JP2021511420A - ポリエステルアミド組成物を含む中間膜 - Google Patents
ポリエステルアミド組成物を含む中間膜 Download PDFInfo
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- JP2021511420A JP2021511420A JP2020540298A JP2020540298A JP2021511420A JP 2021511420 A JP2021511420 A JP 2021511420A JP 2020540298 A JP2020540298 A JP 2020540298A JP 2020540298 A JP2020540298 A JP 2020540298A JP 2021511420 A JP2021511420 A JP 2021511420A
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- Prior art keywords
- acid
- interlayer film
- mol
- diol
- diamine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920006149 polyester-amide block copolymer Polymers 0.000 title claims abstract description 177
- 239000000203 mixture Substances 0.000 title claims description 99
- 239000012528 membrane Substances 0.000 title description 5
- 239000011229 interlayer Substances 0.000 claims abstract description 242
- 150000002009 diols Chemical class 0.000 claims abstract description 119
- 239000010410 layer Substances 0.000 claims description 174
- 150000004985 diamines Chemical class 0.000 claims description 101
- 239000011521 glass Substances 0.000 claims description 85
- 238000000034 method Methods 0.000 claims description 47
- 239000002253 acid Substances 0.000 claims description 46
- -1 alicyclic diamine Chemical class 0.000 claims description 43
- IGSBHTZEJMPDSZ-UHFFFAOYSA-N 4-[(4-amino-3-methylcyclohexyl)methyl]-2-methylcyclohexan-1-amine Chemical group C1CC(N)C(C)CC1CC1CC(C)C(N)CC1 IGSBHTZEJMPDSZ-UHFFFAOYSA-N 0.000 claims description 38
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 38
- 125000000217 alkyl group Chemical group 0.000 claims description 36
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims description 36
- DZIHTWJGPDVSGE-UHFFFAOYSA-N 4-[(4-aminocyclohexyl)methyl]cyclohexan-1-amine Chemical compound C1CC(N)CCC1CC1CCC(N)CC1 DZIHTWJGPDVSGE-UHFFFAOYSA-N 0.000 claims description 34
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 claims description 32
- 230000009477 glass transition Effects 0.000 claims description 31
- 239000000758 substrate Substances 0.000 claims description 25
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 claims description 24
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 claims description 24
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 20
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 19
- 239000001361 adipic acid Substances 0.000 claims description 19
- 235000011037 adipic acid Nutrition 0.000 claims description 19
- 238000003860 storage Methods 0.000 claims description 19
- 239000000654 additive Substances 0.000 claims description 18
- 239000006085 branching agent Substances 0.000 claims description 18
- XBZSBBLNHFMTEB-UHFFFAOYSA-N cyclohexane-1,3-dicarboxylic acid Chemical compound OC(=O)C1CCCC(C(O)=O)C1 XBZSBBLNHFMTEB-UHFFFAOYSA-N 0.000 claims description 18
- BNJOQKFENDDGSC-UHFFFAOYSA-N octadecanedioic acid Chemical compound OC(=O)CCCCCCCCCCCCCCCCC(O)=O BNJOQKFENDDGSC-UHFFFAOYSA-N 0.000 claims description 18
- FQXGHZNSUOHCLO-UHFFFAOYSA-N 2,2,4,4-tetramethyl-1,3-cyclobutanediol Chemical compound CC1(C)C(O)C(C)(C)C1O FQXGHZNSUOHCLO-UHFFFAOYSA-N 0.000 claims description 16
- 229960002255 azelaic acid Drugs 0.000 claims description 16
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 claims description 16
- LWBHHRRTOZQPDM-UHFFFAOYSA-N undecanedioic acid Chemical compound OC(=O)CCCCCCCCCC(O)=O LWBHHRRTOZQPDM-UHFFFAOYSA-N 0.000 claims description 16
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 15
- 229910000077 silane Inorganic materials 0.000 claims description 14
- PXGZQGDTEZPERC-UHFFFAOYSA-N 1,4-cyclohexanedicarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)CC1 PXGZQGDTEZPERC-UHFFFAOYSA-N 0.000 claims description 13
- 125000004427 diamine group Chemical group 0.000 claims description 13
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 12
- QQHJDPROMQRDLA-UHFFFAOYSA-N hexadecanedioic acid Chemical compound OC(=O)CCCCCCCCCCCCCCC(O)=O QQHJDPROMQRDLA-UHFFFAOYSA-N 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 11
- YZZSUMQSGLJDRY-UHFFFAOYSA-N 9-nonyl-10-octylnonadecanedioic acid Chemical compound CCCCCCCCCC(CCCCCCCC(O)=O)C(CCCCCCCC)CCCCCCCCC(O)=O YZZSUMQSGLJDRY-UHFFFAOYSA-N 0.000 claims description 9
- 229920000305 Nylon 6,10 Polymers 0.000 claims description 8
- LUSFFPXRDZKBMF-UHFFFAOYSA-N [3-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCCC(CO)C1 LUSFFPXRDZKBMF-UHFFFAOYSA-N 0.000 claims description 8
- 235000011187 glycerol Nutrition 0.000 claims description 8
- 229910052739 hydrogen Inorganic materials 0.000 claims description 8
- DXNCZXXFRKPEPY-UHFFFAOYSA-N tridecanedioic acid Chemical compound OC(=O)CCCCCCCCCCCC(O)=O DXNCZXXFRKPEPY-UHFFFAOYSA-N 0.000 claims description 8
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 7
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims description 7
- WYHYNUWZLKTEEY-UHFFFAOYSA-N cyclobutane-1,3-dicarboxylic acid Chemical compound OC(=O)C1CC(C(O)=O)C1 WYHYNUWZLKTEEY-UHFFFAOYSA-N 0.000 claims description 7
- YZVSPSQWIMUTNR-UHFFFAOYSA-N cyclooctane-1,4-dicarboxylic acid Chemical compound OC(=O)C1CCCCC(C(O)=O)CC1 YZVSPSQWIMUTNR-UHFFFAOYSA-N 0.000 claims description 7
- RGXHXYGKBCOAFK-UHFFFAOYSA-N cyclooctane-1,5-dicarboxylic acid Chemical compound OC(=O)C1CCCC(C(O)=O)CCC1 RGXHXYGKBCOAFK-UHFFFAOYSA-N 0.000 claims description 7
- LNGJOYPCXLOTKL-UHFFFAOYSA-N cyclopentane-1,3-dicarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)C1 LNGJOYPCXLOTKL-UHFFFAOYSA-N 0.000 claims description 7
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 claims description 7
- QFGCFKJIPBRJGM-UHFFFAOYSA-N 12-[(2-methylpropan-2-yl)oxy]-12-oxododecanoic acid Chemical compound CC(C)(C)OC(=O)CCCCCCCCCCC(O)=O QFGCFKJIPBRJGM-UHFFFAOYSA-N 0.000 claims description 6
- VPRCINUSGGYBRP-UHFFFAOYSA-N 2,4,4-trimethylhexane-1,1-diamine Chemical compound CCC(C)(C)CC(C)C(N)N VPRCINUSGGYBRP-UHFFFAOYSA-N 0.000 claims description 6
- 230000000996 additive effect Effects 0.000 claims description 6
- ARCGXLSVLAOJQL-UHFFFAOYSA-N anhydrous trimellitic acid Natural products OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 claims description 6
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims description 6
- MOFBDJIQKHNGPG-UHFFFAOYSA-N 2,2,4-trimethylhexane-1,1-diamine Chemical compound CCC(C)CC(C)(C)C(N)N MOFBDJIQKHNGPG-UHFFFAOYSA-N 0.000 claims description 5
- AMOKUAKXKXBFIW-WJDWOHSUSA-N 9-[(z)-non-3-enyl]-10-octylnonadecanedioic acid Chemical compound OC(=O)CCCCCCCCC(CCCCCCCC)C(CCCCCCCC(O)=O)CC\C=C/CCCCC AMOKUAKXKXBFIW-WJDWOHSUSA-N 0.000 claims description 5
- GMTFURRRXIRGLH-UHFFFAOYSA-N C12CCCC2C2(CN)CC1CC2 Chemical compound C12CCCC2C2(CN)CC1CC2 GMTFURRRXIRGLH-UHFFFAOYSA-N 0.000 claims description 5
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 5
- QLBRROYTTDFLDX-UHFFFAOYSA-N [3-(aminomethyl)cyclohexyl]methanamine Chemical compound NCC1CCCC(CN)C1 QLBRROYTTDFLDX-UHFFFAOYSA-N 0.000 claims description 5
- HXWSPWCLUDELMS-UHFFFAOYSA-N cycloheptane-1,4-dicarboxylic acid Chemical compound OC(=O)C1CCCC(C(O)=O)CC1 HXWSPWCLUDELMS-UHFFFAOYSA-N 0.000 claims description 5
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 4
- PTBDIHRZYDMNKB-UHFFFAOYSA-N 2,2-Bis(hydroxymethyl)propionic acid Chemical compound OCC(C)(CO)C(O)=O PTBDIHRZYDMNKB-UHFFFAOYSA-N 0.000 claims description 4
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 claims description 4
- ZQHYXNSQOIDNTL-UHFFFAOYSA-N 3-hydroxyglutaric acid Chemical compound OC(=O)CC(O)CC(O)=O ZQHYXNSQOIDNTL-UHFFFAOYSA-N 0.000 claims description 4
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 4
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 4
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 4
- 239000004386 Erythritol Substances 0.000 claims description 4
- UNXHWFMMPAWVPI-UHFFFAOYSA-N Erythritol Natural products OCC(O)C(O)CO UNXHWFMMPAWVPI-UHFFFAOYSA-N 0.000 claims description 4
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 4
- UNXHWFMMPAWVPI-ZXZARUISSA-N erythritol Chemical compound OC[C@H](O)[C@H](O)CO UNXHWFMMPAWVPI-ZXZARUISSA-N 0.000 claims description 4
- 235000019414 erythritol Nutrition 0.000 claims description 4
- 229940009714 erythritol Drugs 0.000 claims description 4
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 4
- 239000000600 sorbitol Substances 0.000 claims description 4
- 239000011975 tartaric acid Substances 0.000 claims description 4
- 235000002906 tartaric acid Nutrition 0.000 claims description 4
- 125000005590 trimellitic acid group Chemical group 0.000 claims description 4
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 claims description 4
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 claims description 4
- ANSXAPJVJOKRDJ-UHFFFAOYSA-N furo[3,4-f][2]benzofuran-1,3,5,7-tetrone Chemical compound C1=C2C(=O)OC(=O)C2=CC2=C1C(=O)OC2=O ANSXAPJVJOKRDJ-UHFFFAOYSA-N 0.000 claims description 3
- 150000001991 dicarboxylic acids Chemical class 0.000 claims 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N hexane Substances CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 abstract description 8
- 239000000178 monomer Substances 0.000 abstract description 8
- 238000010586 diagram Methods 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 description 119
- 239000004014 plasticizer Substances 0.000 description 30
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 24
- 229920002554 vinyl polymer Polymers 0.000 description 22
- 229920005989 resin Polymers 0.000 description 21
- 239000011347 resin Substances 0.000 description 21
- 239000000463 material Substances 0.000 description 19
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 19
- 229920006324 polyoxymethylene Polymers 0.000 description 18
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 18
- 238000000576 coating method Methods 0.000 description 17
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- 239000011248 coating agent Substances 0.000 description 14
- 230000003287 optical effect Effects 0.000 description 14
- 150000001299 aldehydes Chemical class 0.000 description 13
- 229910052751 metal Inorganic materials 0.000 description 13
- 239000002184 metal Substances 0.000 description 13
- TVIDDXQYHWJXFK-UHFFFAOYSA-N n-Dodecanedioic acid Natural products OC(=O)CCCCCCCCCCC(O)=O TVIDDXQYHWJXFK-UHFFFAOYSA-N 0.000 description 13
- WTKWFNIIIXNTDO-UHFFFAOYSA-N 3-isocyanato-5-methyl-2-(trifluoromethyl)furan Chemical compound CC1=CC(N=C=O)=C(C(F)(F)F)O1 WTKWFNIIIXNTDO-UHFFFAOYSA-N 0.000 description 12
- NOKSMMGULAYSTD-UHFFFAOYSA-N [SiH4].N=C=O Chemical class [SiH4].N=C=O NOKSMMGULAYSTD-UHFFFAOYSA-N 0.000 description 12
- 239000000155 melt Substances 0.000 description 12
- 229910052757 nitrogen Inorganic materials 0.000 description 12
- HQHCYKULIHKCEB-UHFFFAOYSA-N tetradecanedioic acid Natural products OC(=O)CCCCCCCCCCCCC(O)=O HQHCYKULIHKCEB-UHFFFAOYSA-N 0.000 description 12
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 10
- 229920000728 polyester Polymers 0.000 description 10
- 229920006254 polymer film Polymers 0.000 description 10
- 239000002952 polymeric resin Substances 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 9
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 9
- 238000001125 extrusion Methods 0.000 description 9
- 239000004593 Epoxy Substances 0.000 description 8
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 8
- 229910052799 carbon Inorganic materials 0.000 description 8
- 238000009472 formulation Methods 0.000 description 8
- 230000008569 process Effects 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 8
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 7
- 239000003054 catalyst Substances 0.000 description 7
- 229920001577 copolymer Polymers 0.000 description 7
- 239000012792 core layer Substances 0.000 description 7
- 239000005340 laminated glass Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- KYXHKHDZJSDWEF-LHLOQNFPSA-N CCCCCCC1=C(CCCCCC)C(\C=C\CCCCCCCC(O)=O)C(CCCCCCCC(O)=O)CC1 Chemical compound CCCCCCC1=C(CCCCCC)C(\C=C\CCCCCCCC(O)=O)C(CCCCCCCC(O)=O)CC1 KYXHKHDZJSDWEF-LHLOQNFPSA-N 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- 239000000853 adhesive Substances 0.000 description 6
- 230000001070 adhesive effect Effects 0.000 description 6
- QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 239000000539 dimer Substances 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 125000000623 heterocyclic group Chemical group 0.000 description 6
- 239000004417 polycarbonate Substances 0.000 description 6
- 229920000515 polycarbonate Polymers 0.000 description 6
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- 239000000243 solution Substances 0.000 description 6
- 229920003002 synthetic resin Polymers 0.000 description 6
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 5
- AMIMRNSIRUDHCM-UHFFFAOYSA-N Isopropylaldehyde Chemical compound CC(C)C=O AMIMRNSIRUDHCM-UHFFFAOYSA-N 0.000 description 5
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- 239000006096 absorbing agent Substances 0.000 description 5
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 5
- 150000001602 bicycloalkyls Chemical group 0.000 description 5
- 238000000113 differential scanning calorimetry Methods 0.000 description 5
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- SFMPLSNCCXLXBZ-UHFFFAOYSA-N ethyl 2-[2-(2-chlorophenyl)hydrazinyl]-2-(oxolan-2-ylmethylimino)acetate Chemical compound C1CCOC1CN=C(C(=O)OCC)NNC1=CC=CC=C1Cl SFMPLSNCCXLXBZ-UHFFFAOYSA-N 0.000 description 5
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- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 4
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical group CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 239000004262 Ethyl gallate Substances 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
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- OXIKYYJDTWKERT-UHFFFAOYSA-N [4-(aminomethyl)cyclohexyl]methanamine Chemical compound NCC1CCC(CN)CC1 OXIKYYJDTWKERT-UHFFFAOYSA-N 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 4
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- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 4
- 238000000937 dynamic scanning calorimetry Methods 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
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- 230000002194 synthesizing effect Effects 0.000 description 4
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- 238000002834 transmittance Methods 0.000 description 4
- LGYNIFWIKSEESD-UHFFFAOYSA-N 2-ethylhexanal Chemical compound CCCCC(CC)C=O LGYNIFWIKSEESD-UHFFFAOYSA-N 0.000 description 3
- JJOJFIHJIRWASH-UHFFFAOYSA-N Eicosanedioic acid Natural products OC(=O)CCCCCCCCCCCCCCCCCCC(O)=O JJOJFIHJIRWASH-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
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- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 3
- 239000004952 Polyamide Substances 0.000 description 3
- 239000004721 Polyphenylene oxide Substances 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
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- 238000004383 yellowing Methods 0.000 description 1
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Abstract
Description
単数形の「a」、「an」、及び「the」は、文脈が明らかに他に示していない限りにおいて複数の指示対象を含む。
「二酸」は、2つのカルボン酸基を有する化学物質を意味する。例としては、1,12−ドデカン二酸、アジピン酸、シクロヘキサンジカルボン酸などが挙げられる。
本出願は、(a)脂環式ジアミン、脂肪族ジアミン、又はこれらの組合せから誘導されるジオール残基0.1〜99モル%を含むジアミン成分;(b)脂環式ジオール、複数の脂環式ジオールの混合物、又は脂環式ジオールと脂肪族ジオールとの混合物である少なくとも1種類のジオールから誘導されるジオール残基0.1〜99モル%を含むジオール成分;及び(c)HO2C−(C2−40)アルキレン−CO2H、又はHO2C−(C3−10)シクロアルキル−CO2H(式中、それぞれのシクロアルキルは非置換であるか又は(C1−3)アルキルによって置換されている)から選択される二酸から誘導される二酸残基0.1〜100モル%を含む二酸成分;を含み;二酸成分の総モル%は100モル%であり、ジオール及びジアミン成分の合計の総モル%は100モル%であるポリエステルアミドを開示する。
本出願はまた、本明細書中に開示されるポリエステルアミドを含む組成物にも関する。本組成物には、当業者に公知の添加剤を更に含ませることができる。一実施形態においては、本組成物は、酸化防止剤、着色剤、離型剤、難燃剤、可塑剤、成核剤、UV安定剤、UV吸収剤、熱安定剤、ガラス繊維、炭素繊維、フィラー、耐衝撃性改良剤、及びシラン(例えばエポキシシラン又はイソシアネートシラン)から選択される添加剤を更に含む。他の実施形態においては、本組成物は1種類より多い添加剤を含む。
本出願はまた、本明細書に開示されるポリエステルアミド又は組成物を含む層、中間膜、シート、又はフィルムにも関する。幾つかの実施形態においては、ポリエステルアミドはアモルファスであってよく、一方で他の実施形態においては、ポリエステルアミドは半結晶質であってよい。本明細書に開示されるポリエステルアミド又は組成物を含む層、中間膜、シート、又はフィルムを形成する方法は、当該技術において周知である。かかる層、中間膜、シート、又はフィルムは、本発明の種々の実施形態によるポリエステルアミド又は組成物から、任意の好適な方法を用いて製造することができ、これとしては、押出、共押出、カレンダー加工、圧縮成形、射出成形、及び溶液キャストが挙げられるが、これらに限定されない。
幾つかの実施形態においては、中間膜は少なくとも40℃のガラス転移温度を有する。幾つかの実施形態においては、中間膜は、DMTAにしたがって求めて、少なくとも50℃、少なくとも55℃、少なくとも60℃、少なくとも65℃、少なくとも70℃、又はそれ以上のガラス転移温度を有する。他の実施形態においては、中間膜は、DMTAにしたがって求めて、40℃未満、35℃未満、30℃未満、又は25℃未満のガラス転移温度値を有する。幾つかの実施形態においては、層又は中間膜は、少なくとも−35℃、少なくとも0℃、少なくとも5℃、少なくとも10℃、又はそれ以上のガラス転移温度を有する。
触媒を用いて1つ又は複数の反応を触媒することができる。使用することができる触媒の例は、チタン、スズ、ガリウム、亜鉛、アンチモン、コバルト、マンガン、ゲルマニウム、アルカリ金属、特にリチウム及びナトリウム、アルカリ土類化合物、アルミニウム化合物、アルミニウム化合物と水酸化リチウム又は水酸化ナトリウムとの組み合わせをベースとする。この実施形態の1つのクラスにおいては、触媒は1〜500ppm存在する。このクラスの1つのサブクラスにおいては、触媒はスズ触媒である。このクラスの1つのサブクラスにおいては、触媒はチタン触媒である。
ADはアジピン酸であり;AZはアゼライン酸であり;1,4−BODは1,4−ブタンジオールであり;DDAは1,12−ドデカン二酸であり;1,4−CHDAは1,4−シクロヘキサンジカルボン酸であり;1,3−CHDAは1,3−シクロヘキサンジカルボン酸であり;ECTMSはトリメトキシ[2−(7−オキサビシクロ[4.1.0]ヘプト−3−イル)エチル]シランであり;GPTMSは(3−グリシジルオキシプロピル)トリメトキシシランであり;H2−ダイマーは水素化ダイマー酸(Pripol 1009、登録番号127290−22−6)であり;MACMは4,4’−メチレンビス(2−メチルシクロヘキシルアミン)で、異性体の混合物であり;MDEAはN−メチルジエタノールアミンであり;ODAは1,18−オクタデカン酸であり;PACMは4,4’−メチレンビス(シクロヘキシルアミン)で、異性体の混合物であり;PTMGはポリテトラヒドロフランジオールであり;SEはセバシン酸であり;T928はTinuvin 928(2−(2H−ベンゾトリアゾル−2−イル)−6−(1−メチル−1−フェニルエチル)−4−(1,1,3,3−テトラメチルブチル)フェノールであり;TCDAは3(4).8(9)−ビス(アミノメチル)トリシクロ[5.2.1.02.6]デカンであり;TMCAは5−アミノ−1,3,3−トリメチルシクロヘキサンメチルアミンであり;TMPはトリメチロールプロパンであり;CHDMAは1,4−ビス(アミノメチル)シクロヘキサンであり;1,3−CHDMAは1,3−ビス(アミノメチル)シクロヘキサンであり;TMCDは2,2,4,4−テトラメチル−1,3−シクロブタンジオールであり;CHDMは1,4−シクロヘキサンジメタノールであり;MPMDは2−メチルペンタメチルジアミンであり;minは分であり;TMHDは2,4,4−トリメチルヘキサンジアミンと2,2,4−トリメチルヘキサンジアミンの混合物である。
本発明において有用な特定のポリマー材料のインヘレント粘度(IV)は、ASTM−D2857−70の手順にしたがい、1/2mLの毛細球を有するLab Glass, Inc.のWagner粘度計において、重量基準で60/40のフェノール/テトラクロロエタン中約0.5重量%のポリマー濃度を使用して求める。この手順は、ポリマー/溶媒系を120℃で15分間加熱し、溶液を25℃に冷却し、25℃における流動時間を測定することによって実施する。IVは、式:
から計算される。インヘレント粘度の単位は、本出願全体を通してデシリットル/グラムである。
にしたがって計算した。
示差走査熱量測定熱分析:
DSC実験は、TA Instrument Q2000−DSCにおいて、冷蔵冷却システムを用いて窒素下で行った。装置の温度及び融解熱は、アダマンタン、鉛、及びインジウムを用いて定期的に較正して検証する。凡その試料をアルミニウムパン内に密封した。試料パンを−50℃で平衡化した後、20℃/分の走査速度で250℃に加熱した。次に、試料を250℃で1分間等温保持して、その熱履歴を除去した。その後、試料パンを20℃/分の速度で−50℃に冷却した後、同じ走査速度で250℃に再加熱した。第2の加熱走査中にガラス転移温度及び融解ピークの両方が獲得された。
ポリマー層のガラス転移温度は、以下の手順にしたがって、動的機械熱分析(DMTA)によって求めることができる。ポリマーシートを直径8ミリメートル(mm)の試料ディスクに成形する。ポリマー試料ディスクを、Rheometrics Dynamic Spectrometer IIの2つの平行プレート試験治具の間に配置する。試料の温度を3℃/分の速度で20℃から100℃へ上昇させながら、ポリマー試料ディスクを剪断モードにおいて1ヘルツの振動数で試験する。温度に依存してプロットしたtanδ(減衰)の最大値の位置を用いてガラス転移温度を求める。実験は、この方法が±1℃の範囲内で再現可能であることを示している。
アジピン酸(43.84g、0.30モル、10当量)、2,2,4,4−テトラメチルシクロブタンジオール(9.08g、0.06モル、2当量)、及びチタンテトライソプロポキシド溶液(イソプロパノール中0.1M、2.6mL、0.26ミリモル)の混合物を、乾燥窒素流下250℃において溶融した。温度を275℃に徐々に上昇させ、275℃において30分間保持した。その時点で、4,4’−メチレンビス(2−メチルシクロヘキシルアミン)(57.22g、0.24モル、8当量)及び水(30mL)を加えた。温度を300℃に徐々に上昇させた。反応混合物を溶融状態に維持するために、必要に応じて温度を上昇させる。次に、この系を高真空(0.1torr)にかけて揮発性物質を除去した。次に、300℃において90分間加熱することによって溶融物を重合させて、実施例1を与えた。
1,12−ドデカン二酸(69.09g、0.3モル、10当量)、2,2,4,4−テトラメチルシクロブタンジオール(29.85g、0.207モル、6.9当量)、4,4’−メチレンビス(2−メチルシクロヘキシルアミン)(14.30g、0.06モル、2.06当量)、4,4’−メチレンビスシクロヘキシルアミン(16.41g、0.078モル、2.6当量)、及びブチルスズトリス−2−エチルヘキサノエート(ブタノール中1.7重量%、1.26mL、200ppm)の混合物を、窒素のための入口、金属スターラー、及び短蒸留カラムを備えた500mLフラスコ中に配置した。フラスコを、乾燥窒素流下において200℃の溶融金属浴中に浸漬した。1分後、浴温を60分間かけて250℃に、そして60分間かけて275℃に徐々に上昇させた。275℃において30分間保持した後、混合物を、次の15分間かけて0.5torrの設定点まで徐々に真空にかけた。溶融物を0.5torrの設定点において275℃に130分間保持して、実施例2を得た。
アジピン酸(146.15g、1.0モル、10当量)、1,4−シクロヘキサンジメタノール(102.40g、0.71モル、7.1当量)、4,4’−メチレンビス(2−メチルシクロヘキシルアミン)(75.29g、0.31モル、3.1当量)、及び水(20mL)の混合物を、窒素のための入口、金属スターラー、及び短蒸留カラムを備えた1リットルのフラスコ中に配置した。フラスコを、乾燥窒素流下において180℃の溶融金属浴中に浸漬した。1分後、浴温を10分間かけて210℃に徐々に上昇させ、210℃において30分間保持した。チタンテトライソプロポキシド溶液(イソプロパノール中0.47重量%、3.0mL、50ppm)を、サイドポートを通して加えた。得られた混合物を250℃に30分間、次に275℃に10分間加熱し、275℃において40分間保持した。次の20分間かけて、0.5トルの設定値まで徐々に真空を印加した。溶融物を0.5torrの設定点において275℃に270分間保持して、実施例3を得た。
1,12−ドデカン二酸(80.61g、0.35モル、10当量)、1,4−シクロヘキサンジメタノール(29.28g、0.203モル、5.5当量)、4,4’−メチレンビス(2−メチルシクロヘキシルアミン)(20.86g、0.088モル、2.5当量)、4,4’−メチレンビスシクロヘキシルアミン(14.73g、0.070モル、2.0当量)、及びチタンテトライソプロポキシド(ブタノール中0.944重量%、0.4mL、30ppm)の混合物を、窒素のための入口、金属スターラー、及び短蒸留カラムを備えた500mLフラスコ中に配置した。フラスコを、乾燥窒素流下において200℃の溶融金属浴中に浸漬した。1分後、浴温を180分間かけて275℃に徐々に上昇させた。275℃において30分間保持した後、混合物を次の15分間かけて0.5torrの設定点まで徐々に真空にかけた。溶融物を、0.5torrの設定点において275℃に260分間保持して、実施例4を得た。
1,4−シクロヘキサンジカルボン酸(17.29g、0.1モル、10当量)、1,4−シクロヘキサンジメタノール(11.54g、0.08モル、8当量)、1,4−シクロヘキサンビス(メチルアミン)(4.27g、0.03モル、3当量)、及びチタンテトライソプロポキシド(イソプロパノール中0.1M、0.2mL、2.0×10−3当量)の混合物を、窒素のための入口、金属スターラー、及び短蒸留カラムを備えた250mLフラスコ中に配置した。フラスコを、乾燥窒素流下において250℃の溶融金属浴中に浸漬した。20分後、浴温を30分間かけて280℃に徐々に上昇させた。280℃において1分間保持した後、浴温を10分間かけて305℃に更に上昇させて0.5分間保持した。混合物を、次の15分間かけて0.5mmHgの設定点まで徐々に真空にかけた。溶融物を、305℃、0.5mmHgにおいて89.5分間保持して、実施例5を得た。
1,12−ドデカン二酸(92.12g、0.40モル、10当量)、1,4−シクロヘキサンジメタノール(32.30g、0.22モル、5.6当量)、4,4’−メチレンビス(2−メチルシクロヘキシルアミン)(44.82g、0.19モル、4.7当量)、及びチタンテトライソプロポキシド(ブタノール中0.64重量%、1.19g、50ppm)の混合物を、窒素用の入口、金属スターラー、及び短蒸留カラムを備えた500mLフラスコ中に配置した。フラスコを、乾燥窒素流下において200℃の溶融金属浴中に浸漬した。1分後、浴温を180分間かけて290℃に徐々に上昇させた。290℃に達した後、トリメトキシ[2−(7−オキサビシクロ[4.1.0]ヘプト−3−イル)エチル]シラン(トルエン中10wt%、2.46g、0.25%)を、サイドポートを通して加えた。290℃において30分間保持した後、混合物を、次の15分間かけて0.5torrの設定点まで徐々に真空にかけた。溶融物を、290℃、0.5torrの設定点において260分間保持して、実施例168を得た。
上記と同じように製造したポリエステルアミド組成物を用いて中間膜シートを製造した。中間膜シートは、種々の組成のポリエステルアミドペレットをプレス又は圧縮成形することによって製造した。ポリエステルアミドシートを形成するために、非粘着性フィルムをステンレス鋼板上に配置した。所望の厚さの正方形のアルミニウムシムを、鋼板の中心のフィルム上に配置した。次に、ポリマーペレットを、アルミニウムシムの中心の非粘着性フィルムの上に、全てのペレットが接触するように配置した。ペレットの上に第2の非粘着性フィルムを配置し、フィルムの上に第2のステンレス鋼板を配置した。
スキン又は外側層として低いTg(66℃)を有するポリエステルアミド材料、及び内側層又はコア層として高Tg(約150℃)のポリエステルアミド、商業的に入手できるポリエステル、又はプラスチック材料、或いは内側層又はコア層として可塑化セルロースエステル(16%の3GEH可塑剤を有するEastman CAP)を使用して多層(3層)中間膜を作成した。使用した低Tgのポリエステルアミド組成物は、100(DDA)53(CHDM)47(MACM)0.25(TMP)であり、使用した高Tgのポリエステルアミド組成物は、60(DDA)40(1,3−CHDA)20(TMCD)80(MACM)であった。中間膜を上記記載と同じように積層してガラス積層体を形成した。積層後、積層体を、色(YI)、曇り度%、圧縮剪断、及び破壊高さに関して試験した。データを下表24に示す。
Claims (20)
- ポリエステルアミド組成物を含む層を含む中間膜であって、前記ポリエステルアミド組成物は、
(a)脂環式ジアミン、脂肪族ジアミン、又はこれらの組み合わせから誘導されるジアミン残基0.1〜99モル%を含むジアミン成分;
(b)脂環式ジオール、複数の脂環式ジオールの混合物、又は少なくとも1種類の脂環式ジオールと少なくとも1種類の脂肪族ジオールとの混合物である少なくとも1種類のジオールから誘導されるジオール残基0.1〜99モル%を含むジオール成分;及び
(c)HO2C−(C2−40)アルキレン−CO2H、又はHO2C−(C3−10)シクロアルキル−CO2H(式中、それぞれのシクロアルキルは非置換であるか又は(C1−3)アルキルによって置換されている)から選択される二酸から誘導される二酸残基0.1〜100モル%を含む二酸成分;
を含み;
前記二酸成分の総モル%は100モル%であり、ジオール及びジアミン成分の合計の総モル%は100モル%である上記中間膜。 - 前記中間膜が、(ASTM−D1003−61(1977年再確認)−手順Bにしたがい、光源Cを使用して、0.76ミリメートルの厚さを有する中間膜について2度の観察角度で測定して)3.0%未満の曇り度を有する、請求項1に記載の中間膜。
- 前記ジアミンが20〜75モル%の量で存在し、前記ジアミンが、4,4’−メチレンビス(2−メチルシクロヘキシルアミン)、4,4’−メチレンビス(シクロヘキシルアミン)、3(4),8(9)−ビス(アミノメチル)トリシクロ[5.2.1.02,6]デカン、N−メチルジエタノールアミン、2,4,4−トリメチルヘキサンジアミンと2,2,4−トリメチルヘキサンジアミンとの混合物、1,3−ビス(アミノメチル)シクロヘキサン、又はこれらの混合物から選択される、請求項1に記載の中間膜。
- 前記ジアミンが40〜60モル%の量で存在する、請求項1〜3のいずれかに記載の中間膜。
- 前記ジアミン成分が少なくとも2種類のジアミンを含む、請求項1〜4のいずれかに記載の中間膜。
- 前記ジオールが、2,2,4,4−テトラメチルシクロブタン−1,3−ジオール、1,3−シクロヘキサンジメタノール、1,4−シクロヘキサンジメタノール、1,4−ブタンジオール、1,6−ヘキサンジオール、又はポリテトラヒドロフランジオールから選択される、請求項1〜5のいずれかに記載の中間膜。
- 前記ジオール成分が少なくとも2種類のジオールを含む、請求項1〜6のいずれかに記載の中間膜。
- 前記二酸が、コハク酸、グルタル酸、アジピン酸、ヘプタン二酸、オクタン二酸、ノナン二酸、デカン二酸、ウンデカン二酸、ドデカン二酸、トリデカン二酸、ヘキサデカン二酸、オクタデカン二酸、エイコサン二酸、9−[(Z)−ノン−3−エニル]−10−オクチルノナデカン二酸、9−ノニル−10−オクチルノナデカン二酸、シクロブタン−1,3−ジカルボン酸、シクロペンタン−1,3−ジカルボン酸、シクロヘキサン−1,4−ジカルボン酸、シクロヘキサン−1,3−ジカルボン酸、シクロヘプタン−1,4−ジカルボン酸、シクロオクタン−1,5−ジカルボン酸、又はシクロオクタン−1,4−ジカルボン酸、或いはこれらの2以上の二酸の組み合わせから選択される、請求項1〜7のいずれかに記載の中間膜。
- 前記ポリエステルアミドが、トリメリット酸、トリメチロールプロパン、トリメチロールエタン、グリセロール、ペンタエリトリトール、クエン酸、酒石酸、3−ヒドロキシグルタル酸、グリセリンエリトリトール、トレイトール、ジペンタエリトリトール、ソルビトール、無水トリメリット酸、ピロメリット酸二無水物、トリメシン酸、又はジメチロールプロピオン酸から選択される化合物から誘導される分岐剤を更に含み、前記分岐剤は前記ポリエステルアミドの総重量%を基準として約0.01〜約10重量%存在する、請求項1〜8のいずれかに記載の中間膜。
- 前記ポリエステルアミドがシラン添加剤を含む、請求項1〜9のいずれかに記載の中間膜。
- 前記ポリエステルアミドが、ASTM−D2857−70にしたがって求めて少なくとも約0.7dL/gのインヘレント粘度を有する、請求項1〜10のいずれかに記載の中間膜。
- 前記中間膜が、DMTAにしたがって求めて少なくとも−35℃のガラス転移温度を有する、請求項1〜11のいずれかに記載の中間膜。
- 前記中間膜がモノリス型中間膜である、請求項1〜12のいずれかに記載の中間膜。
- 前記中間膜をそれぞれ3mmの厚さを有するガラスの2枚のシートの間に積層して積層体を形成した場合に、前記積層体が、ANSI/SAE−Z26.1−1996にしたがって70°Fの温度及び30ミルの中間膜厚さにおいて測定して少なくとも12フィートの平均破壊高さを有する、請求項1〜13のいずれかに記載の中間膜。
- 前記中間膜が、(ASTM−D1003−61(1977年再確認)−手順Bにしたがい、光源Cを使用して、0.76ミリメートルの厚さを有する中間膜について2度の観察角度で測定して)2.0%未満の曇り度を有する、請求項1〜14のいずれかに記載の中間膜。
- 前記中間膜が、DMTAにしたがって求めて少なくとも40℃のガラス転移温度を有する、請求項1〜15のいずれかに記載の中間膜。
- 前記中間膜が、ASTM−D4065−12にしたがって50℃において測定して少なくとも10MPaの剪断貯蔵弾性率を有する、請求項1〜16のいずれかに記載の中間膜。
- 前記中間膜が、ASTM−D4065−12にしたがって80℃において測定して少なくとも2MPaの剪断貯蔵弾性率を有する、請求項1〜17のいずれかに記載の中間膜。
- 前記中間膜をそれぞれ3mmの厚さを有するガラスの2枚のシートの間に積層して積層体を形成した場合に、前記積層体が、ANSI/SAE−Z26.1−1996にしたがって70°Fの温度及び30ミルの中間膜厚さにおいて測定して少なくとも18フィートの平均破壊高さを有する、請求項1〜18のいずれかに記載の中間膜。
- 第1の基材、請求項1〜19のいずれかに記載の中間膜、及び第2の基材を含み、前記中間膜は前記第1の基材と前記第2の基材との間である多層パネル。
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EP3743475A1 (en) | 2018-01-23 | 2020-12-02 | Eastman Chemical Company | Novel polyesteramides, processes for the preparation thereof, and polyesteramide compositions |
EP3795611A1 (en) * | 2019-09-23 | 2021-03-24 | Solvay Specialty Polymers USA, LLC. | Polyamides and corresponding polymer compositions and articles |
CN111363144B (zh) * | 2020-04-30 | 2021-02-26 | 成都肆零壹科技有限公司 | 一种聚酯酰胺的聚合工艺 |
CN112322249B (zh) * | 2020-11-11 | 2022-04-01 | 温州华特热熔胶股份有限公司 | 一种聚酯酰胺硅烷增强热熔胶及其制备方法 |
CN112920403B (zh) * | 2021-01-26 | 2022-03-11 | 安徽农业大学 | 可再加工的热固性聚酯酰胺的制备方法、制得的热固性聚酯酰胺 |
KR20220151878A (ko) * | 2021-05-07 | 2022-11-15 | 에스케이케미칼 주식회사 | 폴리에스테르아미드 수지, 이의 제조 방법, 및 이를 포함하는 이축 연신 필름 |
CN117794983A (zh) * | 2021-08-19 | 2024-03-29 | 首诺公司 | 高分子量聚酯酰胺 |
KR20230167944A (ko) * | 2022-06-03 | 2023-12-12 | 에스케이마이크로웍스 주식회사 | 도장 보호 필름 및 이의 제조방법 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60144330A (ja) * | 1983-12-12 | 1985-07-30 | イ−ストマン コダック カンパニ− | ポリ(エステル‐アミド)組成物 |
JPS60184581A (ja) * | 1984-02-27 | 1985-09-20 | ユニオン・キヤンプ・コ−ポレイシヨン | ポリエステルアミドホツトメルト接着剤 |
JPS62158775A (ja) * | 1985-12-31 | 1987-07-14 | ユニオン・キヤンプ・コ−ポレイシヨン | 新規のポリ(エステル−アミド)系ホツトメルト接着剤 |
JPH069760A (ja) * | 1992-03-16 | 1994-01-18 | Bayer Ag | 包装材料として使用する堆肥化し得る熱可塑性ブロツクコポリエステル |
JP2009030053A (ja) * | 2007-07-25 | 2009-02-12 | Ems-Patent Ag | ホトクロミック成形組成物及びそれから製造される物品 |
JP2010031099A (ja) * | 2008-07-28 | 2010-02-12 | Fuji Kasei Kogyo Co Ltd | ポリエステルアミド樹脂組成物 |
JP2010534256A (ja) * | 2007-07-25 | 2010-11-04 | エーエムエス−パテント アクチェンゲゼルシャフト | 透明なポリアミドエラストマー |
Family Cites Families (98)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA816767A (en) | 1969-07-01 | U. Elam Edward | Linear polyesters and polyester-amides from 2,2,4,4-tetraalkyl-1,3-cyclobutanediols | |
US2071250A (en) | 1931-07-03 | 1937-02-16 | Du Pont | Linear condensation polymers |
US2191367A (en) | 1937-02-15 | 1940-02-20 | E I Du Point De Nemours & Comp | Laminated product |
US2282026A (en) | 1939-04-29 | 1942-05-05 | Du Pont | Treatment of polyvinyl acetal resins |
US2282057A (en) | 1939-04-29 | 1942-05-05 | Du Pont | Purification and stabilization of polyvinyl acetal resins |
US2281415A (en) | 1939-11-07 | 1942-04-28 | Du Pont | Polyester amides |
US2475034A (en) * | 1944-11-07 | 1949-07-05 | California Flaxseed Products C | Polyamide-ester composition |
GB621977A (en) | 1946-12-16 | 1949-04-25 | James Gordon Napier Drewitt | Improvements in the production of poly-ester-amides |
BE592181A (ja) * | 1955-12-22 | |||
BE592180A (ja) | 1956-10-24 | |||
GB1146539A (en) * | 1966-09-21 | 1969-03-26 | Ici Ltd | Laminated glass |
US4013624A (en) * | 1972-03-20 | 1977-03-22 | E. I. Du Pont De Nemours And Company | Branched thermoplastic copolyesters |
DE2542467C2 (de) * | 1975-09-24 | 1983-05-05 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur Herstellung thermoplastisch verarbeitbarer, farbloser bzw. praktisch farbloser Polyesteramide |
DE4107381A1 (de) | 1991-03-08 | 1992-09-10 | Schering Ag | Polyamide und polyesteramide auf basis von trimerisierten fettsaeuren, verfahren zu ihrer herstellung und ihre verwendung als schmelzklebstoffe |
DE4327024A1 (de) * | 1993-08-12 | 1995-02-16 | Bayer Ag | Thermoplastisch verarbeitbare und biologisch abbaubare aliphatische Polyesteramide |
IL110514A0 (en) | 1993-10-04 | 1994-10-21 | Eastman Chem Co | Concentrates for improving polyester compositions and a method for preparing such compositions |
JP3452563B2 (ja) | 1993-10-22 | 2003-09-29 | 積水化学工業株式会社 | ポリエステルアミドの製造方法 |
JP3527736B2 (ja) | 1993-10-22 | 2004-05-17 | 積水化学工業株式会社 | ポリエステルアミドの製造方法 |
JP3705615B2 (ja) * | 1994-07-26 | 2005-10-12 | 横浜ゴム株式会社 | ウレタンオキサゾリジン |
DE19500757A1 (de) | 1995-01-13 | 1996-07-18 | Basf Ag | Biologisch abbaubare Polymere, Verfahren zu deren Herstellung sowie deren Verwendung zur Herstellung bioabbaubarer Formkörper |
JPH08283408A (ja) * | 1995-04-07 | 1996-10-29 | Sekisui Chem Co Ltd | ポリエステルアミドの製造方法 |
US5672676A (en) * | 1995-08-21 | 1997-09-30 | Eastman Chemical Company | Polyesteramides with high heat deflection temperatures |
US5696176A (en) | 1995-09-22 | 1997-12-09 | Eastman Chemical Company | Foamable polyester compositions having a low level of unreacted branching agent |
TW336248B (en) * | 1996-02-05 | 1998-07-11 | Eastman Kodak Co | Polyester/polyesteramide blends the invention relates to polyester/polyesteramide blends |
JPH09316232A (ja) * | 1996-03-29 | 1997-12-09 | Sekisui Chem Co Ltd | 樹脂組成物 |
NL1003459C2 (nl) | 1996-06-28 | 1998-01-07 | Univ Twente | Copoly(ester-amides) en copoly(ester-urethanen). |
AU1339699A (en) | 1997-12-03 | 1999-06-16 | Bayer Aktiengesellschaft | Polyether ester amides |
DE19800698A1 (de) | 1998-01-10 | 1999-07-15 | Bayer Ag | Biologisch abbaubare Polyesteramide mit blockartig aufgebauten Polyester- und Polyamid-Segmenten |
US5939519A (en) | 1998-05-11 | 1999-08-17 | General Electric Co. | Polyesteramides of high crystallinity and reagents for their preparation |
BR0008669A (pt) * | 1999-03-03 | 2002-02-05 | Eastman Chem Co | Processo para a produção de uma mistura de um primeiro polìmero/polìmero do tipo amida, produto, e, mistura de um primeiro polìmero/polìmero do tipo amida |
JP2001131524A (ja) | 1999-11-02 | 2001-05-15 | Nitto Denko Corp | 粘着剤組成物とその粘着シ―ト類 |
JP2001234138A (ja) * | 1999-12-15 | 2001-08-28 | C I Kasei Co Ltd | 透明生分解性粘着フイルム |
EP1193296B1 (en) | 2000-09-29 | 2004-11-24 | Mitsubishi Gas Chemical Company, Inc. | Process for producing polyamide |
WO2002028941A2 (en) | 2000-09-30 | 2002-04-11 | E.I. Du Pont De Nemours And Company | Single-phase or multi-phase continuous polyamide polymerization processes |
JP4774596B2 (ja) | 2001-01-18 | 2011-09-14 | 三菱瓦斯化学株式会社 | ポリアミドの製造方法 |
GB0111794D0 (en) | 2001-05-15 | 2001-07-04 | Ici Plc | Polyamide copolymer |
JP2003200545A (ja) | 2001-10-23 | 2003-07-15 | Toray Ind Inc | 積層フィルムおよびその製造方法 |
EP1418193B1 (en) | 2002-11-07 | 2013-12-18 | Mitsubishi Gas Chemical Company, Inc. | Production method of polyamides |
EP1424362A1 (en) * | 2002-11-27 | 2004-06-02 | DSM IP Assets B.V. | Process for preparing a composition |
WO2005102694A1 (ja) | 2004-04-27 | 2005-11-03 | Ube Industries, Ltd. | 積層構造体 |
US20060287485A1 (en) | 2005-06-17 | 2006-12-21 | Crawford Emmett D | Sound barriers comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol |
EP1864796B1 (en) | 2005-03-31 | 2010-08-11 | Kuraray Co., Ltd. | Multilayer structure |
WO2007099397A2 (en) | 2005-06-16 | 2007-09-07 | Dow Global Technologies Inc. | Aliphatic polyester-amide compositions and a process for producing the same |
US20070003746A1 (en) * | 2005-06-30 | 2007-01-04 | Solutia, Inc. | Polymer interlayers comprising poly(cyclohexanedimethylene terephthalate-co-ethylene terephthalate) copolyester |
WO2007030791A1 (en) | 2005-09-08 | 2007-03-15 | Dow Global Technologies Inc. | Polyester-amide based hot melt adhesives |
DE502006001441D1 (de) * | 2006-01-27 | 2008-10-09 | Ems Chemie Ag | Photochrome Formmassen und daraus hergestellte Gegenstände |
US8450447B2 (en) | 2007-03-14 | 2013-05-28 | Dow Global Technologies Llc | Copolyesteramides with decreased perfection of the amide sequence |
US9150763B2 (en) | 2007-03-14 | 2015-10-06 | Dow Global Technologies Llc | Adhesive polymers for forming laminate structures |
WO2009024836A1 (en) * | 2007-08-22 | 2009-02-26 | Kimberly-Clark Worldwide, Inc. | Multicomponent biodegradable filaments and nonwoven webs formed therefrom |
KR20100115796A (ko) | 2008-03-12 | 2010-10-28 | 아사히 가세이 케미칼즈 가부시키가이샤 | 폴리아미드, 폴리아미드 조성물 및 폴리아미드의 제조 방법 |
CN101585915B (zh) | 2008-05-23 | 2011-04-20 | 北京化工大学 | 扩链制备可生物降解聚酯酰胺的方法 |
US20110135899A1 (en) | 2008-08-06 | 2011-06-09 | Lubrizol Advanced Materials, Inc. | Films And Articles Made With Thermoplastic Block Copolymers |
EP2202260B1 (de) | 2008-12-23 | 2012-12-12 | Ems-Patent Ag | Inhärent stabilisiertes Polyamid-Elastomer sowie Verfahren zu dessen Herstellung |
US9029461B2 (en) * | 2009-02-06 | 2015-05-12 | Eastman Chemical Company | Aliphatic polyester coating compositions containing tetramethyl cyclobutanediol |
US8168721B2 (en) * | 2009-02-06 | 2012-05-01 | Eastman Chemical Company | Coating compositions containing tetramethyl cyclobutanediol |
JP5221423B2 (ja) | 2009-03-11 | 2013-06-26 | 株式会社クラレ | ポリアミド組成物の製造方法、ポリアミド組成物およびポリアミド組成物からなる成形品 |
KR101723254B1 (ko) | 2009-09-08 | 2017-04-04 | 도요보 가부시키가이샤 | 유리/수지 적층체 및 그것을 사용한 전자 디바이스 |
CN102234373A (zh) | 2010-04-30 | 2011-11-09 | 北京化工大学 | 扩链制备可生物降解聚酯酰胺的方法 |
KR101302390B1 (ko) | 2010-07-27 | 2013-09-02 | 미쯔비시 가스 케미칼 컴파니, 인코포레이티드 | 폴리아미드 수지 |
CN102079814B (zh) | 2010-12-21 | 2012-05-30 | 北京化工大学 | 含短聚酰胺段的脂肪族聚酯酰胺的制备方法 |
KR101821310B1 (ko) | 2010-12-27 | 2018-01-23 | 미쯔비시 가스 케미칼 컴파니, 인코포레이티드 | 폴리아미드 조성물 |
CN102643422A (zh) | 2011-02-21 | 2012-08-22 | 北京化工大学 | 可生物降解脂肪族交替聚酯酰胺的制备方法 |
US9127126B2 (en) | 2012-04-30 | 2015-09-08 | Brewer Science Inc. | Development of high-viscosity bonding layer through in-situ polymer chain extension |
EP2871201A4 (en) | 2012-07-09 | 2015-06-24 | Asahi Kasei Chemicals Corp | POLYAMIDE, POLYAMIDE COMPOSITION, AND MOLDED ARTICLE |
EP2902373B1 (en) | 2012-09-28 | 2020-10-21 | Sekisui Chemical Co., Ltd. | Intermediate film for laminated glass, and laminated glass |
US8946351B2 (en) * | 2012-11-19 | 2015-02-03 | King Saud University | Environmental friendly poly(ether-fattyamide) resin composition |
CN103881086A (zh) | 2012-12-22 | 2014-06-25 | 北京化工大学 | 可生物降解交替聚酯酰胺的制备方法 |
KR101570561B1 (ko) | 2012-12-28 | 2015-11-19 | 제일모직주식회사 | 결정성 폴리아미드에스테르 수지, 이의 제조방법 및 이를 포함하는 제품 |
JP6311699B2 (ja) | 2013-03-14 | 2018-04-18 | 三菱瓦斯化学株式会社 | ポリアミド樹脂の製造方法 |
WO2015005201A1 (ja) | 2013-07-10 | 2015-01-15 | 三菱瓦斯化学株式会社 | ポリアミド樹脂の製造方法 |
WO2015030206A1 (ja) | 2013-08-30 | 2015-03-05 | 積水化学工業株式会社 | 合わせガラス用中間膜及び合わせガラス |
WO2015129100A1 (ja) | 2014-02-25 | 2015-09-03 | 住友電気工業株式会社 | 透明ポリアミド樹脂組成物、透明ポリアミド樹脂架橋成形体 |
EP3000837B1 (en) | 2014-09-23 | 2017-06-07 | Lotte Advanced Materials Co., Ltd. | Polyamide ester resin, method for preparing the same, and molded article including the same |
EP3202737B1 (en) | 2014-09-29 | 2020-12-09 | Sekisui Chemical Co., Ltd. | Interlayer film for laminated glass, and laminated glass |
KR102469393B1 (ko) | 2014-11-10 | 2022-11-22 | 쿠라라이 유럽 게엠베하 | 합판 유리용 중간막 및 합판 유리 |
KR102405014B1 (ko) | 2014-12-26 | 2022-06-07 | 미쯔비시 가스 케미칼 컴파니, 인코포레이티드 | 열가소성 수지 조성물 및 이를 포함하는 성형체 |
WO2016195042A1 (ja) | 2015-06-05 | 2016-12-08 | 旭硝子株式会社 | 積層体 |
CN106554618A (zh) * | 2015-09-24 | 2017-04-05 | 捷恩智株式会社 | 热硬化性组合物及其用途 |
EP3385074B1 (en) | 2015-11-30 | 2021-03-24 | Mitsubishi Gas Chemical Company, Inc. | Multi-layer structure |
US11130859B2 (en) | 2015-12-01 | 2021-09-28 | Mitsubishi Gas Chemical Company, Inc. | Polyester-based resin composition and production process therefor, molded object and production process therefor, and masterbatch |
JP6806095B2 (ja) | 2016-02-02 | 2021-01-06 | 三菱瓦斯化学株式会社 | ポリアミド樹脂、成形品、ポリアミド樹脂の製造方法 |
US20190224902A1 (en) | 2016-09-14 | 2019-07-25 | Basf Se | Method for producing a polymer film |
US20190194392A1 (en) | 2016-09-14 | 2019-06-27 | Basf Se | Polymer film comprising a co-polyamide of at least one diamine, a dicarboxylic acid and a dimer acid |
BR112019004928B1 (pt) | 2016-09-14 | 2022-12-13 | Basf Se | Filme de polímero (p), processo para a produção de um filme de polímero (p) e uso de um filme de polímero (p) |
EP3540008B1 (en) | 2016-11-09 | 2023-07-26 | Mitsubishi Chemical Corporation | Resin composition and multilayered structure using same |
CN110114415B (zh) | 2016-12-22 | 2021-09-28 | 三菱瓦斯化学株式会社 | 聚酰胺树脂组合物、成形品及聚酰胺树脂粒料的制造方法 |
WO2018143443A1 (ja) | 2017-02-03 | 2018-08-09 | 積水化学工業株式会社 | 合わせガラス用中間膜及び合わせガラス |
WO2018181995A1 (ja) | 2017-03-30 | 2018-10-04 | 旭化成株式会社 | ポリアミド組成物及び成形品 |
CN106967214B (zh) | 2017-05-10 | 2019-07-12 | 株洲时代新材料科技股份有限公司 | 一种聚酯酰胺弹性体及其制备方法 |
RU2019142121A (ru) | 2017-05-19 | 2021-06-21 | Секисуй Кемикал Ко., Лтд. | Промежуточная пленка для ламинированного стекла и многослойное стекло |
JP7308818B2 (ja) | 2017-09-28 | 2023-07-14 | デュポン ポリマーズ インコーポレイテッド | 重合方法 |
EP3743475A1 (en) | 2018-01-23 | 2020-12-02 | Eastman Chemical Company | Novel polyesteramides, processes for the preparation thereof, and polyesteramide compositions |
WO2019147676A1 (en) | 2018-01-23 | 2019-08-01 | Solutia Inc. | Interlayers comprising polyesteramide compositions |
WO2019146423A1 (ja) | 2018-01-25 | 2019-08-01 | 富士フイルム株式会社 | 投映像表示用部材、ウインドシールドガラスおよびヘッドアップディスプレイシステム |
CN111655649B (zh) | 2018-02-02 | 2023-02-17 | 积水化学工业株式会社 | 夹层玻璃用中间膜、卷体以及夹层玻璃 |
JPWO2019151327A1 (ja) | 2018-02-02 | 2020-12-03 | 積水化学工業株式会社 | 合わせガラス用中間膜及び合わせガラス |
MX2020007936A (es) | 2018-02-02 | 2020-09-03 | Sekisui Chemical Co Ltd | Pelicula intermedia para vidrio laminado y vidrio laminado. |
CN111867835A (zh) | 2018-03-13 | 2020-10-30 | 巴斯夫欧洲公司 | 包含二胺、二聚酸和内酰胺的共聚酰胺的层压多层含聚合物膜 |
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Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60144330A (ja) * | 1983-12-12 | 1985-07-30 | イ−ストマン コダック カンパニ− | ポリ(エステル‐アミド)組成物 |
JPS60184581A (ja) * | 1984-02-27 | 1985-09-20 | ユニオン・キヤンプ・コ−ポレイシヨン | ポリエステルアミドホツトメルト接着剤 |
JPS62158775A (ja) * | 1985-12-31 | 1987-07-14 | ユニオン・キヤンプ・コ−ポレイシヨン | 新規のポリ(エステル−アミド)系ホツトメルト接着剤 |
JPH069760A (ja) * | 1992-03-16 | 1994-01-18 | Bayer Ag | 包装材料として使用する堆肥化し得る熱可塑性ブロツクコポリエステル |
JP2009030053A (ja) * | 2007-07-25 | 2009-02-12 | Ems-Patent Ag | ホトクロミック成形組成物及びそれから製造される物品 |
JP2010534256A (ja) * | 2007-07-25 | 2010-11-04 | エーエムエス−パテント アクチェンゲゼルシャフト | 透明なポリアミドエラストマー |
JP2010031099A (ja) * | 2008-07-28 | 2010-02-12 | Fuji Kasei Kogyo Co Ltd | ポリエステルアミド樹脂組成物 |
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EP3743476A1 (en) | 2020-12-02 |
WO2019147457A2 (en) | 2019-08-01 |
CN111630122A (zh) | 2020-09-04 |
US11578207B2 (en) | 2023-02-14 |
JP7295119B2 (ja) | 2023-06-20 |
US20220119639A1 (en) | 2022-04-21 |
JP2021511231A (ja) | 2021-05-06 |
US11767429B2 (en) | 2023-09-26 |
US20210095073A1 (en) | 2021-04-01 |
CN111630122B (zh) | 2023-07-28 |
US11845864B2 (en) | 2023-12-19 |
US20200362114A1 (en) | 2020-11-19 |
MX2020007159A (es) | 2020-09-09 |
EP3743478A1 (en) | 2020-12-02 |
EP3743475A1 (en) | 2020-12-02 |
CN111655806A (zh) | 2020-09-11 |
US20200354571A1 (en) | 2020-11-12 |
WO2019147457A3 (en) | 2019-12-26 |
WO2019147671A1 (en) | 2019-08-01 |
KR20200110382A (ko) | 2020-09-23 |
CN111655807B (zh) | 2022-07-12 |
JP7274489B2 (ja) | 2023-05-16 |
CN111655806B (zh) | 2023-12-05 |
EP3743477A2 (en) | 2020-12-02 |
US20210094264A1 (en) | 2021-04-01 |
CN111684032A (zh) | 2020-09-18 |
CN111684032B (zh) | 2022-07-12 |
US11242456B2 (en) | 2022-02-08 |
KR20200110383A (ko) | 2020-09-23 |
CN111655807A (zh) | 2020-09-11 |
WO2019147458A1 (en) | 2019-08-01 |
MX2020007741A (es) | 2020-09-25 |
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