JP5283673B2 - 半導体装置の製造方法、成膜方法および基板処理装置 - Google Patents
半導体装置の製造方法、成膜方法および基板処理装置 Download PDFInfo
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- 238000000034 method Methods 0.000 title claims description 116
- 239000000758 substrate Substances 0.000 title claims description 85
- 238000004519 manufacturing process Methods 0.000 title claims description 21
- 239000004065 semiconductor Substances 0.000 title claims description 21
- 238000012545 processing Methods 0.000 title claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 175
- 230000005284 excitation Effects 0.000 claims description 23
- 239000007789 gas Substances 0.000 description 205
- 238000000231 atomic layer deposition Methods 0.000 description 22
- 230000015572 biosynthetic process Effects 0.000 description 13
- 238000001179 sorption measurement Methods 0.000 description 12
- 238000010586 diagram Methods 0.000 description 10
- 238000011144 upstream manufacturing Methods 0.000 description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 238000000151 deposition Methods 0.000 description 4
- 230000008021 deposition Effects 0.000 description 4
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 3
- 238000005229 chemical vapour deposition Methods 0.000 description 3
- 235000012431 wafers Nutrition 0.000 description 3
- 230000007547 defect Effects 0.000 description 2
- MROCJMGDEKINLD-UHFFFAOYSA-N dichlorosilane Chemical compound Cl[SiH2]Cl MROCJMGDEKINLD-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000010574 gas phase reaction Methods 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000036632 reaction speed Effects 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000009832 plasma treatment Methods 0.000 description 1
- 239000012495 reaction gas Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/455—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
- C23C16/45523—Pulsed gas flow or change of composition over time
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
- C23C16/34—Nitrides
- C23C16/345—Silicon nitride
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/455—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
- C23C16/45523—Pulsed gas flow or change of composition over time
- C23C16/45525—Atomic layer deposition [ALD]
- C23C16/45527—Atomic layer deposition [ALD] characterized by the ALD cycle, e.g. different flows or temperatures during half-reactions, unusual pulsing sequence, use of precursor mixtures or auxiliary reactants or activations
- C23C16/45536—Use of plasma, radiation or electromagnetic fields
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/52—Controlling or regulating the coating process
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Description
なお、従来の技術としては、枚葉式であって、反応室内に酸素(O)ラジカルを流し続け、TEOSガスを間欠的に約2秒づつ供給し、凝集膜を形成する成膜装置がある。この装置には、TEOSボンベから反応室へ供給されるガス供給系にガス溜り303、304が設けられ、ガス溜りに溜めたTEOSガスを反応室へ供給させるようになっている。また、ガス溜りを2つ設けることで、一方のガス溜りの使用中に他方のガス溜りにガスを溜めることが可能となり、スループットを向上している。しかし、このガス溜りを設けた装置は反応室容積の小さい枚葉装置についてのものであり、反応室容積の大きな縦型装置についてのものではない。また、反応室内にプロセスガスa、bを交互に供給するALD装置についてのものでもない。
基板を収容した反応室にプラズマ励起されていない第1のプロセスガスを供給し前記反応室の圧力を昇圧しつつ前記基板を前記第1のプロセスガスに晒す工程と、
その後、前記反応室内の雰囲気を排気する第1の排気工程と、
前記反応室にプラズマ励起された第2のプロセスガスを供給し前記反応室の圧力を所定圧に維持しつつ前記基板を前記第2のプロセスガスに晒す工程と、
その後、前記反応室の雰囲気を排気する第2の排気工程と、
を有する半導体装置の製造方法が提供される。
また、本発明によれば、
基板を収容した反応室に、少なくとも予めガス溜りに溜めたプラズマ励起されていない第1のプロセスガスを供給し前記反応室の圧力を昇圧しつつ前記基板を前記第1のプロセスガスに晒す工程と、
その後、前記反応室内の雰囲気を排気する第1の排気工程と、
前記反応室にプラズマ励起された第2のプロセスガスを供給し前記反応室の圧力を所定圧に維持しつつ前記基板を前記第2のプロセスガスに晒す工程と、
その後、前記反応室の雰囲気を排気する第2の排気工程と、
を有する半導体装置の製造方法が提供される。
また、本発明によれば、
基板を収容した反応室にプラズマ励起されていない第1のプロセスガスを供給し前記反応室の圧力を昇圧しつつ前記基板を前記第1のプロセスガスに晒す工程と、
その後、前記反応室内の雰囲気を排気する第1の排気工程と、
前記反応室にプラズマ励起された第2のプロセスガスを供給し前記反応室の圧力を所定圧に維持しつつ前記基板を前記第2のプロセスガスに晒す工程と、
その後、前記反応室の雰囲気を排気する第2の排気工程と、
を有する成膜方法が提供される。
また、本発明によれば、
基板を収容した反応室に、少なくとも予めガス溜りに溜めたプラズマ励起されていない第1のプロセスガスを供給し前記反応室の圧力を昇圧しつつ前記基板を前記第1のプロセスガスに晒す工程と、
その後、前記反応室内の雰囲気を排気する第1の排気工程と、
前記反応室にプラズマ励起された第2のプロセスガスを供給し前記反応室の圧力を所定圧に維持しつつ前記基板を前記第2のプロセスガスに晒す工程と、
その後、前記反応室の雰囲気を排気する第2の排気工程と、
を有する成膜方法が提供される。
また、本発明によれば、
基板を収容する反応室と、
前記反応室を、排気バルブを介して排気する排気路と、
前記反応室に第1供給バルブを介して第1のプロセスガスを供給する第1の供給路と、
前記反応室に第2供給バルブを介して第2のプロセスガスを供給する第2の供給路と、
前記第2のプロセスガスをプラズマ励起するプラズマ励起手段と、
前記反応室にプラズマ励起されていない第1のプロセスガスを供給し前記反応室の圧力を昇圧しつつ前記基板を第1のプロセスガスに晒し、前記反応室内の雰囲気を排気し、前記反応室にプラズマ励起された第2のプロセスガスを供給し前記反応室の圧力を所定圧に維持しつつ前記基板を前記第2のプロセスガスに晒し、前記反応室の雰囲気を排気するよう、前記排気バルブ、前記第1供給バルブ、前記第2供給バルブおよび前記プラズマ励起手段を制御する制御手段と、を備えた基板処理装置が提供される。
また、本発明によれば、
基板を収容する反応室と、
前記反応室を、排気バルブを介して排気する排気路と、
前記反応室に第1供給バルブを介して第1のプロセスガスを供給する第1の供給路と、
前記反応室に第2供給バルブを介して第2のプロセスガスを供給する第2の供給路と、
前記第1の供給路に設けられ、前記第1のプロセスガスを溜めるガス溜りと、
前記第2のプロセスガスをプラズマ励起するプラズマ励起手段と、
前記反応室に少なくとも予めガス溜りに溜めたプラズマ励起されていない第1のプロセスガスを供給し前記反応室の圧力を昇圧しつつ前記基板を第1のプロセスガスに晒し、前記反応室内の雰囲気を排気し、前記反応室にプラズマ励起された第2のプロセスガスを供給し前記反応室の圧力を所定圧に維持しつつ前記基板を前記第2のプロセスガスに晒し、前記反応室の雰囲気を排気するよう、前記排気バルブ、前記第1供給バルブ、前記第2供給バルブおよび前記プラズマ励起手段を制御する制御手段と、を備えた基板処理装置が提供される。
また、好ましくは、前記ガス溜りの容積を前記反応室の容積の1/1000〜3/1000とする。
以下に本発明の実施の形態を説明する。
20 反応室(炉)
22〜25 バルブ
26 ポンプ
38 第2供給配管
40 排気配管
41 第1供給配管
W 基板
Claims (12)
- 基板を収容した反応室にプラズマ励起されていない第1のプロセスガスを供給し前記反応室の圧力を昇圧しつつ前記基板を前記第1のプロセスガスに晒す工程と、
その後、前記反応室内の雰囲気を排気する第1の排気工程と、
前記反応室にプラズマ励起された第2のプロセスガスを供給し前記反応室の圧力を所定圧に維持しつつ前記基板を前記第2のプロセスガスに晒す工程と、
その後、前記反応室の雰囲気を排気する第2の排気工程と、
を有する半導体装置の製造方法。 - 基板を収容した反応室に、少なくとも予めガス溜りに溜めたプラズマ励起されていない第1のプロセスガスを供給し前記反応室の圧力を昇圧しつつ前記基板を前記第1のプロセスガスに晒す工程と、
その後、前記反応室内の雰囲気を排気する第1の排気工程と、
前記反応室にプラズマ励起された第2のプロセスガスを供給し前記反応室の圧力を所定圧に維持しつつ前記基板を前記第2のプロセスガスに晒す工程と、
その後、前記反応室の雰囲気を排気する第2の排気工程と、
を有する半導体装置の製造方法。 - 前記基板を前記第1のプロセスガスに晒す際には、前記反応室内の雰囲気の排気を実質的に止めた状態で行う請求項1または請求項2に記載の半導体装置の製造方法。
- 前記基板を前記第1のプロセスガスに晒す際には、前記反応室内の圧力を266Pa以上にする請求項1乃至請求項3のうちいずれか1項に記載の半導体装置の製造方法。
- 前記反応室内の所定圧力は、10〜100Paである請求項1乃至請求項4のうちいずれか1項に記載の半導体装置の製造方法。
- 前記反応室内の所定圧力は、30〜60Paである請求項1乃至請求項4のうちいずれか1項に記載の半導体装置の製造方法。
- 前記基板を前記第2のプロセスガスに晒す際に、前記ガス溜りに前記第1のプロセスガスを溜める請求項2の半導体装置の製造方法。
- 前記ガス溜りの容積は前記反応室の容積の1/1000〜3/1000である請求項2または請求項7に記載の半導体装置の製造方法。
- 基板を収容した反応室にプラズマ励起されていない第1のプロセスガスを供給し前記反応室の圧力を昇圧しつつ前記基板を前記第1のプロセスガスに晒す工程と、
その後、前記反応室内の雰囲気を排気する第1の排気工程と、
前記反応室にプラズマ励起された第2のプロセスガスを供給し前記反応室の圧力を所定圧に維持しつつ前記基板を前記第2のプロセスガスに晒す工程と、
その後、前記反応室の雰囲気を排気する第2の排気工程と、
を有する成膜方法。 - 基板を収容した反応室に、少なくとも予めガス溜りに溜めたプラズマ励起されていない第1のプロセスガスを供給し前記反応室の圧力を昇圧しつつ前記基板を前記第1のプロセスガスに晒す工程と、
その後、前記反応室内の雰囲気を排気する第1の排気工程と、
前記反応室にプラズマ励起された第2のプロセスガスを供給し前記反応室の圧力を所定圧に維持しつつ前記基板を前記第2のプロセスガスに晒す工程と、
その後、前記反応室の雰囲気を排気する第2の排気工程と、
を有する成膜方法。 - 基板を収容する反応室と、
前記反応室を、排気バルブを介して排気する排気路と、
前記反応室に第1供給バルブを介して第1のプロセスガスを供給する第1の供給路と、
前記反応室に第2供給バルブを介して第2のプロセスガスを供給する第2の供給路と、
前記第2のプロセスガスをプラズマ励起するプラズマ励起手段と、
前記反応室にプラズマ励起されていない第1のプロセスガスを供給し前記反応室の圧力を昇圧しつつ前記基板を第1のプロセスガスに晒し、前記反応室内の雰囲気を排気し、前記反応室にプラズマ励起された第2のプロセスガスを供給し前記反応室の圧力を所定圧に維持しつつ前記基板を前記第2のプロセスガスに晒し、前記反応室の雰囲気を排気するよう、前記排気バルブ、前記第1供給バルブ、前記第2供給バルブおよび前記プラズマ励起手段を制御する制御手段と、を備えた基板処理装置。 - 基板を収容する反応室と、
前記反応室を、排気バルブを介して排気する排気路と、
前記反応室に第1供給バルブを介して第1のプロセスガスを供給する第1の供給路と、
前記反応室に第2供給バルブを介して第2のプロセスガスを供給する第2の供給路と、
前記第1の供給路に設けられ、前記第1のプロセスガスを溜めるガス溜りと、
前記第2のプロセスガスをプラズマ励起するプラズマ励起手段と、
前記反応室に少なくとも予めガス溜りに溜めたプラズマ励起されていない第1のプロセスガスを供給し前記反応室の圧力を昇圧しつつ前記基板を第1のプロセスガスに晒し、前記反応室内の雰囲気を排気し、前記反応室にプラズマ励起された第2のプロセスガスを供給し前記反応室の圧力を所定圧に維持しつつ前記基板を前記第2のプロセスガスに晒し前記反応室の雰囲気を排気するよう、前記排気バルブ、前記第1供給バルブ、前記第2供給バルブおよび前記プラズマ励起手段を制御する制御手段と、を備えた基板処理装置。
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2008
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Also Published As
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US20110176967A1 (en) | 2011-07-21 |
JP2010283388A (ja) | 2010-12-16 |
KR20080006530A (ko) | 2008-01-16 |
US7622396B2 (en) | 2009-11-24 |
US20030213435A1 (en) | 2003-11-20 |
KR101145559B1 (ko) | 2012-05-16 |
KR20030081144A (ko) | 2003-10-17 |
KR20090029241A (ko) | 2009-03-20 |
JP5527863B2 (ja) | 2014-06-25 |
KR100867073B1 (ko) | 2008-11-04 |
KR20120004952A (ko) | 2012-01-13 |
KR20100014210A (ko) | 2010-02-10 |
US20080250619A1 (en) | 2008-10-16 |
US20050217577A1 (en) | 2005-10-06 |
US6905549B2 (en) | 2005-06-14 |
JP2013080979A (ja) | 2013-05-02 |
KR20080044823A (ko) | 2008-05-21 |
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