuse into titanium oxide to make the surface layer hydrophilic. It has the effect of preventing the inhibition of oxidization.
【0009】一方、本発明に係る照度維持方法は、発光
管またはこの発光管を覆うカバーの外表面に光半導体粒
子を含有する表面層が形成されている照明器具を点灯し
て、前記光半導体粒子の励起波長以下の波長の照明光を
前記発光管またはこの発光管を覆うカバーを透過せしめ
て表面層に照射し、光半導体粒子を励起することで前記
表面層を親水性にし、この親水性を呈するようになった
表面層に雨水あるいは洗浄水をかけることで、表面層に
付着している異物を除去するようにした。On the other hand, in the method for maintaining illuminance according to the present invention, the luminaire having a surface layer containing photo-semiconductor particles formed on the outer surface of the arc tube or the cover covering the arc tube is lit to turn on the photo semiconductor. Irradiation light having a wavelength equal to or less than the excitation wavelength of particles is radiated to the surface layer through the light emitting tube or the cover covering the light emitting tube, and the surface layer is made hydrophilic by exciting the photo-semiconductor particles. By applying rainwater or washing water to the surface layer which has become soaked, the foreign matter adhering to the surface layer is removed.
【0010】また、本発明に係る別の照度維持方法は、
発光管またはこの発光管を覆うカバーの外表面に光半導
体粒子を含有する表面層が形成されている照明器具を点
灯して、前記光半導体粒子の励起波長以下の波長の照明
光を前記発光管またはこの発光管を覆うカバーを透過せ
しめて表面層に照射し、光半導体粒子を励起することで
前記表面層を親水性にして表面層に付着する洗浄水、露
または雨水などの水分を水滴にすることなく薄い水膜と
し、この薄い水膜状態の水分を乾燥せしめるようにし
た。Another illuminance maintaining method according to the present invention is
A lighting device having a surface layer containing photo-semiconductor particles formed on the outer surface of a light-emitting tube or a cover covering the light-emitting tube is turned on to emit illumination light having a wavelength equal to or shorter than the excitation wavelength of the light-semiconductor particles. Or irradiate the surface layer through the cover that covers the arc tube, and make the surface layer hydrophilic by exciting the photo-semiconductor particles to make the surface layer hydrophilic, such as cleaning water, dew or rainwater, which is water droplets. Without doing so, a thin water film was formed, and the water in the thin water film state was dried.
【0011】本願発明にあっては、化学的な作用に加え
物理的な作用によって汚れを除去する。即ち、化学的な
作用では、酸化チタン等の光半導体粒子にバンドギャッ
プ以上のエネルギーを有する光(紫外線)を照射するこ
とで、光励起により伝導帯に電子を、荷電子帯に正孔を
生じせしめ、電子の持つ還元力、正孔の持つ酸化力によ
って汚れ成分等を分解する。これに加え物理的な作用で
は、光半導体粒子にバンドギャップ以上のエネルギーを
有する光を照射することで、表面層表面の極性が増し
て、物理吸着水量が増加することにより、親水性が向上
し、これにより汚れを分解することなく、雨水や洗浄水
とともにそのまま照明器具の表面から剥離して除去す
る。この作用により、著しい量の汚れが付着し化学的な
分解作用では分解できない場合でも、容易に汚れを除去
でき、照明機能を維持できる。In the present invention, stains are removed by physical action in addition to chemical action. That is, in the chemical action, photo-semiconductor particles such as titanium oxide are irradiated with light (ultraviolet light) having energy higher than the band gap to generate electrons in the conduction band and holes in the valence band by photoexcitation. , The reducing power of electrons and the oxidizing power of holes decompose dirt components. In addition to this, in the physical action, by irradiating the photo-semiconductor particles with light having energy higher than the band gap, the polarity of the surface layer surface is increased and the amount of physically adsorbed water is increased, thereby improving hydrophilicity. By doing so, the dirt can be peeled off and removed from the surface of the lighting fixture as it is along with rainwater and washing water without decomposing the dirt. By this action, even if a considerable amount of dirt adheres and cannot be decomposed by a chemical decomposition action, the dirt can be easily removed and the illumination function can be maintained.
【0012】[0012]
【発明の実施の形態】以下に本発明の実施の形態を説明
する。 (実施例1)アンモニア解膠型のアナターゼ型チタンゾ
ル(石原産業製STS−11、溶質濃度35重量%、平
均結晶粒子径17nm)と、コロイダルシリカゾル(日
産化学製スノーテクスO、溶質濃度20重量%、平均結
晶粒子径15nm、pH3)を固形分のモル比で88:
12になるように混合した後、図1(a)に示す蛍光灯
1(東芝FL20SW)の表面にディッピング法にて塗
布し、450℃で30分焼成し、同図(b)に示すよう
に蛍光灯1の表面にTiO2とSiO2とからなる表面層2
を3μmの厚さで形成した。また、蛍光灯1の管体の厚
みは2mmでこの厚さは白色蛍光灯から発せられる紫外
線が表面層2に到達するのを妨げない厚さである。上記
によって得られた蛍光灯の焼成直後の表面層の水との接
触角は15°であった。また、上記蛍光灯を暗所に1週
間放置した後に点灯し、点灯してからの経過時間と接触
角の変化を測定した結果、1週間暗所に放置しても水と
の接触角は変化せず15°のままであり、更に点灯を開
始すると、1時間程度で接触角は0°(超親水化)さ
れ、点灯中は常時接触角は0°であった。また、点灯を
停止しても1週間程度は接触角は5°未満であった。こ
の蛍光灯を街路において使用した場合、降雨によってセ
ルフクリーニングされることにより、1ヵ月後も全く照
度低下を生じなかった。Embodiments of the present invention will be described below. (Example 1) Ammonia deflocculating type anatase type titanium sol (STS-11 manufactured by Ishihara Sangyo, solute concentration 35% by weight, average crystal particle diameter 17 nm) and colloidal silica sol (Nissan Chemical Snowtex O, solute concentration 20% by weight) , Average crystal particle diameter 15 nm, pH 3) in a molar ratio of solid content of 88:
After mixing so as to be 12, the surface of the fluorescent lamp 1 (Toshiba FL20SW) shown in FIG. 1 (a) was applied by the dipping method, baked at 450 ° C. for 30 minutes, and as shown in FIG. A surface layer 2 made of TiO 2 and SiO 2 on the surface of the fluorescent lamp 1.
Was formed with a thickness of 3 μm. The tube of the fluorescent lamp 1 has a thickness of 2 mm, which is a thickness that does not prevent the ultraviolet rays emitted from the white fluorescent lamp from reaching the surface layer 2. The contact angle with water of the surface layer of the thus obtained fluorescent lamp immediately after firing was 15 °. Further, after the fluorescent lamp was left in the dark for one week and then turned on, the change in contact angle with the elapsed time from the lighting was measured. When the lighting was started, the contact angle was 0 ° (superhydrophilicity) in about 1 hour, and the contact angle was always 0 ° during lighting. Further, the contact angle was less than 5 ° for about one week even after the lighting was stopped. When this fluorescent lamp was used in a street, it was self-cleaned by rainfall, and no decrease in illuminance occurred even after one month.
【0013】図2(a)は紫外線を照射する前の表面層
の概念図であり、この図に示すように、Si原子にアル
キル基(R)が結合しているため、紫外線を照射する前
の表面層は疎水性を示す。そして、表面層に紫外線を照
射すると、図2(b)に示すように、TiO2の光半導体
効果或いは光触媒効果によってアルキル基(R)が水酸
基(OH)に換わり、この水酸基(OH)に水素結合に
よって物理吸着水が結合し、表面層の表面に薄い水膜が
形成され、親水性が発揮される。FIG. 2 (a) is a conceptual diagram of the surface layer before irradiation with ultraviolet rays. As shown in this figure, since the alkyl group (R) is bonded to the Si atom, before irradiation with ultraviolet rays. The surface layer of is hydrophobic. Then, when the surface layer is irradiated with ultraviolet rays, as shown in FIG. 2B, the alkyl group (R) is converted into a hydroxyl group (OH) by the photo-semiconductor effect or photocatalytic effect of TiO 2 , and the hydroxyl group (OH) is hydrogenated. By the binding, the physically adsorbed water is bound, a thin water film is formed on the surface of the surface layer, and hydrophilicity is exhibited.
【0014】(実施例2)図3(a)に示す白熱灯3
(三菱LW100V19W)の表面にシリコンアルコキ
シドをコーティングした。コーティングの手順は、先ず
テトラエトキシシラン、36%塩酸、純水、エタノール
を6:2:6:86(重量比)で混合し、1時間放置し
て混合による発熱がおさまった後、これをディッピング
により白熱灯3の表面に塗布した。次に、チタンアルコ
キシドをその上にコーティングした。コーティングの手
順は、先ずテトラエトキシシランとエタノールを1:9
(重量比)で混合したものに、更に加水分解速度を抑制
するために36%塩酸をテトラエトキシシランに対し1
0重量%添加して作製した。次に乾燥空気中でこの溶液
を上記シリコンアルコキシド層の上にディッピングし
た。コーティング量は酸化チタン換算で45μg/cm
2とした。次に、1〜10分乾燥処理することによりシ
リコンアルコキシド層及びチタンアルコキシド層の加水
分解、脱水縮合を促進し、シリカ層及び無定形酸化チタ
ン層を形成し、その後450℃で焼成し、図3(b)に
示すように白熱灯3の表面にSiO2層4とTiO2層5か
らなる表面層2を形成した。(Embodiment 2) Incandescent lamp 3 shown in FIG. 3 (a)
The surface of (Mitsubishi LW100V19W) was coated with silicon alkoxide. The coating procedure is as follows: Tetraethoxysilane, 36% hydrochloric acid, pure water, and ethanol are mixed in a ratio of 6: 2: 6: 86 (weight ratio), and the mixture is left for 1 hour to stop heat generation from the mixing, and then dipping Was applied to the surface of the incandescent lamp 3. Next, titanium alkoxide was coated thereon. The coating procedure is as follows: Tetraethoxysilane and ethanol 1: 9
To the mixture mixed in (weight ratio), 36% hydrochloric acid was added to 1% of tetraethoxysilane to further suppress the hydrolysis rate.
It was prepared by adding 0% by weight. This solution was then dipped in dry air onto the silicon alkoxide layer. Coating amount is 45 μg / cm in terms of titanium oxide
And 2 . Next, by performing a drying treatment for 1 to 10 minutes, hydrolysis and dehydration condensation of the silicon alkoxide layer and the titanium alkoxide layer are promoted to form a silica layer and an amorphous titanium oxide layer, followed by firing at 450 ° C., and FIG. As shown in (b), the surface layer 2 including the SiO 2 layer 4 and the TiO 2 layer 5 was formed on the surface of the incandescent lamp 3.
【0015】上記によって作製した白熱灯をトイレにお
いて1週間点灯せずに放置したところ、水との接触角は
30°となった。これを点灯させたところ、6時間で接
触角は0°となった。When the incandescent lamp manufactured as described above was left in the toilet for one week without being turned on, the contact angle with water was 30 °. When this was turned on, the contact angle became 0 ° in 6 hours.
【0016】(実施例3)シリカゾル(日本合成ゴム社
製のグラスカA)中のシリカ分重量と正味のトリメトキ
シメチルシラン(日本合成ゴム社製のグラスカB)重量
が3:1となるように混合し、全溶質濃度20重量%と
した液状物を、図4(a)に示すポリカーボネートの照
明カバー6(厚み2mm)に塗布した。その後、100
℃で加熱固化し、膜厚5μmの樹脂層7を形成した。次
に、アナターゼ型酸化チタンゾル(日産化学社製 TA
−15 溶質濃度10重量%)に上記シリカゾルを添加
し、エタノールで希釈後、上記トリメトキシメチルシラ
ンを添加した溶液を上記樹脂層7の上に塗布した。その
後、150℃で加熱固化し、膜厚0.5μmの表面層2
を形成した。ここで、シリカとトリメトキシメチルシラ
ンの固形分重量(樹脂重量)と酸化チタン固形分重量の
和に対する酸化チタン固形分重量の比率は50%とし
た。(Example 3) Silica sol (Grasca A manufactured by Japan Synthetic Rubber Co., Ltd.) so that the weight of silica and net trimethoxymethylsilane (Grasca B manufactured by Japan Synthetic Rubber Co.) are 3: 1. A liquid material having a total solute concentration of 20% by weight was mixed and applied to the polycarbonate lighting cover 6 (thickness 2 mm) shown in FIG. 4A. Then 100
The resin layer 7 having a film thickness of 5 μm was formed by heating and solidifying at a temperature of ℃. Next, anatase type titanium oxide sol (TA manufactured by Nissan Kagaku Co., Ltd.
-15 solute concentration (10 wt%) was added to the silica sol, diluted with ethanol, and then a solution containing the trimethoxymethylsilane added was applied onto the resin layer 7. Then, the surface layer 2 having a film thickness of 0.5 μm is solidified by heating at 150 ° C.
Was formed. Here, the ratio of the solid content weight of titanium oxide to the sum of the solid content weight (resin weight) of silica and trimethoxymethylsilane and the solid content weight of titanium oxide was 50%.
【0017】上記によって作製した表面層の接触角は当
初90°であったが、点灯してから1週間後の接触角は
0°になった。この照明カバーを付設した照明器具を台
所において使用したところ、飛散した油汚れがカバーに
付着しても、水洗いによって容易に除去可能であった。The contact angle of the surface layer produced as described above was initially 90 °, but the contact angle after one week from lighting was 0 °. When the lighting fixture provided with this lighting cover was used in the kitchen, even if scattered oil stains were attached to the cover, it could be easily removed by washing with water.
【0018】尚、実施例にあっては照明器具の発光管自
体またはカバーの外表面に表面層を形成した例を示した
が、照明ルーバー、反射板等のカバー類の表面に表面層
を形成してもよい。Although the surface layer is formed on the outer surface of the arc tube of the luminaire or the cover in the embodiment, the surface layer is formed on the surface of the covers such as the illumination louver and the reflection plate. You may.
【0019】[0019]
【発明の効果】以上に説明した如く本発明に係る照明器
具は、発光管または発光管を覆うカバーの外表面に酸化
チタン等の光半導体粒子を含有するSi−O結合を有す
る樹脂等からなる表面層を形成し、或いは発光管または
発光管を覆うカバー類に含まれるアルカリ金属の拡散を
防止する下地層を介して光半導体粒子の層を形成し、更
にこの表面層が形成される発光管または発光管を覆うカ
バーの厚みを、発光源からの照明光が前記光半導体粒子
を励起して表面層に親水性を付与し得る厚さとしたの
で、確実に光半導体粒子を励起せしめる照明光を光半導
体粒子に到達せしめることができる。As described above, the lighting equipment according to the present invention is made of a resin or the like having an Si-O bond containing optical semiconductor particles such as titanium oxide on the outer surface of the arc tube or the cover covering the arc tube. An arc tube in which a surface layer is formed, or a layer of optical semiconductor particles is formed through an underlayer that prevents diffusion of an alkali metal contained in the arc tube or covers covering the arc tube, and further this surface layer is formed. Or, the thickness of the cover that covers the arc tube, the illumination light from the light-emitting source is a thickness that can impart hydrophilicity to the surface layer by exciting the photosemiconductor particles, so that the illumination light that surely excites the photosemiconductor particles can be obtained. It can reach the optical semiconductor particles.
【0020】そして、光半導体粒子を含有する表面層に
光半導体粒子を励起せしめる照明光が到達することで、
表面層が親水性となり、この親水性を呈するようになっ
た表面層に雨水あるいは洗浄水をかけることで、表面層
に付着している異物を物理的にも除去することが可能に
なり、洗浄効果が大幅に向上する。When the illumination light that excites the photo-semiconductor particles reaches the surface layer containing the photo-semiconductor particles,
The surface layer becomes hydrophilic, and by adding rainwater or washing water to the surface layer that has become hydrophilic, it becomes possible to physically remove the foreign matter adhering to the surface layer, and to wash it. The effect is greatly improved.
【0021】また、表面層を親水性とすることで、表面
層に付着する洗浄水、露または雨水などの水分が薄い水
膜となるので、短時間のうちに乾燥せしめることがで
き、照明器具としての機能が向上する。Further, by making the surface layer hydrophilic, a water film such as cleaning water, dew or rainwater attached to the surface layer becomes a thin water film, which can be dried in a short time, and the lighting device can be dried. The function as is improved.
【図1】(a)は実施例1に係る照明器具の全体図、
(b)はその拡大断面図FIG. 1A is an overall view of a lighting fixture according to a first embodiment,
(B) is an enlarged sectional view
【図2】(a)は疎水性表面の概念図、(b)は親水性
表面の概念図2A is a conceptual diagram of a hydrophobic surface, and FIG. 2B is a conceptual diagram of a hydrophilic surface.
【図3】(a)は実施例2に係る照明器具の全体図、
(b)はその拡大断面図FIG. 3A is an overall view of a lighting fixture according to a second embodiment,
(B) is an enlarged sectional view
【図4】(a)は実施例3に係る照明器具の全体図、
(b)はその拡大断面図FIG. 4A is an overall view of a lighting fixture according to a third embodiment,
(B) is an enlarged sectional view
1…蛍光灯、2…表面層、3…白熱灯、4…SiO2層、
5…TiO2層、6…カバー、7…樹脂層。1 ... Fluorescent lamp, 2 ... Surface layer, 3 ... Incandescent lamp, 4 ... SiO 2 layer,
5 ... TiO 2 layer, 6 ... cover, 7 ... resin layer.
Claims (6)
表面に光半導体粒子を含有する表面層が形成され、また
この表面層が形成される発光管または発光管を覆うカバ
ー類の厚みは、発光源からの照明光が前記光半導体粒子
を励起して表面層に親水性を付与し得る厚さとされてい
ることを特徴とする照明器具。1. A surface layer containing optical semiconductor particles is formed on the outer surface of an arc tube or covers for covering the arc tube, and the thickness of the arc tube or the covers for covering the arc tube on which the surface layer is formed is A lighting fixture having a thickness capable of exciting the photo-semiconductor particles with illumination light from a light emitting source to impart hydrophilicity to the surface layer.
記表面層はSi−O結合を有する樹脂中に酸化チタンが
分散して存在することを特徴とする照明器具。2. The luminaire according to claim 1, wherein the surface layer comprises titanium oxide dispersed in a resin having a Si—O bond.
記表面層は発光管または発光管を覆うカバー類に含まれ
るアルカリ金属の拡散を防止する下地層を介して形成さ
れていることを特徴とする照明器具。3. The luminaire according to claim 1, wherein the surface layer is formed via an underlayer that prevents diffusion of an alkali metal contained in the arc tube or covers covering the arc tube. And lighting equipment.
記下地層はSi−O結合を有する樹脂または二酸化ケイ
素からなり、また前記表面層は酸化チタンを含む層から
なることを特徴とする照明器具。4. The lighting device according to claim 3, wherein the underlayer is made of a resin having Si—O bond or silicon dioxide, and the surface layer is made of a layer containing titanium oxide. Equipment.
の外表面に光半導体粒子を含有する表面層が形成されて
いる照明器具を点灯して、前記光半導体粒子の励起波長
以下の波長の照明光を前記発光管またはこの発光管を覆
うカバー類を透過せしめて表面層に照射し、光半導体粒
子を励起することで前記表面層を親水性にし、この親水
性を呈するようになった表面層に雨水あるいは洗浄水を
かけることで、表面層に付着している異物を除去するこ
とを特徴とする照度維持方法。5. A lighting fixture having a surface layer containing photo-semiconductor particles formed on the outer surface of a light-emitting tube or covers covering the light-emitting tube is turned on to emit light having a wavelength of not more than the excitation wavelength of the light-semiconductor particles. Irradiation light is transmitted through the arc tube or covers for covering the arc tube to irradiate the surface layer, and the surface layer is made hydrophilic by exciting the photo-semiconductor particles, and the surface becomes hydrophilic. A method for maintaining illuminance, characterized by removing foreign matter adhering to a surface layer by applying rainwater or washing water to the layer.
の外表面に光半導体粒子を含有する表面層が形成されて
いる照明器具を点灯して、前記光半導体粒子の励起波長
以下の波長の照明光を前記発光管またはこの発光管を覆
うカバー類を透過せしめて表面層に照射し、光半導体粒
子を励起することで前記表面層を親水性にして表面層に
付着する洗浄水、露または雨水などの水分を薄い水膜と
し、この薄い水膜状態の水分を乾燥せしめることを特徴
とする照度維持方法。6. A lighting fixture having a surface layer containing photo-semiconductor particles formed on the outer surface of a light-emitting tube or covers for covering the light-emitting tube is turned on to emit light having a wavelength not more than the excitation wavelength of the photo-semiconductor particles. Irradiation light is transmitted through the arc tube or covers for covering the arc tube to irradiate the surface layer, and the washing water attached to the surface layer by making the surface layer hydrophilic by exciting the photo-semiconductor particles, dew or A method for maintaining illuminance, characterized in that water such as rainwater is formed into a thin water film, and the water in the thin water film state is dried.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP8083499A JPH09231821A (en) | 1995-12-22 | 1996-04-05 | Luminaire and method for maintaining illuminance |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP35464995 | 1995-12-22 | ||
JP7-354649 | 1995-12-22 | ||
JP8083499A JPH09231821A (en) | 1995-12-22 | 1996-04-05 | Luminaire and method for maintaining illuminance |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH09231821A true JPH09231821A (en) | 1997-09-05 |
Family
ID=18438979
Family Applications (71)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP8083499A Pending JPH09231821A (en) | 1995-12-22 | 1996-04-05 | Luminaire and method for maintaining illuminance |
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JP2000181287A Expired - Fee Related JP3465664B2 (en) | 1995-12-22 | 2000-06-16 | Building materials for exterior walls |
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JP2000227055A Withdrawn JP2001089752A (en) | 1995-12-22 | 2000-07-27 | Member capable of obtaining hydrophilic nature in accordance with photoexcitation of optical semiconductor and manufacturing method thereof |
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JP2002244772A Pending JP2003113345A (en) | 1995-12-22 | 2002-08-26 | Antistatic coating composition |
Family Applications After (70)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP13408196A Expired - Lifetime JP3385850B2 (en) | 1995-12-22 | 1996-04-19 | Composite material with hydrophilicity |
JP10079496A Expired - Lifetime JP3740736B2 (en) | 1995-12-22 | 1996-04-23 | HEAT EXCHANGER AND HEAT EXCHANGER OPERATION METHOD |
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JP8156383A Pending JPH09231849A (en) | 1995-12-22 | 1996-05-29 | Insulator and dirt preventing method therefore |
JP13653596A Expired - Lifetime JP3339304B2 (en) | 1995-12-22 | 1996-05-30 | Painted object and painting method |
JP8136777A Pending JPH09227178A (en) | 1995-12-22 | 1996-05-30 | Laminated glass and its production |
JP13782996A Ceased JP3189682B2 (en) | 1995-12-22 | 1996-05-31 | Antifouling material |
JP8168643A Pending JPH09232096A (en) | 1995-12-22 | 1996-06-06 | Electrification preventing method, and electrification preventive composite material |
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JP8158518A Pending JPH09225021A (en) | 1995-12-22 | 1996-06-19 | Medical material |
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JP27280996A Expired - Fee Related JP3588202B2 (en) | 1995-12-22 | 1996-09-07 | Anti-fog road mirror and its anti-fog method |
JP8238927A Pending JPH09227159A (en) | 1995-12-22 | 1996-09-10 | Front and rear window glass of vehicle |
JP8275189A Pending JPH09231807A (en) | 1995-12-22 | 1996-09-10 | Vehicle headlight cover, vehicle with it, and its defogging method |
JP27519096A Expired - Lifetime JP3277983B2 (en) | 1995-12-22 | 1996-09-10 | Outdoor display panel and its cleaning method |
JP8281224A Pending JPH09228134A (en) | 1995-12-22 | 1996-09-17 | Antifogging helmet shield and antifogging method |
JP8281220A Expired - Lifetime JP3003593B2 (en) | 1995-12-22 | 1996-09-17 | Photocatalytic hydrophilic member |
JP28122196A Expired - Lifetime JP3743075B2 (en) | 1995-12-22 | 1996-09-17 | Antifogging dental mirror and antifogging method |
JP8281223A Expired - Lifetime JP3063968B2 (en) | 1995-12-22 | 1996-09-17 | Anti-fog vehicle mirror, automobile equipped with the same, anti-fog film for vehicle mirror and anti-fog method for vehicle mirror |
JP8281222A Pending JPH09230106A (en) | 1995-12-22 | 1996-09-17 | Anti-fogging camera filter and its anti-fogging method |
JP8281225A Pending JPH09230107A (en) | 1995-12-22 | 1996-09-17 | Anti-fogging glass lens and its anti-fogging method |
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JP34047196A Expired - Lifetime JP3303696B2 (en) | 1995-12-22 | 1996-12-05 | Photocatalytic hydrophilic coating composition |
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JP2000227055A Withdrawn JP2001089752A (en) | 1995-12-22 | 2000-07-27 | Member capable of obtaining hydrophilic nature in accordance with photoexcitation of optical semiconductor and manufacturing method thereof |
JP2000247609A Pending JP2001122679A (en) | 1995-12-22 | 2000-08-17 | Antifouling tile |
JP2001140242A Pending JP2002030258A (en) | 1995-12-22 | 2001-05-10 | Coated material and method for coating |
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JP (71) | JPH09231821A (en) |
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- 1996-11-01 JP JP8306997A patent/JPH09226060A/en active Pending
- 1996-11-19 JP JP8323516A patent/JPH09241038A/en active Pending
- 1996-12-05 JP JP34047296A patent/JP3348613B2/en not_active Expired - Fee Related
- 1996-12-05 JP JP34047196A patent/JP3303696B2/en not_active Expired - Lifetime
- 1996-12-05 JP JP8340470A patent/JPH09225387A/en active Pending
- 1996-12-09 JP JP08344585A patent/JP3141802B2/en not_active Expired - Lifetime
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1999
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2000
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2001
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2002
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JPS6215496B2 (en) * | 1981-08-06 | 1987-04-08 | Asahi Glass Co Ltd | |
JPS635301A (en) * | 1986-06-25 | 1988-01-11 | Matsushita Electric Works Ltd | Reflecting mirror |
JPS6381176A (en) * | 1986-09-24 | 1988-04-12 | Yoshio Ichikawa | Composition for coating |
JPS63100042A (en) * | 1986-10-14 | 1988-05-02 | Nippon Sheet Glass Co Ltd | Glass article difficult-to be dirtied |
JPH01169866A (en) * | 1987-12-25 | 1989-07-05 | Hitachi Ltd | Discharge lamp |
JPH01218635A (en) * | 1988-02-29 | 1989-08-31 | Hitachi Ltd | Deodorizing agent, its manufacturing method, deodorizing method, deodorizing apparatus and refrigeration cycle apparatus with said deodorizing apparatus |
JPH02216751A (en) * | 1989-02-17 | 1990-08-29 | Toshiba Corp | Ultraviolet ray suppressive light source, application agent for it, and its manufacture |
JPH0330314U (en) * | 1989-07-31 | 1991-03-26 | ||
JPH04174679A (en) * | 1990-11-06 | 1992-06-22 | Nippon Zeon Co Ltd | Optically reactive harmful substance removing agent and harmful substance removal method using same |
JPH05302173A (en) * | 1992-04-28 | 1993-11-16 | Central Glass Co Ltd | Hydrophilic coating film and method for forming the same |
JPH07111104A (en) * | 1992-08-14 | 1995-04-25 | Akira Fujishima | Lighting system |
JPH06298520A (en) * | 1993-04-13 | 1994-10-25 | Agency Of Ind Science & Technol | Production of silica gel containing dispersed ultrafine titanium oxide particle |
JPH07171408A (en) * | 1993-06-28 | 1995-07-11 | Ishihara Sangyo Kaisha Ltd | Photocatalytic body and its production |
JPH0751646A (en) * | 1993-08-12 | 1995-02-28 | Ishihara Sangyo Kaisha Ltd | Method for cleaning off contaminant on solid matter surface |
JPH0760132A (en) * | 1993-08-24 | 1995-03-07 | Matsushita Seiko Co Ltd | Photocatalyst and method for carrying the same |
JPH087643A (en) * | 1994-06-21 | 1996-01-12 | Mitsui Mining & Smelting Co Ltd | Luminaire having photocatalytic function |
JPH0810576A (en) * | 1994-07-05 | 1996-01-16 | Ebara Res Co Ltd | Removing method of harmful gas and device therefor |
JPH08277147A (en) * | 1995-03-31 | 1996-10-22 | Nippon Muki Co Ltd | Plate glass |
JPH09129012A (en) * | 1995-03-31 | 1997-05-16 | Toshiba Lighting & Technol Corp | Photocatalyst, fluorescent lamp and luminaire |
JPH0929103A (en) * | 1995-05-17 | 1997-02-04 | Toshiba Lighting & Technol Corp | Photocatalytic body, photocatalytic device, light source and lightening equipment |
JPH09171707A (en) * | 1995-12-20 | 1997-06-30 | Nippon Soda Co Ltd | Photocatalyst carrying luminaire |
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Title |
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藤嶋 昭,加藤 民彦,前川 悦郎,本多 健一: "疎水化処理をしたTiO2アノードを用いる画像形成", 電気化学および工業物理化学, vol. 54, no. 2, JPNX006027646, 1986, JP, pages 153 - 158, ISSN: 0000749070 * |
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