JP3825478B2 - ポリプロピレンアロイの製造方法 - Google Patents

ポリプロピレンアロイの製造方法 Download PDF

Info

Publication number
JP3825478B2
JP3825478B2 JP50385599A JP50385599A JP3825478B2 JP 3825478 B2 JP3825478 B2 JP 3825478B2 JP 50385599 A JP50385599 A JP 50385599A JP 50385599 A JP50385599 A JP 50385599A JP 3825478 B2 JP3825478 B2 JP 3825478B2
Authority
JP
Japan
Prior art keywords
reactor
gas phase
polymer
phase reactor
process according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP50385599A
Other languages
English (en)
Japanese (ja)
Other versions
JP2002504955A5 (https=
JP2002504955A (ja
Inventor
ハルリン,アリ
アラスタロ,カウノ
キヴェレ,ヨウニ
コルホネン,エサ
Original Assignee
ボレアリス エイ/エス
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ボレアリス エイ/エス filed Critical ボレアリス エイ/エス
Publication of JP2002504955A publication Critical patent/JP2002504955A/ja
Publication of JP2002504955A5 publication Critical patent/JP2002504955A5/ja
Application granted granted Critical
Publication of JP3825478B2 publication Critical patent/JP3825478B2/ja
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24Stationary reactors without moving elements inside
    • B01J19/2415Tubular reactors
    • B01J19/2435Loop-type reactors
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04Monomers containing three or four carbon atoms
    • C08F10/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00051Controlling the temperature
    • B01J2219/00121Controlling the temperature by direct heating or cooling
    • B01J2219/00128Controlling the temperature by direct heating or cooling by evaporation of reactants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00162Controlling or regulating processes controlling the pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00164Controlling or regulating processes controlling the flow
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00184Controlling or regulating processes controlling the weight of reactants in the reactor vessel
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901Monomer polymerized in vapor state in presence of transition metal containing catalyst
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/905Polymerization in presence of transition metal containing catalyst in presence of hydrogen
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/92Apparatus for use in addition polymerization processes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Reinforced Plastic Materials (AREA)
  • Power Steering Mechanism (AREA)
JP50385599A 1997-06-24 1998-06-24 ポリプロピレンアロイの製造方法 Expired - Fee Related JP3825478B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FI972729A FI111846B (fi) 1997-06-24 1997-06-24 Menetelmä ja laitteisto polypropeeniseosten valmistamiseksi
FI972729 1997-06-24
PCT/FI1998/000555 WO1998058977A1 (en) 1997-06-24 1998-06-24 Process for preparing polypropylene alloys

Publications (3)

Publication Number Publication Date
JP2002504955A JP2002504955A (ja) 2002-02-12
JP2002504955A5 JP2002504955A5 (https=) 2005-03-10
JP3825478B2 true JP3825478B2 (ja) 2006-09-27

Family

ID=8549124

Family Applications (1)

Application Number Title Priority Date Filing Date
JP50385599A Expired - Fee Related JP3825478B2 (ja) 1997-06-24 1998-06-24 ポリプロピレンアロイの製造方法

Country Status (10)

Country Link
US (1) US6469110B1 (https=)
EP (1) EP0991684B1 (https=)
JP (1) JP3825478B2 (https=)
CN (1) CN1140555C (https=)
AT (1) ATE316539T1 (https=)
AU (1) AU7921298A (https=)
DE (1) DE69833324T2 (https=)
ES (1) ES2256942T3 (https=)
FI (1) FI111846B (https=)
WO (1) WO1998058977A1 (https=)

Families Citing this family (194)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW526209B (en) * 1999-10-21 2003-04-01 Asahi Chemical Ind Method for producing an olefin homopolymer or an olefin copolymer
DE60106219T2 (de) * 2001-06-27 2006-03-09 Borealis Technology Oy Propylen-Copolymer mit zufälliger Comonomerverteilung und Verfahren zu seiner Herstellung
WO2003022888A1 (en) * 2001-09-07 2003-03-20 Uop Llc Process for reducing transient operation time in polymerization reactors
US6916892B2 (en) * 2001-12-03 2005-07-12 Fina Technology, Inc. Method for transitioning between Ziegler-Natta and metallocene catalysts in a bulk loop reactor for the production of polypropylene
KR101186268B1 (ko) 2002-06-26 2012-09-27 애버리 데니슨 코포레이션 폴리프로필렌/올레핀 탄성체 혼합물을 포함하는 배향된 필름
US7550528B2 (en) 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
ES2394304T3 (es) 2002-10-15 2013-01-30 Exxonmobil Chemical Patents, Inc. Sistema de múltiples catalizadores para la polimerización de olefinas y polímeros producidos a partir de éstos
ES2296888T3 (es) * 2002-10-30 2008-05-01 Borealis Technology Oy Proceso y aparato para la produccion de polimeros de olefinas.
EP1484343A1 (en) * 2003-06-06 2004-12-08 Universiteit Twente Process for the catalytic polymerization of olefins, a reactor system and its use in the same process
CN100355835C (zh) * 2005-02-02 2007-12-19 何光临 高分子聚合物合金的制备方法及专用的微闪蒸挤出机
US7098301B1 (en) 2005-07-29 2006-08-29 Exxonmobil Chemical Patents Inc. High pressure filter method of separating polymer solids and unreacted monomer
EP1862479A1 (en) * 2006-05-31 2007-12-05 Borealis Technology Oy Olefin polymerisation catalyst
US9662867B2 (en) 2006-06-14 2017-05-30 Avery Dennison Corporation Conformable and die-cuttable machine direction oriented labelstocks and labels, and process for preparing
WO2007149900A2 (en) 2006-06-20 2007-12-27 Avery Dennison Corporation Multilayered polymeric film for hot melt adhesive labeling and label stock and label thereof
CN100427509C (zh) * 2006-12-30 2008-10-22 中国石化扬子石油化工有限公司 一种聚烯烃合金的制备方法
CN101827869B (zh) * 2007-09-19 2013-03-27 巴塞尔聚烯烃意大利有限责任公司 用于烯烃聚合的多级方法
US7910679B2 (en) * 2007-12-20 2011-03-22 Exxonmobil Research And Engineering Company Bulk homogeneous polymerization process for ethylene propylene copolymers
US20100125124A1 (en) * 2008-11-17 2010-05-20 Fina Technology, Inc. Methods of catalyst activation
CN101787089B (zh) * 2009-01-23 2013-05-29 中国石油化工股份有限公司 一种用于烯烃聚合的串联反应器工艺
ES2370689T3 (es) 2009-02-25 2011-12-21 Borealis Ag Polímero multimodal de polipropileno, composición que comprende el mismo y un procedimiento para producir el mismo.
EP2223944A1 (en) 2009-02-26 2010-09-01 Borealis AG Process for producing semicrystalline propylene polymers
CN101942051B (zh) * 2009-07-09 2012-11-21 中国石油化工股份有限公司 一种液相丙烯本体聚合反应连续聚合工艺
CN102020733B (zh) * 2009-09-10 2012-04-18 中国石油化工股份有限公司 一种多相共聚聚丙烯生产工艺
EP2322568B1 (en) 2009-11-13 2013-05-15 Borealis AG Process for producing an olefin polymerization catalyst
ES2424958T3 (es) 2009-11-13 2013-10-10 Borealis Ag Proceso para polimerización de olefinas
US8603933B2 (en) 2009-11-13 2013-12-10 Borealis Ag Process for recovering a transition metal compound
WO2011058089A1 (en) 2009-11-13 2011-05-19 Borealis Ag Process for producing a polymerization catalyst
EP2374823A1 (en) 2010-04-07 2011-10-12 Borealis AG Production of alpha-olefin copolymers in a loop reactor with variable comonomer feed
EP2402376A1 (en) 2010-06-29 2012-01-04 Borealis AG Process for producing a prepolymerised catalyst, such prepolymerised catalyst and its use for producing a polymer
US9108147B2 (en) * 2010-10-15 2015-08-18 Chevron Phillips Chemical Company Lp Component separations in polymerization
EP2452960B1 (en) 2010-11-12 2015-01-07 Borealis AG Process for preparing propylene polymers with an ultra high melt flow rate
EP2452957A1 (en) 2010-11-12 2012-05-16 Borealis AG Improved process for producing heterophasic propylene copolymers
EP2452959B1 (en) 2010-11-12 2015-01-21 Borealis AG Process for producing propylene random copolymers and their use
EP2452976A1 (en) 2010-11-12 2012-05-16 Borealis AG Heterophasic propylene copolymers with improved stiffness/impact/flowability balance
CN102127263B (zh) * 2011-01-27 2013-01-23 中国汽车工程研究院股份有限公司 一种汽车用釜内合金聚丙烯材料的改性方法
EP2535372B1 (en) 2011-06-15 2016-09-14 Borealis AG In-situ reactor blend of a Ziegler-Natta catalysed, nucleated polypropylene and a metallocene catalysed polypropylene
EP2594333B1 (en) 2011-11-21 2014-07-30 Borealis AG Method for recovering polymer and apparatus therefor
EP2602367B1 (en) * 2011-12-06 2015-05-13 Borealis AG PP copolymers for melt blown/pulp fibrous nonwoven structures with improved mechanical properties and lower hot air consumption
EP2607385B1 (en) 2011-12-19 2014-03-19 Borealis AG Loop reactor providing an advanced production split control
EP2617741B1 (en) 2012-01-18 2016-01-13 Borealis AG Process for polymerizing olefin polymers in the presence of a catalyst system and a method of controlling the process
EP2820053B1 (en) 2012-02-27 2016-12-21 Borealis AG Process for the preparation of polypropylene with low ash content
RU2015106531A (ru) 2012-08-07 2016-09-27 Бореалис Аг Способ получения полипропилена, имеющий повышенную производительность
JP6027240B2 (ja) 2012-08-07 2016-11-16 ボレアリス・アクチェンゲゼルシャフトBorealis Ag 生産性を高めたポリプロピレンの製造方法
US9676532B2 (en) 2012-08-15 2017-06-13 Avery Dennison Corporation Packaging reclosure label for high alcohol content products
EP2719725B1 (en) 2012-10-11 2018-12-05 Abu Dhabi Polymers Company Limited (Borouge) Nucleated polypropylene composition for containers
CN103804556B (zh) * 2012-11-07 2016-09-14 中国石油化工股份有限公司 烯烃聚合方法和乙烯聚合物及其制备方法
ES2531334T3 (es) 2012-11-16 2015-03-13 Borealis Ag Resina de PP altamente isotáctico con ancha distribución de fusión y que tiene mejoradas propiedades como película de BOPP y características de fácil procesamiento
EP2749580B1 (en) 2012-12-28 2016-09-14 Borealis AG Process for producing copolymers of propylene
JP6152219B2 (ja) 2013-04-09 2017-06-21 ボレアリス・アクチェンゲゼルシャフトBorealis Ag ポリプロピレンの製造方法
EP2796499B1 (en) 2013-04-22 2018-05-30 Abu Dhabi Polymers Company Limited (Borouge) Polypropylene composition with improved impact resistance for pipe applications
EP2796501B9 (en) 2013-04-22 2019-05-01 Abu Dhabi Polymers Company Limited (Borouge) Multimodal polypropylene composition for pipe applications
PL2796498T3 (pl) 2013-04-22 2019-03-29 Abu Dhabi Polymers Company Limited (Borouge) Multimodalna kompozycja polipropylenowa do zastosowania w rurach
EP2796473B1 (en) 2013-04-22 2017-05-31 Borealis AG Multistage process for producing low-temperature resistant polypropylene compositions
EP2796474B1 (en) 2013-04-22 2018-01-10 Borealis AG Multistage process for producing polypropylene compositions
ES2632593T3 (es) 2013-04-22 2017-09-14 Borealis Ag Procedimiento de dos fases de producción de composiciones de polipropileno
EP2796502A1 (en) 2013-04-22 2014-10-29 Abu Dhabi Polymers Company Limited (Borouge) Propylene random copolymer composition for pipe applications
PL2796500T3 (pl) 2013-04-22 2018-12-31 Abu Dhabi Polymers Company Limited (Borouge) Kompozycja kopolimeru przypadkowego propylenu do zastosowań do rur
ES2652323T5 (es) 2013-05-22 2021-10-19 Borealis Ag Copolímero de propileno para embalaje de pared delgada
ES2589053T3 (es) 2013-06-10 2016-11-08 Borealis Ag Procedimiento para la preparación de un polímero de propileno
CN105283503A (zh) 2013-06-19 2016-01-27 博里利斯股份公司 具有宽分子量分布的聚丙烯
PL3010974T3 (pl) 2013-06-19 2017-12-29 Borealis Ag Polipropylen o ekstremalnie szerokim rozkładzie masy cząsteczkowej
PL3010947T5 (pl) 2013-06-19 2023-06-19 Borealis Ag Sposób wytwarzania polipropylenu o wysokiej polidyspersyjności
AU2014301234B2 (en) 2013-06-26 2016-11-10 Borealis Ag Propylene copolymer for extrusion blow molded bottles
ES2651456T3 (es) 2013-08-14 2018-01-26 Borealis Ag Composición de propileno con mejor resistencia al impacto a baja temperatura
MX2016001705A (es) 2013-08-21 2016-05-18 Borealis Ag Composicion de poliolefina de alto flujo con alta rigidez y tenacidad.
MX2016001930A (es) 2013-08-21 2016-05-26 Borealis Ag Composicion de poliolefina de alto flujo con alta rigidez y tenacidad.
EP2853562A1 (en) 2013-09-27 2015-04-01 Borealis AG Two-stage process for producing polypropylene compositions
PT2853563T (pt) 2013-09-27 2016-07-14 Borealis Ag Filmes adequados para processamento de bopp a partir de polímeros com xs elevada e tm elevado
ES2568615T3 (es) 2013-10-11 2016-05-03 Borealis Ag Película para etiquetas orientada en la dirección de la máquina
ES2661108T3 (es) 2013-10-24 2018-03-27 Borealis Ag Homopolímero de polipropileno de bajo punto de fusión con alto contenido de regioerrores y alto peso molecular
EP2865713B1 (en) 2013-10-24 2016-04-20 Borealis AG Blow molded article based on bimodal random copolymer
EP3063185B9 (en) 2013-10-29 2017-11-15 Borealis AG Solid single site catalysts with high polymerisation activity
MX368147B (es) 2013-11-22 2019-09-20 Borealis Ag Homopolímero de propileno de baja emisión con alto flujo de masa fundida.
MX366147B (es) 2013-11-22 2019-06-28 Borealis Ag Homopolimero de propileno de baja emision.
WO2015082379A1 (en) 2013-12-04 2015-06-11 Borealis Ag Phthalate-free pp homopolymers for meltblown fibers
BR112016011854B1 (pt) 2013-12-04 2021-09-08 Borealis Ag Composição de polipropileno, artigo, e, uso de uma composição de polipropileno
CN105980457B (zh) 2013-12-18 2019-03-22 博里利斯股份公司 具有改善的刚性/韧性平衡的bopp膜
US20160312018A1 (en) 2013-12-31 2016-10-27 Borealis Ag Process for producing propylene terpolymer
EP3094660B1 (en) 2014-01-17 2018-12-19 Borealis AG Process for preparing propylene/1-butene copolymers
US10100186B2 (en) 2014-02-06 2018-10-16 Borealis Ag Soft and transparent impact copolymers
WO2015117958A1 (en) 2014-02-06 2015-08-13 Borealis Ag Soft copolymers with high impact strength
EP2907841A1 (en) 2014-02-14 2015-08-19 Borealis AG Polypropylene composite
EP2913345B1 (en) 2014-02-28 2016-11-02 Borealis AG Gas phase polymerization process
EP2913346B1 (en) 2014-02-28 2016-11-02 Borealis AG Process for polymerizing olefins in a fluidized bed
EP2933291A1 (en) 2014-04-17 2015-10-21 Borealis AG Propylene copolymer composition for pipe applications
ES2659731T3 (es) 2014-05-20 2018-03-19 Borealis Ag Composición de polipropileno para aplicaciones en interiores de automóviles
CA2951030C (en) 2014-06-02 2023-03-28 Christopher J. Blackwell Films with enhanced scuff resistance, clarity, and conformability
TR201809062T4 (tr) 2014-06-27 2018-07-23 Borealis Ag Çekirdekli polipropilen bileşiği.
EP2965908B1 (en) 2014-07-09 2018-03-21 Borealis AG Propylene random copolymer for film applications
AU2015289353C1 (en) 2014-07-15 2018-06-21 Borealis Ag Nucleated phthalate-free PP homopolymers for melt-blown fibers
KR101907331B1 (ko) 2014-11-26 2018-10-11 보레알리스 아게 필름 층을 위한 폴리에틸렌 조성물
US10494465B2 (en) 2014-11-26 2019-12-03 Borealis Ag Film layer
US11292156B2 (en) 2014-12-08 2022-04-05 Borealis Ag Process for producing pellets of copolymers of propylene
EP3053976A1 (en) 2015-02-09 2016-08-10 Borealis AG Adhesive composition
KR101894687B1 (ko) 2015-02-20 2018-10-04 보레알리스 아게 프로필렌의 헤테로상의 공중합체를 제조하기 위한 공정
WO2016135108A1 (en) 2015-02-25 2016-09-01 Borealis Ag Propylene copolymer composition with improved long-term mechanical properties
CN107580611B (zh) 2015-05-20 2019-12-24 博里利斯股份公司 用于制备聚乙烯组合物的方法
BR112017022651B1 (pt) 2015-06-12 2021-11-16 Borealis Ag Processo para a preparação de composições de polímero de propileno
ES2673428T3 (es) 2015-06-12 2018-06-21 Borealis Ag Procedimiento y aparato para la polimerización de olefinas en fase gaseosa
EP3184167B8 (en) 2015-12-22 2022-03-30 Borealis AG A method for returning polymer to a fluidised bed reactor
EP3184166A1 (en) 2015-12-22 2017-06-28 Borealis AG A method for withdrawing agglomerates from a fluidised bed reactor
WO2017148969A1 (en) 2016-03-04 2017-09-08 Borealis Ag High flow heterophasic polyolefin composition having improved stiffness/impact balance
KR102113467B1 (ko) 2016-03-04 2020-05-22 보레알리스 아게 개선된 강성/충격 균형을 갖는 고 유동 헤테로상 폴리올레핀 조성물
WO2017178046A1 (en) 2016-04-13 2017-10-19 Borealis Ag Injection molded article based on propylene homopolymer
KR20190021323A (ko) 2016-06-17 2019-03-05 보레알리스 아게 낮은 불포화 수준을 갖는 이정 또는 다정 폴리에틸렌
EP3257879A1 (en) 2016-06-17 2017-12-20 Borealis AG Bi- or multimodal polyethylene with low unsaturation level
EP3257895A1 (en) 2016-06-17 2017-12-20 Borealis AG Bi- or multimodal polyethylene terpolymer with enhanced rheological properties
WO2017216094A1 (en) 2016-06-17 2017-12-21 Borealis Ag Bi- or multimodal polyethylene with enhanced rheological properties
KR20190021324A (ko) 2016-06-17 2019-03-05 보레알리스 아게 향상된 유동학적 특성을 갖는 바이모달 또는 멀티모달 폴리에틸렌 삼원공중합체
WO2017220724A1 (en) 2016-06-23 2017-12-28 Borealis Ag Process for catalyst deactivation
WO2018011165A1 (en) 2016-07-12 2018-01-18 Borealis Ag Solid catalyst for the preparation of nucleated polyolefins
IT201600081868A1 (it) * 2016-08-03 2018-02-03 Versalis Spa Metodo e sistema per il controllo di un impianto di produzione in continuo di un polimero.
KR102056578B1 (ko) 2016-12-09 2019-12-17 보레알리스 아게 다층 부직포 구조
CN110177815B (zh) 2017-01-30 2022-06-07 博里利斯股份公司 光学性能改善的多相聚烯烃组合物
US11230637B2 (en) 2017-04-04 2022-01-25 Borealis Ag Soft polypropylene composition with improved properties
EP3395377A1 (en) 2017-04-28 2018-10-31 Borealis AG Soft polypropylene composition with improved properties
EP3625273B1 (en) 2017-05-18 2021-05-05 Borealis AG Heterophasic polyolefin composition with excellent optical properties
CN110678491B (zh) 2017-05-18 2022-04-26 博里利斯股份公司 成核的c3c4共聚物和成核的c3c4c2三元共聚物
EP3418309A1 (en) 2017-06-20 2018-12-26 Borealis AG A method, an arrangement and use of an arrangement of preparing polymer
ES2786756T3 (es) 2017-06-20 2020-10-13 Borealis Ag Un método, una disposición y uso de una disposición para la polimerización de olefinas
ES2786567T3 (es) 2017-06-23 2020-10-13 Borealis Ag Procedimiento y aparato para la retirada de material polimérico de un reactor de polimerización de olefinas con gases y sólido
CA3065881A1 (en) 2017-06-26 2019-01-03 Borealis Ag Polypropylene composition with excellent surface appearance
CN109135067A (zh) 2017-06-27 2019-01-04 阿布扎比聚合物有限责任公司(博禄) 用于制造高压管的聚丙烯组合物
EP3421537B1 (en) 2017-06-29 2023-08-02 Borealis AG Polypropylene composition with outstanding impact performance
PT3456776T (pt) 2017-09-13 2020-03-09 Borealis Ag Composição de polipropileno
CN109627570A (zh) * 2017-10-09 2019-04-16 高煦 丙烯多段聚合方法
DK3473674T3 (da) 2017-10-19 2022-06-20 Abu Dhabi Polymers Co Ltd Borouge Llc Polypropylensammensætning
WO2019081611A1 (en) 2017-10-24 2019-05-02 Borealis Ag MULTILAYER POLYMER FILM
EP3486260B1 (en) 2017-11-17 2020-04-01 Borealis AG Method of splitting the return fluidization gas in a gas solids olefin polymerization reactor
EP3486261B1 (en) 2017-11-17 2020-06-24 Borealis AG Method for improving the cooling capacity of a gas solids olefin polymerization reactor
ES2837424T3 (es) 2017-12-05 2021-06-30 Borealis Ag Composición de polipropileno reforzada con fibra
ES2864224T5 (es) 2017-12-05 2024-11-14 Borealis Ag Composición de polipropileno reforzada con fibra
EP3495423B1 (en) 2017-12-05 2021-03-03 Borealis AG Article comprising a fiber reinforced polypropylene composition
PT3502177T (pt) 2017-12-20 2020-03-17 Borealis Ag Composição de polipropileno
WO2019141462A1 (en) 2018-01-22 2019-07-25 Borealis Ag Nucleated c3c4 copolymers
EP3759147B1 (en) 2018-03-02 2025-10-01 Borealis GmbH Olefin polymerisation process
CN111684006B (zh) 2018-03-21 2023-08-11 博里利斯股份公司 双峰或多峰聚乙烯组合物
PL3567061T3 (pl) 2018-05-09 2024-02-26 Borealis Ag Kompozycja polipropylenowa dla rur
CN108794669A (zh) * 2018-06-13 2018-11-13 浙江卫星能源有限公司 一种丙烯的多段聚合方法及装置
WO2019238428A1 (en) 2018-06-14 2019-12-19 Borealis Ag Process for polymerizing olefin in a gas phase reactor with improved thermal homogeneity
CA3106413A1 (en) 2018-07-19 2020-01-23 Borealis Ag Process for the preparation of an uhmwpe homopolymer
CN112424235B (zh) 2018-08-02 2023-04-21 北欧化工公司 在多阶段聚合工艺中聚合乙烯的方法
CN113242883B (zh) 2018-11-07 2023-09-22 北欧化工公司 抗冲击性和抗致白性改善的聚烯烃组合物
EP3880430B1 (en) 2018-11-15 2024-09-25 ABU DHABI POLYMERS CO. LTD (BOROUGE) - Sole Proprietorship L.L.C. Polymer composition for blow molding applications
EP3887412A1 (en) 2018-11-29 2021-10-06 Borealis AG Process to produce a polymer and polymer
WO2020148319A1 (en) 2019-01-15 2020-07-23 Borealis Ag Random propylene polymer composition and use in extrusion blow moulding
US12359047B2 (en) 2019-04-12 2025-07-15 Borealis Ag Low stress whitening polypropylene composition
CN111848850A (zh) * 2019-04-29 2020-10-30 中国石油化工股份有限公司 一种丙烯聚合方法
CN113993616B (zh) 2019-06-04 2023-06-02 北欧化工股份公司 用于增强气固流化床反应器中流体动力学的方法和反应器组件
EP3980474B1 (en) 2019-06-07 2024-10-02 Borealis AG Heterophasic propylene polymer composition with high toughness and stiffness
EP3983455A1 (en) 2019-06-17 2022-04-20 Borealis AG Articles with high rigidity and low warpage comprising heterophasic propylene polymer composition and uses therefor
US12291594B2 (en) * 2019-06-24 2025-05-06 Borealis Ag Process for preparing polypropylene with improved recovery
EP3766924A1 (en) 2019-07-19 2021-01-20 Borealis AG Polypropylene cast film with improved performance produced by a new process
EP4025614A1 (en) 2019-09-05 2022-07-13 ExxonMobil Chemical Patents Inc. Processes for producing polyolefins and impact copolymers with broad molecular weight distribution and high stiffness
US12509577B2 (en) 2019-09-20 2025-12-30 Borealis Ag Heterophasic propylene polymer composition with improved property profile
EP3835327B1 (en) 2019-12-09 2024-07-31 Borealis AG System for producing polyolefin and process for recovering polymerization product from gas phase reactor
EP3838971B1 (en) 2019-12-16 2023-02-08 Abu Dhabi Polymers Co. Ltd (Borouge) Llc. Foamed polypropylene composition suitable for sheets and articles
US20230056312A1 (en) 2020-01-24 2023-02-23 Exxonmobil Chemical Patents Inc. Methods for producing bimodal polyolefins and impact copolymers
US20230077569A1 (en) 2020-02-17 2023-03-16 Exxonmobil Chemical Patents Inc. Propylene-based polymer compositions having a high molecular weight tail
PL3868793T3 (pl) 2020-02-24 2026-04-20 Borealis Gmbh Sposób produkcji polimerów alfa-olefinowych w procesie polimeryzacji wieloetapowej
EP4126993A1 (en) 2020-03-24 2023-02-08 Borealis AG Polyethylene composition for a film layer
CN115335420B (zh) 2020-03-24 2024-04-05 北欧化工股份公司 膜层用聚乙烯组合物
WO2022018239A1 (en) 2020-07-23 2022-01-27 Borealis Ag Multimodal ethylene copolymer
CN114058112B (zh) * 2020-08-06 2023-08-22 中国石油天然气股份有限公司 一种低熔指无规共聚聚丙烯树脂及其制备方法
CN116547313B (zh) 2020-11-23 2026-03-27 博里利斯股份公司 齐格勒-纳塔催化的成核聚丙烯和茂金属催化的聚丙烯的原位反应器共混物
EP4005669A1 (en) * 2020-11-25 2022-06-01 Borealis AG Propylene polymerization plant revamping process
EP4029914B1 (en) 2021-01-14 2025-03-05 Borealis AG Heterophasic polyolefin composition
CN117897272A (zh) 2021-08-04 2024-04-16 博里利斯股份公司 多层非织造结构
ES2982603T3 (es) 2021-08-31 2024-10-17 Borealis Ag Una mezcla de homopolímero y copolímero aleatorio con un equilibrio beneficioso de propiedades ópticas y mecánicas
US20240409673A1 (en) 2021-10-14 2024-12-12 Borealis Ag Process for forming a ziegler-natta catalyst component
ES3000011T3 (en) 2022-02-28 2025-02-27 Borealis Ag Nucleated bimodal polypropylene
EP4249388B1 (en) 2022-03-23 2024-06-19 Borealis AG Living hinge of an alpha-nucleated propylene copolymer
EP4253453A1 (en) 2022-04-01 2023-10-04 Borealis AG Blown film
PL4257640T3 (pl) 2022-04-04 2025-03-24 Borealis Ag Rura zawierająca kompozycję polipropylonową
US20260015443A1 (en) 2022-07-27 2026-01-15 Exxonmobil Chemical Patents Inc. Polyproplyene compositions with enhanced strain hardening and methods of producing the same
EP4317216A1 (en) 2022-08-03 2024-02-07 Abu Dhabi Polymers Co. Ltd (Borouge) LLC Low density ethylene terpolymer composition
EP4389418A1 (en) 2022-12-19 2024-06-26 Abu Dhabi Polymers Co. Ltd (Borouge) - Sole Proprietorship L.L.C. Multilayer collation shrink film
EP4389414A1 (en) 2022-12-19 2024-06-26 Abu Dhabi Polymers Co. Ltd (Borouge) - Sole Proprietorship L.L.C. Multilayer collation shrink film
EP4389820A1 (en) 2022-12-21 2024-06-26 Borealis AG Polypropylene random copolymer compositions with improved impact resistance for pipe applications
CN120981343A (zh) 2023-03-24 2025-11-18 北欧化工有限责任公司 具有pp-evoh多层结构的无pet包装
EP4450539B1 (en) 2023-04-21 2025-10-29 Borealis GmbH Blown film
EP4450538A1 (en) 2023-04-21 2024-10-23 Borealis AG Blown film
EP4716625A1 (en) 2023-05-23 2026-04-01 Borealis GmbH Process for producing pellets of polyolefins, and pellets so produced
EP4495148A1 (en) 2023-07-21 2025-01-22 Borealis AG Polypropylene compositions with improved sealing and barrier properties
CN121548591A (zh) 2023-07-21 2026-02-17 博里利斯有限责任公司 具有改进的密封和阻隔性能的丙烯组合物
WO2025021581A1 (en) 2023-07-21 2025-01-30 Borealis Ag Cast film comprising polypropylene composition with improved mechanical, optical and barrier properties
EP4541583A1 (en) 2023-10-18 2025-04-23 Abu Dhabi Polymers Co. Ltd (Borouge) - Sole Proprietorship L.L.C. Multilayer film
EP4570856A1 (en) 2023-12-14 2025-06-18 Borealis AG Polypropylene random copolymer compositions with improved impact resistance for pipe applications
EP4624518A1 (en) 2024-03-28 2025-10-01 Borealis GmbH Process for producing blown films based on ssc c2c3 random copolymer
WO2025242653A1 (en) 2024-05-22 2025-11-27 Borealis Gmbh Polyolefin compositions for blown films
CN118491149B (zh) * 2024-07-18 2024-11-26 北京科力丹迪技术开发有限责任公司 一种液相环管聚乙烯装置脱气仓排放气分子综合利用的方法
WO2026022364A1 (en) 2024-07-26 2026-01-29 Borealis Gmbh Cast film consisting of a polypropylene composition
CN119591763A (zh) * 2024-12-17 2025-03-11 浙江大学 一种聚丙烯组合物的聚合方法

Family Cites Families (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3622553A (en) 1967-12-18 1971-11-23 Phillips Petroleum Co Agitated reactor and gas fluidized bed reactor in series for polymerization of vinyl chloride
GB1532231A (en) 1975-04-18 1978-11-15 Ici Ltd Polymerisation process
DE2803281C2 (de) 1978-01-26 1982-12-02 Chemische Werke Hüls AG, 4370 Marl Verfahren zur mehrstufigen Polymerisation von Äthylen, allein oder zusammen mit anderen Olefinen
US4492787A (en) * 1981-09-18 1985-01-08 Mitsubishi Chemical Industries Limited Process for continuously producing propylene-ethylene block copolymer
US4424341A (en) 1981-09-21 1984-01-03 Phillips Petroleum Company Separation of solid polymers and liquid diluent
DZ520A1 (fr) 1982-03-24 2004-09-13 Union Carbide Corp Procédé perfectionné pour accroitre le rendement espace temps d'une réaction de polymérisation exothermique en lit fluidisé.
US4543399A (en) 1982-03-24 1985-09-24 Union Carbide Corporation Fluidized bed reaction systems
US4588790A (en) 1982-03-24 1986-05-13 Union Carbide Corporation Method for fluidized bed polymerization
US4740550A (en) 1986-06-18 1988-04-26 Shell Oil Company Multistage copolymerization process
US4740551A (en) * 1986-06-18 1988-04-26 Shell Oil Company Multistage copolymerization process
DE3751734T2 (de) * 1986-07-22 1996-09-19 Mitsubishi Chem Corp Verfahren zur Herstellung von alpha-Olefin-Blockcopolymeren
CA1284549C (en) * 1986-09-26 1991-05-28 Fathi David Hussein Process for the polymerization of propylene
DE3881728T3 (de) * 1987-03-14 1998-01-15 Mitsubishi Chem Ind Verfahren zur Herstellung eines Propylen-alpha-Olefin-Blockkopolymers.
US5234879A (en) 1990-12-19 1993-08-10 Neste Oy Method for the modification of catalysts intended for the polymerization of olefins
FI89929C (fi) 1990-12-28 1993-12-10 Neste Oy Foerfarande foer homo- eller sampolymerisering av eten
FI86867C (fi) 1990-12-28 1992-10-26 Neste Oy Flerstegsprocess foer framstaellning av polyeten
FI94164C (fi) 1991-03-21 1995-07-25 Borealis Polymers Oy Menetelmä juoksevaksi saatetun polymerointikatalyytin annostelemiseksi polymerointireaktoriin
FI88048C (fi) 1991-05-09 1993-03-25 Neste Oy Grovkornig polyolefin, dess framstaellningsmetod och en i metoden anvaend katalysator
FI88047C (fi) 1991-05-09 1993-03-25 Neste Oy Pao tvenne elektrondonorer baserad katalysator foer polymerisation av olefiner
FI88049C (fi) 1991-05-09 1993-03-25 Neste Oy Polyolefin med stora porer, foerfarande foer dess framstaellning och en i foerfarandet anvaend katalysator
IT1246614B (it) 1991-06-03 1994-11-24 Himont Inc Procedimento per la polimerizzazione in fase gas delle olefine
IT1254279B (it) 1992-03-13 1995-09-14 Montecatini Tecnologie Srl Procedimento per la polimerizzazione in fase gas delle olefine
FI95387C (fi) 1992-12-29 1996-01-25 Borealis As Menetelmä -olefiinien polymeroimiseksi sekä esipolymeroitu katalyyttikompositio ja menetelmä tämän valmistamiseksi
EP1623999A1 (en) 1993-04-26 2006-02-08 ExxonMobil Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
ZA943399B (en) 1993-05-20 1995-11-17 Bp Chem Int Ltd Polymerisation process
FI96615C (fi) 1993-06-04 1996-07-25 Neste Oy Menetelmä C4-C40- -olefiinien polymeroimiseksi tai kopolymeroimiseksi muiden -olefiinien kanssa
US5453471B1 (en) 1994-08-02 1999-02-09 Carbide Chemicals & Plastics T Gas phase polymerization process
FI96216C (fi) * 1994-12-16 1996-05-27 Borealis Polymers Oy Prosessi polyeteenin valmistamiseksi
JP3355864B2 (ja) * 1995-04-24 2002-12-09 チッソ株式会社 高剛性プロピレン・エチレンブロック共重合体の連続製造法
JP3421053B2 (ja) * 1995-10-10 2003-06-30 ボレアリス、アクティーゼルスカブ プロピレンホモポリマーもしくはコポリマーを製造する方法
FI105820B (fi) * 1995-10-10 2000-10-13 Borealis Tech Oy Prosessi propeenin homo- tai kopolymeerien valmistamiseksi
FI105818B (fi) 1996-03-13 2000-10-13 Borealis Tech Oy Prosessi olefiinimonomeerien polymeroimiseksi
FI963707A0 (fi) 1996-09-19 1996-09-19 Borealis Polymers Oy Foerfarande foer polymerisering av alfa-olefiner, vid polymerisering anvaendbar katalysator och foerfarande foer framstaellning av densamma

Also Published As

Publication number Publication date
FI972729A0 (fi) 1997-06-24
EP0991684B1 (en) 2006-01-25
WO1998058977A1 (en) 1998-12-30
ES2256942T3 (es) 2006-07-16
FI972729A7 (fi) 1998-12-25
DE69833324T2 (de) 2006-09-21
AU7921298A (en) 1999-01-04
JP2002504955A (ja) 2002-02-12
US6469110B1 (en) 2002-10-22
EP0991684A1 (en) 2000-04-12
FI111846B (fi) 2003-09-30
ATE316539T1 (de) 2006-02-15
CN1140555C (zh) 2004-03-03
DE69833324D1 (de) 2006-04-13
CN1268146A (zh) 2000-09-27

Similar Documents

Publication Publication Date Title
JP3825478B2 (ja) ポリプロピレンアロイの製造方法
JP5072637B2 (ja) プロピレンポリマーの製造方法
KR100576928B1 (ko) 프로필렌 단일중합체 및 공중합체를 제조하는 방법 및 장치
EP0887381B1 (en) Process for preparing propylene polymers and impact modified polymers
EP0887380B1 (en) Process for preparing propylene copolymers
US5610244A (en) Process for the gas phase polymerization of alpha-olefins
KR100414235B1 (ko) 프로필렌단일중합체또는공중합체를제조하는방법
KR0175672B1 (ko) 알파-올레핀의 기체상 중합 방법 및 이를 위한 장치
EP2788393A2 (en) Multistage process for the polymerization of olefins
CN101065408B (zh) 浆料相聚合法
JP2018021123A (ja) ポリオレフィン製造システム、ポリオレフィンの製造方法およびヘテロファジックプロピレン重合材料の製造方法
CN101072799B (zh) 浆料相聚合法
EP3986608B1 (en) Process for preparing polypropylene with improved recovery

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20040602

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20040602

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20051101

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20051024

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20060131

A602 Written permission of extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A602

Effective date: 20060320

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20060501

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20060620

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20060630

R150 Certificate of patent or registration of utility model

Free format text: JAPANESE INTERMEDIATE CODE: R150

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20090707

Year of fee payment: 3

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20100707

Year of fee payment: 4

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20110707

Year of fee payment: 5

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20110707

Year of fee payment: 5

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20120707

Year of fee payment: 6

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20120707

Year of fee payment: 6

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20130707

Year of fee payment: 7

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

LAPS Cancellation because of no payment of annual fees