JPH07111104A - Lighting system - Google Patents
Lighting systemInfo
- Publication number
- JPH07111104A JPH07111104A JP4216871A JP21687192A JPH07111104A JP H07111104 A JPH07111104 A JP H07111104A JP 4216871 A JP4216871 A JP 4216871A JP 21687192 A JP21687192 A JP 21687192A JP H07111104 A JPH07111104 A JP H07111104A
- Authority
- JP
- Japan
- Prior art keywords
- light emitting
- light
- cover member
- ultraviolet rays
- semiconductor material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Arrangement Of Elements, Cooling, Sealing, Or The Like Of Lighting Devices (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は照明機能以外に周囲の消
臭、消毒及び紫外線カット等の副次的機能を備えた照明
装置に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a lighting device having secondary functions such as deodorizing, disinfecting, and ultraviolet ray shielding in addition to a lighting function.
【０００２】[0002]
【従来の技術】一般に、照明装置は室内、トイレ、電話
ボックス、トンネル、地下鉄駅ホーム等の空間を照明す
ることのみを目的としている。この照明装置は、前記閉
鎖的な空間の天井等の日常活動に支障を来さない部分に
設けられている。2. Description of the Related Art Generally, a lighting device is intended only for illuminating a space such as a room, a toilet, a telephone booth, a tunnel, and a subway station platform. This lighting device is provided in a portion such as the ceiling of the closed space that does not interfere with daily activities.
【０００３】一方、前記室内、電話ボックス等の閉鎖的
な空間では、悪臭のある気体や有毒な気体が発生した場
合、これらの気体は前記空間が閉鎖的であるが故にこの
空間内に籠ってしまい、支障を来すことがある。このと
き、籠った気体を効率的に外部に排出することができな
い場合には消臭及び消毒のための装置を特別に設けなけ
ればならない。On the other hand, in a closed space such as a room or a telephone box, when a gas having a foul odor or a toxic gas is generated, these gases are trapped in this space because the space is closed. It may cause troubles. At this time, if the trapped gas cannot be efficiently discharged to the outside, a device for deodorizing and disinfecting must be specially provided.
【０００４】また、前記照明装置として使用する蛍光灯
等には、それから射出される光に紫外線を含むものがあ
る。この紫外線は特に安価な蛍光灯の射出光に多く含ま
れているが、この紫外線は人体に有害である。このた
め、蛍光灯等はその射出光に紫外線を極力含まないよう
に改良されている。Some fluorescent lamps used as the illuminating device include ultraviolet rays in the light emitted therefrom. This ultraviolet ray is contained in the emitted light of an inexpensive fluorescent lamp in particular, but this ultraviolet ray is harmful to the human body. Therefore, fluorescent lamps and the like have been improved so that the emitted light thereof does not contain ultraviolet rays as much as possible.
【０００５】[0005]
【発明が解決しようとする課題】ところが、前記照明装
置と前記消臭又は消毒のための装置は独立した別々の装
置であり、それぞれ個別に設けなければならなかった。However, the illuminating device and the deodorizing or disinfecting device are independent devices and have to be individually provided.
【０００６】また、射出光に紫外線を含まないように改
良した蛍光灯等は、必然的にコストが嵩み、高価なもの
となっていた。[0006] Further, a fluorescent lamp or the like improved so that the emitted light does not contain ultraviolet rays inevitably has a high cost and is expensive.
【０００７】本発明は上記問題点に鑑みなされたもの
で、照明のための装置と前記消臭又は消毒のための装置
とを一体にしコンパクトで周囲の障害にならないと共
に、紫外線吸収機能をも備えた照明装置を提供すること
を目的とする。The present invention has been made in view of the above problems, and it is compact and does not interfere with the surroundings by integrating a device for lighting and a device for deodorizing or disinfecting, and also has an ultraviolet absorbing function. It is an object of the present invention to provide a lighting device.
【０００８】[0008]
【課題を解決するための手段】上記課題を解決するため
に本発明は、発光部と、この発光部の一部又は全部を覆
って設けられ、該発光部から射出された光を反射又は透
過するカバー部材とを有する照明装置であって、前記発
光部から射出された光を吸収して光触媒反応を示す半導
体物質を前記カバー部材の表面に存在させたことを特徴
とする。In order to solve the above-mentioned problems, the present invention provides a light emitting section and a part or all of the light emitting section, and reflects or transmits light emitted from the light emitting section. A lighting device having a cover member for absorbing light emitted from the light emitting unit and causing a photocatalytic reaction to occur on the surface of the cover member.
【０００９】前記半導体物質は特にカバー部材の内側表
面に存在させることが望ましい。また、半導体物質とし
ては、パラジウム、白金、ニッケル、ロジウム、ニオ
ブ、銅、スズ、酸化ルテニウム及び酸化ニッケルのうち
１種又は２種以上で修飾した半導体物質を用いることが
望ましい。前記半導体物質としては酸化チタン、酸化
鉄、酸化タングステン、酸化亜鉛又はチタン酸ストロン
チウムを用いることが望ましい。さらに、前記発光部と
しては紫外線を多く含む光源を用いることが望ましい。The semiconductor material is preferably present on the inner surface of the cover member. As the semiconductor substance, it is desirable to use a semiconductor substance modified with one or more of palladium, platinum, nickel, rhodium, niobium, copper, tin, ruthenium oxide and nickel oxide. It is desirable to use titanium oxide, iron oxide, tungsten oxide, zinc oxide, or strontium titanate as the semiconductor material. Further, it is desirable to use a light source containing a large amount of ultraviolet rays as the light emitting unit.
【００１０】[0010]
【作用】前述の構成により、発光部からの光は通常の機
能である照明を行うと共に、半導体物質に吸収されて光
触媒反応を示し、この半導体物質近傍の悪臭のある気体
や有毒な気体を無臭、無害なものにする。これと共に、
紫外線が半導体物質に吸収されるため、有害な紫外線が
外部に照射されるのを防止することができる。With the above-described structure, the light from the light emitting portion performs the normal function of illumination, and is absorbed by the semiconductor material to show a photocatalytic reaction. , Make it harmless. With this,
Since the ultraviolet rays are absorbed by the semiconductor material, it is possible to prevent harmful ultraviolet rays from being irradiated to the outside.
【００１１】この場合、半導体物質をカバー部材の内側
表面に存在させることで、この半導体物質が発光部によ
り直接照射され、光触媒反応を効率的に起こさせること
ができる。半導体物質として酸化チタン等をパラジウム
等で修飾したものを用いることで、より効率的に消臭、
消毒及び有害な紫外線のカットを行うことができる。さ
らに、発光部として紫外線を多く含む光源を用いること
で、光触媒反応速度を促進させることができる。In this case, by allowing the semiconductor material to exist on the inner surface of the cover member, the semiconductor material is directly irradiated by the light emitting portion, and the photocatalytic reaction can be efficiently caused. Deodorizing more efficiently by using titanium oxide etc. modified with palladium etc. as the semiconductor substance,
It can disinfect and block harmful UV rays. Further, by using a light source containing a large amount of ultraviolet rays as the light emitting section, the photocatalytic reaction rate can be accelerated.
【００１２】[0012]
【実施例】以下、本発明の実施例について図面を参照し
ながら詳細に説明する。Embodiments of the present invention will now be described in detail with reference to the drawings.
【００１３】図１に示す本実施例の照明装置１は、室
内、トイレ、電話ボックス、トンネル、地下鉄駅ホーム
等の閉鎖的な空間の天井等、日常活動に支障を来さない
部分に設けられるものである。具体的には、発光部２
と、この発光部２を覆って配置され、発光部２から射出
された光を透過するカバー部材３と、このカバー部材３
の内側表面に施され発光部２からの光によって光触媒反
応を示す半導体物質４とから構成されている。The lighting device 1 of the present embodiment shown in FIG. 1 is provided in a portion such as a ceiling of a closed space such as a room, a toilet, a telephone booth, a tunnel, a subway station platform, etc. that does not interfere with daily activities. It is a thing. Specifically, the light emitting unit 2
And a cover member 3 which is disposed so as to cover the light emitting unit 2 and transmits the light emitted from the light emitting unit 2, and the cover member 3
And a semiconductor material 4 which is applied to the inner surface of the and shows a photocatalytic reaction by light from the light emitting portion 2.
【００１４】発光部２には射出光中に紫外線を多く含む
光源、特に蛍光灯を用いる。この蛍光灯［特に安価な蛍
光灯、例えば白色蛍光灯（東芝ＦＬ−４Ｗ）］には光触
媒反応に寄与する４００ｎｍ以下の紫外線を多く含む。
特に、３６５ｎｍの紫外線が多く含まれている。また、
ＢＬランプ［例えばＢＬＢ蛍光灯（三共電気ＦＬ４ＢＬ
Ｂ）］には中心波長が３５０ｎｍの紫外線が多く含まれ
ている。これらの波長の紫外線は光触媒反応に適してい
る。なお、ＢＬランプは可視光をほとんど含まないの
で、通常の蛍光灯と併用する。また、紫外線としては３
００ｎｍ以下の波長のものは人体にとって非常に危険で
あるが、本実施例の発光部２から射出される３００〜４
００ｎｍの近紫外線は、人体に対する危険度が少なく、
さらに後述の半導体物質４は紫外線を吸収する紫外線フ
ィルタとしての効果を有するため、発光部２からの紫外
線による人体への影響はない。For the light emitting section 2, a light source containing a large amount of ultraviolet rays in the emitted light, particularly a fluorescent lamp is used. This fluorescent lamp [especially inexpensive fluorescent lamp, for example, white fluorescent lamp (Toshiba FL-4W)] contains a large amount of ultraviolet rays of 400 nm or less that contribute to the photocatalytic reaction.
In particular, it contains a large amount of ultraviolet rays of 365 nm. Also,
BL lamp [eg BLB fluorescent lamp (Sankyo Electric FL4BL
B)] contains a large amount of ultraviolet rays having a center wavelength of 350 nm. Ultraviolet rays of these wavelengths are suitable for photocatalytic reactions. Since the BL lamp contains almost no visible light, it is used together with a normal fluorescent lamp. Also, as ultraviolet rays, 3
Those having a wavelength of 00 nm or less are very dangerous to the human body, but 300 to 4 emitted from the light emitting unit 2 of this embodiment.
Near-ultraviolet rays of 00 nm are less dangerous to the human body,
Further, since the semiconductor material 4 described later has an effect as an ultraviolet filter that absorbs ultraviolet rays, the ultraviolet rays from the light emitting section 2 do not affect the human body.
【００１５】カバー部材３は、発光部２を囲繞すること
でこの発光部２を含んで空間を形成している。このカバ
ー部材３は可視光線を透過する材料からなる。さらに、
カバー部材３にはその下部と上部にそれぞれ気体の流入
口３Ａと流出口３Ｂとが設けられ、カバー部材３内で発
光部２によって暖められ膨張した空気が軽くなって上昇
し、上部にある流出口３Ｂから外部に流出すると共に、
これに伴ってカバー部材３の外部からの空気が流入口３
Ａからカバー部材３内部に流入するようになっている。
この流入口３Ａの外側には、発光部２からの紫外線が直
接に外部に射出されないように、遮蔽板３Ｃが設けられ
ている。The cover member 3 surrounds the light emitting portion 2 to form a space including the light emitting portion 2. The cover member 3 is made of a material that transmits visible light. further,
The cover member 3 is provided with a gas inlet 3A and a gas outlet 3B at its lower portion and upper portion, respectively. While flowing out from the outlet 3B,
Along with this, air from the outside of the cover member 3 is introduced into the inflow port 3
It flows from A into the cover member 3.
A shielding plate 3C is provided outside the inflow port 3A so that the ultraviolet rays from the light emitting unit 2 are not directly emitted to the outside.
【００１６】カバー部材３の内側には半導体物質４が設
けられている。半導体物質４としては、酸化チタン、酸
化鉄、酸化タングステン、酸化亜鉛、チタン酸ストロン
チウム等が用いられる。この半導体物質４を修飾する金
属又は金属酸化物としては、パラジウム、白金、ニッケ
ル及びロジウム、ニオブ、銅、スズ、酸化ルテニウム、
酸化ニッケル等が用いられる。これらのうち１種又は２
種以上を半導体物質４に修飾させる。この半導体物質４
に発光部２からの光を照射すると光触媒反応を示し、各
種の悪臭を放つ物質や有害物質が光化学的に常温で分解
除去される。これと共に光触媒反応に伴い半導体物質４
が発光部２からの紫外線を吸収する。A semiconductor material 4 is provided inside the cover member 3. As the semiconductor material 4, titanium oxide, iron oxide, tungsten oxide, zinc oxide, strontium titanate or the like is used. Examples of the metal or metal oxide that modifies the semiconductor material 4 include palladium, platinum, nickel and rhodium, niobium, copper, tin, ruthenium oxide,
Nickel oxide or the like is used. One or two of these
The semiconductor substance 4 is modified with at least one species. This semiconductor material 4
When the light from the light emitting section 2 is irradiated to the photocatalyst, it shows a photocatalytic reaction, and various kinds of malodorous substances and harmful substances are photochemically decomposed and removed at room temperature. Along with this, the semiconductor material 4 accompanying the photocatalytic reaction
Absorbs the ultraviolet rays from the light emitting section 2.
【００１７】ここで、前記半導体物質４の層を成形する
手段としては、以下のものが考えられる。Here, the following means can be considered as means for molding the layer of the semiconductor material 4.
【００１８】(1) 半導体薄膜 スピンコーティング、ディップコーティング、ゾルゲル
法、スパッタリング法等で基体の上に半導体薄膜を作
る。(1) Semiconductor thin film A semiconductor thin film is formed on a substrate by spin coating, dip coating, sol-gel method, sputtering method or the like.
【００１９】(2) 半導体粉末 粉末状の半導体微粒子をなんらかの手段で基体上に固定
する。この場合、微粒子表面が非活性物質（例えば接着
剤等）で覆われると光触媒反応が起らないので、注意す
る必要がある。(2) Semiconductor powder The semiconductor particles in powder form are fixed on the substrate by some means. In this case, it should be noted that the photocatalytic reaction does not occur when the surface of the fine particles is covered with an inactive substance (eg, an adhesive).
【００２０】以上の２つの手段のうち、反応活性の高い
半導体を得るには、(2)の半導体粉末の方が容易である
が、半導体粉末を固定するのは困難である。このため、
(1)の半導体薄膜か、(1)の半導体薄膜と(2)の半導体粉
末のハイブリッド系、即ち酸化チタンゾル液の中に微粒
子を懸濁させ、これをスピンコート又はディップコーテ
ィング法等で基体上に付け、固定するのがよい。Of the above two means, the semiconductor powder of (2) is easier to obtain a semiconductor having high reaction activity, but it is difficult to fix the semiconductor powder. For this reason,
The semiconductor thin film of (1) or a hybrid system of the semiconductor thin film of (1) and the semiconductor powder of (2), that is, fine particles are suspended in a titanium oxide sol liquid, and this is suspended on a substrate by spin coating or dip coating. It is better to attach it to and fix it.
【００２１】次に、この光触媒反応による消臭、消毒及
び紫外線カットの作用を説明する。発光部２からの光が
半導体物質４に照射されることにより、光エネルギーが
吸収され、価電子帯電子が励起されて活性化し、強い酸
化、還元のエネルギーを持つようになる。この状態で前
記悪臭を放つ物質や有害物質が半導体物質４の表面に接
触すると、この半導体物質４の強い酸化力、還元力によ
り無臭、無害の気体に改質されていく。半導体物質４に
照射された紫外線はこの半導体物質４に吸収され、外部
に射出されることはない。即ち、半導体物質４は紫外線
を吸収する紫外線フィルタとして機能する。（なお、光
触媒反応等の具体的な内容は、特公平２−９８５０号公
報、Ｊournal of JSES Vol.15,No.1 1989年 P30〜33、
月刊「化学工業」Vol.39,No.5 1988年5月号 P47(407),P
48(408)を参照されたし）このとき、カバー部材３内部
の空気が暖められ、上昇して流出口３Ｂから外部に流出
する。これに伴ってカバー部材３内に流入口３Ａを介し
て外部から新たな空気が流入する。これにより、悪臭、
有毒な気体は空気と共にカバー部材３内に流入し、光触
媒反応により無臭、無害の気体となって外部に流出す
る。そして、この作用が順次繰り返され、室内等の空間
全体が無臭、無害の空気となる。Next, the action of deodorization, disinfection and ultraviolet ray cut by the photocatalytic reaction will be described. When the semiconductor material 4 is irradiated with the light from the light emitting portion 2, the light energy is absorbed, the valence band electrons are excited and activated, and the semiconductor material 4 has strong oxidation and reduction energy. In this state, when the substance that gives off a bad odor or the harmful substance comes into contact with the surface of the semiconductor substance 4, it is transformed into an odorless and harmless gas by the strong oxidizing power and reducing power of the semiconductor substance 4. The ultraviolet rays applied to the semiconductor substance 4 are absorbed by the semiconductor substance 4 and are not emitted to the outside. That is, the semiconductor material 4 functions as an ultraviolet filter that absorbs ultraviolet rays. (Specific details of the photocatalytic reaction are described in Japanese Examined Patent Publication No. 2-9850, Journal of JSES Vol.15, No.1 1989 P30-33,
Monthly "Chemical Industry" Vol.39, No.5 May 1988 P47 (407), P
48 (408)) At this time, the air inside the cover member 3 is warmed, rises, and flows out through the outlet 3B. Along with this, new air flows into the cover member 3 from the outside through the inflow port 3A. This makes the stench,
The toxic gas flows into the cover member 3 together with the air, and becomes a odorless and harmless gas by a photocatalytic reaction and flows out to the outside. Then, this operation is sequentially repeated, and the entire space such as the room becomes odorless and harmless air.
【００２２】この作用は、照明装置１が点灯している間
中行われる。即ち、その空間の利用者がいる限り、照明
装置１は点灯され、その間中は前記消臭、消毒作用が行
われる。This operation is performed while the lighting device 1 is on. That is, as long as there is a user in the space, the lighting device 1 is turned on, and the deodorizing and disinfecting actions are performed during that period.
【００２３】以上のように作用することにより、空間全
体の悪臭、有毒な気体を効率的に消臭、消毒すると共
に、人体に有害な紫外線を効率的にカットすることがで
きるようになる。By the above-mentioned actions, it is possible to efficiently deodorize and disinfect the bad odors and toxic gases in the entire space, and to effectively cut the ultraviolet rays harmful to the human body.
【００２４】また、光触媒反応は、酸化触媒等に比して
熱劣化や被毒元素による活性低下等がなく、脱臭、消毒
作用及び紫外線フィルタとしての寿命を大幅に延ばすこ
とができる。Further, the photocatalytic reaction is free from heat deterioration and activity reduction due to poisoning elements as compared with the oxidation catalyst and the like, and can greatly extend the deodorizing and disinfecting action and the life of the ultraviolet filter.
【００２５】照明装置１は発光部２にカバー部材３を設
けただけの簡単な構成なので、全体をコンパクトにする
ことができ、電話ボックス等の狭い空間にも容易に使用
することができると共に、安価に製造することができ
る。Since the illuminating device 1 has a simple structure in which the light emitting portion 2 is provided with the cover member 3, it can be made compact as a whole and can be easily used in a narrow space such as a telephone box. It can be manufactured at low cost.
【００２６】さらに、安価で紫外線を出しやすい蛍光灯
等の発光部２を使用する場合にも、紫外線は半導体物質
４で吸収され、外部に漏れることがないので、安価でし
かも安全な照明装置１を提供することができる。Further, even when the light emitting section 2 such as a fluorescent lamp which is inexpensive and emits ultraviolet rays easily is used, the ultraviolet rays are absorbed by the semiconductor material 4 and do not leak to the outside. Therefore, the lighting apparatus 1 is inexpensive and safe. Can be provided.
【００２７】次に、第２実施例を説明する。Next, a second embodiment will be described.
【００２８】本実施例の照明装置は、発光部２を覆うカ
バーの一部が反射板となっているものである。図２中の
７は発光部２を囲繞するカバー部材で、このカバー部材
７の上側部が反射板８となっている。カバー部材７の下
側面は光を透過する部材である透過板９で成形され、こ
れら反射板８と透過板９とで発光部２を囲繞している。
さらに、これら反射板８と透過板９との内側面全域に
は、前記同様の半導体物質１０が施されている。カバー
部材７の下側部には流入口７Ａが設けられ、上側部には
流出口７Ｂが設けられている。流入口７Ａの外側には、
発光部２からの紫外線が直接に外部に射出されないよう
に、遮蔽板７Ｃが設けられている。In the lighting device of this embodiment, a part of the cover for covering the light emitting portion 2 is a reflector. Reference numeral 7 in FIG. 2 denotes a cover member that surrounds the light emitting unit 2, and an upper portion of the cover member 7 serves as a reflection plate 8. The lower side surface of the cover member 7 is formed by a transmission plate 9 that is a member that transmits light, and the reflection plate 8 and the transmission plate 9 surround the light emitting unit 2.
Further, a semiconductor material 10 similar to the above is applied to the entire inner side surfaces of the reflection plate 8 and the transmission plate 9. An inflow port 7A is provided on the lower side of the cover member 7, and an outflow port 7B is provided on the upper side. Outside the inflow port 7A,
A shielding plate 7C is provided so that the ultraviolet rays from the light emitting unit 2 are not directly emitted to the outside.
【００２９】これにより、通常の照明機能としては、発
光部２による直接光と反射板８による反射光によって反
射板８の前方を中心に照射することができる。これに加
えて前記第１実施例と同様の作用により、室内等の空間
内の悪臭を放つ気体や有毒な気体に対して消臭、消毒す
ることができると共に、発光部２からの紫外線を反射板
８及び透過板９に施された半導体物質１０が吸収して紫
外線フィルタとして機能する。Thus, as a normal illumination function, direct light from the light emitting section 2 and reflected light from the reflecting plate 8 can illuminate the front of the reflecting plate 8 as a center. In addition to this, by the same action as that of the first embodiment, it is possible to deodorize and disinfect a bad smelling gas or a toxic gas in the space such as the room and to reflect the ultraviolet rays from the light emitting section 2. The semiconductor material 10 applied to the plate 8 and the transmission plate 9 absorbs and functions as an ultraviolet filter.
【００３０】さらに、反射板８の内側面にも半導体物質
１０を施したので、この反射板８の内側面が光触媒反応
によって浄化され、この反射板８を常に良好な状態に維
持することができるようになる。Further, since the semiconductor material 10 is also applied to the inner surface of the reflector 8, the inner surface of the reflector 8 is purified by the photocatalytic reaction, and the reflector 8 can be always maintained in a good condition. Like
【００３１】なお、前記２つの実施例においては、カバ
ー部材３，７を発光部２を完全に覆ってしまうように形
成したが、図３に示すように、カバー部材１１を発光部
２の下側のみを覆い上側を開放するように形成し、鎖１
２等で発光部２とともに取り付けるようにしてもよい。
この場合、発光部２の上側が開放されているので、前記
２つの実施例に比しても空気の対流がよくなり、消臭、
消毒作用効率が向上する。Although the cover members 3 and 7 are formed so as to completely cover the light emitting portion 2 in the above two embodiments, the cover member 11 is provided below the light emitting portion 2 as shown in FIG. Chain 1 formed so that only the side is covered and the upper side is opened
You may make it attach | attach with 2 and the light-emitting part 2.
In this case, since the upper side of the light emitting unit 2 is open, the convection of air is improved and the deodorization is improved, compared with the above two embodiments.
The disinfection action efficiency is improved.
【００３２】さらに、カバー部材１１の側壁部１１Ａに
は、図４に示すように、空気流通板１２を設けてもよ
い。この空気流通板１２は側壁部１１Ａの一部を取り除
き、細長い板を多段に配設したもので、カバー部材１１
内での空気の対流をさらによくすることができる。Further, the side wall 11A of the cover member 11 may be provided with an air circulation plate 12 as shown in FIG. This air circulation plate 12 is one in which a part of the side wall portion 11A is removed and elongated plates are arranged in multiple stages.
The convection of air inside can be further improved.
【００３３】次に消臭効果の具体的な実験例（Ａ）を示
す。Next, a specific experimental example (A) of the deodorizing effect will be shown.
【００３４】実験装置としては図５に示すものを用い
た。図中の１５は臭気を封入する反応槽である。この反
応槽１５内に発光部１６を装着し、この発光部１６の側
面及び下側を覆うように、内側に半導体物質を施したカ
バー部材１７を装着した。さらに、反応槽１５の床部に
は、光照射時に内部の気体の対流を良くするためにファ
ン１８を設けた。The experimental apparatus shown in FIG. 5 was used. Reference numeral 15 in the figure is a reaction tank for sealing the odor. A light emitting portion 16 was mounted in the reaction tank 15, and a cover member 17 provided with a semiconductor material inside was mounted so as to cover the side surface and the lower side of the light emitting portion 16. Further, the floor of the reaction tank 15 is provided with a fan 18 in order to improve the convection of the gas inside when the light is irradiated.
【００３５】発光部１６としては次の４種類の光源を用
いた。The following four types of light sources were used as the light emitting section 16.
【００３６】 (1) ナショナルパルック（ＥＸ−Ｎ）１０Ｗ (2) ナショナル昼光色（Ｄ） １０Ｗ (3) ブラックライト（ＢＬ） １０Ｗ (4) 低圧水銀灯 １０Ｗ これらのうち、任意の３本を組合わせて発光部１６とし
た。反応槽１５としては１０リットルの容器を用いた。(1) National Palook (EX-N) 10W (2) National Daylight (D) 10W (3) Black Light (BL) 10W (4) Low Pressure Mercury Lamp 10W The light emitting unit 16 was used. As the reaction tank 15, a 10 liter container was used.
【００３７】また、カバー部材１７としては次のものを
用いた。As the cover member 17, the following is used.
【００３８】(1) 石英ガラス (2) ＴｉＯ2膜をコートした石英ガラス、ただし、Ｔｉ
Ｏ2膜は多木化学（株）製のＴｉＯ2ゾルをスピンコート
で塗布した後に４００℃で焼成したものを用いた。(1) Quartz glass (2) Quartz glass coated with a TiO 2 film, provided that Ti
As the O 2 film, a TiO 2 sol manufactured by Taki Chemical Co., Ltd. was applied by spin coating and then baked at 400 ° C.
【００３９】臭気成分としては、初期濃度約１０ppmの
アセトアルデヒドを用いた。分析法としては、ガスクロ
マトグラフによる定量、定性分析を用いた。As the odorous component, acetaldehyde having an initial concentration of about 10 ppm was used. As the analysis method, quantitative and qualitative analysis by gas chromatography was used.
【００４０】以上の装置を用いた実験によって、図６の
グラフに示す結果が得られた。このグラフはＴｉＯ2膜
をコートした石英ガラスをカバー部材１７として用いた
ものによる結果で、特性線２１は光未照射の場合、特性
線２２は昼光色３本を発光部１６として用いた場合、特
性線２３はブラックライト１本とパルック２本を組合わ
せたものを発光部１６として用いた場合、特性線２４は
低圧水銀灯１本とパルック２本を組合わせたものを発光
部１６として用いた場合の結果を示す。By the experiment using the above apparatus, the results shown in the graph of FIG. 6 were obtained. This graph shows the results obtained by using quartz glass coated with a TiO 2 film as the cover member 17, and the characteristic line 21 shows the characteristics when no light is irradiated, and the characteristic line 22 shows the characteristics when three daylight colors are used as the light emitting section 16. Line 23 is a case where a combination of one black light and two Palooks is used as the light emitting unit 16, and characteristic line 24 is a case where a combination of one low-pressure mercury lamp and two Palooks is used as the light emitting unit 16. The result is shown.
【００４１】この結果から、発光部１６として低圧水銀
灯１本とパルック２本を組合わせたものが特性線２４の
ように最も効率的に消臭することができた。なお、光未
照射の場合に特性線２１のようにアセトアルデヒドが減
少するのは、反応槽１５の内壁面に吸着されるためであ
る。From these results, it was found that the combination of one low-pressure mercury lamp and two Palook as the light emitting section 16 was able to deodorize most efficiently as indicated by the characteristic line 24. It should be noted that the reason why acetaldehyde is reduced as shown by the characteristic line 21 when light is not irradiated is that it is adsorbed on the inner wall surface of the reaction tank 15.
【００４２】また、ＴｉＯ2膜をコートしない石英ガラ
スを用いた場合は、図６のグラフにおける光未照射の場
合の特性線２１と実験誤差内で一致した。この場合も前
述したように、反応槽１５の内壁面にアセトアルデヒド
が吸着されるためである。パルックのみ３本用いた場合
も光未照射の場合の特性線２１と一致した。When the silica glass not coated with the TiO 2 film was used, it coincided with the characteristic line 21 in the graph of FIG. Also in this case, as described above, acetaldehyde is adsorbed on the inner wall surface of the reaction tank 15. The characteristic line 21 in the case of not irradiating light also coincided with the case where only three pieces of Palook were used.
【００４３】なお、前記実験では、臭気成分としてアセ
トアルデヒドを用いたが、このアセトアルデヒドは臭気
成分の代表的なものである。ＴｉＯ2光触媒の数多くの
研究からＴｉＯ2でアセトアルデヒドが分解されれば、
他のほとんどすべての臭気成分（チオール、アンモニ
ア、メルカブタン等）も分解されることが知られてい
る。 次に消臭効果の実験例（Ｂ）を示す。Although acetaldehyde was used as the odor component in the above experiment, this acetaldehyde is a typical odor component. If acetaldehyde is decomposed by TiO 2 from a number of studies of the TiO 2 photocatalyst,
It is known that almost all other odorous components (thiol, ammonia, mercaptan, etc.) are also decomposed. Next, an experimental example (B) of the deodorizing effect is shown.
【００４４】本実験ではカバー部材１７のＴｉＯ2半導
体層として、多木化学（株）製のＴｉＯ2ゾル中に日本
アエロジル社製の酸化チタン粉末（Ｐ−２５）を１０mg
／１０ml混入し、スピンコート後、４００℃で焼成した
半導体物質４を用いた。発光部１６としては、ブラック
ライト１本とパルック２本を組合わせたものを用いた。
これ以外は前記実験例（Ａ）と同様である。In this experiment, as the TiO 2 semiconductor layer of the cover member 17, 10 mg of titanium oxide powder (P-25) manufactured by Nippon Aerosil Co., Ltd. was added to TiO 2 sol manufactured by Taki Chemical Co., Ltd.
/ 10 ml was mixed, spin-coated, and then baked at 400 ° C. for use as semiconductor material 4. As the light emitting unit 16, a combination of one black light and two Palooks was used.
Other than this, it is the same as the experimental example (A).
【００４５】この実験によって、約１０分の光照射でア
セトアルデヒド残存率が約３０％になった。即ち、実験
例（Ａ）の場合のＴｉＯ2膜をコートした石英ガラスの
カバー部材１７に比べて脱臭能が約1.5倍増加した。According to this experiment, the acetaldehyde residual rate became about 30% by the light irradiation for about 10 minutes. That is, the deodorizing ability was increased by about 1.5 times as compared with the quartz glass cover member 17 coated with the TiO 2 film in the experimental example (A).
【００４６】次にＴｉＯ2膜の紫外線吸収能の実験例
（Ｃ）を示す。Next, an experimental example (C) of the ultraviolet absorption ability of the TiO 2 film is shown.
【００４７】発光部１６として次の４つの光源を用い
た。The following four light sources were used as the light emitting section 16.
【００４８】(1) 太陽光 (2) ６Ｗ−ＵＶランプ (3) ２Ｗ−水銀ランプ (4) １５Ｗ−昼光色蛍光灯 紫外線吸収基材としては次の２つの材料を用いた。(1) Sunlight (2) 6W-UV lamp (3) 2W-mercury lamp (4) 15W-daylight fluorescent lamp The following two materials were used as an ultraviolet absorbing base material.
【００４９】(1) 石英ガラス (2) ＴｉＯ2膜をコートしたアルカリガラス、なお、Ｔ
ｉＯ2膜の作成法は実験例（Ａ）と同様である。焼成温
度のみ変えてある。(1) Quartz glass (2) Alkali glass coated with TiO 2 film, T
The method for forming the iO 2 film is the same as in the experimental example (A). Only the firing temperature is changed.
【００５０】吸収スペクトル測定は紫外・可視分光光度
計によって行った。紫外線強度測定はトプコンＵＶＲ−
１紫外線強度計によって行った。The absorption spectrum was measured by an ultraviolet / visible spectrophotometer. Ultraviolet intensity measurement is Topcon UVR-
1 Ultraviolet intensity meter was used.
【００５１】ＴｉＯ2膜の吸収スペクトル測定結果を図
７に示す。吸収端は約３８０ｎｍである。ＴｉＯ2膜を
コートしないアルカリガラス基材に比べてＴｉＯ2膜を
コートしたアルカリガラスは約５０ｎｍだけ長波長側に
シフトしている。FIG. 7 shows the result of absorption spectrum measurement of the TiO 2 film. The absorption edge is about 380 nm. Alkali glass coated with TiO 2 film as compared with the alkali glass substrate which is not coated with TiO 2 film is shifted by about 50nm to the long wavelength side.
【００５２】紫外線強度の測定方法は、図８に示すよう
に、光源又は窓の外の自然太陽光（例えば晴天の午後１
時）３１から６０ｃｍ離れた位置に基材（石英ガラス、
ＴｉＯ2膜をコートしたアルカリガラス）３２を置き、
この基材の裏側に紫外線強度計３３を設置して測定し
た。As shown in FIG. 8, the method of measuring the intensity of ultraviolet rays is as follows.
At the position 60 cm away from the substrate 31 (quartz glass,
Alkaline glass 32 coated with TiO 2 film is placed,
An ultraviolet intensity meter 33 was installed on the back side of this substrate for measurement.
【００５３】この測定結果を図９（ａ），（ｂ），
（ｃ）のグラフに示す。図９（ａ）は基材を設けない場
合、図９（ｂ）は石英ガラスを置いた場合、図９（ｃ）
はＴｉＯ2膜をコートしたアルカリガラスを置いた場合
の測定結果である。この結果からわかるように、ＴｉＯ
2膜をコートしたアルカリガラスの場合には３６０ｎｍ
付近の紫外線もほとんどカットしてしまうことが分か
る。The measurement results are shown in FIGS. 9 (a), (b),
It is shown in the graph of (c). FIG. 9A shows the case where no base material is provided, FIG. 9B shows the case where quartz glass is placed, and FIG.
Is a measurement result when an alkali glass coated with a TiO2 film is placed. As you can see from this result, TiO
360 nm in the case of alkali glass coated with 2 films
You can see that most of the ultraviolet rays in the vicinity are also cut.
【００５４】[0054]
【発明の効果】以上詳述したように本発明の照明装置に
よれば、次のような効果を奏する。As described above in detail, the lighting device of the present invention has the following effects.
【００５５】（１） カバー部材の表面に存在させた半
導体物質の光触媒反応によって、悪臭、有毒な気体を効
率的に消臭、消毒することができると共に、発光部から
の紫外線を吸収し、この紫外線が外部に射出するのを防
止することができるようになる。(1) By the photocatalytic reaction of the semiconductor substance existing on the surface of the cover member, it is possible to efficiently deodorize and disinfect a foul odor and a toxic gas, and at the same time, absorb the ultraviolet rays from the light emitting part, It becomes possible to prevent the ultraviolet rays from being emitted to the outside.
【００５６】（２） 光触媒反応は酸化触媒等に比して
熱劣化や被毒元素による活性低下等がなく、脱臭、消毒
作用及び紫外線フィルタとしての寿命を大幅に延ばすこ
とができる。(2) The photocatalytic reaction is free from heat deterioration and activity reduction due to poisoning elements as compared with an oxidation catalyst and the like, and can significantly extend the deodorizing and disinfecting action and the life of the ultraviolet filter.
【００５７】（３） 照明装置は発光部にカバー部材を
設けただけの簡単な構成なので、全体をコンパクトにす
ることができ、トイレ等の狭い空間にも容易に使用する
ことができると共に安価に製造することができる。(3) Since the lighting device has a simple structure in which the light emitting portion is provided with a cover member, the lighting device can be made compact as a whole and can be easily used in a narrow space such as a toilet and at a low cost. It can be manufactured.
【００５８】（４） 安価で紫外線を出しやすい蛍光灯
を使用する場合にも、紫外線は半導体物質で吸収され、
外部に漏れることがないので、安価でしかも安全な照明
装置を提供することができる。(4) Even when using an inexpensive fluorescent lamp that easily emits ultraviolet rays, the ultraviolet rays are absorbed by the semiconductor material,
Since it does not leak to the outside, it is possible to provide an inexpensive and safe lighting device.
【００５９】（５） 反射部材の内側面に半導体物質を
施したので、この反射部材の内側面が光触媒反応によっ
て浄化され、常に良好な状態に維持することができる。(5) Since the semiconductor material is applied to the inner surface of the reflecting member, the inner surface of the reflecting member is purified by the photocatalytic reaction and can always be maintained in a good state.
【図１】本発明の第１実施例に係る照明装置を示す概略
断面図である。FIG. 1 is a schematic cross-sectional view showing a lighting device according to a first embodiment of the present invention.
【図２】本発明の第２実施例に係る照明装置を示す概略
断面図である。FIG. 2 is a schematic cross-sectional view showing a lighting device according to a second embodiment of the present invention.
【図３】本発明の変形例を示す概略断面図である。FIG. 3 is a schematic sectional view showing a modified example of the present invention.
【図４】図３のカバー部材の側壁部の変形例を示す部分
断面図である。FIG. 4 is a partial cross-sectional view showing a modified example of the side wall portion of the cover member of FIG.
【図５】消臭効果の実験に用いた実験装置を示す概略構
成図である。FIG. 5 is a schematic configuration diagram showing an experimental apparatus used for an experiment of a deodorizing effect.
【図６】消臭効果の実験結果を示すグラフである。FIG. 6 is a graph showing experimental results of deodorizing effect.
【図７】ＴｉＯ2膜の吸収スペクトル測定結果を示すグ
ラフである。FIG. 7 is a graph showing the results of absorption spectrum measurement of a TiO 2 film.
【図８】紫外線強度の測定試験に用いる装置の構成を示
す概略説明図である。FIG. 8 is a schematic explanatory diagram showing a configuration of an apparatus used for an ultraviolet intensity measurement test.
【図９】紫外線強度の測定結果を示すグラフである。FIG. 9 is a graph showing measurement results of ultraviolet intensity.
１…照明装置、２…発光部、３，７…カバー部材、４，
１０…半導体物質、８…反射板、９…透過板。DESCRIPTION OF SYMBOLS 1 ... Illumination device, 2 ... Light emission part, 3, 7 ... Cover member, 4,
10 ... Semiconductor material, 8 ... Reflective plate, 9 ... Transmissive plate.
Claims (5)
覆って設けられ、該発光部から射出された光を反射又は
透過するカバー部材とを有する照明装置において、 前記発光部から射出された光を吸収して光触媒反応を示
す半導体物質を前記カバー部材の表面に存在させたこと
を特徴とする照明装置。1. A lighting device having a light emitting portion and a cover member which covers part or all of the light emitting portion and reflects or transmits light emitted from the light emitting portion, wherein the light emitting portion emits light. An illumination device, wherein a semiconductor material that absorbs the generated light and exhibits a photocatalytic reaction is present on the surface of the cover member.
たことを特徴とする照明装置。2. The lighting device according to claim 1, wherein the semiconductor material is present on an inner surface of the cover member.
て、 前記半導体物質として、パラジウム、白金、ニッケル、
ロジウム、ニオブ、銅、スズ、酸化ルテニウム及び酸化
ニッケルのうち１種又は２種以上で修飾した半導体物質
を用いたことを特徴とする照明装置。3. The lighting device according to claim 1, wherein the semiconductor material is palladium, platinum, nickel,
A lighting device comprising a semiconductor material modified with one or more of rhodium, niobium, copper, tin, ruthenium oxide and nickel oxide.
おいて、 前記半導体物質として酸化チタン、酸化鉄、酸化タング
ステン、酸化亜鉛又はチタン酸ストロンチウムを用いた
ことを特徴とする照明装置。4. The lighting device according to claim 1, wherein titanium oxide, iron oxide, tungsten oxide, zinc oxide or strontium titanate is used as the semiconductor material.
置において、 前記発光部に紫外線を多く含む光源を用いたことを特徴
とする照明装置。5. The lighting device according to claim 1, 2, 3 or 4, wherein a light source containing a large amount of ultraviolet rays is used for the light emitting unit.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4216871A JP3036247B2 (en) | 1992-08-14 | 1992-08-14 | Lighting equipment |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4216871A JP3036247B2 (en) | 1992-08-14 | 1992-08-14 | Lighting equipment |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11241840A Division JP2000100221A (en) | 1999-08-27 | 1999-08-27 | Lighting system |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH07111104A true JPH07111104A (en) | 1995-04-25 |
| JP3036247B2 JP3036247B2 (en) | 2000-04-24 |
Family
ID=16695225
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4216871A Expired - Lifetime JP3036247B2 (en) | 1992-08-14 | 1992-08-14 | Lighting equipment |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3036247B2 (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH087643A (en) * | 1994-06-21 | 1996-01-12 | Mitsui Mining & Smelting Co Ltd | Luminaire having photocatalytic function |
| JPH09100140A (en) * | 1995-07-31 | 1997-04-15 | Toshiba Lighting & Technol Corp | Glass formed body, lighting fixture and production of glass formed body |
| JPH09140782A (en) * | 1995-11-22 | 1997-06-03 | Sharp Corp | Illuminator provided with air purifying function |
| JPH09190712A (en) * | 1995-11-10 | 1997-07-22 | Daiko Denki Kk | Lighting system with deodorizing function |
| JPH09225011A (en) * | 1995-04-28 | 1997-09-02 | Toshiba Lighting & Technol Corp | Lighting apparatus |
| JPH09231821A (en) * | 1995-12-22 | 1997-09-05 | Toto Ltd | Luminaire and method for maintaining illuminance |
| JPH09251804A (en) * | 1996-03-14 | 1997-09-22 | Toshiba Lighting & Technol Corp | Lighting system |
| JPH09314137A (en) * | 1996-05-29 | 1997-12-09 | Daikin Ind Ltd | Fluid treatment apparatus |
| EP0887104A1 (en) * | 1996-12-09 | 1998-12-30 | Toshiba Lighting & Technology Corporation | Photocatalyst, light source and lighting device |
| FR2864844A1 (en) * | 2004-01-07 | 2005-07-08 | Saint Gobain | A lighting device for use in tunnels and vehicular, boat, or aircraft lights and airport landing lights has a cover coated with a photocatalytic layer able to degrade contaminants even in low light |
| JP2018092927A (en) * | 2016-11-29 | 2018-06-14 | 熊本電気工業株式会社 | Luminaire and cover for lighting fixture |
-
1992
- 1992-08-14 JP JP4216871A patent/JP3036247B2/en not_active Expired - Lifetime
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH087643A (en) * | 1994-06-21 | 1996-01-12 | Mitsui Mining & Smelting Co Ltd | Luminaire having photocatalytic function |
| JPH09225011A (en) * | 1995-04-28 | 1997-09-02 | Toshiba Lighting & Technol Corp | Lighting apparatus |
| JPH09100140A (en) * | 1995-07-31 | 1997-04-15 | Toshiba Lighting & Technol Corp | Glass formed body, lighting fixture and production of glass formed body |
| JPH09190712A (en) * | 1995-11-10 | 1997-07-22 | Daiko Denki Kk | Lighting system with deodorizing function |
| JPH09140782A (en) * | 1995-11-22 | 1997-06-03 | Sharp Corp | Illuminator provided with air purifying function |
| JPH09231821A (en) * | 1995-12-22 | 1997-09-05 | Toto Ltd | Luminaire and method for maintaining illuminance |
| JPH09251804A (en) * | 1996-03-14 | 1997-09-22 | Toshiba Lighting & Technol Corp | Lighting system |
| JPH09314137A (en) * | 1996-05-29 | 1997-12-09 | Daikin Ind Ltd | Fluid treatment apparatus |
| EP0887104A1 (en) * | 1996-12-09 | 1998-12-30 | Toshiba Lighting & Technology Corporation | Photocatalyst, light source and lighting device |
| EP0887104A4 (en) * | 1996-12-09 | 2001-01-10 | Toshiba Lighting & Technology | Photocatalyst, light source and lighting device |
| EP1352881A2 (en) * | 1996-12-09 | 2003-10-15 | Toshiba Lighting & Technology Corporation | Photocatalyst, lightsource and lighting device |
| EP1352881A3 (en) * | 1996-12-09 | 2004-01-28 | Toshiba Lighting & Technology Corporation | Photocatalyst, lightsource and lighting device |
| FR2864844A1 (en) * | 2004-01-07 | 2005-07-08 | Saint Gobain | A lighting device for use in tunnels and vehicular, boat, or aircraft lights and airport landing lights has a cover coated with a photocatalytic layer able to degrade contaminants even in low light |
| WO2005070540A1 (en) * | 2004-01-07 | 2005-08-04 | Saint-Gobain Glass France | Self-cleaning lighting device |
| US7985443B2 (en) | 2004-01-07 | 2011-07-26 | Saint-Gobain Glass France | Self-cleaning lighting device |
| JP2018092927A (en) * | 2016-11-29 | 2018-06-14 | 熊本電気工業株式会社 | Luminaire and cover for lighting fixture |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3036247B2 (en) | 2000-04-24 |
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