JP5258363B2 - ゴルフボール - Google Patents
ゴルフボール Download PDFInfo
- Publication number
- JP5258363B2 JP5258363B2 JP2008109169A JP2008109169A JP5258363B2 JP 5258363 B2 JP5258363 B2 JP 5258363B2 JP 2008109169 A JP2008109169 A JP 2008109169A JP 2008109169 A JP2008109169 A JP 2008109169A JP 5258363 B2 JP5258363 B2 JP 5258363B2
- Authority
- JP
- Japan
- Prior art keywords
- golf ball
- cover
- mass
- thermoplastic polyurethane
- core
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 82
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 79
- 239000004433 Thermoplastic polyurethane Substances 0.000 claims description 78
- 239000000203 mixture Substances 0.000 claims description 78
- 229920005862 polyol Polymers 0.000 claims description 42
- 150000003077 polyols Chemical class 0.000 claims description 41
- 229920005989 resin Polymers 0.000 claims description 33
- 239000011347 resin Substances 0.000 claims description 33
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 27
- 239000011541 reaction mixture Substances 0.000 claims description 19
- 238000002156 mixing Methods 0.000 claims description 17
- 239000000155 melt Substances 0.000 claims description 9
- 229920001971 elastomer Polymers 0.000 description 40
- 239000005056 polyisocyanate Substances 0.000 description 32
- 229920001228 polyisocyanate Polymers 0.000 description 32
- 239000005060 rubber Substances 0.000 description 31
- 238000004132 cross linking Methods 0.000 description 27
- -1 isocyanate compound Chemical class 0.000 description 26
- 239000012948 isocyanate Substances 0.000 description 21
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 19
- 150000002513 isocyanates Chemical class 0.000 description 16
- 229920000768 polyamine Polymers 0.000 description 15
- 229920002635 polyurethane Polymers 0.000 description 14
- 239000004814 polyurethane Substances 0.000 description 14
- 239000002585 base Substances 0.000 description 13
- 239000010410 layer Substances 0.000 description 13
- 238000000465 moulding Methods 0.000 description 13
- 230000000694 effects Effects 0.000 description 12
- 125000003118 aryl group Chemical group 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 11
- 230000007423 decrease Effects 0.000 description 11
- 229920005992 thermoplastic resin Polymers 0.000 description 11
- 150000007934 α,β-unsaturated carboxylic acids Chemical class 0.000 description 11
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 10
- 229920000554 ionomer Polymers 0.000 description 10
- GUUVPOWQJOLRAS-UHFFFAOYSA-N Diphenyl disulfide Chemical class C=1C=CC=CC=1SSC1=CC=CC=C1 GUUVPOWQJOLRAS-UHFFFAOYSA-N 0.000 description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 9
- 239000000806 elastomer Substances 0.000 description 9
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 8
- 125000005442 diisocyanate group Chemical group 0.000 description 8
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 8
- 125000003277 amino group Chemical group 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 7
- 239000003431 cross linking reagent Substances 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 229910021645 metal ion Inorganic materials 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- FKTHNVSLHLHISI-UHFFFAOYSA-N 1,2-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC=C1CN=C=O FKTHNVSLHLHISI-UHFFFAOYSA-N 0.000 description 6
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 6
- 239000005977 Ethylene Substances 0.000 description 6
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
- 239000000654 additive Substances 0.000 description 6
- 230000000996 additive effect Effects 0.000 description 6
- 239000000945 filler Substances 0.000 description 6
- 239000003999 initiator Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000008188 pellet Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 125000002947 alkylene group Chemical group 0.000 description 5
- 230000003712 anti-aging effect Effects 0.000 description 5
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 239000002356 single layer Substances 0.000 description 5
- 229910052725 zinc Inorganic materials 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 229920006347 Elastollan Polymers 0.000 description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
- 244000043261 Hevea brasiliensis Species 0.000 description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 4
- 239000004793 Polystyrene Substances 0.000 description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 238000005299 abrasion Methods 0.000 description 4
- 206010000496 acne Diseases 0.000 description 4
- 230000006835 compression Effects 0.000 description 4
- 238000007906 compression Methods 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 125000000524 functional group Chemical group 0.000 description 4
- 238000005227 gel permeation chromatography Methods 0.000 description 4
- 230000005484 gravity Effects 0.000 description 4
- 238000001746 injection moulding Methods 0.000 description 4
- 229920003052 natural elastomer Polymers 0.000 description 4
- 229920001194 natural rubber Polymers 0.000 description 4
- 229920002223 polystyrene Polymers 0.000 description 4
- 229920001169 thermoplastic Polymers 0.000 description 4
- 229920001187 thermosetting polymer Polymers 0.000 description 4
- 239000004416 thermosoftening plastic Substances 0.000 description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
- 239000011701 zinc Substances 0.000 description 4
- NNOZGCICXAYKLW-UHFFFAOYSA-N 1,2-bis(2-isocyanatopropan-2-yl)benzene Chemical compound O=C=NC(C)(C)C1=CC=CC=C1C(C)(C)N=C=O NNOZGCICXAYKLW-UHFFFAOYSA-N 0.000 description 3
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 3
- BYPFICORERPGJY-UHFFFAOYSA-N 3,4-diisocyanatobicyclo[2.2.1]hept-2-ene Chemical compound C1CC2(N=C=O)C(N=C=O)=CC1C2 BYPFICORERPGJY-UHFFFAOYSA-N 0.000 description 3
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 239000004594 Masterbatch (MB) Substances 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 150000002898 organic sulfur compounds Chemical class 0.000 description 3
- 229920002857 polybutadiene Polymers 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
- 229920002725 thermoplastic elastomer Polymers 0.000 description 3
- 229920006346 thermoplastic polyester elastomer Polymers 0.000 description 3
- 239000012463 white pigment Substances 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- ALQLPWJFHRMHIU-UHFFFAOYSA-N 1,4-diisocyanatobenzene Chemical compound O=C=NC1=CC=C(N=C=O)C=C1 ALQLPWJFHRMHIU-UHFFFAOYSA-N 0.000 description 2
- GQHTUMJGOHRCHB-UHFFFAOYSA-N 2,3,4,6,7,8,9,10-octahydropyrimido[1,2-a]azepine Chemical compound C1CCCCN2CCCN=C21 GQHTUMJGOHRCHB-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 2
- 229920002943 EPDM rubber Polymers 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000005063 High cis polybutadiene Substances 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 238000005481 NMR spectroscopy Methods 0.000 description 2
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 2
- 229920002614 Polyether block amide Polymers 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 230000001588 bifunctional effect Effects 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 150000002009 diols Chemical class 0.000 description 2
- 239000001530 fumaric acid Substances 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- 230000003472 neutralizing effect Effects 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 150000001451 organic peroxides Chemical class 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- IVDFJHOHABJVEH-UHFFFAOYSA-N pinacol Chemical compound CC(C)(O)C(C)(C)O IVDFJHOHABJVEH-UHFFFAOYSA-N 0.000 description 2
- 229920001610 polycaprolactone Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920005906 polyester polyol Polymers 0.000 description 2
- 229920000921 polyethylene adipate Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
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- 239000002904 solvent Substances 0.000 description 2
- 229920003051 synthetic elastomer Polymers 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 2
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 2
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 238000004073 vulcanization Methods 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- LGXISKQYIKXYTC-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-[(2,3,4,5,6-pentabromophenyl)disulfanyl]benzene Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1SSC1=C(Br)C(Br)=C(Br)C(Br)=C1Br LGXISKQYIKXYTC-UHFFFAOYSA-N 0.000 description 1
- LSVXAQMPXJUTBV-UHFFFAOYSA-N 1,2,3,4,5-pentachloro-6-[(2,3,4,5,6-pentachlorophenyl)disulfanyl]benzene Chemical compound ClC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1SSC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl LSVXAQMPXJUTBV-UHFFFAOYSA-N 0.000 description 1
- ZNTWBKFKQSOEPV-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-[(2,3,5,6-tetrachlorophenyl)disulfanyl]benzene Chemical compound ClC1=CC(Cl)=C(Cl)C(SSC=2C(=C(Cl)C=C(Cl)C=2Cl)Cl)=C1Cl ZNTWBKFKQSOEPV-UHFFFAOYSA-N 0.000 description 1
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 description 1
- ZZOCRFAYVJWKBF-UHFFFAOYSA-N 1,3,5-trichloro-2-[(2,4,6-trichlorophenyl)disulfanyl]benzene Chemical compound ClC1=CC(Cl)=CC(Cl)=C1SSC1=C(Cl)C=C(Cl)C=C1Cl ZZOCRFAYVJWKBF-UHFFFAOYSA-N 0.000 description 1
- VFBSQBTUKCZKTI-UHFFFAOYSA-N 1,3-dibromo-5-[(3,5-dibromophenyl)disulfanyl]benzene Chemical compound BrC1=CC(Br)=CC(SSC=2C=C(Br)C=C(Br)C=2)=C1 VFBSQBTUKCZKTI-UHFFFAOYSA-N 0.000 description 1
- LSMZVCLPPFOFNM-UHFFFAOYSA-N 1,3-dichloro-2-[(2,6-dichlorophenyl)disulfanyl]benzene Chemical compound ClC1=CC=CC(Cl)=C1SSC1=C(Cl)C=CC=C1Cl LSMZVCLPPFOFNM-UHFFFAOYSA-N 0.000 description 1
- JMQANWHMOHXBEA-UHFFFAOYSA-N 1,3-dichloro-5-[(3,5-dichlorophenyl)disulfanyl]benzene Chemical compound ClC1=CC(Cl)=CC(SSC=2C=C(Cl)C=C(Cl)C=2)=C1 JMQANWHMOHXBEA-UHFFFAOYSA-N 0.000 description 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
- RSZIPSKIWRSQAU-UHFFFAOYSA-N 1,4-dibromo-2-[(2,5-dibromophenyl)disulfanyl]benzene Chemical compound BrC1=CC=C(Br)C(SSC=2C(=CC=C(Br)C=2)Br)=C1 RSZIPSKIWRSQAU-UHFFFAOYSA-N 0.000 description 1
- QGKFQPPIXYPVIE-UHFFFAOYSA-N 1,4-dichloro-2-[(2,5-dichlorophenyl)disulfanyl]benzene Chemical compound ClC1=CC=C(Cl)C(SSC=2C(=CC=C(Cl)C=2)Cl)=C1 QGKFQPPIXYPVIE-UHFFFAOYSA-N 0.000 description 1
- SBJCUZQNHOLYMD-UHFFFAOYSA-N 1,5-Naphthalene diisocyanate Chemical compound C1=CC=C2C(N=C=O)=CC=CC2=C1N=C=O SBJCUZQNHOLYMD-UHFFFAOYSA-N 0.000 description 1
- PEHGERSYFVVLQN-UHFFFAOYSA-N 1-bromo-3-[(3-bromophenyl)disulfanyl]benzene Chemical compound BrC1=CC=CC(SSC=2C=C(Br)C=CC=2)=C1 PEHGERSYFVVLQN-UHFFFAOYSA-N 0.000 description 1
- VZQVHIINDXJOQK-UHFFFAOYSA-N 1-bromo-4-[(4-bromophenyl)disulfanyl]benzene Chemical compound C1=CC(Br)=CC=C1SSC1=CC=C(Br)C=C1 VZQVHIINDXJOQK-UHFFFAOYSA-N 0.000 description 1
- OLOYVIPZMIIGOH-UHFFFAOYSA-N 1-chloro-3-[(3-chlorophenyl)disulfanyl]benzene Chemical compound ClC1=CC=CC(SSC=2C=C(Cl)C=CC=2)=C1 OLOYVIPZMIIGOH-UHFFFAOYSA-N 0.000 description 1
- ZIXXRXGPBFMPFD-UHFFFAOYSA-N 1-chloro-4-[(4-chlorophenyl)disulfanyl]benzene Chemical compound C1=CC(Cl)=CC=C1SSC1=CC=C(Cl)C=C1 ZIXXRXGPBFMPFD-UHFFFAOYSA-N 0.000 description 1
- HABDEXOINBJHPA-UHFFFAOYSA-N 1-iodo-4-[(4-iodophenyl)disulfanyl]benzene Chemical group C1=CC(I)=CC=C1SSC1=CC=C(I)C=C1 HABDEXOINBJHPA-UHFFFAOYSA-N 0.000 description 1
- ICLCCFKUSALICQ-UHFFFAOYSA-N 1-isocyanato-4-(4-isocyanato-3-methylphenyl)-2-methylbenzene Chemical compound C1=C(N=C=O)C(C)=CC(C=2C=C(C)C(N=C=O)=CC=2)=C1 ICLCCFKUSALICQ-UHFFFAOYSA-N 0.000 description 1
- VOZKAJLKRJDJLL-UHFFFAOYSA-N 2,4-diaminotoluene Chemical compound CC1=CC=C(N)C=C1N VOZKAJLKRJDJLL-UHFFFAOYSA-N 0.000 description 1
- PISLZQACAJMAIO-UHFFFAOYSA-N 2,4-diethyl-6-methylbenzene-1,3-diamine Chemical compound CCC1=CC(C)=C(N)C(CC)=C1N PISLZQACAJMAIO-UHFFFAOYSA-N 0.000 description 1
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 description 1
- QWGRWMMWNDWRQN-UHFFFAOYSA-N 2-methylpropane-1,3-diol Chemical compound OCC(C)CO QWGRWMMWNDWRQN-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 description 1
- VXRYPDVFWGPCRW-UHFFFAOYSA-N 3-bromo-2-[(2-bromo-4-chloro-6-cyanophenyl)disulfanyl]-5-chlorobenzonitrile Chemical compound N#CC1=CC(Cl)=CC(Br)=C1SSC1=C(Br)C=C(Cl)C=C1C#N VXRYPDVFWGPCRW-UHFFFAOYSA-N 0.000 description 1
- YBRVSVVVWCFQMG-UHFFFAOYSA-N 4,4'-diaminodiphenylmethane Chemical compound C1=CC(N)=CC=C1CC1=CC=C(N)C=C1 YBRVSVVVWCFQMG-UHFFFAOYSA-N 0.000 description 1
- BCUVQZBVGSXWCG-UHFFFAOYSA-N 4-[(4-cyanophenyl)disulfanyl]benzonitrile Chemical compound C1=CC(C#N)=CC=C1SSC1=CC=C(C#N)C=C1 BCUVQZBVGSXWCG-UHFFFAOYSA-N 0.000 description 1
- LXVBPLSCYANPQH-UHFFFAOYSA-N 4-bromo-2-[(5-bromo-2-chlorophenyl)disulfanyl]-1-chlorobenzene Chemical compound ClC1=CC=C(Br)C=C1SSC1=CC(Br)=CC=C1Cl LXVBPLSCYANPQH-UHFFFAOYSA-N 0.000 description 1
- AOFIWCXMXPVSAZ-UHFFFAOYSA-N 4-methyl-2,6-bis(methylsulfanyl)benzene-1,3-diamine Chemical compound CSC1=CC(C)=C(N)C(SC)=C1N AOFIWCXMXPVSAZ-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N Bisphenol A Natural products C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- WKBDBPHLZOPUJR-UHFFFAOYSA-N C(O)C=1C(=C(N(O)O)C=CC1)CO Chemical compound C(O)C=1C(=C(N(O)O)C=CC1)CO WKBDBPHLZOPUJR-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- RYECOJGRJDOGPP-UHFFFAOYSA-N Ethylurea Chemical compound CCNC(N)=O RYECOJGRJDOGPP-UHFFFAOYSA-N 0.000 description 1
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 1
- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 1
- 239000004472 Lysine Substances 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 description 1
- SVYKKECYCPFKGB-UHFFFAOYSA-N N,N-dimethylcyclohexylamine Chemical compound CN(C)C1CCCCC1 SVYKKECYCPFKGB-UHFFFAOYSA-N 0.000 description 1
- QORUGOXNWQUALA-UHFFFAOYSA-N N=C=O.N=C=O.N=C=O.C1=CC=C(C(C2=CC=CC=C2)C2=CC=CC=C2)C=C1 Chemical compound N=C=O.N=C=O.N=C=O.C1=CC=C(C(C2=CC=CC=C2)C2=CC=CC=C2)C=C1 QORUGOXNWQUALA-UHFFFAOYSA-N 0.000 description 1
- MBOZGLMBKQFIBB-UHFFFAOYSA-N N=C=O.OP(O)(=S)OC1=CC=CC=C1 Chemical compound N=C=O.OP(O)(=S)OC1=CC=CC=C1 MBOZGLMBKQFIBB-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- GKXVJHDEWHKBFH-UHFFFAOYSA-N [2-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=CC=C1CN GKXVJHDEWHKBFH-UHFFFAOYSA-N 0.000 description 1
- ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 239000001055 blue pigment Substances 0.000 description 1
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 1
- BMRWNKZVCUKKSR-UHFFFAOYSA-N butane-1,2-diol Chemical compound CCC(O)CO BMRWNKZVCUKKSR-UHFFFAOYSA-N 0.000 description 1
- OWBTYPJTUOEWEK-UHFFFAOYSA-N butane-2,3-diol Chemical compound CC(O)C(C)O OWBTYPJTUOEWEK-UHFFFAOYSA-N 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- ARUKYTASOALXFG-UHFFFAOYSA-N cycloheptylcycloheptane Chemical compound C1CCCCCC1C1CCCCCC1 ARUKYTASOALXFG-UHFFFAOYSA-N 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 239000012975 dibutyltin dilaurate Substances 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000003480 eluent Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000006081 fluorescent whitening agent Substances 0.000 description 1
- 125000001207 fluorophenyl group Chemical group 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 150000002314 glycerols Chemical class 0.000 description 1
- 238000010559 graft polymerization reaction Methods 0.000 description 1
- MHIBEGOZTWERHF-UHFFFAOYSA-N heptane-1,1-diol Chemical compound CCCCCCC(O)O MHIBEGOZTWERHF-UHFFFAOYSA-N 0.000 description 1
- TZMQHOJDDMFGQX-UHFFFAOYSA-N hexane-1,1,1-triol Chemical compound CCCCCC(O)(O)O TZMQHOJDDMFGQX-UHFFFAOYSA-N 0.000 description 1
- ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- XCPCSFWIASFZOP-UHFFFAOYSA-N isocyanic acid;nonane Chemical compound N=C=O.CCCCCCCCC XCPCSFWIASFZOP-UHFFFAOYSA-N 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 1
- QATBRNFTOCXULG-UHFFFAOYSA-N n'-[2-(methylamino)ethyl]ethane-1,2-diamine Chemical compound CNCCNCCN QATBRNFTOCXULG-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- OEIJHBUUFURJLI-UHFFFAOYSA-N octane-1,8-diol Chemical compound OCCCCCCCCO OEIJHBUUFURJLI-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- UWJJYHHHVWZFEP-UHFFFAOYSA-N pentane-1,1-diol Chemical compound CCCCC(O)O UWJJYHHHVWZFEP-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920006124 polyolefin elastomer Polymers 0.000 description 1
- 229920000909 polytetrahydrofuran Polymers 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 229920003225 polyurethane elastomer Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 238000011417 postcuring Methods 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 238000005488 sandblasting Methods 0.000 description 1
- MXNUCYGENRZCBO-UHFFFAOYSA-M sodium;ethene;2-methylprop-2-enoate Chemical compound [Na+].C=C.CC(=C)C([O-])=O MXNUCYGENRZCBO-UHFFFAOYSA-M 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 229920006027 ternary co-polymer Polymers 0.000 description 1
- 229920006345 thermoplastic polyamide Polymers 0.000 description 1
- 229920006230 thermoplastic polyester resin Polymers 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical compound NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
- XKMZOFXGLBYJLS-UHFFFAOYSA-L zinc;prop-2-enoate Chemical compound [Zn+2].[O-]C(=O)C=C.[O-]C(=O)C=C XKMZOFXGLBYJLS-UHFFFAOYSA-L 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B37/00—Solid balls; Rigid hollow balls; Marbles
- A63B37/0003—Golf balls
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B37/00—Solid balls; Rigid hollow balls; Marbles
- A63B37/0003—Golf balls
- A63B37/0023—Covers
- A63B37/0024—Materials other than ionomers or polyurethane
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B37/00—Solid balls; Rigid hollow balls; Marbles
- A63B37/0003—Golf balls
- A63B37/0023—Covers
- A63B37/0029—Physical properties
- A63B37/0031—Hardness
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B45/00—Apparatus or methods for manufacturing balls
Description
ポリイソシアネート−(ポリオール−ポリイソシアネート)n (1)
(1)流動開始温度
流動開始温度は、流動特性評価装置(島津製作所製、フローテスターCFT−500D)を用いて、ペレット状の試料について、下記条件で測定した。
測定条件
プランジャー面積:1cm2
DIE LENGTH:1mm
DIE DIA:1mm
荷重:588.399N
開始温度:30℃
昇温速度:3℃/分
溶融粘度は、流動特性評価装置(島津製作所製、フローテスターCFT−500D)を用いて、ペレット状の試料について、下記条件で測定した。
測定条件
DIE LENGTH:1mm
DIE DIA:1mm
荷重:294N
温度:190℃、210℃
ASTM−D2240に規定するスプリング式硬度計ショアD型を備えた高分子計器社製自動ゴム硬度計P1型を用いて、球状コアの表面部において測定したショアD硬度を、球状コアの表面硬度とし、球状コアを半球状に切断し、切断面の中心において測定したショアD硬度を球状コアの中心硬度とした。
カバー用組成物を用いて、熱プレス成形により、厚み約2mmのシートを作製し、23℃で2週間保存した。このシートを、測定基板等の影響が出ないように、3枚以上重ねた状態で、ASTM−D2240に規定するスプリング式硬度計ショアD型を備えた高分子計器社製自動ゴム硬度計P1型を用いて測定した。
ゴルフラボラトリー社製のスイングロボットM/Cに市販のピッチングウエッジを取り付け、ヘッドスピード36m/秒でボールの2箇所を各1回打撃し、打撃部を観察して、4段階で評価した。
評価基準
◎:ゴルフボールの表面にほとんど傷がない。
○:ゴルフボールの表面に傷がわずかに生じる。
△:ゴルフボールの表面が少し削れており、毛羽立ちが生じている。
×:ゴルフボールの表面がかなり削れており、毛羽立ちが目立つ。
ゴルフラボラトリー社製のスイングロボットM/Cにメタルヘッド製#W1ドライバーを取り付け、各ゴルフボールをヘッドスピード45m/秒で打撃して衝突板に衝突させた。これを繰り返して、ゴルフボールが壊れるまでの打撃回数を測定した。各ゴルフボールの耐久性は、ゴルフボールNo.1の打撃回数を100として、各ゴルフボールについての打撃回数を指数化した値で示した。指数化された値が大きいほど、ゴルフボールが耐久性に優れていることを示す。
ゴルフラボラトリー社製スイングロボットM/Cに、アプローチウェッジ(SRIスポーツ社製、SRIXON I−302)を取り付け、ヘッドスピード21m/秒でゴルフボールを打撃し、打撃されたゴルフボールを連続写真撮影することによってスピン速度(rpm)を測定した。測定は、各ゴルフボールについて10回ずつ行い、その平均値をスピン速度とした。各ゴルフボールの耐久性は、ゴルフボールNo.1のスピン速度を100として、各ゴルフボールについてのスピン速度を指数化した値で示した。
表1に示したポリイソシアネートとポリオールとを所定量用いて、80℃で2時間、乾燥窒素雰囲気下で反応させて、イソシアネート基末端ウレタンプレポリマー(B)を得た。
熱可塑性ポリウレタン(A)(BASF社製、エラストランXNY85A10)100質量部と、イソシアネート混合物(大日精化株式会社製、クロスネートEM−30)10質量部を、単軸型押出機(東洋精機社製、2D25S)によりミキシングして混合物Iのペレットを得た。混合物は、押出機のダイの位置で150〜230℃に加熱された。
4,4’−ジフェニルメタンジイソシアネートとポリテトラメチレングリコール(数平均分子量1,000)とを所定量用いて、80℃で2時間、乾燥窒素雰囲気下で反応させて、イソシアネート基末端ウレタンプレポリマーを得た。次に、イソシアネート基と実質的に反応しない熱可塑性樹脂として、熱可塑性ポリエステルエラストマー(東レ・デュポン社製、「ハイトレル(登録商標)3046」)を予め乾燥して水分を除去したものを用意した。上記で得たイソシアネート基末端ウレタンプレポリマー35質量部と熱可塑性ポリエステルエラストマー65質量部とを、ミキシングロールにて、120℃〜180℃で5分間〜10分間混練した。得られた混練物を取り出し、粉砕してウレタンプレポリマーのマスターバッチを得た。
MDI:4,4’−ジフェニルメタンジイソシアネート
PTMG:ポリテトラメチレンエーテルグリコール
クロスネートEM−30:大日精化株式会社製、熱可塑性ポリエステル樹脂にMDIを分散させたもの(MDI含有量30質量%)
(1)コアの作製
表2に示す配合のコア用ゴム組成物を混練し、半球状キャビティを有する上下金型内で160℃、13分間加熱プレスすることにより直径40.7mmの球状のコアを得た。
アクリル酸亜鉛:日本蒸留社製、「ZNDA−90S」
酸化亜鉛:東邦亜鉛社製、「銀嶺R」
硫酸バリウム:堺化学社製、「硫酸バリウムBD」
ジフェニルジスルフィド:住友精化社製
ジクミルパーオキサイド:日油社製、「パークミル(登録商標)D」
表3に示す反応混合物(A+B)または混合物と、カバー用添加剤(酸化チタン)とを、タンブラー型混合機を用いてドライブレンドしてカバー用組成物を調製した。
得られたカバー用組成物をコア上に直接射出成形することにより、カバーを成形した。カバー成形用上下金型は、半球状キャビティを有し、ピンプル付きで、ピンプルの一部が進退可能なホールドピンを兼ねている。上記ホールドピンを突き出し、コアを投入後ホールドさせ、80トンの圧力で型締めした金型に210℃に加熱した樹脂を0.3秒で注入し、30秒間冷却して型開きしてゴルフボール本体を取り出した。
得られたゴルフボールについて、耐擦過傷性、耐久性およびスピン性能について評価した結果を併せて表3に示した。
Claims (6)
- コアとカバーとを有するゴルフボールであって、
前記カバーは、樹脂成分として、熱可塑性ポリウレタン(A)とイソシアネート基を2個以上有するウレタンプレポリマー(B)とを溶融混合して得られる反応混合物(A+B)を含有するカバー用組成物から形成されていることを特徴とするゴルフボール。 - 前記反応混合物(A+B)が、前記熱可塑性ポリウレタン(A)100質量部に対して、ウレタンプレポリマー(B)を1質量部〜50質量部混合したものである請求項1に記載のゴルフボール。
- 前記反応混合物(A+B)の流動開始温度(TA+B)と、前記熱可塑性ポリウレタン(A)の流動開始温度(TA)との差(TA+B−TA)が、−5℃〜40℃である請求項1または2に記載のゴルフボール。
- 前記反応混合物(A+B)の溶融粘度(ηA+B)と、前記熱可塑性ポリウレタン(A)の溶融粘度(ηA)との比(ηA+B/ηA)が、0.7〜12.0である請求項1〜3のいずれか一項に記載のゴルフボール。
- 前記ウレタンプレポリマー(B)を構成するポリオール成分の数平均分子量が650以上である請求項1〜4のいずれか一項に記載のゴルフボール。
- 前記カバー用組成物のスラブ硬度が、ショアD硬度で20〜60である請求項1〜5のいずれか一項に記載のゴルフボール。
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Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5371881B2 (ja) * | 2009-12-10 | 2013-12-18 | 三井化学株式会社 | カバー材の製造方法およびカバー材 |
JP4927930B2 (ja) * | 2009-12-16 | 2012-05-09 | Sriスポーツ株式会社 | ゴルフボール用材料およびこれを用いたゴルフボール |
TWI546105B (zh) | 2010-07-21 | 2016-08-21 | 耐基創新公司 | 高爾夫球及製造高爾夫球的方法 |
JP6977242B2 (ja) * | 2016-05-25 | 2021-12-08 | 住友ゴム工業株式会社 | ゴルフボール |
Family Cites Families (59)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US106473A (en) * | 1870-08-16 | Improvement in vegetable-knives | ||
US106474A (en) * | 1870-08-16 | Improvement in medical compound for the cure op gravel | ||
US276596A (en) * | 1883-05-01 | Machine | ||
US142127A (en) * | 1873-08-26 | Improvement in rein-guides for vehicles | ||
US3395109A (en) | 1962-10-08 | 1968-07-30 | Spalding A G & Bros Inc | Golf ball cover composition comprising a blend of polyesterurethane elastomers |
US3989568A (en) | 1974-11-21 | 1976-11-02 | Acushnet Company | Polyurethane covered golf balls |
US4123061A (en) | 1976-05-20 | 1978-10-31 | Acushnet Company | Ball and process and composition of matter for production thereof |
US4248432A (en) | 1979-07-16 | 1981-02-03 | The B. F. Goodrich Company | Golf ball |
JPS582063B2 (ja) * | 1980-05-29 | 1983-01-13 | 大日精化工業株式会社 | 熱硬化性ポリウレタン成形品の製造法 |
NZ238970A (en) | 1990-07-20 | 1993-02-25 | Acushnet Co | Golf ball with a polyurethane cover cured by slow reacting polyamine curing agent |
JP2910516B2 (ja) | 1993-07-08 | 1999-06-23 | ブリヂストンスポーツ株式会社 | スリーピースソリッドゴルフボール |
JPH09215778A (ja) | 1996-02-09 | 1997-08-19 | Bridgestone Sports Co Ltd | ツーピースソリッドゴルフボール |
JPH1099469A (ja) | 1996-09-26 | 1998-04-21 | Bridgestone Sports Co Ltd | ゴルフボール及びゴルフボール成形用金型 |
JPH1189967A (ja) | 1997-09-16 | 1999-04-06 | Bridgestone Sports Co Ltd | ゴルフボール |
JP3912448B2 (ja) | 1997-11-05 | 2007-05-09 | ブリヂストンスポーツ株式会社 | ゴルフボール成形用金型及びゴルフボール |
US6582325B1 (en) | 1997-12-17 | 2003-06-24 | Bridgestone Sports Co., Ltd. | Solid golf balls and method of making |
JP4038625B2 (ja) | 1997-12-17 | 2008-01-30 | ブリヂストンスポーツ株式会社 | ソリッドゴルフボール及びソリッドゴルフボールの製造方法 |
JPH11189632A (ja) * | 1997-12-25 | 1999-07-13 | Nippon Miractran Kk | イソシアネートカプセルの製造方法 |
JP2000279553A (ja) | 1999-01-27 | 2000-10-10 | Bridgestone Sports Co Ltd | ゴルフボール |
US6368238B1 (en) | 1999-01-27 | 2002-04-09 | Bridgestone Sports Co., Ltd. | Dimpled golf ball |
US6258310B1 (en) * | 1999-03-18 | 2001-07-10 | Basf Corporation | Cross-linking thermoplastic polyurethane |
JP2002159598A (ja) | 2000-11-27 | 2002-06-04 | Sumitomo Rubber Ind Ltd | ゴルフボール成形型及びゴルフボール |
JP2002200196A (ja) | 2000-12-28 | 2002-07-16 | Sumitomo Rubber Ind Ltd | ソリッドゴルフボール |
JP4387605B2 (ja) | 2001-03-13 | 2009-12-16 | Sriスポーツ株式会社 | ゴルフボール |
JP2002336380A (ja) | 2001-05-17 | 2002-11-26 | Bridgestone Sports Co Ltd | ゴルフボール |
JP4651853B2 (ja) | 2001-05-17 | 2011-03-16 | ブリヂストンスポーツ株式会社 | ゴルフボールカバー改質用組成物 |
US6939251B2 (en) | 2001-05-17 | 2005-09-06 | Bridgestone Sports Co., Ltd. | Golf ball |
JP4823434B2 (ja) | 2001-05-17 | 2011-11-24 | ブリヂストンスポーツ株式会社 | ゴルフボールの製造方法 |
JP2002336378A (ja) | 2001-05-17 | 2002-11-26 | Bridgestone Sports Co Ltd | ゴルフボール |
JP4782942B2 (ja) | 2001-05-17 | 2011-09-28 | ブリヂストンスポーツ株式会社 | ゴルフボールの製造方法 |
JP2003070936A (ja) | 2001-06-21 | 2003-03-11 | Bridgestone Sports Co Ltd | ツーピースソリッドゴルフボール |
JP5142429B2 (ja) | 2001-06-25 | 2013-02-13 | ブリヂストンスポーツ株式会社 | ツーピースソリッドゴルフボール |
JP4054970B2 (ja) | 2002-05-31 | 2008-03-05 | ブリヂストンスポーツ株式会社 | ゴルフボール |
JP4035002B2 (ja) | 2002-06-18 | 2008-01-16 | キャスコ株式会社 | マルチピースソリッドゴルフボール |
JP4122509B2 (ja) | 2002-09-11 | 2008-07-23 | 日本ポリウレタン工業株式会社 | ゴルフボールインナー又はカバー用熱可塑性ポリウレタン樹脂、及びそれを用いたゴルフボール |
JP4031353B2 (ja) | 2002-11-15 | 2008-01-09 | Sriスポーツ株式会社 | ゴルフボール |
JP2004180793A (ja) | 2002-11-29 | 2004-07-02 | Bridgestone Sports Co Ltd | ツーピースソリッドゴルフボール |
JP2004180797A (ja) | 2002-11-29 | 2004-07-02 | Bridgestone Sports Co Ltd | マルチピースソリッドゴルフボール |
JP4105653B2 (ja) | 2003-04-09 | 2008-06-25 | アクシュネット カンパニー | ゴルフ道具用のポリ尿素及びポリウレタン組成物 |
JP4414207B2 (ja) | 2003-11-26 | 2010-02-10 | Sriスポーツ株式会社 | ゴルフボール |
JP2005224514A (ja) | 2004-02-16 | 2005-08-25 | Bridgestone Sports Co Ltd | スリーピースソリッドゴルフボール |
JP4489456B2 (ja) | 2004-02-23 | 2010-06-23 | Sriスポーツ株式会社 | ゴルフボール |
US7090799B2 (en) | 2004-03-09 | 2006-08-15 | Bridgestone Sports Co., Ltd. | Golf ball and method for preparing golf ball |
JP4553114B2 (ja) | 2004-06-17 | 2010-09-29 | ブリヂストンスポーツ株式会社 | ゴルフボール用樹脂成形物及びゴルフボール |
US7294068B2 (en) | 2005-05-24 | 2007-11-13 | Bridgestone Sports Co., Ltd. | Multi-piece solid golf ball |
US7273425B2 (en) | 2005-12-05 | 2007-09-25 | Bridgestone Sports Co., Ltd. | Solid golf ball |
JP4523912B2 (ja) * | 2005-12-16 | 2010-08-11 | Sriスポーツ株式会社 | ゴルフボールおよびその製造方法 |
JP2007159996A (ja) * | 2005-12-16 | 2007-06-28 | Sri Sports Ltd | ウレタンカバーを有するゴルフボールおよびその製造方法 |
US7322892B1 (en) | 2006-08-15 | 2008-01-29 | Bridgestone Sports Co., Ltd. | Golf ball |
US7335115B1 (en) | 2006-09-12 | 2008-02-26 | Bridgestone Sports Co., Ltd. | Multi-piece solid golf ball |
US8349952B2 (en) * | 2006-12-28 | 2013-01-08 | Dunlop Sports Co. Ltd. | Golf ball |
US20090111608A1 (en) | 2007-10-29 | 2009-04-30 | Bridgestone Sports Co., Ltd. | Multi-piece solid golf ball |
JP5258263B2 (ja) | 2007-11-08 | 2013-08-07 | ダンロップスポーツ株式会社 | ゴルフボール |
JP5258262B2 (ja) | 2007-11-08 | 2013-08-07 | ダンロップスポーツ株式会社 | ゴルフボール |
JP5258264B2 (ja) * | 2007-11-08 | 2013-08-07 | ダンロップスポーツ株式会社 | ゴルフボール |
JP5430865B2 (ja) | 2008-02-29 | 2014-03-05 | ダンロップスポーツ株式会社 | ゴルフボール |
US8029193B2 (en) | 2008-03-07 | 2011-10-04 | Pacific Bearing Company | Guide rail and method for manufacturing same |
JP2009226122A (ja) | 2008-03-25 | 2009-10-08 | Sri Sports Ltd | ゴルフボール |
JP2009226115A (ja) | 2008-03-25 | 2009-10-08 | Sri Sports Ltd | ゴルフボール |
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