JPH08277147A - Plate glass - Google Patents
Plate glassInfo
- Publication number
- JPH08277147A JPH08277147A JP7100445A JP10044595A JPH08277147A JP H08277147 A JPH08277147 A JP H08277147A JP 7100445 A JP7100445 A JP 7100445A JP 10044595 A JP10044595 A JP 10044595A JP H08277147 A JPH08277147 A JP H08277147A
- Authority
- JP
- Japan
- Prior art keywords
- plate glass
- photocatalyst
- glass
- room
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000005357 flat glass Substances 0.000 title claims abstract description 39
- 239000011941 photocatalyst Substances 0.000 claims abstract description 27
- 229910003849 O-Si Inorganic materials 0.000 claims abstract description 5
- 229910003872 O—Si Inorganic materials 0.000 claims abstract description 5
- 238000013032 photocatalytic reaction Methods 0.000 claims description 8
- 229910010413 TiO 2 Inorganic materials 0.000 claims 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract description 28
- 239000011347 resin Substances 0.000 abstract description 12
- 229920005989 resin Polymers 0.000 abstract description 12
- 239000002243 precursor Substances 0.000 abstract description 8
- 230000001877 deodorizing effect Effects 0.000 abstract description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 4
- 239000002904 solvent Substances 0.000 abstract description 4
- 239000004925 Acrylic resin Substances 0.000 abstract description 2
- 229920000178 Acrylic resin Polymers 0.000 abstract description 2
- 238000006243 chemical reaction Methods 0.000 abstract description 2
- 238000000354 decomposition reaction Methods 0.000 abstract description 2
- 235000019645 odor Nutrition 0.000 description 21
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 17
- 239000011521 glass Substances 0.000 description 15
- 235000019504 cigarettes Nutrition 0.000 description 8
- 239000000463 material Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 4
- 238000001035 drying Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 238000010304 firing Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 description 2
- INNSZZHSFSFSGS-UHFFFAOYSA-N acetic acid;titanium Chemical compound [Ti].CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O INNSZZHSFSFSGS-UHFFFAOYSA-N 0.000 description 2
- 235000019441 ethanol Nutrition 0.000 description 2
- 229960002715 nicotine Drugs 0.000 description 2
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 2
- 238000006864 oxidative decomposition reaction Methods 0.000 description 2
- RCYJPSGNXVLIBO-UHFFFAOYSA-N sulfanylidenetitanium Chemical compound [S].[Ti] RCYJPSGNXVLIBO-UHFFFAOYSA-N 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 2
- 102100040160 Rabankyrin-5 Human genes 0.000 description 1
- 101710086049 Rabankyrin-5 Proteins 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 206010047700 Vomiting Diseases 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000005329 float glass Substances 0.000 description 1
- 239000005338 frosted glass Substances 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 230000011514 reflex Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 230000000391 smoking effect Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- -1 titanium alkoxide Chemical class 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 230000008673 vomiting Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は板ガラスに関し、特に部
屋の中の様々な臭いを分解除去することができる窓ガラ
ス等の内装材に用いられる板ガラスに関するものであ
る。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a plate glass, and more particularly to a plate glass used as an interior material such as a window glass capable of decomposing and removing various odors in a room.
【０００２】[0002]
【従来の技術】従来、部屋の中の様々な臭いを除去する
装置として、実開平３−３０３１４号に示されるよう
に、蛍光灯の上部に２５４ｎｍの光透過面を作製し、そ
こを通過した２５４ｎｍの光で蛍光灯の上方に設けられ
た光触媒を励起して脱臭処理する脱臭機構付き蛍光灯照
明器具が知られている。また、空気清浄機等も知られて
いる。2. Description of the Related Art Conventionally, as a device for removing various odors in a room, a light transmission surface of 254 nm was formed on the upper part of a fluorescent lamp as shown in Japanese Utility Model Laid-Open No. 3-30314 and passed through it. BACKGROUND ART A fluorescent lamp illuminator with a deodorizing mechanism that excites a photocatalyst provided above a fluorescent lamp with light of 254 nm to perform deodorizing is known. Air cleaners and the like are also known.
【０００３】[0003]
【発明が解決しようとする課題】しかしながら、前記従
来の照明器具の場合、蛍光灯内部に蛍光塗料を塗布しな
い面を作るという通常の製造工程では行わない新たな、
非常に難しい工程を経る必要がある。また、蛍光灯菅の
材質も２５４ｎｍの光を透過するものである必要があ
り、それには高価な石英質ガラスを用いねばならず、コ
ストアップにつながる。また、光触媒についても、２５
４ｎｍ（４．８８ｅＶ）と高いエネルギの光でしか光触
媒反応を起こさないものであるので、エネルギコスト的
にも不利である。なお、この２５４ｎｍの光は一般には
殺菌灯として用いられている光であり、人体、特に目に
対しては有害な光であるので、この波長の光を用いるこ
とは好ましくない。However, in the case of the above-described conventional lighting fixture, a new manufacturing process which is not performed in the usual manufacturing process of forming a surface not coated with fluorescent paint inside the fluorescent lamp,
It has to go through a very difficult process. In addition, the material of the fluorescent lamp must also be one that transmits light of 254 nm, and expensive quartz glass must be used for that, which leads to an increase in cost. For photocatalyst, 25
Since the photocatalytic reaction occurs only with light having a high energy of 4 nm (4.88 eV), it is also disadvantageous in terms of energy cost. Note that this 254 nm light is generally used as a germicidal lamp and is harmful to the human body, especially to the eyes. Therefore, it is not preferable to use light of this wavelength.
【０００４】また、空気清浄機等の室内に新たに設置す
る装置は高価であり、そのイニシャルコストに加え、ユ
ーティリティ等のランニングコストや、定期的に掃除す
るなどのメンテナンスを必要とする。本発明の目的は、
部屋の中の様々な臭いを、複雑な装置や新たな装置を設
けることなく、通常の蛍光灯や白熱電灯からの光や太陽
光で分解除去できるようにした板ガラスを提供すること
にある。Further, an apparatus newly installed in the room such as an air purifier is expensive, and in addition to its initial cost, running costs such as utilities and maintenance such as periodical cleaning are required. The purpose of the present invention is to
An object of the present invention is to provide a plate glass capable of decomposing and removing various odors in a room with light from a normal fluorescent lamp or incandescent lamp or sunlight without providing a complicated device or a new device.
【０００５】[0005]
【課題を解決するための手段】本発明の板ガラスは、上
記目的を達成すべく、光触媒をその表面に担持したこと
を特徴とする。本発明でいう「板ガラス」には、例え
ば、建築物、自動車等の分野において内装材などとして
用いられるガラスが包含される。即ち、住宅・オフィス
などの居住空間の開口部に設けられるガラス、外界或い
は居住空間内部の透視性のために設けられるガラス、外
界からの自然光の導入のために或いは外界との障壁とし
て用いるガラスなどがある。具体的には、例えば、室内
と屋外とをあるいは部屋と部屋とを隔離する窓ガラス、
扉等に取り付けられているガラス板、部屋の中に置くガ
ラス製の間仕切りやブラインド、食器棚や本棚等の家具
に取り付けられているガラス板、自動車用窓ガラス等が
あるが、本発明はこれらの種類に限定されるものではな
い。また、これらの板ガラスは透明ガラス、曇ガラス、
模様ガラス、装飾ガラス等であってよい。The plate glass of the present invention is characterized in that a photocatalyst is carried on the surface thereof in order to achieve the above object. The "plate glass" in the present invention includes, for example, glass used as an interior material in the fields of buildings, automobiles and the like. That is, glass provided in an opening of a living space such as a house or office, glass provided for the transparency of the outside world or the inside of the living space, glass used for introducing natural light from the outside world or as a barrier to the outside world, etc. There is. Specifically, for example, a window glass for separating the room from the outdoors or the room to the room,
There are glass plates attached to doors, glass partitions and blinds placed in the room, glass plates attached to furniture such as cupboards and bookshelves, automobile window glass, etc. It is not limited to the type. In addition, these plate glasses are transparent glass, frosted glass,
It may be patterned glass, decorative glass or the like.
【０００６】該光触媒としては、４ｅＶ以下の低エネル
ギ光で光触媒反応を起こすもの、特に酸化チタンが適し
ている。該酸化チタンはルチル形あるいはアナターゼ
形、またはこれらの共存形のいずれでもかまわない。よ
り低エネルギの光に反応させるにはルチル形が適してお
り、また反応の活性を高めるためにはアナターゼ形が適
している。As the photocatalyst, one that causes a photocatalytic reaction with low energy light of 4 eV or less, particularly titanium oxide is suitable. The titanium oxide may be in the rutile type or the anatase type, or in the coexisting form thereof. The rutile form is suitable for reacting with lower energy light, and the anatase form is suitable for increasing the activity of the reaction.
【０００７】板ガラスの表面に酸化チタン光触媒を担持
させる場合、その界面をＴｉ−Ｏ−Ｓｉ結合で接合させ
ることが望ましい。このようにＴｉ−Ｏ−Ｓｉ結合で接
合させることは、以下述べるように、加熱により酸化チ
タンとなる酸化チタンの前駆体と有機物樹脂との溶液を
出発原料として用いることにより可能である。かかる酸
化チタンの前駆体としては、チタンアルコキシド、チタ
ン塩化物、チタン硫化物、チタン酢酸塩等が使用できる
が、有機物樹脂との相溶性の関係から、アルコール類を
相溶性溶媒として用いる場合はチタンアルコキシド、水
を相溶性溶媒として用いる場合はチタン塩化物、チタン
硫化物、チタン酢酸塩を選択することが好ましい。しか
し、前記先駆体と有機物樹脂とが相溶する場合はどの組
み合わせを選択してもかまわない。When the titanium oxide photocatalyst is carried on the surface of the plate glass, it is desirable to bond the interface with a Ti--O--Si bond. As described below, the Ti-O-Si bond can be used for bonding by using a solution of a titanium oxide precursor that becomes titanium oxide by heating and an organic resin as a starting material. As the titanium oxide precursor, titanium alkoxide, titanium chloride, titanium sulfide, titanium acetate and the like can be used. However, when alcohols are used as a compatible solvent, titanium is used because of the compatibility with the organic resin. When alkoxide or water is used as a compatible solvent, titanium chloride, titanium sulfide or titanium acetate is preferably selected. However, when the precursor and the organic resin are compatible with each other, any combination may be selected.
【０００８】また、有機物樹脂としては、アクリル系、
オレフィン系等が一般的であるが、製造工程中の焼成工
程で酸化分解することが必要であるため、分解温度が２
００℃以上かつ焼成温度以下の樹脂であって、更に該酸
化チタンの前駆体との相溶性があれば良く、モノマーの
種類や分子量によって限定されるものではない。As the organic resin, acrylic resin,
Olefin-based compounds are generally used, but the decomposition temperature is 2 because oxidative decomposition is required in the firing process during the manufacturing process.
It is sufficient that the resin is at least 00 ° C. and not more than the firing temperature, and it is compatible with the titanium oxide precursor, and is not limited by the type or molecular weight of the monomer.
【０００９】上記したように、選定された前駆体と有機
物樹脂とを相溶性のある溶媒に溶解してなる溶液を酸化
チタン光触媒製造用の出発原料とする。即ち、この出発
原料から光触媒を得るためには、例えば担持体となる板
ガラスをこの原料液にディップするか、または板ガラス
に該原料液を塗布するかスプレーし、乾燥した後焼成す
ればよい。この乾燥は、１５０℃以下で３０分以上行う
ことが好ましい。液担持後乾燥までおよび乾燥後焼成ま
での昇温速度は１０℃／分以下が好ましい。また最終焼
成工程は基材の耐熱性を考慮して行う必要があるが、５
５０℃以下の温度で焼成することが好ましい。本発明の
光触媒担持板ガラスは、上記したようにして得られる
が、これらの方法に限定されるものではなく、例えば、
フロートガラスのような板ガラスの場合、ガラス製造時
のオンラインでスプレー適用してもよいことは言うまで
もない。As described above, a solution prepared by dissolving the selected precursor and the organic resin in a compatible solvent is used as a starting material for producing a titanium oxide photocatalyst. That is, in order to obtain a photocatalyst from this starting raw material, for example, a plate glass serving as a carrier may be dipped in this raw material liquid, or the raw material liquid may be applied or sprayed on the plate glass, dried and then baked. This drying is preferably performed at 150 ° C. or lower for 30 minutes or more. The temperature rising rate from the liquid loading to the drying and the drying to the firing is preferably 10 ° C./min or less. In addition, it is necessary to consider the heat resistance of the base material in the final baking step,
Baking at a temperature of 50 ° C. or lower is preferable. The photocatalyst-supporting plate glass of the present invention is obtained as described above, but is not limited to these methods.
It goes without saying that in the case of flat glass such as float glass, spray application may be performed online during glass production.
【００１０】[0010]
【作用】上記酸化チタン等の光触媒は、そのバンドギャ
ップが３〜３．２ｅＶと小さいので、エネルギの小さい
光でも容易に励起される。日常生活で通常用いられる蛍
光灯や白熱電灯の光には、４．５ｅＶ以上の高いエネル
ギを有する紫外光はほとんど含まれていないが、酸化チ
タンのバンドギャップ以上のエネルギを有する光は含ま
れているので、これらの通常光により本発明で用いる光
触媒は容易に励起され光触媒反応を引き起こす。また、
通常の透明板ガラスを透過してくる太陽光は３．７ｅＶ
以下のエネルギ光であるが、これも酸化チタンのバンド
キャップ以上のエネルギを有するので、これら板ガラス
を透過してくる太陽光により本発明で用いる光触媒は容
易に励起され光触媒反応を引き起こす。この光触媒反応
によりニコチン、タール、ヤニ等のタバコ臭やペット臭
やトイレ臭などの室内に発生する悪臭は容易に分解され
る。Since the photocatalyst such as titanium oxide has a small band gap of 3 to 3.2 eV, it can be easily excited by light having a small energy. The light of fluorescent lamps and incandescent lamps, which are usually used in daily life, contains almost no ultraviolet light having high energy of 4.5 eV or more, but contains light having energy more than the band gap of titanium oxide. Therefore, the photocatalyst used in the present invention is easily excited by these ordinary lights to cause a photocatalytic reaction. Also,
The sunlight that passes through the ordinary transparent glass is 3.7 eV
The energy light is as follows, but since it also has energy higher than the band cap of titanium oxide, the photocatalyst used in the present invention is easily excited by sunlight passing through these plate glasses to cause a photocatalytic reaction. Due to this photocatalytic reaction, odors such as nicotine, tar, tar and the like that are produced in the room such as cigarette odor, pet odor and toilet odor are easily decomposed.
【００１１】また、ガラスはＳｉＯ2 が主成分であり、
これに光触媒としての酸化チタンを担持させ、該板ガラ
スの表面と該光触媒との界面をＴｉ−Ｏ−Ｓｉ結合で接
合せしめる場合には、光触媒の出発原料として有機物樹
脂と酸化チタンの前駆体との混合液を用い、これらを構
成している有機残基の酸化分解反応によって生成する燃
焼熱により板ガラスの表面にＴｉ−Ｏ−Ｓｉ結合を形成
させている。かくして基材と光触媒とは強固な結合で接
合されることになり、光触媒は脱落しない。上記方法で
作製した光触媒担持板ガラスによれば、蛍光灯や白熱電
灯などの通常の照明器具より発生する光や板ガラスを透
過してくる太陽光で光触媒反応が進行し、周囲のタバコ
臭等の室内で発生する悪臭が分解除去される。Further, the glass is mainly composed of SiO 2 ,
When titanium oxide as a photocatalyst is supported on this and the interface between the surface of the plate glass and the photocatalyst is bonded by a Ti-O-Si bond, an organic resin and a precursor of titanium oxide are used as starting materials for the photocatalyst. A Ti-O-Si bond is formed on the surface of the plate glass by using a mixed solution and by the combustion heat generated by the oxidative decomposition reaction of the organic residues constituting them. Thus, the base material and the photocatalyst are joined together by a strong bond, and the photocatalyst does not fall off. According to the photocatalyst-supporting plate glass produced by the above method, the photocatalytic reaction progresses by the light generated from a normal lighting fixture such as a fluorescent lamp or an incandescent lamp and the sunlight passing through the plate glass, and the indoor odor such as cigarette odor in the surroundings The offensive odor generated in is decomposed and removed.
【００１２】[0012]
【実施例】透明な窓ガラスに、酸化チタンの前駆体であ
るチタンイソプロポキシド７６０ｇと有機物樹脂４００
ｇとをエチルアルコール８４０ｇに溶解した溶液を塗布
した。この窓ガラスを、６０℃で１時間乾燥し、その後
毎分１℃の速度で３５０℃まで昇温し、３５０℃で１２
時間焼成した。この処理で有機物樹脂は完全に除去さ
れ、更にチタンイソプロポキシドはアナターゼ型を主体
とする酸化チタンに変化し、窓ガラスの表面に強固に酸
化チタンを被覆できた。得られた酸化チタンの膜厚は約
０．３ミクロンであった。EXAMPLE A transparent window glass was used, and 760 g of titanium isopropoxide, which is a precursor of titanium oxide, and 400 of organic resin.
A solution obtained by dissolving g and 840 g in ethyl alcohol was applied. This window glass is dried at 60 ° C. for 1 hour, then heated to 350 ° C. at a rate of 1 ° C./min, and heated at 350 ° C. for 12 hours.
Burned for hours. By this treatment, the organic resin was completely removed, and the titanium isopropoxide was changed to titanium oxide mainly composed of anatase type, and the surface of the window glass could be firmly coated with titanium oxide. The thickness of the obtained titanium oxide was about 0.3 micron.
【００１３】脱臭・消臭効果の実験を以下の通りに行っ
た。広さ３．６ｍ×２．７ｍ、天井高さ２．６ｍの会議
室をＡおよびＢの二室使用した。各部屋には１．２ｍの
蛍光灯（４０Ｗ）６本が天井に取り付けられており照明
は点灯されている。実験は夜行ったため太陽光はない。
両室とも高さ１４５０ｍｍ、幅８２０ｍｍの窓ガラスが
４枚づつ取り付けられている。Ａ室には前記光触媒を担
持した窓ガラス４枚、Ｂ室には光触媒を担持していない
通常の窓ガラス４枚が取り付けられている。両室とも換
気扉はない。この両室に６名のタバコ愛用者（男性）が
それぞれ入室し、常に二人が喫煙するようにして１時間
喫煙を行った。喫煙実験終了後、被験者全員が退室し、
その直後と１時間後にタバコ非愛用者（女性）５名がＡ
室、Ｂ室にそれぞれ入室し、その時のタバコ煙による臭
気や生理的反応の程度を評価し、その結果を表１に示
す。Experiments for deodorizing and deodorizing effects were conducted as follows. Two meeting rooms A and B were used, each having a size of 3.6 m × 2.7 m and a ceiling height of 2.6 m. In each room, six 1.2 m fluorescent lamps (40 W) are attached to the ceiling and the lights are turned on. The experiment was done at night, so there is no sunlight.
Each of the two chambers is equipped with four window glasses each having a height of 1450 mm and a width of 820 mm. Four glass windows supporting the photocatalyst are attached to the chamber A, and four ordinary glass windows not supporting the photocatalyst are attached to the chamber B. There is no ventilation door in both rooms. Six cigarette users (male) entered each of these rooms and smoked for one hour so that two people always smoked. After the smoking experiment, all the subjects left the room,
Immediately after and 1 hour later, 5 non-cigarette users (female)
Room B and Room B were respectively entered, and the odor and the degree of physiological reaction due to cigarette smoke at that time were evaluated, and the results are shown in Table 1.
【００１４】臭気の評価は次の６段階で行った。 ランク０：「無臭」；全く感知しえない。 ランク１：「明確」；正常な人に容易に嗅ぎだしうる
が、不快ではない。 ランク２：「普通」；愉快ではないが不快でもない。室
内での許容の強さ。 ランク３：「強し」；不快である。空気は嫌悪される。 ランク４：「猛烈」；猛烈であり不快である。 ランク５：「耐えれず」；嘔吐を催す。The odor was evaluated in the following 6 stages. Rank 0: "no odor"; no sense Rank 1: “Clear”; can be easily sniffed by a normal person, but is not uncomfortable. Rank 2: "Normal"; Not unpleasant but not uncomfortable. The strength of tolerance in the room. Rank 3: "Strong"; unpleasant. The air is disliked. Rank 4: "Furious"; Furious and uncomfortable. Rank 5: "Unbearable"; Vomiting occurs.
【００１５】[0015]
【表１】 [Table 1]
【００１６】光触媒を担持した窓ガラスを取り付けたＡ
室は、通常の窓ガラスを取り付けたＢ室と比べ、５人の
パネラの臭気判定の平均値は直後で１．２、１時間後で
０．４と小さい値であった。このように、光触媒を担持
した窓ガラスを設置した部屋ではタバコ臭等の悪臭が分
解されていることが確認できた。A equipped with a window glass carrying a photocatalyst
In the room, the average value of the odor judgment of the five panelers was 1.2, which was a small value, 0.4 after 1 hour, compared with the room B in which a normal window glass was attached. As described above, it was confirmed that a bad odor such as cigarette odor was decomposed in the room where the window glass supporting the photocatalyst was installed.
【００１７】[0017]
【発明の効果】本発明によれば、板ガラスの表面に光触
媒が担持されているので、特別な脱臭装置を設けること
なく室内のタバコ臭等の悪臭を容易に分解できる。ま
た、本発明で用いる光触媒は、通常の室内で得られる蛍
光灯や白熱電灯などの４ｅＶ以下の低エネルギ光や板ガ
ラスを透過してくる太陽光により光触媒反応を起こすの
で、ニコチン、タール、ヤニ等のタバコ臭やペット臭や
トイレ臭等の種々の臭いを分解除去することができる。According to the present invention, since the photocatalyst is carried on the surface of the plate glass, it is possible to easily decompose a bad smell such as a cigarette odor in a room without providing a special deodorizing device. Further, the photocatalyst used in the present invention causes a photocatalytic reaction by low energy light of 4 eV or less such as fluorescent lamps and incandescent lamps obtained in a normal room and sunlight passing through plate glass. Therefore, nicotine, tar, tar, etc. It is possible to decompose and remove various odors such as cigarette odor, pet odor and toilet odor.
Claims (4)
る板ガラス。1. A plate glass having a surface supported with a photocatalyst.
とする請求項１記載の板ガラス。2. The plate glass according to claim 1, wherein the photocatalyst is TiO 2 .
Ｏ−Ｓｉ結合で接合されていることを特徴とする請求項
２記載の板ガラス。3. The interface between the photocatalyst and the plate glass is Ti--
The flat glass according to claim 2, which is joined by an O-Si bond.
光触媒反応を起こすものであることを特徴とする請求項
１乃至３の何れかに記載の板ガラス。4. The plate glass according to claim 1, wherein the photocatalyst causes a photocatalytic reaction with energy light of 4 eV or less.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7100445A JPH08277147A (en) | 1995-03-31 | 1995-03-31 | Plate glass |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7100445A JPH08277147A (en) | 1995-03-31 | 1995-03-31 | Plate glass |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH08277147A true JPH08277147A (en) | 1996-10-22 |
Family
ID=14274130
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7100445A Pending JPH08277147A (en) | 1995-03-31 | 1995-03-31 | Plate glass |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH08277147A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08309202A (en) * | 1995-05-22 | 1996-11-26 | Bridgestone Corp | Photocatalytic body |
| JPH09231821A (en) * | 1995-12-22 | 1997-09-05 | Toto Ltd | Luminaire and method for maintaining illuminance |
| JPH10165821A (en) * | 1996-12-09 | 1998-06-23 | Toshiba Lighting & Technol Corp | Photocatalyst body, light source and lighting fixture |
| JP2000063118A (en) * | 1998-08-14 | 2000-02-29 | Jsr Corp | Titanium dioxide precursor composition and titanium dioxide |
| KR100475687B1 (en) * | 2002-10-26 | 2005-03-10 | 한국과학기술원 | Preparation method of titania particles |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63100042A (en) * | 1986-10-14 | 1988-05-02 | Nippon Sheet Glass Co Ltd | Glass article difficult-to be dirtied |
| JPH06205977A (en) * | 1992-09-01 | 1994-07-26 | Toto Ltd | Production of photocatalystic composition and photocatalystic composition |
| JPH06278241A (en) * | 1992-09-22 | 1994-10-04 | Takenaka Komuten Co Ltd | Building material |
| JPH06287090A (en) * | 1993-03-31 | 1994-10-11 | Nippon Muki Co Ltd | Formation of functional thin film |
| JPH0751646A (en) * | 1993-08-12 | 1995-02-28 | Ishihara Sangyo Kaisha Ltd | Method for cleaning off contaminant on solid matter surface |
-
1995
- 1995-03-31 JP JP7100445A patent/JPH08277147A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63100042A (en) * | 1986-10-14 | 1988-05-02 | Nippon Sheet Glass Co Ltd | Glass article difficult-to be dirtied |
| JPH06205977A (en) * | 1992-09-01 | 1994-07-26 | Toto Ltd | Production of photocatalystic composition and photocatalystic composition |
| JPH06278241A (en) * | 1992-09-22 | 1994-10-04 | Takenaka Komuten Co Ltd | Building material |
| JPH06287090A (en) * | 1993-03-31 | 1994-10-11 | Nippon Muki Co Ltd | Formation of functional thin film |
| JPH0751646A (en) * | 1993-08-12 | 1995-02-28 | Ishihara Sangyo Kaisha Ltd | Method for cleaning off contaminant on solid matter surface |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08309202A (en) * | 1995-05-22 | 1996-11-26 | Bridgestone Corp | Photocatalytic body |
| JPH09231821A (en) * | 1995-12-22 | 1997-09-05 | Toto Ltd | Luminaire and method for maintaining illuminance |
| JPH10165821A (en) * | 1996-12-09 | 1998-06-23 | Toshiba Lighting & Technol Corp | Photocatalyst body, light source and lighting fixture |
| JP2000063118A (en) * | 1998-08-14 | 2000-02-29 | Jsr Corp | Titanium dioxide precursor composition and titanium dioxide |
| KR100475687B1 (en) * | 2002-10-26 | 2005-03-10 | 한국과학기술원 | Preparation method of titania particles |
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